Search Documents

By David J. MacDonald

Stability constants, that is, equilibrium constants for complex-formation reactions, have been determined by a titrimetric method for complexes formed by the transition metal ions Ni2+, Cu2+, Zn2+, and Cd2+ with the structurally analogous bidentate ligands N-ethylethylenediamine and 2-(ethylthio)-ethylamine. The sulfur containing ligand was found to be the weaker of the two chelating agents for each of the four metals. Absorption spectra of the individual complexes have been determined in order to calculate their crystal field stabilization energies. The combined results suggest a linear relation between free energy of chelation and ionic radius of the metal ion.

Jan 1, 1972

By Foster Fraas

A method is presented for the linear evaluation of adsorption data using the equations dC = Ae-rv dv and v = [jT] - q, where dC is the phase composition increment, v a calculated parameter, T the absolute temperature, and A, r, h, g, and q the constants. The value of v is calculated from the composition C for both the adsorption surface and the immersion phase. A plot of v for each phase on Cartesian coordinates results in straight line graphs. With temperature variation, a plot of v versus,[ ] also results in straight line graphs. The equations are applicable to electronic and salt equilibria.

Jan 1, 1962

By Frank A. Peters

This description of process evaluation techniques used by the Bureau of Mines for studying proposed processing techniques has been prepared to provide those interested in using these studies with an understanding of the methodology. The methods used for preparing both capital and operating cost estimates are described. Each step in preparing the evaluations is described. Types of equipment costs are shown and factors used in the estimates are defined. Uses of the estimates are suggested and several examples are included. The accuracy of various types of estimates is discussed, along with an explanation of the reason for selecting the type used in the Bureau's process evaluation studies.

Jan 1, 1987

By A. J. Barry

A method was developed for testing the anchorages obtained with 3/4-inch, expansion-type, headed bolt and shell assemblies. The apparatus is a modification of that used in testing -inch-diameter, slotted-type bolts. Four makes of expansion-type shells were used in 64 tests made in sandstone and shale roof. The results show that for 3 makes of shells the anchorage effectiveness is independent of the installed land, and for the fourth make of shell a better anchorage is obtained when instilled at a load of 8,000 pounds. The results also show that deformation of the expansion plug influences the majority of the anchorages obtained with two makes of shells. This deformation causes a larger increase in displacement for a given added increment of load. The data from 48 of the 64 tests were combined to establish a relationship between average displacement and increase in bolt load (above the installed load). This relationship can be used to evaluate the anchorage effectiveness of any 3/4-inch-diameter, expansion-type, headed bolt and shell assembly tested in the field.

Jan 1, 1956

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

C. 4 Hoist Assemblies (not man-rated) A large number of manufacturers supply materials handling winches. These units are predominately electric powered while a limited number of vendors supply air powered equipment. Air powered units are currently used extensively for underground materials handling purposes. Suppliers of materials handling equipment normally include a disclaimer statement in their published literature which clearly states that the equipment "is not designed or suitable for lifting or lowering persons " This category of commercially available equipment can be adequate for emergency man hoisting provided that its' capacity is suitably derated and provided also that the necessary safety features are incorporated. Section C. 5 details the equipment which could be added to a commercial materials hoist to meet these needs. Four commercially available hoist assemblies, two electric and two pneumatic are discussed in the following paragraphs. This equipment is typical of what is commercially available and three of the units are currently used extensively in mining applications. Each hoist description includes a remarks paragraph which identifies the additional equipment each hoist would require for emergency hoist use.

Jan 1, 1976

The Bureau of Mines has developed test procedures and criteria for evaluating explosive reactivity of explosive-contaminated solid waste substances generated by U.S. Army ammunition plants. These substances are produced as explosive-contaminated sludge from wastewater treatment plants, residues from the burning of munitions and explosives on open ground, and residues from deactivation furnaces. The characterization of explosive reactivity is a prerequisite for disposal of such waste materials, which may be contaminated with primary explosives, propellants, or pyrotechnic materials. The Bureau has proposed two tests for this purpose. These tests were developed to evaluate the explosive reactivity as defined in Title 40, Code of Federal Regulations (CFR), part 261.23(a)(6) and (7). These are the Bureau's gap and internal ignition tests, which determine the sensitivity to shock and thermal stimuli, respectively. This report also includes gap and internal ignition reference data for typical blasting agents, high explosives, propellants, and marginally reactive substances. These reference data were used to establish test criteria. The Bureau has evaluated over 400 samples of contaminated soil, sludge, and burning residues using these two test methods.

