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One of the main bottlenecks in the carbon-in pulp process for the recovery qf gold is the elution procedure, which typically requires the heading of caustic cyanide eluants to high temperatures for 16 to 24 hours. The present work demonstrates that sodium sulphide solution as an alternative eluant can effect complete elution in about 4 hours at ambient temperatures. Elution efficiencies of around 100 per cent were obtained in 4 hours with a single pass of eluant containing 0,2 M Na2S and 0,4 NaOH about 10 bed-volumes of eluant The initial rate was slow over the first hour of elution, probably because the activated carbon catalysed the oxidation of sulphide to polysulphide. Elution efficiencies of around 100 per cent were also obtained in less than 4 hours during the batch elution of carbon at liquid-to-solid ratio of about 100. Lower liquid to solid ratio resulted in the re-adsorption of gold, probably owing to the oxidation of sulphide to polysulphide, with the resultant formation of gold complexes that were eluted less readily. Improved rates of elution were obtained at higher sulphide concentrations and pH values greater than about 13. Higher temperatures increased the initial elution rate, but lowered the overall extraction efficiency, probably because of the deposition of elemental gold on the carbon. Variation of the ionic strength by the addition of NaCl had no defect on the elution, which confirms that the elution mechanism in the case of sulphide is different from that when cyanide or I1)1droxide is used as the eluant. It is proposed that the elution of gold by sulphide solutions proceeds by means of an initial step that involves the reaction of polysulphide ions with the adsorbed aurocyanide speeds, forming AuCN on the carbon and thiocyanate in solution. This step is followed by the formation of poorly adsorbed complexes with sulphide ions, such as [AUS3-2]-The presence of polysulphides, whether generated in situ by the catalytic oxidation effect of activated carbon or by the addition of elemental sulphur, reduces the elution rate and efficiency dramatically. This is probably due to the formation of complexes such as AUS-3 and AUS-2 , which have a high adsorption affinity.

Jan 1, 1994

By J. P. Coetzee

Dr. K. Gebhard In his excellent and comprehensive survey on the future development of the Iron and Steel Industry in South Africa, Mr. Coetzee has also mentioned the direct reduction processes as a possible method of converting iron ore to iron. Mr. Coetzee has made it quite clear that at this stage one should not consider these processes as a 'magic formula' which herald a 'break through'. I agree entirely with this point of view. Once upon a time I held the opposite view, but in the meantime I have revised my views. To do so, I had 40 years at my disposal. In 1930 I had the privilege of being connected with the first commercial sponge iron plant in Germany1 - a plant which was capable of producing 40 tons of sponge iron a day. We were determined to prove that the blast furnace would become obsolete in the near future. We considered it as an unnecessary detour to convert iron ore first into an iron-carbon alloy, which contained further quite a number of undesirable elements, and to remove this carbon by an endothermic process. Direct iron-making seemed to be a logical short cut. Unfortunately, we were not able to establish this 'short cut,', but the life of our sponge iron plant was cut short. We had solved all technical but not the economic problems. Basically the positon is still the same today - mainly economic and to a lesser degree technological aspects determine the rate at which sponge iron plants are installed. More has been said and written than done about direct reduction plants. I think that there are two main reasons for this stagnation in the introduction of direct reduction processes. The first reason is that modern blast furnaces are just too good and too economic ever to be replaced by direct reduction processes on a large scale. This, of course, already limits the field of application for direct reduction plants. The second reason is that sponge iron production and utilisation is based on technical considerations, which increase not only the production cost of sponge iron but also the conversion cost to steel to such an extent that under special conditions only are direct reduction plants an economic proposition. Are these technical considerations still as forceful and valid today as they were when 'direct steelmaking' was first contemplated? The development of sponge iron production as a method of direct

