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By N. S. Dalal, V. Castranova, K. Van Dyke, V. Vallyathan, J. H. Kang

"We have reported previously that crushing or grinding crystalline silica results in the generation of silica-based radicals on the particulate surface and that these radicals can generate hydroxyl radicals in aqueous solution. Data in the present study indicate that freshly ground silica is more cytotoxic and is a more potent activator of alveolar macrophages than comparably sized aged silica. That is, compared to aged silica, fresh silica is 4.2-fold more potent in decreasing the membrane integrity of macro· phages; is 50% more potent in activating hydrogen peroxide secretion by macro· phages; and is 4.frfold more potent in stimulating cellular chemiluminescence. Prosil 28, an organosilane material, is an effective coating agent for fresh silica. It decreases the cytotoxicity of fresh silica by as much as 78% and decreases the ability of fresh silica to induce chemiluminescence from alveolar macrophages by 58%. The data suggest that surface radicals associated with freshly cleaved dust may be an important factor in the induction of pulmonary disease. Furthermore, treating dust with coating agents may substantially decrease toxicity. INTRODUCTIONThe U.S. Department of Labor estimates that over 1.25 million American workers may be exposed to crystalline silica and that nearly 60,000 may be at risk of developing some degree of occupational lung disease (Parkes, 1982; Peters, 1986). Occupations of concern include miners, stone quarry workers, sand and gravel workers, sandblasters, foundry workers, and glass workers. Acute silicosis is characterized by inflammation, alveolar lipoproteinosis, and the rapid development of respiratory disability (Banks, 1986). In contrast, chronic silicosis develops 20-40 yr after initial exposure and is characterized by the appearance of concentric hyalinized nodular lesions and the progressive development of dyspnea (Parkes, 1982; Ziskind et al., 1976)."

Mar 1, 1992

By M. R. Peterson

The U.S. Bureau of Mines investigated column flotation for recovery of a high-grade fluorite (CaF2) concentrate and byproduct concentrates from the Fish Creek fluorite deposit in Eureka County, NY. The recovery scheme consisted of (1) grinding the ore to minus 48 mesh, (2) fluorite rougher and cleaner flotation, (3) desliming the rougher fluorite flotation tailings at 20 Jjm, (4) mica flotation, and (5) silicate rougher flotation. Acid-grade fluorspar, mica, free silica (Si02) sand, and low-grade beryl (Be3Al2S~018) concentrate were produced in a 100 lb/h continuous column flotation unit (CCFU). The highest results achieved were %.6-pct CaF2 recovery in a fIrst cleaner concentrate containing 99.7 pct CaF2. Beryl recovery was as high as 92 pct at a grade of 5.3 pct BeO. The silica sand, which assayed 98 pct Si02, was recovered as the rougher beryl flotation tailings. Collector reagent consumption was reduced 45 pct for fluorite and 58 pet for silicate flotation in comparison with bench-scale conventional flotation. All products were signillcantly improved in both grade and recovery over conventional flotation results, and the recovery scheme was simplifIed by removal of several stages of flotation in the fluorite and silicate flotation steps.

Jan 1, 1990

By Chester L. Arnold, Reinhardt Thiessen, Alexander Lowy

"INTRODUCTION Peat is the accumulated mass of plant materials that remain after partial decay under specific conditions. In the swampy peat bogs dead material which falls on the surface immediately is attacked by fungi and aercbic bacteria. Decay under these conditions is rapid, but of relatively short duration, since the constant addition of new material soon forces the older layers below the water level, in this position, without access to oxygen, the plant constituents are attacked mainly by anaerobic bacteria, and decomposition proceeds slowly. The largest part of peat is contributed by the woody tissues of plants, the chief constituents of which are cellulose and lignin, together with a small proportion of hemicelluloses. During the normal process of biological decay celluloses disappear more rapidly than lignin. The result is a complex substance known as humin, from which the humic acids may be extracted.In 1826, Sprengel 5 found that when decayed plant materials were extracted with alinnli and the resulting black liquid acidified with mineral acid a brown gelatinous precipitate was formed. To this product, which was a brown amorphous powder when dry, he gave the name ""humic acid'. Since that time, chemists have used the name rather loosely to designate products which have been isolated by very diverse means from soils, decayed woods, peat, lignite, and coal. An excellent review of the early work on humic acids was published by Baumann 6 in 1909. This publication aroused the interest of Oden, who then investigated the humic acids. An account of Oden’s work, as a good survey of the literature, is contained in his monograph “Die Huminsauren”. 7"

