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By N. S. Dalal, B. Jafari, X. Shi, M. M. Suryan

"It is well known that prevalence and severity of coal worker's pneumoconiosis (CWP) differ markedly in different regions and mines despite comparable exposures. These variations in the pathogenicity of different coal mine dusts can only partially be explained by the mineral composition of the coal mine dust and the rank of coal. Laboratory studies also do not correlate with the human experience. One major difference between human exposure and laboratory studies is that the coal miner breathes dust from freshly broken coal, while the animals or cells are exposed to stale dust. In an effort to find biochemical clues for resolving this apparent paradox, we have carried experiments to detect differences in chemical reactivities of fresh versus stale coal dust from several U.S. coal mines. Electron spin resonance (ESR) was used as a technique for the direct detection of the concentration and reactivity of free radicals. ESR measurements of freshly ground coal dusts of different ranks and composition showed significant differences in the amount and reactivities of the organic free radicals produced. The half-lives and reactivity patterns of these newly formed species of free radicals seem to correlate with the expected toxicity and pathogenicity of the dust, thereby, providing new clues to the biochemical mechanisms and pathogenesis of CWP. Similar detection of free radicals in freshly crushed quartz suggest that free radicals might play a significant role in the pathogenicity of quartz in causing fibrosis and eventually silicosis.IntroductionThe pathogenesis of coal workers' pneumoconiosis (CWP) has been an important topic of concern for decades, but the mechanism of CWP is still not understood. It is well known, for example, that the prevalence and severity of CWP differ markedly in different regions and mines despite com¬parable exposure'(1,2) but these observations can only par¬tially be explained by differences in mineral composition and rank of coal (3-5) Specifically, while epidemiological studies of coal miners indicate (1,2) that the effectiveness of coal in producing CWP correlates roughly with the rank (i.e. %,carbon content) of coal, such correlation has not been established via biological studies.(4-6)"

Mar 1, 1989

As part of remote sensing research on an abandoned mine lands (AML) site in the Colorado Springs, Colorado area, a geographic information system (GIS) database was generated. This GIS database contains information on the locations and extents of abandoned underground coal mines, the geology of the area, subsidence features and degrees of subsidence risk, topography, drill hole locations, and lineaments (linear features) related to subsurface geologic structures. A GIS database allows the reproducible and accurate comparison and analysis of any data sets which geographically overlap and are within the same coordinate system. The database has been released to the public domain so that government agencies, researchers, educators, and the general public can access this coherent database for the purposes of better understanding the study area and GIS technology. Data files and maps are available in formats that are compatible with the GIS software used in the research project and with most CAD systems so that as many people as possible can make use of the majority of the database. This document serves as the data dictionary for the database by providing descriptions and origins of the data files.

Jan 1, 1992

By F. P. Haver

The Federal Bureau of Mines investigated aqueous electrolysis as a means for reducing lead chloride prepared by ferric chloride leaching of galena concentrate: NaC1 PbS + 2FeC13 ? PbC12 + 2FeC12 + S°. During electrolysis, metal was produced from solid lead chloride in contact with the cathode rather than from lead in solution. Relatively high current densities--up to 300 amp/ft2--were possible when operating in this way. A very simple cell, having a horizontal lead cathode at the bottom and a vertical graphite anode at the top, was employed. Lead chloride crystals, covering the cathode, were converted to metal powder during electrolysis, and chlorine gas or FeCls was produced at the anode, depending on the electrolyte composition. Electrolytes tried included aqueous solutions of HCI, NaCl, NH4Cl, and FeC12-NaC1. Optimum results (96-pct current efficiency, 0.23 kwhr/lb Pb) were obtained with 20 pct HC1 at 25° C, using a current density of 15 amp/ft2 and an electrode spacing of 1 inch. When the current density was increased, the energy requirement increased also but only to 0.41 kwhr/lb at 150 amp/fr3 and 0.58 kwhr/lb at 300 amp/ft2.

Jan 1, 1978

By R. W. Lewis

Spectrochemical procedures were developed using dc arc excitation for the determination, in parts per million, of 18 impurity elements in electrorefined beryllium and high-purity beryllium oxide. The metal samples were dissolved in dilute hydrochloric acid, evaporated to dryness, and converted to the oxide in a muffle furnace at 900° C. Germanium oxide was added as an internal standard for the determination of 15 of the elements, copper oxide for boron and molybdenum, and neodymium oxide for calcium. The average coefficient of variation was 11 percent with the exception of copper, which averaged about 43 percent.

