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By J. M. Riley

A fluorometric method using morin in an alkaline-buffered chelating solution has been developed by the Bureau of Mines for determining beryllium in ores and mill products. Apparatus for measuring fluorescence intensities of the beryllium-morin reaction is described. Preparation of the sample for analysis consists essentially of digestion with sulfuric, nitric, and hydrofluoric acids, fusion of the residue with sodium carbonate and sodium borate, Solution of the melt with sulfuric acid, and proper dilution. Chemical separation of other ions is usually unnecessary. The method rave reliable beryllium determinations on samples in the 0.01- to 0.37-percent BeO range. The method is particularly applicable to low-grade beryllium ores; however, semiquantitative beryllium determinations have been made on beryl containing 12.0 percent BeO.

Jan 1, 1956

By Ivan L. Nichols

Tailings dumps at Mercur, Utah, contain about $7 million worth of gold in 3.5 million tons of mill tailings assaying about 0.07 ounce of gold per ton. Commercial mining and milling at Mercur ceased in 1942. To determine whether improved technology was now available that might permit economic reprocessing of the Mercur dumps, the Bureau of Mines probed for a low-cost method that would be applicable to these tailings. A composite sample prepared for laboratory studies assayed 0.062 ounce gold per ton. About 10 percent of the gold occurred as a water-soluble cyanide. Conventional cyanide leaching dissolved 32 percent of the gold, and hot, strong cyanide solution dissolved 42 percent. Results were not improved by pretreatment with acids, bases, or oxidants. After expensive preroasting, gold recovery by cyanidation was increased to 65 percent. The simple procedures were ineffective, and more effective procedures were too costly for economical processing of Mercur tailings.

Jan 1, 1970

By Donald R. Corson

The Bureau of Mines is conducting research on the effects of various established and potential soil-stabilization additives to hydraulic backfill. This initial phase is an evaluation of the effect of inclusion of varying amounts of Portland cement and combinations of cement and a dispersant on the bearing strength of backfill. Results of unconfined compression tests are given for over 200 sample cylinders incorporating a fill material with cement or cement and dispersant. Inclusion of a minor amount of dispersant (0.2 percent by weight) is found to yield a significant increase in strength for 20-to-1 and leaner sand-cement mixes. An apparent optimum concentration of dispersant exists beyond which no further increase in strength is achieved. A dispersant-cement ratio of l.8- to-1 yielded a strength increase of 515 percent over the strength of untreated 40-to-l sand-cement mixes.

Jan 1, 1966

By H. W. Kilau

Thermodynamic calculations indicate that an electrochemical cell might serve as an analytical device for determining the composition of high-purity metals. An equation, readily derived, for the cell voltage, E, is as follows: [E I RT In F NFe unknown sample T of L NFe standard] The cell, however, must come to equilibrium, must be reversible, and must have no thermal effects or complicating side reactions whose magnitude is indeterminable. This Bureau of Mines investigation explores the feasibility of an electrochemical technique for the analysis of high-purity iron. Experiments were conducted using room-temperature aqueous cells and high-temperature molten salt cells. The room-temperature cells proved to be irreversible. The high-temperature cells utilizing FeCl2 and a eutectic mixture of KC1-LiCl were reversible, but did not attain a constant voltage necessary for analytical considerations.

Jan 1, 1963

By John C. Machisak

INJURY DATA and experience at coal mines in the United States for 1957 are presented in this bulletin under the following general sections: (A) General injury experience: Tables 1-6: Current data on number of fatal and nonfatal injuries, frequency and severity rates, and average severity. (B) Selected injury experience: Tables 7-36: Current data on causes of injuries, distribution of injuries by part of body injured, days of disability, extent of hand and machine loading, experience by employ¬ment and production groups, and various other operating factors and physical conditions related to the occurrence of injuries at the Nation's coal mines. (C) Injury experience, by States: Tables 37-41: Data on injuries, injury rates, employment, causes of injuries, and severity rates. (D) Major disasters: Table 42: Data on major disasters from 1948 to 1957. A major disaster is defined as a single accident in which, or as a result of which, five persons or more are killed instantly or die at any time thereafter. (E) Historical coal-mine-fatality experience: Tables 43-47: Data on fatalities and their causes at bituminous-coal, lignite, and anthracite mines from the earliest records through 1957.