Nov 1, 1934

By M. F. Chambers

The U.S. Bureau of Mines conducted experiments on electrowinning of neodymium metal by using a molten-metal cathode at 650° C and an electrolyte of 50 mol pct NdCl3 (neodymium chloride) and 50 mol pct KCI (potassium chloride). The molten-metal cathodes were alloys of magnesium and zinc or magnesium and cadmium. Current efficiencies were 90 pct with a Mg-Zn cathode and 80 pct with a Mg-Cd cathode; The Mg-Cd cathode was easily separated from the electrolyte. In contrast, the Mg-Zn cathode tended to mix with the electrolyte, making separation difficult. The cathode metals were separated from the neodymium by distillation at 1,100° C under a vacuum of 10-3 torr. Neodymium metal of 99.9+ purity was recovered from the Mg-Cd alloy cathode after 30 min distillation time. The neodymium recovered from the Mg-Zn system contained almost 2 pct Zn after vacuum distillation. Continuous operation using the Mg-Cd alloy cathode was demonstrated.

Jan 1, 2010

By R. V. Ramani, A. S. C. Owili-eger

List of Numbers

Jan 1, 1974

By W. W. Simpson

During cyanidation of mercury-bearing gold-silver ores, significant amounts of mercury are extracted. The presence of mercury decreases. gold loading and increases mercury stripping time on activated carbon, complicates fire refining of the gold cathodes, and creates a potential health hazard. Addition of calcium sulfide (CaS) to the cyanide leach slurry precipitates the solubilized mercury but also some silver. The Bureau of Mines investigated silver loss during CaS precipitation of mercury. Addition of 0.1 lb CaS per short ton ore to a mercury-bearing gold-silver ore precipitated both mercury and silver. However, if copper was added with CaS, or if the ore contained copper, much of the sil-ver loss was prevented. Addition of 235 ppm Cu with 0.1 lb/st CaS, prior to carbon-in-pulp adsorption, resulted in 89-to 97-pct, 80-to 91-pct, and O-pct adsorption of the solubilized gold, silver, and mer-cury, respectively, on the activated carbon.

Jan 1, 1986

By E. P. Youngman

This paper is one of a series of digests of foreign mining legislation and court decisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to can and ore rate mines in various foreign countries. This interpretation of the mining laws of the Irish Free State has been prepared from the best available material in Washington and is released subject to amplification and correction, if necessary, by American foreign-service officials. INTRODUCTION This paper is based upon the mines and minerals act, 1931, enacted by the Legislature (Oireachtas) of the Irish Free State (Saorstát Eireann), December 22, 1931, the lull title of which is "An act to establish a board to perform functions in relation to mines and minerals, to authorize the making of lenses of mines and minerals belonging to or vested in Saorstát Eireann, to name provider for facilitating the working of other mines and minerals and, for imposing restrictions on the working of minerals required for the support of buildings and works, to amend the law with respect to mines, and for other purposes incidental to the matters aforesaid.'