Jan 3, 1971

By M. Helm

Over the last 40 years, numerous investigations have focussed on the preg-robbing capacity of carbonaceous material during gold ore processing. Various techniques have been applied to characterize the physical and chemical properties of the carbonaceous material in efforts to predict its preg-robbing capacity. The present study, which forms part of an ongoing investigation, is specifically designed to increase the understanding of preg-robbing in ores containing carbonaceous material. In excess of 100 samples from 13 gold mines located in major gold provinces of the world have been incorporated into the present study. These samples were characterized using industry standard metallurgical techniques and were shown to have gold adsorption capacities ranging from a few grams to many hundreds of grams of gold per ton of ore. Further analysis showed that the crystalline nature of the carbonaceous material, which is related to its geological history, is important in determining the preg-robbing capacity of an ore. This finding builds on the common understanding that the preg-robbing behaviour of an ore is related to the amount (or abundance) of carbonaceous material present in that ore. In this study, Raman spectroscopy was used to evaluate the physical nature of carbonaceous material. This is a tool which has been successfully applied by researchers for the characterisation of carbon materials, with respect to crystallite size and lattice defects. Raman analysis of the samples included in this study showed varying degrees of disorder in the carbonaceous materials from the different deposits. Comparison of the Raman spectra with the gold loading capacities of the samples indicated a direct relationship between the structure of the carbonaceous material and its capacity to preg-rob gold. From this, a simple and robust method has been developed based on the Raman spectra of the sample and carbonaceous material content to predict the preg-robbing capacity of an ore. The potential exists to develop a predictive tool using Raman spectroscopy for characterising the preg-robbing capacity of an ore. Such a tool would have potential application in projects ranging from the early stage of exploration through to more detailed feasibility studies and mining operations. The result of applying the predictive method outlined in this paper would be the effective and proactive management of the deleterious influence of carbonaceous material on gold recovery in mining operations.

Jan 1, 2009

By E. E. Almási, G. Mucsi, G. Rákhely, Á. Rácz, B. Csőke, Zs. Pap, K. Bohács, N. Halyag

Wet stirred media milling is a widely applied grinding process in the field of mineral processing to produce <10 μm ground materials. In this paper, the results of wet stirred media milling of different Ti, Fe and Cu-oxide and phosphate minerals are presented. During the experimental work, grinding of ilmenite, vivianite, hematite and cuprite was carried out in a continuous operation wet stirred media mill. During the experiments, the particle size distribution and specific surface area of the ground materials were determined after a certain grinding time, as well as measuring the specific grinding energy, thereby determining the grinding kinetics of the different minerals. The measurement results showed the differences and similarities in the grindability of the individual minerals. Nano particulate vivianite, hematite and ilmenite was successfully manufactured in a stirred media mill; however cuprite was characterised as the coarsest final product for the same grinding circumstances. Keywords: Wet stirred media mill, cuprite, vivianite, ilmenite, hematite

Jan 1, 2020

By M. Lange

The postulation that primary platinum group metal (PGM) matte will chemically react with magnesia-chrome bricks when temperatures exceed 1500°C was tested. Magnesia-chrome brick samples were heated in contact with matte at 1300°C to 1750°C for 30 minutes, after which the refractory samples were analysed using reflected light microscopy and scanning electron microscopy. The samples were all completely penetrated by matte. As the temperature increased the matte also penetrated the fused aggregate grains and disintegrated them. The chromium concentration of the matte inside the refractory samples was found to be slightly higher than that of the bulk matte. At temperatures of 1500°C and higher, MgO, FeO, and magnesium-rich silicate crystals could be identified in the matte directly adjacent to the refractorymatte interface. Phase relations clearly indicated that chemical reactions take place between primary PGM matte and the magnesiachrome refractory material at temperatures above 1500°C, but that these reactions are more complex than expected from FactSAGE® calculations.

Jan 1, 2014

By N. B. Strydom

The data on heat stroke cases reported during the past five years were examined to determine the influence of age on the incidence of heat stroke. Relating the age distribution of these cases to that of the total number of Bantu mine workers showed clearly that the older men run a significantly higher risk of developing heat stroke than the younger men. Although the number of Bantu over 40 years of age in the industry is less than 10 per cent of the total they nevertheless accounted for 50 per cent of the fatal heat stroke and 25 per cent of the nonfatal heat stroke cases during the period under review. Age must, therefore, be recognised as a causal factor in heat stroke and the worker over 40 years of age should be allocated to work on surface, or in cool areas or to non-strenuous and supervisory tasks in hot areas.

