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By P. M. Gruzensky

A survey of the literature has been made covering the extraction of bismuth from raw materials, its separation from lead, and its subsequent refining. The use of aqueous, nonaqueous, and fused electrolytes in electrolytic refining is reviewed. This literature survey has been prepared preliminary to some proposed investigations concerning the electrometallurgy of bismuth, and, although an effort has been made to cover a majority of the applicable references, a critical review was not attempted and no assertion is made that this manuscript is exhaustive in nature. Titles of publications in parenthesis are translations from the language in which the reference was originally published.

Jan 1, 1954

By Donald W. Scott

Chemical thermodynamic properties for the ideal gas state from 0 to 1500 K are tabulated for all of the alkane hydrocarbons through C10. These properties are based on correlations of the extant data for the entropy, vapor heat capacity, and enthalpy of formation of individual alkanes and the equilibrium constants of alkane isomerization reactions.

Jan 1, 1974

By Lee Blackman

The Malheur-Jordan Resource Areas (MJRA?s) is a tract of approximately 6.5 million acres of federal and non-federal land in the southeast corner of Oregon. This study evaluated the Resource Areas' economically recoverable mineral potential based on geological estimates provided in the USGS report (Smith, 1994). The mineral terranes are believed by geologists to contain undiscovered resources. The geological data is probabilistic; with estimates of the possible number of deposits and their grades and tonnages. Possible future development scenarios range from no development to numerous mines. Based on the analysis performed on these terranes, the most likely (in a statistical sense) future scenario for the resource areas would include the potential for two medium sized, predominately gold, mines. These would supply direct and indirect employment of up to about a thousand workers.

Jan 1, 1995

By C. I. Pierce

The Bureau of Mines used an electrolytic tank model to investigate the response of guard electrodes of different dimensions under different simulated reservoir conditions. Sandstone disks from the Berea and Connellsville Formations were used as resistive beds in the model, and agar gel or water was used as conductive beds. In the experiments, bed thickness, hole diameter, mud resistivity, and bed resistivity were varied. The guard electrode is an excellent tool for determining true bed resistivity in the thin-bedded oil reservoirs of the Appalachian area. Vertical resolution and resistivity values are good when there is little or no invasion. Resistivity values are near true bed resistivity in beds thicker than about six hole diameters when the electrode-to-hole-diameter ratio is close to 1. However, low-resistivity muds cause false peaks to appear on the logs near bed boundaries in thick beds, and for resistive beds having a thickness approximately three to five times the hole diameter, apparent resistivities tend to be excessively high when mud resistivity is low.

Jan 1, 1966

By R. E. Meaker

Electrical conductivities and densities of molten fluoride systems were measured as functions of the melt temperature and composition. For any given mixture, the two properties change linearly with temperature. Three alkali metal fluorides were selected as solvents for melts of the type LiF-, NaF-, and KF-MFx, where M is a metal selected from the alkali metal or alkaline earth groups, or from the lanthanide or actinide series of elements, and x = 1-4. Heats of activation for conductance were calculated from the experimental data and varied from 2.3 to 9.2 kcal/mole at 1,000° C. Some relation between position in the phase diagram and the conductivity changes was suggested.

Jan 1, 1971

By William K. Tolley

The U.S. Bureau of Mines (USBM) is investigating hydrometallurgical processing techniques to recycle metals from semiconductors and other advanced materials. Cadmium and tellurium were recovered from mixed CdTe/CdS scrap produced in the manufacture of thin-film photovoltaic devices. Selective cadmium dissolution was achieved using oxygen-pressure leaching in dilute sulfuric acid. Leaching the scrap for 90 min at 110° C in 2.2NH2S04 under 400 psig 02 yielded 97% Cd extraction; however, cadmium content of the residue ranged between 4% and 7%. Soluble iron was added to the lixiviant to catalyze oxidation of the CdS component. Tellurium and sulfur remained in the leach residue primarily in the elemental form. The iron and tellurium were removed from the cadmium-rich leach liquor by adjusting the pH to 5.3. The cadmium was recovered as cadmium sulfate crystals by evaporating the solution. Alternative leaching and purification schemes are discussed.