Jan 1, 1933

By Jerry E. Olson

In 1984, the U.S. Bureau of Mines conducted a mineral survey of the Black Rock Desert Wilderness Study Area (WSA) (NV-020-620), which covers approximately 319,000 acres in Humboldt County, Nevada. About 90% of the WSA is underlain by Pleistocene desert playa sediments; the remainder is comprised of Jurassic-Triassic metamorphic rocks, a Cretaceous intrusive and Tertiary volcanic rocks. Most of the WSA is within a down-dropped fault block of the Basin and Range physiographic province. No mines or evidence of major exploration were identified within the WSA; but five claim blocks within or adjacent to the WSA and zones of anomalous character as defined by the Bureau of Land Management were examined. No mineral resources were identified, but anomalous gold, silver, and indicator element content of samples taken near Pinto Hot Springs indicate resources may exist. Lithium content of samples from near-surface sediments on the desert playa is too low for resources, out geologic conditions are favorable for higher concentrations at depth. Occurrences of zeolites are not considered to be of commercial interest. Approximately 27,000 acres are held under geothermal lease, and most of the WSA is of interest for oil and gas. No evaluation of these commodities was made by the Bureau of Mines

Jan 1, 1985

By A. Adams

The quality of hafnium metal produced by the Kroll process depends upon the purity of the hafnium tetrachloride. This investigation of methods for purification of hafnium tetrachloride was undertaken to aid in producing a higher purity hafnium metal than is currently produced by the Kroll process, The quantities of metallic impurities in hafnium metal were decreased by contact with molten alkali-metal chloride salt. Contact was achieved by a semicontinuous process of bubbling gaseous hafnium tetrachloride through a molten salt bath or by a batch process, first fusing the tetrachloride with a combination of alkali chlorides and then heating the mixture to sublime the hafnium tetrachloride. Low-melting mixtures of sodium, potassium, and lithium chlorides were used to purify hafnium tetrachloride. About 30 percent of the initial hafnium tetrachloride was trapped during purification with alkali- metal chloride salts. The 95-percent confidence limits (6)4 for the amount of oxygen decrease 60 and 34.3 parts per million when the batch purification is combined with a reduction so that both take place in the same equipment,

Jan 1, 1961

By David C. Scott

Between 1990 and 1991, the Bureau of Mines studied the mineral resources of the Kaibab National Forest to appraise the resources present and to determine the types of deposits, and their location. The study included a comprehensive literature search and a limited amount of field investigation of minerals and mining activity in and near the Forest. Small amounts of copper with lesser amounts of gold and silver have been produced from limestone-hosted, strata-bound deposits in the North Kaibab and Tusayan Ranger Districts. In addition to these small metallic deposits, volcanic cinders, pumice, flagstone, and sand and gravel have been quarried in the Chalendar and Williams Ranger Districts. At least ten uranium-mineralized breccia pipes have been identified in the Tusayan Ranger District, One of these, the Canyon pipe, contains a high-grade uranium ore body with associated silver, copper, lead, vanadium, and zinc. The mine permit for the Canyon pipe has been approved and the mine shaft head frame erected.

Jan 1, 1992

By George T. Faust, S. R. B. Cooke

"The Southern Experiment Station of the Bureau of Mines, United States Department of the Interior, in cooperation with the University of Alabama, is investigating the preparation of pulverized coal for fuel. In this study the relative amount of surface in various products and samples had to be assessed. Because of the familiarity with screens and because of the simplicity of using the inverse ratio of the opening for ascertaining the amount of relative surface in the respective sizes, screens down to and including 270-mesh were used. This choice was made in full cognizance of the irregularity of screens, but it seemed that if the same screens were used throughout all the tests the relative values would be satisfactory.In dealing with the subsieve sizes, pneumatic elutriation was used to make several fractions to extend the sizing analysis into the range of hypothetical screens. This kind of a sizing analysis was thought necessary because it is familiar to all operators, and, furthermore, it is amenable to several ways of plotting curves that bring out the characteristics of various coals and various methods of grinding.The method of obtaining the data from which to set up the hypothetical screen scale is the subject of this paper. It consists in determining the average projected area of the particles in the respective elutriated products. By extending the ""area method"" to sieve sizes, a factor is found that may be applied to the subsieve sizes, and thus the scale is projected in a regular manner. This method avoids contentions about specific surface and steers clear of ""average diameter"" except as material sized on screens may be said to have an average diameter."