By A. L. Hinde, A. A. Bradley, K. H. Stanton, P. J. D. Lloyd, G. K. Schymura

As part of its programme to develop methods for concentrating minerals underground, the Chamber of Mines of South Africa in conjunction with Lurgi evolved and tested a I MW centrifugal mill. The machine is capable, in the autogenous mode, of grinding more than 25 t/h of minus 75 plus 44 mm hard quartzite to a minus 3 mm product containing over 50 per cent minus 75 µm material, and as a ball mill of grinding more than 60 t/h of minus 19 mm quartzite to a minus 3 mm product containing over 35 per cent minus 75 µm material. Extrapolation of computer models of the process suggests that these limits can be comfortably exceeded. Long-term continuous testing is in hand, aimed at proving that this I m in diameter by I m long mill is in every respect the equivalent of a conventional 4 m by 6 m ball mill.

Jan 1, 1982

By V. J. Moore

Introduction Although months have passed since APCOM 87, held from 19th to 23rd September, 1987, the vivid memories of all aspects of its activities remain as clear in one&apos;s mind as if it all happened only yesterday. The Symposium, which was held at the Johannesburg Sun Hotel, was organized by The South African Institute of Mining and Metallurgy in collaboration with the Council for Mineral Technology (Mintek), supported by The Geostatistical Association of South Africa, The Operations Research Society of South Africa, and the Computer Society of South Africa, and was backed financially by the Chamber of Mines of South Africa. The total number of registrants amounted to 375 delegates and 50 affiliates: 100 of the delegates were from outside the Republic of South Africa and represented 15 countries, namely Australia, Brazil, Canada, Chile, France, Great Britain, Greece, Italy, Namibia, Phillipines, Sweden, Turkey, United States of America, West Germany, and Zimbabwe.

Jan 1, 1988

By Y. Hwang, C Kang

To understand the effect of thermal loading from HLW on the groundwater flow nearby, the coupling of TH in an equivalent porous medium is studied. Results indicate that under given conditions the alteration of groundwater flow by decay heat is localized phenomena. More comprehensive studies are underway for THM coupling. Zum Verstandnis fur die Wirkung der thermischen Belastung von HLW in der Nahe von Grundwasserstrom, ist die Verbindung von TH in den entsprechenden porigen Medium erarbeitet. Die Ergebnisse zeigen, dass unter vorgegebenen Bedingungen die Anderung von Grundwasserstrom durch Zerfallwarme lokalisiert wird. Zusatzliche umfassende Arbeiten sind fur die THM Kupplung auf dem Wege. Pour comprendre l&apos;effet du chargement thermique de HLW sur l&apos;écoulement d&apos;eaux souterraines tout près, l&apos;accouplement du TH dans un milieu poreux équivalent est étudié. Les résultats indiquent que dans des conditions données le changement d&apos;écoulement d&apos;eaux souterraines par la chaleur d&apos;affaiblissement est des phénomènes localisés. Des études plus complètes sont en cours pour l&apos;accouplement de THM.

Jan 1, 2003

By M. J. Gouws, T. P. Knoetze

The spontaneous combustion of coal and the explosion of coal dust are two phenomena that were identified by the South African mining industry as requiring investigation. Research contracts were awarded to the G.P. Badenhorst Research Facility of the CSIR and the Department of Mining Engineering of the university of the Witwatersrand by the now defunct National Energy Council. Both projects entailed tests on numerous coal samples in specially designed apparatus. Since the completion of the project, attempts have been made to predict experimental results without incurring the cost of performing experiments. This paper describes predictive indices, based on routine laboratory tests, that were developed by the different research teams for their particular projects. A comparison of the results obtained by applying the spontaneous combustion liability index and the explosibility index to common coal samples indicates that, in general, propensity to spontaneous combustion and explosibility exhibit an inverse relationship. A brief overview is given of some major South African coal-mine disasters.

