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By H. M. Krieg, M. J. Ungerer, C. G. C. E. van Sittert, D. J. van der Westhuizen

"The transition metals tantalum (Ta) and niobium (Nb) are of significant importance, for example in the nuclear energy sector where they are used as cladding materials, as well as in capacitors and specialized materials. For these applications a high-purity metal is needed. The separation of Ta and Nb is always a challenge since they are found together in nature and have similar chemical and physical properties, resulting in costly and laborious separation processes. A technology that has been used successfully for the separation of these metals entails solvent extraction (SX)1. While separation was achieved in a previous SX study using a sulphuric acid (H2SO4) medium with the extractants diiso-octyl phosphinic acid (PA) and di-(2-ethylhexyl) phosphoric acid (D2EHPA), due to the absence of speciation data for Ta and Nb it is not clear how the separation occurred.One method that might be suitable for determining the speciation of a reaction is molecular modelling. Calculations based on the densityfunctional theory (DFT) are now used not only for light elements and small molecules, but also metal complexes, heavy metals, and especially metal separation in SX2. In this study the aqueous phase used during SX was investigated by studying periodic systems of Ta, as a metal and in salt form, when it is in contact with H2O and H2SO4. The results were used to predict the reaction mechanism occurring during SX. Results showed that (i) in a 1:1 acid-water ratio, the deprotonation of H2SO4 was endothermic, (ii) in a 1:5 ratio deprotonation was exothermic forming HSO4 -, and (iii) in a 1:10 ratio double deprotonation occurred to form SO42- exothermically."

Jan 1, 2017

Toxic gases, mostly carbon monoxide (CO) and nitrous oxides (NOx), are invariably generated by commercial explosives under practical conditions of usage because of oxygen unbalance and non-ideal chemical reaction. Permitted explosives are statutorily required to meet the criteria stipulated by regulatory authority for their toxic fume quality for their safe use in underground coalmines. Solid blasting using P5 explosives contribute around 60% production from Indian underground coal mines. Low pull and yield per blast in solid blasting has been identified as a reason for low production and productivity of Indian underground coal mines. In an effort to improve performance of solid blasting, it was envisaged to apply air decking between suitable P5 explosives using high density polyethylene (HDPE) spacers under a Ministry of Coal, Government of India funded project. A non-deflagrating slurry explosive composition having high air gap sensitivity was specially developed for this purpose, so that air decked cartridges get detonated sympathetically with single priming. However, statutory authority in India apprehended that the use of oxygen negative HDPE spacers can influence the generation of toxic gases. The effect of using HDPE spacers on the generation of toxic gases was studied under simulated laboratory conditions with newly developed as well as with three commercial P5 explosives. The results of studies presented in this paper revealed that the level of carbon monoxide increases linearly and there is no significant effect on the level of oxides of nitrogen due to the use of HDPE spacers with selected explosives. Studies also revealed that this newly developed slurry explosive can be used for air decking up to 15 cm using HDPE spacers of weight not more than 21 g without exceeding the permissible limits for toxic gases.

Jan 1, 2008

By N. Coulson, P. Ledwaba

"The University of the Witwatersrand presents an accredited four-course training programme for community relations practitioners (CRPs). Between May 2013 and October 2014 six courses were facilitated for 145 participants, of whom 82% were from sub-Saharan Africa, 62% worked in mining, and 58% worked directly with communities. Thematic analysis of the comments of course participants collected during course exercises found that there were a set of coherent drivers for resilient companycommunity relationships, but that the restrainers to resilient relationships were often context-specific and dominated by politics. CRPs reported facing as many difficulties in the internal company environment as in the external environment. These findings for CRPs in Africa resonate with those worldwide.InroductionMuch has changed in how the extractive industry responds to social and community issues. There has been a growing prioritization of community-related issues within the extractive industry globally (Kemp, 2010; Tatar, n.d.). According to Kemp (2010) this can be attributed partly to escalating pressure from local-level stakeholders to push mining companies to take greater responsibility for the social, economic, and environmental impacts of mining. Securing and maintaining the social licence to operate is ranked fourth in terms of the top risks facing the mining and metals industry in 2016, up one place from 2015 (Ernst & Young, 2016).Conflicts between local communities and large-scale mining companies arise because of the social, environmental, and economic impacts of mining. Worldwide, large-scale mining companies have a poor reputation amongst communities, including those in Africa (Gilberthorpe and Banks, 2012; Kemp and Owen, 2013a; van Wyk, n.d.). For mining companies, conflicts for whatever reason, result in loss of productivity, lost opportunities, lost time, and adverse impacts on reputation (International Council on Mining and Metals, 2015). Conflicts also have a significant financial impact on mining operations (Franks et al., 2014). Davis and Franks (2014), estimated that US$10 000–50 000 is lost each day when a project is delayed during the exploration phase, and about US$20 million per week when in operation. Today these costs could be expected to be higher due to increasing input costs."