Jan 1, 1962

By J. J. Drost

This Bureau of Mines investigation studied the effect of thermal treatments upon concentratability of a western Mesabi Range nonmagnetic taconite ore and is a sequel to Bureau of Mines RI 7567. Magnetic tube tests were used to develop the data needed to calculate separation efficiency, the primary measure of concentratability. A horizontal tube furnace was employed to heat treat and reduce the hematitic ore samples. The two variables studied were roasting temperature and cooling method. The manner of cooling, either by slow cooling or quenching in water, produced no significant difference in concentratability. Roasting temperatures employed ranged from 500° to 1,000° C, and a temperature of 650° C effected the best concentratability. The temperature of 650° C correlated with the most effective roasting temperature for grindability.

Jan 1, 1973

By Carl F. Wingquist

Electrical resistance heating to effect thermal fragmentation of semiconductive rock was examined by the Bureau of Mines. Tests were carried out on copper-bearing ores of the Nonesuch Shale Formation in the laboratory and in the the field at White Pine, Mich. Fieldwork included primary and secondary breakage tests. Heating tests on in situ rock failed to produce thermal dam-age to an extent considered useful; however, boulders up to 30 ft3 were effectively broken by the method. Power input to the test rock was taken from a 50-kV, 5-amp dc power supply.

Jan 1, 1976

By E. P. Youngman

Except possibly by individual natives and Liberians (small specters), is now being carried on in Liberia, according to a late report. definite information is obtainable with respect to the mineral resources of e country, except that iron ores are said to be abundant. Tin, copper, zinc, site, corundum, lead, bitumen or li nite, and diamonds have all been re- parte, but no commercial Geposits are known to have, been found. Gold has been duce, but not in significant amounts, as may be inferred from the customs - rt for Liberia recording the exportation of gold to the value of $4.80 Germany from the port of Cape Mount in 1925. It is not uncommon for atives to come into towns with African gold and valuable minerals, but they e reluctant to sive information concerning then. Some years ago the Liberian Government was seeing a loan in return for oil concessions, but apparently no drilling bea boon don

Jun 1, 1932

By Len Blackman

The Absaroka-Beartooth Study Area is a tract of approximately 1.4 million acres of National forest land in southern Montana, part of the Greater Yellowstone Area. This study evaluated the mineral potential of four mineral terranes containing undiscovered resources in the area. The geological data is probabilistic, with estimates of the possible number: of deposits and their grades and tonnages. Possible future development scenarios range from no development to many mines, including some very large. As two thirds of the study area is within the Absaroka-Beartooth Wilderness, the future development scenarios reflect the area's mineral potential, not what we expect to see in the foreseeable future. Based on the analysis performed on these four terranes, the most likely future scenario for the study area would include the potential for two medium sized, (predominately) gold, mines, each employing a few hundred workers. There is a small chance, less than 5%, that a large Porphyry Copper or Superior Iron deposit would be discovered and be economically feasible to develop.

Jan 1, 1994

Develop a more efficient method of testing the integrity of in-situ leach mining operations. The Problems For economic and environ-mental reasons, in-situ leaching operations must be sure that wells do not leak. Loss of solution in large quantities can be expensive in itself, and if such losses result in pollution the costs can be even higher. Wells are usually tested for leaks by sealing them with packers, pressurizing them and monitoring the pressure drop. However, many commercially-available packers are designed to be used in steel-cased wells rather than the fiberglass-or plastic-cased wells used for in-situ mining. These packers are heavy, cumbersome, expensive, and often leak. In addition, commonly used well-integrity-test systems require lengthy test periods and drill rigs or hoist trucks with rigid pipes must be used to run the packers in and out of the well. The Bureau of Mines has developed a mobile, self-contained leak-testing system that is faster, uses trailer-mounted equipment that can be operated by one person, and features a new inflatable packer.