Jan 1, 2010

By A. A. Sonnek

A simple, portable helium analyzer was developed primarily for field use. Its utility lies in making preliminary surveys before exact analyses are required. The analyzer is based upon chromatographic principles; that is, separation of gas mixtures resulting from variable retention times of the components with respect to a separation medium (column-packing material). It uses thermistors for sensing detectors, a dry battery as source of power, and a micro-ammeter for indicating helium concentration. The absolute accuracy of the instrument depends upon the recency and care with which the instrument is calibrated with a standard gas. The unknown gas should be analyzed immediately after calibration, and another calibration should be made before another unknown sample is analyzed. The instrument is simple to operate, requiring approximately 15 minutes, after calibration, to determine the helium content of a natural gas sample. Although developed primarily for helium determination, the analyzer possibly can be used for other analyses that can be performed at ambient temperatures.

Jan 1, 1965

By John B. Gayle

The suitability of fluid petroleum coke as a blending agent for producing metallurgical coke has been investigated using the Tuscaloosa and sole-heated experimental ovens. From the results of tests with three representative blends, it has been fond that additions of fluid petroleum coke effect the following changes: (1) Increase in size, resistance to shatter, and apparent specific gravity of cokes produced; (2) little or no change in coke hardness and stability or in the amount of breeze formed; (3) increased charge density; (4) modification of expansion characteristics of blends charged; and (5) decreased ash and increased sulfur contents of blends charged and cokes produced. Substitution of a calcined sample of fluid coke of greatly reduced sulfur content resulted in a coke of inferior physical properties. This effect indicates that additions of the calcined product should probably be limited and that other methods for producing a low sulfur fluid coke should be considered.

Jan 1, 1956

By Harry Perry, Mary S. Esfandiary

This is a revision of a directory of coal research organizations throughout the world that was first published in 1961 as Bureau of Mines Information Circular 8008. Because of the wide acceptance of the first edition , a revision which would supply up- to - date information on coal research and which would facilitate communication among organizations of similar interest seemed important . This compilation includes the names and activities of organizations of various types -government , university , private , and industry . The areas of investigation that each organization is engaged in are indicated in broad terms : Analysis and constitution , mining and geology , preparation , briquetting , combustion , high- and low-temperature carbonization , gasification , conversion to solid and liquid fuels , and health and safety . Publications issued by and describing the work of each organization are cited ; almost all of the organizations also publish results of their investigations in the technical press . Selected technical and trade publications that publish information on the science and technology of coal and are not published directly by any of the organizations listed are cited in the pages following the list of organizations in each country . Information that would improve coverage and accuracy of the next revision of the publication will be welcomed by the Bureau of Mines .

Jan 1, 1966

By Robert M. Doerr

The oxidation kinetics of Ni-Y alloys in the range 0.04 to 8 weight-percent Y, and of high-purity Ni, were compared by the use of a sensitive volumetric apparatus. The reactions followed approximately the parabolic rate law; for oxidations in 02 at 0.5 atm and 1,200° C, the parabolic rate constant was about 0.37 + (0.064) (Y-2.11) mg cm-2 min-1/2, where Y represents the weight-percent Y in the alloy. Internal oxidation of Y occurred in the alloy specimens and the resultant Y203 particles, which were in patterns related to the eutectic structure of the alloys, served as markers showing that the subsequent oxidation of the surrounding Ni was by inward diffusion of O. The scale consisted in each case of NiO, but the inner parts of the scale on the alloy specimens included the patterned Y203 particles. The thicknesses of the inner parts of the scale depended directly on the Y concentration, and the thicknesses of the Y2O3-free outer parts of the scale were inversely related to the Y content of the alloys. There is thus a relationship between the thickness of the outer part of the scale and the protectivity of the scale. Outward diffusion of Ni and inward movement of 0, from the inner boundary of the Y2O3-free part of the scale, is proposed as a mechanism for these results.

Jan 1, 1966

This Bureau of Mines report on underground mine communications addresses methods and equipment to meet the communication requirements of working sections and places of coal and metal-nonmetal mines. A review of the status of trapped miner detection is also presented.