Jan 1, 2017

By C. Nangolo

Mineral commodity prices comprise one of the key criteria in the selection of mining stocks. We contend that of the three principal elements of mineral commodity prices, spot price, forward price and long-term price, one has a greater impact on the share valuation processes used by investors. This research paper examines the extent to which each of these elements influences the valuation process. The intention is to provide investors in mining stocks with a greater understanding of how fluctuations of commodity prices over time affect the prices of the mining stocks they hold, or intend to sell or buy. Three mineral commodities, gold, silver, and copper, were used as case studies, since market data on these commodities is readily available in the public domain. Nine market indices covering all three mineral commodities were selected. These are based on clearly defined criteria with the intention of eliminating ambiguity and to test for correlation with the three sets of mineral commodity prices. Nine mining companies, which were not the primary drivers of the relevant indices employed in the study, were used to validate the results obtained from the indices in order to avoid duplication of the same correlation during cross-checking. Each commodity price was adjusted for operating costs. For each market index, an average operating cost was calculated from the companies comprising its basket, while each company?s annual operating costs were used for the stocks of the individual companies examined. The data was collected for the period January 2004 to October 2010. This period was further split up into three sub-periods to account for the Global Financial Crisis (GFC) period that started in mid-2008. We conclude that mining stock prices are correlated with mineral commodity prices, but with spot and forward prices exhibiting stronger correlations than long-term price. This finding should be useful for evaluation purposes. Where cash flow methodologies such as discounted cash flow or earnings per share are used to value ordinary shares and commodity prices are required to estimate future cash flows, the findings suggest that spot prices should be used as opposed to long-term prices. The work reported in this paper is part of a current MSc research study at the University of the Witwatersrand.

Jan 1, 2011

By I. D. Wood

The geostatistical methods given for the estimation of low-ash coal reserves take into account the geological structure of the seam, and consequently give far more reliable results than have been obtained in the past. Confidence limits are given for all the estimates.

Jan 1, 1979

By J. Levin

Bond's Standard Work Index (SWi) indicates the grindability of an ore, and his Operating Work Index (OWI) indicates the performance of a grinding mil or circuit. The comparison of the two indices offers a measure of the efficiency of the grinding operation. Mil (or circuit) performance, particularly on the Witwatersrand, is often indicated by the index kilowatt -hours per tonne of minus 75 µm material produced (kWh/t minus 75µm or OE75)' The paper shows that a standard kWh/t minus 75 µm index (SE75) can be obtained from the standard Bond grindability test (which provides the SWi), and asks whether the two E75 indices can be used in the various ways in which the two Work Indices are used. For the answer, the paper presents averaged values for the standard grindability indices of the gold ores of the Witwatersrand, averaged values for the performance of grinding mils operating on those ores, and the results of laboratory grinding tests on a composite of several Witwatersrand ores. The particle-size indicator for the calculation of the Wi indices, the am size, is constant in its relation to the largest particles present, whereas the percentage minus 75 µm, the indicator of size for the E75 index, varies with the degree of grinding in its relation to the size of the largest particles. Because of this difference, the standard Work Index increases as the grind becomes finer, whereas the standard kWh/t minus 75 µ value decreases. The Wi and E75 indices nevertheless serve similar purposes when applied to moderately fine grinding-finer than 70 per cent minus 75 µm. Open circuit laboratory grinding tests revealed three stages in the grinding process, and credible values for the open circuit Work Index were obtained only from the second stage. The conversion of the open circuit Work Indices to the equivalent of close circuit indices by the application of Bonds open circuit inefficiency factor (a constant for grinds indicated by the d80 size) was of limited success; however, the development of a conversion factor related to particle-size should not be difficult. Initially difficulty was experienced in the calculation of the 0E75 indices from the results of the laboratory tests, but it was eventually considered that a constant value of the index derived from the results would be close to the true open-circuit index. The open-circuit grinding test could there fore be a convenient method for the detection of differences in the grindability of ores.

