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By W. M. Deaton

The formation of gas hydrates in natural-gas pipe lines depends on temperature and pressure conditions in the lines as well as on the presence of condensed water. The operating pressure in a pipe line may be determined easily and usually is available from the records of operation, but the temperature seldom is known. In cooperation with the American Gas Association, the Bureau of Mines, in its investigation of gas hydrates, conducted a pipe-line-temperature survey and studied underground temperatures at depths at which pipe lines ordinarily are buried and the relationship of these temperatures to prevailing atmospheric conditions. A similar but mere limited study of this type was conducted by engineers of the Bureau of Mines a number of yours ago.4/ A summary of the earlier findings was included in a general report by the Bureau on the flew of natural gas through high-pressure transmission lines.5/ In the present study, data on temperature variations were obtained at several places widely separated geographically. This information should assist pipe-line engineers in designing and operating natural-gas pipe lines.

Jan 1, 1941

By Shail J. Butani

In 1986, the Bureau of Mines conducted a probability sample survey, Mining Industry Population Survey, to measure such employee characteristics as occupation; principal equipment operated; work location at the mine; present job, present company, and total mining experience; job-related training during the last 2 yr; age; sex; race; and education. The population estimates are necessary to properly analyze the Mine Safety and Health Administration (MSHA) injury (includes illness and fatality data) statistics; that is, to compare and contrast injury rates for various subpopulations in order to identify those groups that are exhibiting higher than average injury rates. This report uses the survey's results to characterize the U.S. coal mining workforce from March through September 1986. A companion report, Information Circular (IC) 9193, "Characterization of the 1935 Metal and Nonmetal Mining Workforce:' provides similar information for the U.S metal and nonmetal mining industry.

Jan 1, 1988

By Normal Seidle

This report (rind related Appendices) provides a description of the functional design specifications and related rationale for development of a training system for dragline equipment operators. Phase I activities involved a delineation and detailed analysis of specific behavioral requirements for successful dragline operation. Following the field data collection effort, job/activity/task descriptions were formulated into training requirements which can be achieved by a trainee with training hardware having specific functional capabilities. The training system analysis integrated the training requirements and the trainer functional capabilities into recommendations which configure a total training system. The objective of the training system described in this report is to provide new operators of dragline equipment with the requisite skills and knowledge to assure cost-effective development and an adequate supply of our human resources.

Jan 1, 1975

By Ernest E. Berger

"INTRODUCTIONOne of the outstanding problems in the normetallic industries, and one which involves two of the greatest of these industries, cement and gypsum, is the reaction of Portland cement with calcium sulphate. To all Portland cement clinker there is added in the manufacturing process, a small amount of retarder, as a necessary ingredient of the finished product. This retards the initial set, increases the strength, and adds to the plasticity of the cement so it will have the desired working and setting qualities. The retarder commonly used is gypsum, (CaSOA.2HO), which is the hydrous form calcium sulphate. Calcium sulphate is also available as plaster of Paris (CaSO4 1/2 HC) and anhydrite (CaSO4). The purpose of this inquiry was to determine the form or mixture of forms best adapted for retarder. The problem is complicated by the fact that cement clinker is a complex mixture of calcium silicates and aluminates, and that clinker from different mills, making cement of approximately equal quality, differs considerably in chemical constitution. Thus the same retarder may give very different results with different types of clinker, especially in the percentage of retarder required for the same degree of retardation.It has been known for some time that a small percentage of plaster of Paris will greatly retard the time of set of Portland cement as well as increase its strength and plasticity, but whether gypsum and anhydrite will have a similar effect is as such disputed question. The offects of gypsum have received little consideration in laboratory research because, even though it will not retard a clinker when the two are mixed in the laboratory, as has been noted in some instances, the cement will have a normal set when the two arc mixed in the large tube mill at the plant, so that practically, gypsum seems to be equally as goou as plaster of Paris, and because of the great saving in cost it has been used almost exclusively."

Sep 1, 1925

By Stanley K. Haines

This Bureau of Mines publication comprises 19 tables of data concerning domestic barite production and consumption, imports, and world production for the years 1880 to 1976. Barite is vital to the petroleum industry, with 90 percent of domestic consumption used in drilling muds. Domestic production has traditionally fallen short of consumption: in 1976, 41 percent of the 2.2 million tons consumed was imported. World production of barite increased from 269,000 tons in 1923 to 5.2 million tons in 1975 but is in danger of falling short of future demand. The compiled data provide a comprehensive base of information.

Jan 1, 1978

By Thomas E. Finch

This report is an engineering-economic evaluation of alternate methods of handling the parting between two coal seams. It consists of evaluations of parting stowing techniques applicable in a representative, thick seam western United States mine. Methods are examined for their potential implementation, and an estimated operating cost per yard of material moved is developed. The methods are of two categories castback or haulback. Haulback methods use truck haulage except With scrapers, and the castback methods are a direct stowage with no intermediate haulage equipment. Possible equipment combinations include draglines, shovels, hydraulic backhoes, bucket wheel excavators, scrapers, and front end loaders. The purpose of this report is to evaluate the effective competetiveness of the various alternatives.