Jan 1, 1988

By J. M. Singer

Approximate equations were used to compute the radiant heating of float coal dust by approaching flames for various combinations of particle size, dust path length (flame travel distance), flame temperature, dust concentration, flame speed, and flame length. The computed values of degree of radiant heating and flame travel distance for preheating the coal dust should be useful for estimating the increased fire hazard of different coal dust-flame parameters. Some findings relating to coal mine disaster control are-- 1. Coal dust clouds cannot be preheated to ignition temperatures by flame radiation alone when deflagration speeds are greater than about 10 m/sec. Thus it appears unlikely that radiation alone will cause flames propagating in dust clouds to accelerate to detonation velocities. 2. Small particles in the radiation flame zone caused by burnout and soot formation increase the degree of preheat significantly. 3. The concentration of float coal dust (radii = 3 to 40 microns) for maximum radiant heating usually peaks in the range 50 to 200 mg/liter of air.

Jan 1, 1970

Develop a method for recovering phosphate from a wide variety of complex western phosphate materials, including low-grade ores, tailings, and unused fines. Approach A flotation technique is used for this broad type of extraction. The method includes depression of phosphate minerals and anionic flotation of carbonate minerals, followed by cationic flotation of silicate minerals. How It Works A slurry is prepared for flotation by sizing to remove a low-grade, high-impurity slime fraction. Depending on the material, further sizing and/or grinding steps may be used to produce a size concentrate or to remove gangue. The flotation feed is conditioned with H2SiF6 and a fatty acid emulsion. The H2SiF6 is absorbed chemically to the phosphate mineral surface, making it strongly attracted to water and preventing adsorption of the fatty acid. Under these conditions, the fatty acid is a selective collector for carbonate minerals, which are removed as a froth product. Next, the silicates are floated with an amine reagent added directly to the slurry without additional pulp preparation.

Jan 1, 1982

Determine the effectiveness of remining operations in reducing contaminant load (acidity, iron, and sulfate) of discharges emanating from abandoned surface and underground coal mines. Background Until the implementation of remining initiatives, most States had regulations that held the operator remining an abandoned site responsible for preexisting acid mine drainage (AMD) discharges. For example, if a mining. company wanted to remine an area hydrologically connected to an existing AMD discharge, the company became responsible, as soon as the site was activated, for treating that discharge to meet effluent standards. If the mining operation improved the quality of the discharge, but the discharge failed to meet effluent standards, the company was held accountable for perpetual treatment. Because of this regulation, most mine operators avoided abandoned sites with minable coal reserves and AMD discharges. However, changes in remining legislation allow coal companies to be released from treatment liability as long as the post-remining pollution load does not exceed the pre-remining level. If remining can improve water quality through improved mining and abatement techniques, abandoned mine land (AML) areas that previously were liabilities could become

Jan 1, 1994

By J. H. Russell

As part of its efforts to maximize resource recovery, the Bureau of Mines conducted studies to recover valuable byproducts from Western phosphate beneficiation tailings. Potential byproducts include phosphorus, vanadium, and uranium. The objective was to determine roasting and leaching conditions for maximum dissolution of vanadium from tailings containing approximately 13 pct P205 and 0.23 pct V. Sulfuric acid leaching tests were conducted with the tailings either as a dilute suspension dried, or in a roasted condition with or without NaCl added during roasting. More than 90 pct of the vanadium was dissolved by roasting at 850° C for 120 min with 8-pct NaCl and leaching at 75°C for 120 min with an excess of 2N H2S04, By roasting without NaCl and avoiding the difficulties of the chloride impurity, nearly 80-pct vanadium dissolution was achieved with an 800° C roast for 180 min. Quadratic regression equations were derived to relate vanadium dissolution to roasting and leaching conditions.

Jan 1, 1982

By Jack C. White

The purpose of this Bureau of Mines work was to develop information useful in improving copper recovery during copper milling operations. Eleven copper mill tailings from the Western United States were subjected to froth flotation and cyanide leaching to provide an experimental basis for comparing their beneficiation response. Recoveries in flotation concentrates made from mill tailings ranged from 65 to 15 percent, at copper grades of 13 and 2.2 percent, respectively. Liberated copper sulfide minerals present in two samples were readily recovered by laboratory froth flotation. Nine of the samples were less amenable to froth flotation because of physical locking between copper sulfide minerals and gangue. Correlations among tailings indicated that recovery of sulfide copper by flotation was directly related to the sulfide copper content. Empirical equations derived from flotation data provided average values for unrecoverable copper and for recovery efficiency. Flotation response of copper mill tailings may be predicted from the equations. Data from cyanide leaching provides an equation describing the limiting high values for removal of copper by this method.