Jan 1, 1992

By R. W. O. Kersten

This paper describes the method used at Agnes Gold Mine in the calculation of pillar strengths, which involves a back-analysis type of approach. The results obtained there are comparable with those obtained by accepted formulae for pillar strength. It was found that a stress level of 70 MPa for the width of combined pillars (Le. crown and sill pillars) causes failure of the reef drives as well as the tops and bottoms of the stope side walls. As shrinkage stoping to depths of more than 650 m would result in very low percentage extractions, alternative methods of stoping will have to be investigated for these depths.

Jan 1, 1984

By Z. Zitron, G. J. de Korte, D. W. Horsfall

This paper summarizes work carried out on the treatment of fine coal, nominally classified as minus 0,5 mm (wedge-wire screen), which is removed from the raw coal prior to the treatment of the plus 0,5 mm sizes. The minus 0,5 mm coal divides, for treatment purposes, into fines, nominally between 500 and 150 !tm, and ultrafines, nominally minus 150 !tm. Studies on processes for the treatment of minus 0,5 mm coal are discussed, and the lower size limit beneficiated is indicated for each process. The installation and operational results from a pilot froth-flotation plant treating minus 150!tm coal are described.

Jan 1, 1986

By A. C. Scott

A detailed fundamental model of a zinc electrowinning cell has been developed and validated for both steady state and dynamic simulations. This model was used to investigate the effects of a range of operating variables and to find their optimum values. As well as providing useful design information for a planned upgrading of the EZ refinery, more generally it demonstrates the potential benefits to the minerals industry of the applications of modern CAD flowsheeting techniques. The SPEEDUP equation oriented CAD package was found most suitable for this task as the user can easily generate models specific to his site with any number of components and mixture properties.

Jan 1, 1987

By A. Montini

The problems encountered in the design of control systems for milling cir- cuits when the model of the system and the model parameters are uncertain are discussed. Considering these uncertainty factors has led to the development of a technique that gives a quantitative assessment of real system stability, reveals the trade-offs between performance and stability and helps the designer in deciding what level of model complexity to use in the controller design. Furthermore, it allows for on- or off-line optimization of the milling circuit performance as it provides the base for the design of a controller which is stable over the plant operating range.

Jan 1, 1987

By A. L. Hinde

A review of real-time particle size analysers A. L. HINDE,. B.Sc., A.R.C.S., D.I.C., Ph.D. The physical principles of different sizing techniques are critically examined in order to evaluate the suitability of the techniques for real-time particle size assessment. Examples of both successful and unsuccessful attempts at producing an acceptable real-time sizer are described in order to delineate the difficulties involved in making rapid and accurate size measurements. Only two of the examples described have proved to be suitable for on-line particle size monitoring, namely the "MintekjRSM Onstream Slurry Sizer" manufactured by Cartner Group, Ltd., and the "PSM System 100" made by Autometrics Co. Both these commercial systems are capable of assessing particle size with an accuracy comparable with that obtained by routine sieving and weighing. The "PSM System 100" has been used successfully for automatic control of grinding circuits. Economic benefits derived from this system, operating under rigorous plant conditions for several months, have proved that real-time size analysers are of significant value to the mining and metallurgical industry.