Aug 1, 1939

By M. J. Ankeny

This is a study of 58 fatal haulage accidents investigated by Federal coal-mine inspectors during the period January - June 1951. The information presented in this circular was obtained by analyzing fatal haulage accidents in 33 bituminous-coal producing counties representing 11 States. The physical conditions represent a cross section off producing coal beds. Mining and transportation methods vary, from those of small hand-loading mines to those of large modern mechanized operations. These data are thought to be representative of haulage conditions within the bituminous-coal mining industry and are submitted to follow up the Information Circular 7604 ?Analysis of Haulage Fatalities in Bituminous-Coal Mines - 1950.? Coal-mine haulage ranks second as a cause of coal-mine fatalities, and the problem of haulage safety is complex. It is subject to constant change and is comprised of numerous influencing variables, which are not always obvious. The solution to this problem will not come through the application of any standard formula or mechanical approach since the inherent factors are strongly influenced by the human equation, and the chain of circumstances is further affected by expediency.

Jan 1, 1951

By R. Dell Davidson

This report contains the results of the work performed by Dayton T. Brown. Inc., Testing Laboratories, Bohemia, New York, under the Department of Interior, Bureau of Mines, Contract J0166089 entitled "Performance Testing of Air-Line Linking Components." The objectives of the program consisted of the following: 1. To conduct engineering tests that will provide data to recommend the performance criteria for air hose and piping connections. 2. To determine the requirements for restraining devices which are used to comply with MESA Health and Safety Standards 55, 56, 57,13-21.

Jan 1, 1978

By A. T. Iannacchione, D. G. Puglio

The Bureau of Mines established geologic factors affecting the mining of the Lower Kittanning coalbed to aid in coalbed minability studies and examined the occurrence of "wants" (places where coal is missing) and types of unstable roof rock strata. Trends established from mapping, including prediction of areas of high methane emissions, were extrapolated to unmined areas. "Wants" in the coalbed are of two types: Erosional and depositional. Erosional features occur where north-south-trending sand-filled channels cut into the coalbed. Variations in depositional environments have caused the coalbed to "split" into several thinner units. Slickensides, commonly indicative of unstable roof, are adjacent to and on the underside of sandstone channels; they were caused by differential compaction and by soft sediment sliding along the contact between the sandstone and adjacent shale. The frequency of unstable roof also increases where the interval between the Middle and Lower Kittanning coalbed is less than 30 feet. The zones of weakness at the contacts above and below the Middle Kittanning coalbed are the controlling factors for unstable roof in these strata. Methane emissions from the coalbed are controlled primarily by depth, fracture permeability, and rank of coal. Local geologic factors are coalbed thickness, associated rock strata, structure, and proximity to outcrop.

Jan 1, 1979

By F. N. Kissell, C. H. Elder, C. M. McCulloch

The applicability of the "direct method" for determining the methane content of virgin coalbeds was tested. Preliminary results indicate that the direct method, when applied to exploration cores, can be successfully used to estimate coalbed gas content and also approximately predict the total gas emission from a prospective mine located in the coalbed at the exploration site.

Jan 1, 1973

By Robert H. Merrill

Measurement of the deformation of a borehole in rock subjected to a change in applied stress can be used to calculate the magnitude and direction of the applied stress, provided a satisfactory deformation-applied stress relationship exists , In this investigation by the Bureau of Mines the deformation of a bore- hole in a rock model subjected to a known applied stress was compared with the theoretical deformation of a hole in an elastic, isotropic plate and was found to be in good agreement. Hence, this relationship can be used to calculate the applied stress on a borehole from borehole deformation measurements.