Jan 1, 1974

By N. E. Hanna

The effect of small percentages of sodium chloride on the incendivity of permissible explosives was studied by the Bruceton up-and-down technique in gallery tests. Both the reduction in incendivity achieved by addition of sodium chloride and application of the test method to explosives evaluation are discussed. It is demonstrated that the up-and-down technique in gallery testing is suitable for distinguishing differences in incendivity between different explosive compositions and between lots of the same composition. The study also shows that addition of relatively small quantities of sodium chloride tends to reduce the incendivity of explosives to firedamp, but addition of sodium chloride cannot insure reduced incendivity. Any improvement attributable to the salt can be counteracted by undefined variations in the explosive. The need for experimental investigations of a number of factors that may affect the safety of permissible explosives is emphasized. ACKNOWLEDGMENTS Grateful acknowledgment is made of the assistance of Roy L. Grant in analyzing for normality of distribution of the data obtained by the up-and-down methods and to Harold E. Tubbs for numerous calculations.

Jan 1, 1959

By R. K. Koch

In seeking substitutes for such critical metals as chromium, cobalt, and nickel, the Bureau of Mines investigated techniques for shape-casting titanium in rammed sand molds. Castings were made in olivine, garnet, chromite, and, for comparison, zircon. It was found that commercial-grade castings up to 31 lb (maximum capacity of furnace) could be made in zircon or olivine molds if a zirconia mold wash was used. Castings up to 4 lb could be made in chromite molds, but heavier castings suffered from some mold-metal reaction. Garnet molds were found to be unsatisfactory for castings of all sizes because of gas blows and rough surfaces. In other tests shell castings of acceptable quality were produced in water-glass-bonded zircon and olivine molds up to weights of 8 lb, but chromite molds were unsatisfactory because rough casting surfaces were caused by mold-metal reaction. Unlike the currently used commercial processes, neither the rammed-sand nor the shell-molding processes developed by the Bureau of Mines generate noxious fumes at any step.

Jan 1, 1980

By J. Bender

The objective of this research was to (1) Further develop cyanobacteria mats' for metal-tolerance and cold-tolerance, (2) test them for durability in the field environment and (3) assess them for metal sequestering potential with actual and simulated field samples. Results show that mats performed well In the field and effectively sequestered metals from actual and simulated field samples. Metal uptake from Iron Mountain Hine samples was for Ins 87%, Cu and Cd 99%, Initial concentrations (mg/L) were Zn = 3,250, Cu , 279, Cd = 28. In solutions simulating the Gulf Tunnel drainage, Zn and Mn were effectively removed by mats immobilized on glass wool. Effluent water, after treatment, generally had a Ph of 7 .5-8.5. Al though the final metal concentrations in the mats 'harvested from the decontaminated water were only 1% or less, the actual mechanism of metal deposit was probably a mat-mediated alteration of the environmental conditions causing the metals to deposit outside the mat as oxides or carbonates. Bioflocculents, released by the mats, were likely involved in the metal-removal process.

Jan 1, 1996

By Ira E. Sproat

The question "Why can not American kaolins be substituted for English china clay?" has been asked time and time again, and more often since the beginning of the present war in Europe, which has threatened to cut off the supply of European clays imported from abroad. The answer to this question has invariably been, that the domestic kaolins are not as pure and uniform in composition as the imported clays. This demand for white-burning American clays is of such economic importance that it was considered advisable to determine whether some of our vast deposits of impure white clays could not be refined sufficiently to permit their being substituted for the foreign materials. Up to the present time mechanical principles only have been applied in the refining of kaolins, but in order to keep pace with the increasing requirements for better quality and uniformity of product, the application of the principles of colloidal chemistry is necessary. The investigation described in this report was carried on to deter- mine the practicability of applying technical control of clay disperse systems to the refining of kaolins and the utilization of the prepared clay in the manufacture of vitreous china and wall tile. It is hoped that this report will prove a stimulus to the clay- washing industry; will point out a method of refining certain Amer- ican clays, and will lead to the substitution of domestic kaolins for imported china clays by manufacturers of high-grade ceramic wares.