By Y. P. Shoupletsov

ABSTRACT. A retrospective analysis of some geomechanical classifications for rock masses is presented. It is shown that estimates of rock mass strength according to geomechanical classifications developed, e.g., for construction of tunnels and for ore mines can differ very much. Development of specifically oriented classifications for rock masses with certain geomechanical properties is required. ZUSAMMENFASSUNG. Es wurde eine retrospektive Analyse einiger geomechanoschen Klassifikationen von Gesteinsmassiven durchgefuhrt. Es idt aufgezeigt worden, dass die Bes-timmung der Festigkeit des Massivs nach geomechanischen Klassifikationen, die z.B. fur den Bau von Tunnelen und fur Erzbergwerke entwickelt wurden, sich um etliche Male unterscheiden kann. Es ist eine Entwicklung von spezialisierten Klassifikationen fur Gesteinsmassive mit bestimmten geomechanischen Eigenschaften erforderlich. RESUME. Il a ete fait l’analyse retrospective de certaines classifications geomecaniques des massifs de roche. Il a ete montre que les estimations de solidite du massif suivant les classifications geomecaniques etudiees, par exemple, pour la construction des tunnels et pour les puits de minerai peuvent differer en quelques fois. Il est donc necessaire d’etudier les classifications specialisees pour les massifs aux proprietes geomecaniques particulieres.

Jan 1, 2003

By R. J. Gordon, N. J. Keys, N. F. Peverett

Photometric sorting of ore on a South African gold mine by N. J. KEYS. B.E. Met. (Queensland) (Visitor). R. J. GORDON. (Visitor). And N. F. PEVERETT. B.Sc. (Eng.) (Wits) (Fellow) This paper concerns the development and application of a high-throughput, multi-stream photometric sorting machine developed for the South African gold mines. It is now believed that this sorter and its progeny may be found suitable for a large proportion of all possible sorting applications. A laser-light source and sensitive photomultiplier are employed in a scanning system to detect light reflected from the surfaces of rocks passing through the sorting zone. Electronic circuitry then analyses the photomultiplier signal, which represents the varying intensity of the reflected light, and produces control signals to actuate the appropriate valves of an array of air-blast rejection devices to remove from the feed certain particles selected by the analysing process. Typical throughput per machine ranges from 50 t/h for a minus 60mm plus 30mm feed to 200 t/h for minus 150mm plus 70mm material.

Jan 9, 1974

By E. J. Margi

Deep gold exploration such as is used for Witwatersrand gold deposits is both expensive and time-consuming. This paper provides quantitative guidelines as to the economic optimum number of boreholes and deflections within each borehole for a certain reef characterized by its variability pattern and depth below surface in order to maximize the level of confidence for a fixed drilling budget or to minimize the total drilling cost for a given level of confidence. Portions of the Basal, Vaal, and Elsburg Reefs that show a wide range of variability (sample logarithmic variances of 0,63, 1,05, and 2,06 respectively) are examined at depths below surface ranging from 1000 m to 4000 m over a simulated mining property covering 7000 ha (7000 m by 10000 m). It is concluded that four intersections per borehole are optimum in al the cases considered, which cover the majority of current Witwatersrand exploration, with the exception of the highly variable Elsburg Reef at depths of 1000 m and 2000 m, where boreholes with one and two intersections respectively should be preferred.

Jan 1, 1987

By Ralph H. Nafziger

This paper reviews the major deposits of lower-grade chromite in the world, and a wide variety of methods used for the recovery of chromium from them. Gangue materials in more coarsely sized ores can be separated by gravity means, whereas flotation techniques are required for finer-grained materials. However, unless there is considerable Iron In the ores, physical means cannot increase the Cr/Fe ratios. Chemical techniques such as hydrometallurgical methods, chlorination, roasting and leaching, and smelting are required for this purpose. A greater understanding of the physical properties of chromites and the chemical reactions that take place in the recovery operations is required before. the recoveries from lower-grade chromites can be maximized. More efficient recovery operations can be realized If It can be shown definitively that the reduction of chromites occurs via either a gas-solld or solid-solid mechanism, for example. The effects of specific impurities on the chromite reduction reactions need to be better understood, as do reagent and pH control in the flotation of chromite.