Jan 1, 1960

By O. C. Ralston

The Bureau of Mines has under development on a technical scale an electrolytic process for treating oxidized ores of zinc , using caustic soda as an electrolyte . Whereas the Bureau process can alternately make either solid zinc or zinc dust , the following paper , from the Ludwigshafen research laboratory of the well -known I. G. Farbenindustrie , A. G. , of Germany, deals only with production of zinc dust from sodium zincate solutions and may well serve as introduction to the subject for American metallurgists . The Bureau of Mines pioneered in the idea ; a study on laboratory scale by H. J. Morgan and 0. C. Ralston was made early in the First World War, and published in Transactions of the American Electrochemical Society . The Eckardt paper , translation of which follows , goes more thoroughly into the preparation of electrolytic zinc dust , and later publications of the Bureau of Mines will deal with broader details and application of the idea to treatment of lowgrade ores and metallurgical intermediates , which is the point where Eckardt left off . 4 The Eckardt report became available through operations of Field Information Agency , Technical ( FIAT ) of the Office of Military Government for Germany (US ) , which made bibliofilm copies of the files of internal technical reports of many of the German industrial establishments , Eckardt's report is dated April 1939 and was taken on FIAT Microfilm Reel MM 106 , frames 82-101 , which is on file as Publication Board Document 41411 in Office of Technical Services of the U. S. Department of Commerce , Washington , D, C , Eckardt points out that the normal source of zinc dust is the blue powder of the zinc retorts , which decreases in volume every year owing to technologic improvements in zinc smelting. I. G. saw the importance of making a

May 1, 1948

By Oliver Bowles

"Introduction.During recent months the Bureau of Mines has conducted a detailed study of the slate industry with special reference to increased efficiency in its production, preparation and utilization. The results of these investigations will be incorporated in a forthcoming bulletin. The purpose of this preliminary paper is three-fold. One object is to bring to the attention of slate producers certain modifications in manufacture and classification which would encourage a wider use of slate. A second purpose is to direct the thought of roofers toward the importance of proper laying of slate, and the third object is to acquaint the general public with its enduring qualities.Origin and character.Without entering into any detailed discussion of the origin and history of slate, a subject to be covered in the bulletin mentioned, it may be of interest to the general reader to know that slate is originally formed from mud or soft clay, carried down by streams and laid down in successive layers in deep water. The pressure of superimposed materials gradually compresses the clay into a firm rock known as shale. In many places this shale was, during the succeeding ages, subjected to intense pressure and folding due to mountain-building forces within the earth. This intense pressure, together with high temperature, changed the clay into other minerals such as mica, chlorite, and silica, which are very resistant to weathering, and also developed a very definite cleavage or splitting direction which characterizes the rock as slate. It is this property which renders slate of value for roofing, for, by using a broad chisel and a wooden mallet, a slate worker can readily split it into thin sheets which are later trimmed into rectangles of various sizes."

Jul 1, 1921

By H. W. Wainwright

1. A schematic diagram and a description of the apparatus are presented. 2. Five runs were made using gas having a hydrogen-carbon monoxide ratio of about 2:1 and sulfur concentrations ranging from nil to 1.53 grains per 100 std. c.f. 3. At constant space velocity of synthesis gas the product of the sulfur concentration and days of operation, with conversion of H2 + CO above 97 percent, was constant. With a gas containing 0.04 grain of sulfur ac carbonyl sulfide per 100 std, cu. ft ,, the conversion of H2 + CO remained over 97 percent for 40 days. During that time the heating value of the product gas (on a C02-free basis) remained relatively constant at 940 B .t .u. per c.f., based on dry gas measured at 600 F. and 30 inches Hg.

Jan 1, 1954

By Thomas E. Green

A combined solvent extract ion-spectrophotometric method for the determination of as little as 1 ppm of copper in tungsten metal or tungstic oxide has been developed and evaluated. Metallic samples are converted to tungstic oxide by treatment with hydrofluoric and nitric acids. The oxide is then dissolved in sodium hydroxide, and the copper is extracted as the colored neocuproine complex. Total elapsed time for the analysis is approximately 1-1/2 days; however, actual working time for a group of six or eight determinations is less than 4 hours. Precision at the 2-ppm level is better than 0.1 ppm.