Jan 1, 1977

By D. Bienstock

A rig was constructed to burn 100 to 125 lb of coal per hour at 4,000° F in a cyclone burner with oxygen-enriched air preheated to 1,500° F to ascertain the problems in the coal-fired MHD generation of power. Potassium carbonate was added to the coal at several concentrations up to 1.23 g-moles/kg of coal (17 lb K2C03/100 lb coal). Boiler-tube materials maintained at wall temperatures of 800° to 1,500° F were exposed to the combustion effluent of 1,800° to 2,500° F. Practically complete removal of sulfur dioxide from the stack gas was achieved with the seed addition. Nitric oxide formation followed theoretical expectations at combustion temperatures with some decomposition of the NO occurring as the gas cooled flowing through the system. Nitrates in the fly ash were less than 1.7 percent of the total fixed nitrogen. With aqueous extraction of the fly ash a maximum recovery of 75 percent of the potassium was obtained. Haynes 25 was unattacked at a wall temperature of 1,500° F in combustion gas at 2,500° F; the stainless steels 310, 316, and 446 were resist-ant at a metal temperature of 1,100° F in gas at 2,100° F.

Jan 1, 1970

By Walter E. Lewis

This circular presents the method of making tests and apparent results of comparing performance of tungsten carbide insert bits and steel detachable bits by the Cleveland-Cliffs Iron Co. at the company's mines on the Marquette iron range of Michigan. The mines are at Ishpeming and Negaunee, Mich., and include the Cliffs Chaft, Mather "A", Cambria-Jackson, and Mather "B". There are four general characteristic types of high-grade iron ore on the Marquette range. B. H. Boyum2/ classifies the Cliffs Shaft as "hard-ore" and the Cambria-Jackson and Mather "A" as "soft-ore" types of deposit. Shaft sinking through Jasper, slate, and graywacke was in progress at this writing at the Mather "B", with completion at 3,100-foot depth in August 1949. The many different kinds of rock and ore at the mines of the Cleveland- Cliffs Iron Co. and the experimental work being carried on with carbide in- sert bits make it possible to compare, generally, the carbide insert and steel detachable bit. The type of "hard ore" at the Cliffs Shaft mine re- quired close study of the possible use of the insert tit, and their records are more complete than those of the "soft-ore" mines. History and development of tungsten carbide tips inserted in rock drill bits have been covered by R. W. Adamson, C. H. Vivian, R. C. Sullivan,5/ and others. Tungsten carbide insert rock bits have only recently been introduced to the domestic mining industry. Although unusual performance records are being reported at operations employing the insert bits, the general adaptability of the tool to all rock types and the advantages to be gained by using carbide insert tits remains to be demonstrated. Insert-bit performance is being observed at numerous mines and quarries throughout the United States The several mining operations at the Cleveland-Cliffs Iron Co. at Ishpeming, Mich., is one site where exhaustive comparative tests of insert and conventional steel detachable bits are currently in progress. Results to date are sufficiently impressive to be of general interest to the mining

Mar 1, 1950

By Lloyd Carpenter

Eighteen elements were determined spectrochemically in vanadium metal and its compounds in the general range of 1 to 1,000 ppm by means of spark-ignited unidirectional arc excitation. The samples were converted to vanadium pentoxide and combined with a mixture of graphite, lithium carbonate, and gallium oxide. For the molybdenum determination, the oxidized samples were mixed with sodium chloride and packed in copper electrodes. Average precision of the method was 15.6 percent relative standard deviation and relative error was 4.4 percent.

Jan 1, 1963

By Nicholls Harry R.

The Bureau of Mines studied the effect of varying the, diameter of explosive charges on the generation and propagation of strain waves. The parameters compared were strain amplitude, impulse, energy, and pulse shape. Three different explosives were detonated in three different charge diameters. Charges of cast 50/50 pentolite-detonated at the same velocity in 5-, 2.5-, and 1.5-inch diameters. Charges of ammonium nitrate-fuel oil prills and 45-percent semigelatin dynamite showed a strong detonation rate-diameter dependency. Detonation of these two explosives was considered nonideal. Differences in the diameter of the charge caused less difference in the strain-generating abilities of pentolite than in those of the other two explosives. This was also true for impulse and energy. Rise and fall times of the strain pulses for all three explosives were proportional to detonation time and cavity volume, respectively.