Jan 1, 1982

Proceedings of the Ninth International Symposium on Techniques for Decision-Making in the Mineral Industry, Montreal, June 1970. The Ninth International Symposium on Techniques for Decision-Making in the Mineral Industry was sponsored by The Canadian Institute of Mining and Metallurgy, McGill University and Ecole Poly technique. The programme included 71 papers on various topics, as follows: Market Analysis and Logistics Planning; Quantification of Geological Variables; Blending; Capital Investment Decisions; Mining; Financial and Economic Analysis; Search for Mineral Deposits; Market Forecasting and Strategies; Operations Research in Process Modelling; Ore Reserve Estimation; Management Information Systems; Optimization and Control of Mineral Processes. In addition to general sessions, a special feature of the Symposium was Executives' Day, which was held to provide top and middle management with a broad understanding of the usefulness of decision-making techniques and their role in the mining organization. Panel Discussions and two keynote speakers provided a review, in non-technical terms, of the areas in which decision-making techniques have proven valuable. The present volume contains 65 papers submitted for publication, along with a complete account of the Executives' Day discussion. It is broadly divided according to the above subject headings. Approximately 550 pages, illustrated. Price: $15.00; $12.00 to students, plus 50 cents for handling costs. Order now from CIM headquarters: Canadian Institute of Mining and Metallurgy, 906-1117 Ste. Catherine St. W. Montreal 110, Quebec.

By L. A. Vermeulen, D. D. Howat

The use of pebbles as the medium in the grinding of quartz gravel in a laboratory mil provided experimental data that were used to quantify the relationships between the feed rate of ore to the mil, the fineness of grind of the product, and the wear rate and consumption of the grinding medium. Fineness of grind is expressed as the inverse of the harmonic mean size, a quantity that is calculated from data obtained by sieve analyses. The commonly used criterion for fineness of grind (the percentage of material smaller than 75 µm in the mil product) is shown to corelate approximately linearly with the inverse of the harmonic mean size. An increase in the feed rate was found to cause the harmonic mean size of the product to increase linearly, Le. the relationship previously found for metalic grinding media is applicable to al grinding media, irespective of shape or composition. Simple expressions for the consumption and wear rate of pebbles are derived from the experimental data, and are shown to be functions of the feed rate. The expression for wear rate is a monotonicaly increasing function, while that for consumption is a hyperbolicaly decreasing function of the feed rate. In contrast, a linear relationship was found between the rate of wear of the grinding medium and the rate production of fines. The expressions that were previously developed in relation to the use of metalic grinding media are shown to be equally applicable to pebble milling.

Jan 1, 1988

By A. N. Brown

Rock breakage by drilling and blasting is fundamental to every hard-rock mining operation. The subject was an apt choice for a mining school because many technological changes have taken place since the subject was last presented some ten years ago. However, because of the development of surface mining, it was decided that two schools should be held: one for underground mining, and the other for surface mining. The School on Underground Mining was held at the University of the Witwatersrand in February 1986.Copper 87 COPPER 87 is an international conference organized by metallurgical and academic institutions of two of the largest producers of copper in the world, Chile and Canada.

Jan 1, 1986

By S. J. Webber

This paper reports on the use of the MINSIM-D stress-analysis program for the modeling of two large seismic events that occurred on the same fault eleven years apart. It was found that the first event (magnitude 5,2) could not be ascribed to purely mining-induced stresses, indicating that the largest seismic events probably result from the interaction of mining-induced stresses with large scale tectonic stresses. However, the stress changes induced during eleven years of mining were found to be capable of generating sufficient excess shear stress (ESS) to be responsible for the second event (magnitude 4,3), The upper limit for the magnitude of purely mining-induced events was found to be approximately 4,3.

Jan 1, 1990

By O. G. Pauw

The relationships between mill power and pebble load, bulk density of the load, and circulating load were investigated on the pebble mills in the grinding circuit at Buffelsfontein Gold Mine. This paper describes the most significant relationships among the operating and control variables on the plant, and illustrates these by reference to experimental data gathered from the plant during operation. The results were used for the development of very successful multivariable peak-seeking controllers for the pebble load and bulk density of the load on these pebble mills. The peak-seeking control algorithms are described in detail. The control system has operated successfully at Buffelsfontein for more than 18 months and is still in operation.

Jan 1, 1985