Jan 1, 1916

By J. J. Rutledge, C. A. Herbert

In 1916 the Bureau of Mines, the Illinois Geological Survey, and the University of Illinois, working under a cooperative agreement, began an investigation of the subsidence of the surface above coal- mining operations. Four widely separated places where mining was in progress were selected as observation stations-one in the northern Illinois longwall coal field, one in the central Illinois coal field where the room-and- pillar panel system of mining was being used, and two in the thick coal of southern Illinois where the room-and-pillar panel system of mining was employed. These four points of mining activity gave a rather wide opportunity for observing subsidence when different mining methods were used. The four places selected for investigation of surface subsidence due to coal mining have been designated as follows: 1. A, in the northern Illinois longwall coal field, where the coal company has been operating coal mines for 30 years and where long- wall advancing is the only method of mining. 2. B, in Perry County, where panel room-and-pillar mining of a thick seam of coal is in progress and where mining operations have been carried on about 40 years. 3. C, in Macoupin County, where the coal company has been min- ing coal by the panel room-and-pillar method for about 15 years. 4. D, in Franklin County, where the coal company has been mining coal for 10 years by the panel room-and-pillar method.

Jan 1, 1927

By Kevin Connor

The mineral industry continued to be an almost negligible contributor to the country's economy as the Government continued its 1979 ban on any mineral exploitation for export; a policy initiated at the end of 1979. A national program had been underway since that time to map and inventory all mineral resources so as to permit future exploitation of mineral wealth in the beat interests of the country and its inhabitants. In March 1982, the British Sulphur Corp. Ltd., under contract to the Burundi Government and the International Bank for Reconstruction and Development (World Bank), began a feasibility study of Burundi's phosphate deposits at Matongo-Bandaga for potential commercial exploitation. The 1-year project effort was to define ore reserves, conceptually design mining operations and processing facilities, estimate capital and production cost, and develop a regional market and distribution survey. Work completed during the year comprised geological exploration and reconnaissance and 1,200 meters of core drilling. Reserves in excess of 5 million tons of ore-grade phosphate were estimated available for mining. Rare earth mineralization was associated with the primary apatite. The associated carbonatite within the rock matrix was preliminarily assessed to be of value as a raw material for the manufacture of cement. The contract effort was valued at $1.2 million? Matongo-Bandaga is located approximately 40 kilometers north of the capital city of Bujumbura and alongside one of the country's few paved roads.

Jan 1, 1984

By L. H. Wullstein

Bureau of Mines research on methods for reclaiming land disturbed by the minerals sector of the economy has produced a specific procedure for effectively germinating seed of Indian ricegrass, a drought-tolerant plant valuable for reclaiming arid and semiarid sites. This report describes the procedure which consists of acid-treating the seed followed by temperature and light cycling treatments. Use of the procedure resulted in an average germination rate of 29 percent, ranging from 18 to 56 percent. Seed subjected to long cold treatment but with acid treatment yielded an average germination rate of 9.2 percent, ranging from 6.6 to 14.7 percent. Untreated seeds (controls) gave germination rates less than 0.1 percent.

Jan 1, 1979

By I. AITKENS

The group of gems included under the general name "feldspar" occupies only a minor place in jewelry. Feldspars, with the possible exception of quartz, are the most important of rock-forming minerals, but most occurrences are of quite ordinary varieties, without striking color and unattractive. Few specimens are suitable for use as gem stones, but occasional crystals that exhibit unusual brilliance or play of color are cut into various shapes for personal adornment or for architectural decoration. The best known of the feldspar gems, and probably the most important in point of production, is the moonstone. Amazon stones, labradorite, sunstone, and a number of less common varieties have been produced in various parts of the world.

Nov 1, 1931

By W. C. Smith

The U.S. Bureau of Mines examined previous research on rib stability in an effort to develop a practical approach to understanding, characterizing, and controlling weak rib conditions in underground coal mines. Because success in stabilizing ribs depends on a basic knowledge of how weak ribs behave, the report reviews the mechanics of rib failure and the relationship of coal mine geology and pillar constraint to rib instability. Strategies for choosing an effective method of rib support are considered, and various rib support methods are discussed. Finally, the report documents techniques for monitoring ribs and use of models to assess rib stability; such monitoring and modeling can also help determine the most effective method for roof support.

Jan 1, 1992