Jan 1, 1995

It is a great honour to officiate at the celebration of the centenary of the South African Institute of Mining and Metalurgy. Tonight&apos;s festivities bring back happy memories of my association with South Africa&apos;s mining industry during my tenure of office as Minister of Mineral and Energy Affairs. They also remind me of the illustrious personalities who have preceded me on this podium. The Pioneers They include Sir Percy Fitzpatrick, who spoke in 1909 on the eve of the Union, General Smuts, and, on many occasions during the 1920s and 1930, Jan H. Hofmeyr. The basic issues addressed by them continue to enjoy the Institute&apos;s attention today, namely the optimal and safe exploitation of our country&apos;s mineral resources and cost-effective extraction of minerals from their ores. Translated into the Institute&apos;s key objective it reads: To initiate and give effect to the means whereby the requirements for technology and scientific knowledge if the minerals and metals section if the South African economy is satisfied.

Jan 1, 1994

By J. C. Zachariades, D. M. Fraser

The leaching of pyrolusite in acidic ferous sulphate solution was studied so that the important factors governing the kinetics of the reaction could be determined. The reaction is very rapid, and was monitored by continuous measurement and logging of the redox potential in solution by use of a microcomputer. The relationship between redox potential and manganese extraction was established empiricaly for each set of conditions by the use of a technique in which a calibration run was conducted in paralel with each leaching run. The study involved a number of batch leaching runs, and demonstrated that, of the variables investigated, only the initial ferous ion concentration and the reaction temperature afect the rate of manganese extraction. The final extraction did not vary. The reaction was modeled from the results by use of the shrinking-core model and Britan&apos;s activation-energy model. The later was found to provide a significantly better fit to the data.

Jan 1, 1991

By J. Svoboda, W. J. C. Venter, R. N. Guest

SYNOPSIS Wet high-intensity magnetic separation was examined as a method for the recovery of copper and lead from Tsumeb flotation tailings. Bench-scale and pilot-plant tests were conducted and, despite the very low magnetic susceptibilities of all the complex copper and lead minerals, copper and lead recoveries of over 60 per cent and almost 50 per cent respectively were obtained at a combined copper and lead grade of up to 13,5 per cent. The recoveries were found to be practically independent of magnetic induction in the range 0,5 to 2,2 T, and the grade of the magnetic concentrate decreased with increasing magnetic induction. The grade of the magnetic concen¬trate improved when the flowrate of the slurry was increased, and desliming was found to have a profound effect on the. metallurgical process. Particles smaller than 10 µm were not recovered, and their presence in inefficiently deslimed samples impaired the overall performance of the magnetic separation

Jan 1, 1988

By A. M. Copeland, A. J. Barrett

The use of hydraulically placed backfill in the deep gold mines of South Africa has increased rapidly over the past decade. The backfill that is delivered to the placement areas has a relatively high moisture content, and it is therefore pumped into geotextile containment bags that allow excess water to drain out but retain solid particles. The specific problems associated with this process that are addressed in this paper include the loss of solid particles entrained in the excess water, the rate of strength gain of the backfill, and the post-placement shrinkage of the backfill. The results of laboratory, surface stope, and underground tests are described. The parameters that were varied included the slurry density, the particle-size distribution, and the feed rate of the slurry the concentration of added flocculant; and the type of geotextile used as containment. Suggestions are given for the optimization of the placement properties of backfill.

Jan 1, 1994

By J. R. de Wet

The behaviour of mild steel in aqueous cyanide solutions similar to caustic cyanide elution solutions was investigated at high temperature in electrochemical experiments. The anodic polarization diagrams of mild steel indicated that steel may undergo active dissolution under these conditions. The rare occurrence of gold plating in practice is the result of the limiting of the anodic dissolution of the steel by the presence of a passive layer on the steel. This passive layer is stable only in a certain potential range, and the free corrosion potential attained determines whether the steel will be passive or active. For conditions typical of elution columns, several corrosion potentials are possible, depending primarily on the initial condition of the steel and the concentration of oxygen in the solution. If these conditions result in the formation of a passive layer on the steel, changes in concentration and temperature will not necessarily result in plating since the layer may exist in a metastable form.