Jan 1, 1963

By W. B. Berwald, T. W. Johnson

"The United States Bureau of Mines, in cooperation with the Natural Gas Department of the American Gas Association, has been studying actively for the past several years the flow of natural as through high-pressure pipe lines. 4 This report deals with that part of the study involving the design of pipe-line systems consisting of lines laid parallel to each other. The lines are referred to as the original line and the parallel line. The paralleling lire may or may not extend the entire length &f the original line; however, the parallel line is connected at its two ends to the original line.As a result of the large expansion of the natural-gas industry almost all markets within economic distance, from the developed as fields have at least one pipe line supplying them with natural gas. Small increases in the consumers' demand for natural-gas can be met usually by increasing operating pressures, but any marked increase in demand necessitates paralleling sections of the existing systems. It is believed that to a large extent future expansion in the natural—gas industry will consist of paralleling the present lines. The several formulas given in this report have been developed to aid in the design of such systems. Curves and tables were prepared from these formulas to simplify the calculations materially and to facilitate determination of the sizes of pine to be used in paralleling various diameter lines to give the most economical design. The formulas are presented without detailed derivations, as a complete report on the flow of natural gas through pipe lines is being prepared which will contain the derivations of these formulas. Examples included here show the detail of application of the several formulas to problems of design of parallel lines."

Jun 1, 1934

By David Montgomery

The feasibility of building a calibrator for the DuPont D-100 audio dosimeter is discussed. The desired specifications are used as guidelines but the possibility of their relaxation is also considered. Commercially available equipment is surveyed and found to not satisfy the guidelines. Several alternate concepts are investigated, and recommendations for further work are presented.

Jan 1, 1974

By G. M. Kintz, E. H. Denny

Although some engineering colleges recognize the importance of instructing young engineers in industrial safety , the different institutions handle this instruction in various ways . It is believed that a recent industrial safety course , conducted at the Colorado School of Mines through the cooperation of this school and the Bureau of Mines , U. S. Department of Commerce , presents some unusual features that are of interest to other schools and to the mining public .

Sep 1, 1930

By S. P. Sandoval

Several researchers have shown that the surface of chalcopyrite becomes hydrophobic under oxidizing conditions. Because dissolution of copper from chalcopyrite in dump leaching occurs under oxidizing conditions, the U.S. Bureau of Mines studied the effect of surfactants on chalcopyrite leaching under dump chemical conditions. Surfactants were selected for study because they can lower interfacial tension. The tests were conducted in shaking water baths using 250-mL Erlenmeyer flasks in statistical experimental design formats. The addition of nonionic surfactants increased copper extraction in the fernc sulfate leaching of chalcopyrite when sufficient Fe3+ was present. A positive interaction between Fe3l+ concentration and surfactant concentration was demonstrated. Copper concentration in the leachhing solutions was increased by as much as 100 pct at 25° and 50° C by adding nonionic surfactants. ionic surfactants decreased leaching. The structure of the nonionic surfactants and their hydrophile-lipophile balance (HLB) influenced surfactant performance. The branched hydrophile of an ethoxypolyol was beneficial to surfactant performance. The ethoxypolyol was the superior surfactant at 25° C, but became unstable at 50° C. Four surfactants, an ethoxyalchohol and three block copolymers, performed best at 50° C.

Jan 1, 1990

By Robert L. Rough

The 1954 field tests consisted of six experimental shots in relatively deep holes in a sandstone similar to many oil-bearing sandstones. Water-injection measurements were made before and after each shot to establish the change in conductivity of the fluid caused by the shot. The pressure pulse produced by the shot was recorded in nearby holes to monitor the shot and to determine if any relation existed between the change in conductivity and the nature of the pressure pulse. The results of water-injection tests showed the range of conductivity of fluid before and after shooting with two different types of explosives. Because of the large spread in data for similar shots, not enough information was available to evaluate the differences in increased conductivity produced by the two explosives or any relation between the increased conductivity and the nature of the pressure pulse. However, these results, with the results of other tests involving explosive shots in rock, provide guidance for future research on the oil-well-shooting problem.