Jan 1, 1985

By S. J. Pearce

The need for a simple, very sensitive, and accurate method for the determination of benzene in blood and urine was evident throughout a recent study of chronic benzene (C6H6) poisoning conducted cooperatively by the United States Bureau of Mines, The Barrett Company, and the producers of benzene. A combustion method which will be described in a later publication, end a previously described5/ adaptation of Smyth's method were developed and used during that investigation. The adaptation of Smyth's method gave satisfactory results when dealing with exposure conditions that produced chronic poisoning in a comparatively few days, but it was time-consuming and lacked the accuracy necessary for a study of the absorption, distribution, and fate of benzene in the body during exposure to threshold concentrations of benzene vapor in air. The combustion procedure was satisfactory from the standpoint of sensitivity but was cumbersome, intricate, time-consuming, and required the use of special and somewhat expensive physical and. chemical apparatus. Following the termination of this study of chronic poisoning, possibilities for developing better methods occurred, and these have been investigated by the Bureau of Mines with the aid of Relief Works Division personnel. A microcolorimetric method for the determination of benzene in air has been described recently.6/ The present report deals with the adaptation of this new colorimetric method to the determination

Jan 1, 1936

By G. W. Birge

As a part of its overall program of coal carbonization, the Bureau of Mines is studying the coking properties of coals that may be used for metallurgical purposes. The objectives of this study were given in detail in a previous report.2/ The inherent suitability of coal for metallurgical use depends primarily on (1) chemical composition, (2) preparation characteristics, and (3) carbonization behavior. The first two factors, as well as the available reserves, are considered in selecting coals for carbonization tests. The selection of coal beds in Westmoreland County for coking tests was based, in part, on estimates of the coal reserves by Dowd,3/ who estimated the recoverable reserves in beds 28 inches or more thick, in thousands of tons, as follows: [ ]

Jan 1, 1957

By R. L. Andrews

The Bureau of Mines investigated means of electrodepositing iridium to form thick coatings suitable for the protection of such metals as tungsten and molybdenum, which oxidize rapidly at high temperatures. Using a fused sodium cyanide bath, thick, adherent, and coherent deposits of iridium up to 15 mils thick were plated on tungsten and molybdenum substrates at 600° C and current densities of 10 to 100 ma/cm2. Limited oxidation testing of molybdenum encapsulated with pure iridium indicates that the coating may offer protection to approximately l,000° C in flowing air, but that at higher temperatures, the volatility of its oxide limits use of pure iridium. Alloy coatings of iridium with platinum, palladium, and rhodium up to 4 mils thick were formed from a fused sodium cyanide electrolyte; because their oxides are less volatile, these alloys may protect substrates at higher temperatures. Deposits made from aqueous electrolytes either had very low rates of deposition or were highly stressed and cracked when heavy deposits were made.

Jan 1, 1967

By Laxman S. Sundae

In the vast majority of American coal mines, roof bolt holes are drilled dry, mainly because of mine operator concern with the spent water creating adverse working conditions. Wet drilling, however, can increase drilling rates and the effective lifetime of the drill bits used. This study, carried out as part of an ongoing cooperative research program between the U.S. Bureau of Mines and the University of Missouri-Rolla, shows that the large volumes of water conventionally used in wet drilling are not necessary, and the performance benefits from wet drilling can be achieved with total volume flows on the order of 0.4 L per hole. This conclusion is validated based on the measured respirable dust generated in drilling Berea sandstone. The results are confirmed using a variety of bit shapes, which are also shown to have a significant effect on penetration rate.

Jan 1, 2010

By R. V. Ramani, S. Shankar

"The phenomenon of re-entrainment is seen in environments such as sand dune formation, soil erosion, fugitive dust emission and the spread of radionuclides from accidents involving nuclear weapons. A thorough review of existing literature reveals that work on re-entrainment of dust in mine atmospheres is scant. The present study was undertaken as a part of ongoing research at the Generic Mineral Technology Center on Respirable Dust at the Pennsylvania State University on the development of methods to predict ambient dust concentrations in mine atmospheres (Ramani, 1983). The contribution of re-entrainment to the spatial and temporal concentration of dust in mine airways is being studied. The research has included wind tunnel and in-mine studies.A set of seven experiments was performed under controlled conditions in the US Bureau of Mines' Lake Lynn Laboratory mine. Two types of source coal dust, anthracite and bituminous, were subjected to various airflow rates and were subjected to walking by two different individuals. Six sets of instruments were used along the test section for sampling airborne particles. The average air velocity just above the coal dust bed varied between 2.1 to 3.2 m/sec.Due to re-entrainment as a result of the airflow conditions, the average respirable dust concentration in the center of the mine airway increased to 0.09 mg!m3 (standard deviation= 0.03 mg/m3)from an initial value of 0.02 mg/m3. The concentration of all (total) airborne dust increased to 0.17 mg/m3 (standard deviation = 0.10 mg/m3) from an initial value of 0. 02 mg/m3. The action of people walking, however, caused higher amounts of re-entrainment. The average concentration of respirable and total dust at the center of the mine airway increased to values of 0. 28 mg/m3 (standard deviation of 0.12 mg/m3) and 1.53 mg/m3 (standard deviation of 1.0 mg/m3), from initial values of 0.03 and 0.05 mg/m3, respectively. Jr was observed that the dust concentrations were much higher near the floor, immediately at the end of the coal-dust bed.Depending on the level of activity and the amount of dust deposited in the mine airways, re-entrainment may become an important source of airborne dust in areas away from the point of actual mining."