Jan 1, 1993

By J. H. Bulloch

The paper gives an assessment of the available data on the linear elastic fracture mechanics involved in stress corrosion cracking and in the behaviour of reactor pressure-vessel materials exposed to a simulated pressurized water-reactor environment. As a result of the different experimental techniques used in the various studies mentioned, only a few detailed conclusions can be drawn. The data from constant-displacement wedge-opening loading (WOL) tests, with the exception of one study, exhibited very limited or no crack extension during exposure periods of up to 14000 hours. The data from constant-load tests indicated evidence of crack extension, but the nature and extent of the crack extension are still unclear. When crack extension did occur, it was exclusively transgranular in nature. Certain differences in the available test data are tentatively explained in terms of the experimental procedures used, and the need for a consistent code of experimental techniques is highlighted.

Jan 1, 1987

By W. A. Lenhardt

During the past five years, several research projects on the causes of mining induced seismicity have been carried out by the Rockburst Research Department at Western Deep levels Limited. This paper summarizes the results of these investigations. Several types of mining-induced seismic events are addressed, and models of their mechanisms are presented. It is shown that most of the seismicity results from mining in geologically disturbed areas, and ways and means are discussed to reduce the seismic potential. Stabilizing pillars, for instance, have been introduced to reduce stresses at the stope face and to alleviate the facebursting problem. Facebursts still occur in areas of very low stresses, and pillars became the source of very large seismic events (M >3). At this stage, the understanding gained of pillar-associated events allows a review of current mining practices. Further, it makes possible an examination of the efficiency of measures to alleviate the effects of various seismically prone situations.

Jan 1, 1992

By R. M. Falcon

The paper opens with a summary of the major factors responsible for spontaneous combustion in coal discards. These include heat arising from the oxidation of coal and pyrite, and from the weting of dry or oxidized coal and pyrite; and certain petrographic conditions leading to self-ignition of the coal such as low rank, the presence of a high proportion of reactive constituents, and the occurence of highly porous and botanicaly structured inertinite macerals, The analyses of 6 samples from 2 discard dumps in the Witbank coalfield are included, which show that, according to a three-grade classification of liability to spontaneous combustion, one dump is &apos;reasonably liable&apos; and the other is &apos;most liable&apos;, It is pointed out that factors other than liability to self-ignition determine the possible utilization of such discards, and that the prevention of oxidation is of great importance if they are to be utilized and spontaneous combustion to be prevented,

Jan 1, 1986

By R. J. Dippenaar, J. C. van den Berg

This paper describes an investigation into the prereduction of hematite fines in a fluidized-bed reactor as a means by which they can be prepared for direct smelting in a transfered-arc plasma furnace. A single-stage fixed fluidized bed reactor using the in situ gasification of coal was employed. It is shown that the hematite is reduced to magnetite at 1000 QC, the degree of reduction being limited by the inherent shortcomings of a single-stage reactor in which both the gasification and the reduction reactions have to occur. Methods by which the degree of reduction can be increased are suggested. The gasification process was studied in some detail, and three different reducing agents are compared. The dominating effect of the Boudouard reaction on the behaviour of the fluidized bed is clearly illustrated. Non-coking coals of high reactivity are best suited to this process, a finding that would complement the trend away from coke as a metallurgical reducing agent.

Jan 1, 1989

By C. J. Fauconnier

The main purpose of the paper is to determine the contribution of fluctuations in barometric pressure to flammable gas explosions in South African mines. For this purpose, the barometric-pressure patterns preceding each of the 59 major explosions in South African gold and coal mines over the past 20 years were analysed. It is concluded that diurnal fluctuations in pressure do not have a major influence on the accumulation of gas in the underground workings, but that pressure drops associated with cyclonic weather systems moving across the country over a number of days are the major factor contributing to gas explosions in mines. To illustrate some of the points made in the paper, the Hlobane Colliery explosion of September 1983 is used as a case study. In the final section, several general conclusions are drawn and recommendations put forward as to how mines should recognize and react to meteorological phenomena that may lead to an increased probability of gas explosions in underground workings.

Jan 1, 1992