Jan 1, 1957

By H. J. Heinen

This report summarizes preliminary research studies by the Bureau of Mines in electrowinning molybdenum directly from pure or impure molybdenum trioxide (MoO3) by fused-bath electrolysis in an open graphite cell without need of a protective inert atmosphere. A formulated electrolyte of the tertiary system containing 41.6 percent sodium pyrophosphate, 16.7 percent sodium tetraborat, 33.3 percent sodium chloride, and 8,4 percent molybdenum trioxide, by weight, electrolyzed at 1,000° C,, gave excellent results. Current density studies were made over a range from 20 to 260 amperes per square decimeter. Current efficiencies of 80 to 90 percent were obtained over the entire range. Yields up to 500 grams of molybdenum per kilowatt-hour were obtained. Higher current densities, however, reduced yields and produced a finer grained metal. The two most important facets in electrowinning molybdenum from MoO3, in an open cell, are temperature and electrode spacing to minimize or eliminate the formation of the suboxide MoO2, the major source of oxygen contamination. At temperatures of 1,000° C. and higher, together with the proper spacing of the electrodes, formation of oxides are practically eliminated. Molybdenum metal electrowon from pure MoO3 was 99.9 percent pure and contained 0,056 percent oxygen and 0,007 percent carbon. This metal, when arc-melted, had a Vickers hardness number of 175 and contained 50 parts per million oxygen and less than 10 parts per million carbon. Molybdenum metal electrowon directly from an impure MoO3 containing 90 percent MoO3 resulted in a metal of 99.8 percent purity.

Jan 1, 1961

By Linneas W. Laage

Coal production from underground coal mines has been important to the development of the industrial economy of the United States. Environmental problems have developed from some abandoned operations. These problems include: mine and refuse pile drainage, subsidence, unsafe mine openings and to a lesser extent mine gases, slope stabilities, mine and refuse pile fires and abandoned equipment and structures. Field investigations in three eastern coal mining districts, two in Ohio and one in Illinois, were performed to document the mine closure procedures used and subsequent problems that developed. The purpose was to identify, evaluate, and rank the seriousness of these problems. Based upon this evaluation, the undesirable present day situations could have been avoided or at least minimized by varying certain mining practices or mine closure procedures. It was found that federal regulations address all of these problems during the pre mining, active mining and post mining phases except for abandoned equipment which is the least threatening problem category. Ideally current practice would prevent future problems. However, the extensive and complicated nature of the legislation, environment and mining practices will necessitate adjustments to the law. The investigator recommends the following: 1) Goal oriented legislation encouraging complete resource extraction, standardization and compilation of mining generated hydrological data, periodic review of the coal mining regulations, and improved communication and cooperation between coal interests, regulators and the public. 2) Permitting effluent limitations to accurately reflect natural conditions. 3) Solidly back filling shafts and individual assessment of sealing or capping requirements. 4) Installing shaft vent pipes into the fill material to intercept and vent methane.

Jan 1, 1982

By F. B. Tough

"INTRODUCTION Organizations formed for the purpose of conducting conservation work in oil fields, in order to conserve and prolong the supply of crude petroleum are rare and novel. Such an organization is the Rocky Mountain Petroleum Association, Denver, Colo, As our production of petroleum can no longer keep with the consumption, the plan of organization, character of work, and results obtained by this association are well worth considering. It is hoped that the results achieved in the Wyoming fields will serve to stimulate similar organizations among operators in the state or other oil fields of the United States, The Rocky Mountain Petroleum Association, Danvers Colo., was formed in May, 1919. It comprises the Midwest Refining Co,. The Ohio Oil Co., and the Continental Oil Co. These three companies entered into a cooperative agree¬ment with the Federal Bureau of Mines whereby $30,000 would be spent under the direction of the bureau, which agreed to furnish competent men, and to furnish the work and expenditure of funds. Although the financial burden for the first year's work, now drawing o a close, was carried by only three companies, they stipulated their desire that the benefit of the work should accrue to the industry, and that the personnel employed should be as zealous to assist one operator as another, without regard to whether ha was contributing to the support of the work or not."