Jan 1, 1961

Lower workers' dust exposures during bag stacking while ergonomically improving the bag stacking process. Approach Install a new pallet loading dust control system which uses a push-pull ventilation technique along with a hydraulic lift table to control the pallet loading height throughout the entire loading cycle. How It Works A low-volume, high-velocity blower system operating at approximately at 120 cfm blows a stream of air over the top layer of bags on the pallet. The blower system is composed of two 3-inch air jets (approximately 1,200-ft/min velocity) directed toward an exhaust system on the opposite side of the pallet. As these air jets travel across the pallet, they en-train dust generated during bag stacking. The dust laden air is then captured by the exhaust ventilation system which draws approximately 2,500 cfm through an exhaust hood on the opposite side of the pallet.

Jan 1, 1989

By Lester G. Morrel

THE RICH and varied occurrences of metallic ores in Australia, extensive nickel deposits on New Caledonia and phosphate rock on several widely scattered small islands were important aspects of the economy of the South Pacific area. Relatively small quantities of gold and nonmetallic minerals produced in New Zealand, Fiji, and the Territory of Papua-New Guinea remained important to the domestic economies of these islands, but had little importance to overall world mineral supplies. The value of mineral commodities produced in this area in 1964 was estimated at $658 million,3 compared with $585 million in 1963. The year's greatest commodity gains were in bauxite and aluminum, beryl concentrate, manganese ore, nickel smelter products, tin, and coal. Annual increases were recorded in virtually all countries and possessions in the area except Papua-New Guinea, where the drop in output of alluvial gold accounted for a decline of about $160,000. Mineral industry activities in Australia overshadowed those in all other parts of the South Pacific in 1964. Outstanding developments were the sales contract negotiations and physical preparation for exploiting the rich iron ore discoveries in Western Australia, the initiation of domestic crude oil production, the commissioning of two new steal mills and an alumina refinery and a start on the new alumina-aluminum project based on Cape fork bauxite deposits. The principal mineral development in 1864 in New Zealand was the progress on plans of the Newzealand Steel Co. to use indigenous iron sans as the resource base for a local steel industry. In New Caledonia, additions and expansion of the nickel mining and smelting facilities continued throughout the year. Plans for extensive geophysical studies were announced by the Government Geological Departments of British Solomon Islands and Fiji.

Jan 1, 1966

By John Furness Park

This paper, which describes the mining methods and practices at the Jarbidge mines of the Elkoro Mines Co., is one of a series of papers being issued by the United States Bureau of Mines on mining methods and costs in various districts throughout the United States. LOCATION AND HISTORY The Elkoro Mines Co.'s property is located at Jarbidge in the northeast corner of the State of Nevada (fig. 1). The camp is 9 miles south of the Idaho line; the nearest railroad point is 70 miles to the northeast at Rogerson, Idaho. A road leading to the south and connecting with Deeth, Nev., is passable during the summer months; the heavy snowfall which generally takes place early in the winter usually closes the road until the first of July.

Jan 1, 1931

By T. H. Jeffers

The U.S. Bureau of Mines has developed porous beads containing immobilized biological materials such as sphagnum peat moss for extracting metal contaminants from waste waters. The beads, designated as BIO-FIX beads, have removed toxic metals from over 100 waters in laboratory tests. These waters include acid mine drainage (AMD) water from mining sites, metallurgical and chemical industry waste water, and contaminated ground water. Following the laboratory studies, cooperative field tests were conducted to evaluate the metal adsorption properties of the beads in column and low-maintenance circuits, determine bead stability in varied climatic situations, and demonstrate the beads' potential as a viable waste water treatment technique. Field results indicated that BIO-FIX beads readily adsorbed cadmium, lead, and other toxic metals from dilute waters; effluents frequently met drinking water standards and other discharge criteria. The beads exhibited excellent handling characteristics in both column and low-maintenance circuits, and continued to extract metal ions after repeated loading-elution cycles. Based on laboratory and field data, cost evaluations for using BIO-FIX technology to treat two AMD waters were prepared. Operating costs for BIO-FIX treatment, which ranged from $1.40 to $2.30 per 1,000 gal of water treated, were comparable with chemical precipitation costs.

Jan 1, 2010