Jan 1, 1966

By Van E. Shaw

Three comparatively simple, efficient, and rapid extraction methods for the dissolution of yttrium and rare-earth elements from a euxenite carbonate residue have been developed, using dilute sulfuric acid as the solvent. Extraction processes have resulted in yields of 98+ percent of the total rare-earth elements and yttrium contained in the residue and have given preliminary separation between the cerium-group and the yttrium-group rare-earth elements. Extraction procedures presented are: Procedure 1. -The recovery of total rare-earth elements and yttrium by a cold dilute sulfuric acid leach at a pH of 2.5. Procedure 2. -The recovery of yttrium and yttrium-group rare-earth elements by leaching with dilute sulfuric acid at 125° F. and a pH of 3.0, with subsequent recovery of the cerium-group rare-earth elements by a cold dilute sulfuric acid leach of the residue at a pH of 2.5. Procedure 3. -The recovery of the total rare-earth elements and yttrium by fractional leaching as in procedure 1, followed by boiling the sulfate solution, which precipitates the cerium-group rare-earth elements and leaves the yttrium-group rare-earth elements in solution.

Jan 1, 1959

By Donald W. Mitchell, John Nagy, Edwin M. Murphy

To increase safety and productivity in mining , the potential uses and hazards of rigid foam were investigated by the Bureau of Mines Experimental Coal Mine . This research resulted in the development of chemical formulations , spraying equipment , and application procedures that permit safe and effective use of urethane foams for improving mine ventilation , for reducing weathering of mine rock and steel , for constructing seals in fire areas , and for thermal insulation .

Jan 1, 1964

? CAGER, CAGE RIDER, CAGE TENDER, SHAFT MEN All of the above job titles are variously associated with the handling of men and material at hoist stations. Generally, these classifications of personnel are involved with riding cages with personnel and in hoisting supplies into the mine. Job titles and activity description will be defined in the respective chapters. ? FLOW CHART SYMBOLS [Vertical Transportation Horizontal Transportation Storage Operation Delay ]

Jan 1, 1975

By G. M. Potter

During the investigation of the occurrence of manganese deposits in the western United States, examining engineers of the Bureau of Mines collected samples from four properties in Siskiyou and Mendocino Counties northern California. As the ores were too low-grade to be acceptable to manufacturers of ferromanganese, beneficiation studies were made between 1941 and 1945 to determine the amenability of the ores to concentration. The Johnson and Reynolds properties are near Fort Jones Siskiyou County. The ore occurs in a number of small lenses in that area. Samples were taken for testing for amenability to treatment in a small custom-gravity plant, tentatively planned. by the Waiter Johnson interests of San Francisco. A 2-ton representative sample was obtained from numerous exposed portions of an outcrop on the property of the Mayland Mining Co. The Mayland mine is about 8 miles from Sawyers Bar in Siskiyou County. The ore body consists of stringers and irregular masses of oxide, and. silicate ore scattered through quartz, which these minerals have replaced.

Jan 1, 1952

By F. S. Crawford

It has been said that safety promotion passes through four stages--the band-playing, the machine-guarding, the protective equipment, and finally the educational stage; the last is the most important in the development of the safety program. It has been estimated that only 15 percent of accidents can be pre- vented by machine guarding and protective equipment; the other 85 percent must be stopped by the safety efforts of the individual workers and their supervisory officials, and one of the fundamentals of safety work is the education of workers to develop safety consciousness or safety mindedness. One way of educating men to think about safety is by the use of posters. Safety engineers at the Calumet 2 Hecla mines in Michigan have been conduct- ing a safety contest among the men by the use of posters of an unusual type in addition to those usually employed to illustrate bad practices and to display the number of days without a lost-time accident. The first requisite for the success of the safety poster is a good artist or draftsman; in the poster contest instituted at the Calumet & Hecla mines two sheets were prepared illustrating various conditions in the slope workings, including a large number of unsafe practices. The object of the contest was to get the men to think about safety through criticism of the unsafe conditions displayed on the posters. The following notice accom- panied the posters:

Feb 1, 1935