Apr 1, 1920

By Irving Hartmann

When permissible explosives are used in coal mines according to the procedure recommended by the Bureau of Mines they are relatively safe, and no mine explosions are known to have resulted from this type of blasting. However, unsafe blasting practices - the use of nonpermissible explosives or the improper use of permissible explosives - have caused many serious disasters. In fact, such unsafe practices constitute the third most important cause (exceeded only by electricity and the use of open lights and smoking) of coal-mine explosions in the United States. During 1929-1947, inclusive, 81 explosions, resulting in 475 fatalities, were ascribed to unsafe blasting. The hazards of black powder, dynamite, and other nonpermissible explosives in coal mines have been recognized for many years, and attention has been called to this in numerous Bureau of Mines publications. Not only can these explosives ignite namable gas-air mixtures readily, but they can also ignite coal dust, as has been illustrated repeatedly in tests and at educational public demonstrations at Bruceton and elsewhere.

Jan 1, 1952

By R. A. Beall

Homogeneous zirconium-alloy ingots have been cast on a production basis by the consumable-electrode arc-melting process at the Northwest Electrodevelopment Experiment Station, Bureau of Mines, Albany, Oreg. This paper describes the various methods used to introduce alloying materials into the ingot and evaluates 1 each method by the degree of homogeneity of resulting ingots, as determined in tests on sections cut from the ingots. As many as 30 or more ingots, each 6 to 10 inches in diameter and weighing 300 to 500 pounds, were melted, using each method; and, as most of them subsequently were fabricated to strip 0.1 inch thick, the test results are considered to be representative of production practice. Ingot homogeneity has been considered more difficult to achieve in arc-melting practice than by methods where the molten metal is poured into molds and the addition can be stirred into the total mass of metal before casting. Owing to the unique requirements of consumable-electrode arc melting the addition can be made only to that part of the total mass of the ingot that is molten at one time. Observation of the flowlines in 500-pound ingots produced at Albany indicates that the molten pool has a maximum depth about equal to the ingot diameter. The weight of metal molten at one time is, therefore, not over 100 pounds. Characteristically, the arc-melting process is conducive to segregation, which can be overcome, at least partly, by adding the alloy constituents almost continuously during casting.

Jan 1, 1956

By Irving Hartmann, F. P. Christofel, John Nagy, E. B. McGibbeny

"INTRODUCTION When permissible explosives are used in c procedure recommended by the Bureau of Mines 5/ they are relatively safe, and, no mine explosions are known to have resulted from this type of blasting. However, unsafe blasting practices - the use of nonpermissible explosives or the improper use of permissible explosives - have caused many serious disasters. In fact, such unsafe practices constitute the third most important cause (exceeded only by electricity and the use of open lights and smoking) of coal-mine explosions in the United States. During 1929-1947, inclusive, 81 explosions, resulting in 475 fatalities, were ascribed to unsafe blasting. 6/The hazards of black powder, dynamite, and other nonpermissible explosives in coal mines have been recognized for many years, and attention has been called to this in numerous Bureau of Mines publications. Not only can these explosives ignite flammable gas-air mixtures readily, but they can also ignite coal dust, as has been illustrated repeatedly in tests and at educational public demonstrations at Bruceton and elsewhere. 7/Research in the Experimental coal mine 8/ of the Bureau of Mines at Bruceton, Pa., and unfortunate experience in commercial mines have proved beyond doubt that improper use of explosives that have passed the official permissibility tests can cause as explosions. In limited tests with a fey American permissibles at Bruceton, and in more, extensive tests with permitted explosives at the Polish experiment station, 9/ explosive charges were fired from steel cannon and freely suspended in coal-dust clouds. In these experiments coal dust was ignited under some conditions. However, it has never been definitely established whether permissible explosives can initiate coal-dust explosions when fired in a coal seam. It is true that a few mine explosions were strongly suspected to have resulted from ignition of coal dust by misuse of permissibles, but in each case other complicating factors introduced some doubt in the minds of the investigators. Full knowledge of the problem is important, because coal dust is present in most blasting operations in coal."

Apr 1, 1952