Dec 1, 1996

By L. C. George

Addition of an acid waste to an alkaline cyanide waste was investigated for five different combinations of electroplating wastes. At the optimum final pH values of the mixtures, metals and cyanides were almost quantita¬tively precipitated. No evolution of hydrogen cyanide was detected by a few additional processing steps, significant amounts of variable metals were recovered for recycling the waste-plus-Waste step is attractive because no reagents are required, metals arc concentrated, and a relatively harmless effluent that meets most water quality Standards for cyanide content is produced.

Jan 1, 1970

By Foster Fraas

Calculations based on data related to the electrostatic precipitator illustrate the variation in the electric forces on a particle with change in position in the ionized field. The feeble forces in some separators are explained by the low field intensity at midpoint locations between the electrodes. When the particles are in contact with the exterior surface of a rotating cylindrical electrode, a high field intensity at the electrode surface combined with the image charge results in large electric forces. The permissible feed velocity increases as the square root of the electrode diameter, providing high values in efficiency and feed rate capacity, particularly in surface-to-mass ratio separations such as are encountered in secondary materials recycling operations.

Jan 1, 1971

By W. G. Pariseau

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. The present study uses rock deformation measurements to validate and calibrate a geomechanical model of the experimental Lucky Friday underhand longwall (LFUL) stope on the 5,100-ft level of the Lucky Friday Mine, Mullan, ID. The calibrated three-dimensional, finite-element model and measurements of rock mass displacement show a correlation of 0.795. The calibration reduces rock mass modulus to 14 to 17 pet of laboratory values and rock mass strength (with an energy rule) to 37 to 41 pet of laboratory values. This model suggested that stress-related ground control problems would be encountered west of the stope where the vein makes a right-angle turn and then splits. Rock burst activity was concentrated in this area during mining of the LFUL stope.

Jan 1, 2010

By Robert W. Freedman

The Bureau of Mines investigated methods of analysis of free silica in respirable dust, including both work done at the Bureau of Mines and work done elsewhere. The review covers both coal dust and noncoal dust, taking into account both existing and proposed chemical and spectroscopic procedures.

Jan 1, 1971

By J. D. Marchant

The Bureau of Mines studied solid-state electromigration to determine the value of the technique as a method of purifying cerium metal. Cerium metal in bars 6 inches long and 1/2 inch in diameter was refined at 600° C by solid-state electrolysis to remove iron, copper, and manganese. Iron and manganese were electrotransported to the anode and copper was electrotransported to the cathode. The concentration of iron at the anode of a cerium bar was 800 times greater than the concentration at the cathode. The concentration of manganese at the anode was twice the value at the cathode. The concentration of copper was 170 times greater at the cathode than at the anode. A radiotracer technique was used to follow the iron migration in the cerium metal. Molybdenum, silicon, and aluminum impurities were not electrotransported.

Jan 1, 1967

By Bill M. Stewart

To decrease the potential for fine coal waste slurry impoundment failures, the Bureau of Mines investigated a new disposal technique. The fine coal waste slurry is rapidly thickened (i.e., dewatered) and deposited on a slightly sloping surface. To accomplish rapid dewatering, a chemical flocculation system using polymers was developed to treat the fine coal waste slurry stream. The fine solids formed flocs, settled from suspension, and rapidly released excess water. During the last 5 days of the field test, slurry flowing at rates from 498 to 675 gal/min with a specific gravity range of 1.15 to 1.33 was successfully treated and dewatered. During this period, untreated slurry had an average moisture content of 227.4 pct (30.7 wt pct solids). The effectiveness of the dewatering system was determined by monitoring the moisture content of the deposited waste with respect to time. Sixty-five hours after ending the field test the average moisture content was 54.9 pct (64.5 wt pct solids); 68 days after the field test the average moisture content was 28.8 pct (78.0 wt pct solids).

Jan 1, 1986