Jan 1, 1975

By Kihong Park, Matthews C. Habjan, Arthur L. Miller

New Mining Safety and Health Administration (MSHA) regulations limit the mass concentration of airborne diesel particulate matter (DPM) or, more specifically, the concentration of elemental carbon (EC), in underground mines. The mine operators are responding by introducing a variety of controls to reduce DPM in the mines, potentially including the evaluation of new maintenance procedures to reduce underground mine vehicle emissions. There is currently a lack of an inexpensive and dependable method to directly measure the DPM concentration emitted from the vehicle tailpipe. To that end, this work demonstrated a simple field portable method for estimating the mass concentration of elemental carbon exiting the tailpipe of a diesel engine using a direct reading photometer. Simultaneous measurements of tailpipe exhaust were made with a Thermo Electron Personal DataRAM 1200 photometer (particulate mass concentration based on light scattering) and by analyzing PM2.5 and PM1.0 samples collected on quartz fiber filters using the National Institute of Occupational Safety and Health (NIOSH) method 5040 (mass concentration of EC via thermal-optical method). Results indicate surprisingly good correlation (R2 ) 0.97) of the two methods when the data are adjusted for relative humidity (RH) and corrected using an empirically generated calibration factor. Although preliminary, it may be possible to implement this method in maintenance shops to monitor emission trends and to compare emissions of various vehicles in a fleet. Such data will be useful for fleet planning to meet new air quality standards.

By L. R. Herrmann

The research described in this report is the first phase of a comprehensive program for the development of a characterization for the structural properties of rock masses. The mathematical expression of the characterization is especial' tailored for use in conjunction with modern structural analysis procedures. The objective of the first phase of the project is to determine the feasibility of representing the structural properties of rock masses in terms of the analysis of an appropriate "representative volume" the results of this investigation are described in detail in the body of the report. The current state-of-the-art concerning the understanding and description of the fundamental mechanisms of rock behavior are determined from a survey of existing literature. The development of a representative volume that captures the most important of these mechanisms is described, In order not to unduly obscure the fundamental aspects of this development, the mathematical analysis of the representative volume is limited to plane strain conditions. A subroutine for the numerical evaluation of the proposed model (i.e., the analysis of the representative volume) is presented. The steps necessary for the incorporation of the subroutine directly into existing two-dimensional finite element structural analysis programs are described. Comparisons between the predictions of the proposed characterization and published results of simple laboratory tests are presented and discussed. Finally recommendations are given concerning suggested improvements of the model and the extension of it to the general three-dimensional case.

Jan 1, 1974

By L. F. Heising

This report is a general summary of pertinent data on the manufacture and use of synthetic ammonia products. It provides a condensed summary of the potentialities of a synthetic ammonia industry in North Dakota for Federal, State, and private organizations that may be interested in helping to develop an integrates synthetic ammonia and fertilizer industry. The report contains discussions of: (1) Materials used in the manufacture of nitrogenous fertilizers, nitric acid, and urea; (2) National production, imports, exports, and consumption; (3) the ammonia industry, location, capacity of plants; (4) processes used in manufacturing synthetic ammonia, nitric acid, and urea; (5) other potential industries; and (6) analyses of manufaturing and plant cosh;. Additional information on industrial compounds from ammonia and plant nutrients removed by crops is given in Appendixes 1 and 2. Synthetic ammonia is one of the primary ingredients in fertilizers. Resources required in synthetic ammonia manufacture are available in North Dakota. Hydrogen is available from the petroleum and natural gas resources, particularly in the Williston Basin, and from the large lignite resources in the State. Hydrogen can be produced from lignite by a gasification process developed by the Bureau of Mines at Grand Forks, N. Dak.

Jan 1, 1954

By J. D. Dixon

This Bureau of Mines report describes the results of an investigation for developing and applying procedures for stabilizing excavations openings in highly yielding ground. The approach developed in this report involves nonlinear modeling of the progressive relaxation of the zones of rock mass around the excavations opening where Coulomb criterion of failure is exceeded. Stresses are calculated by using a computer code; Coulomb-failure condition is examined for both intact rock and joints (using strength parameters [~] and c). The rock mass in the failed zones is relaxed by reducing the Young's modulus of the rock based on an empirical formulation that is a function of the shape of the opening and the extent of the failed zone. In addition, the material in the failed zone is assigned reduced strength paramters 0' and c'. The limiting (or convergent) relaxed zone is obtained through an iterative process by manually changing the rock modulus and the strength parameters between iterations. Support pressures are computed by applying forces normal to the excavation surface. The approach is applied to the analysis of stability and support requirements for an entry in a longwall coal mine.

Jan 1, 1985

By K. L. Paciorek

The aim of the present study is to determine on a gram per gram basis the toxic products of the thermal oxidative degradations of selected compositions. Four families of materials were investigated under the subject contract namely polyvinyl chloride and neoprene compositions, rigid urethane foams I and woods. Three methods were employed to conduct the thermal oxidative degradations: a sealed system (quiescent environment) I a stagnation burner arrangement (dynamic environment) I and a flow-through apparatus (dynamic I but less severe than stagnation burner conditions). The majority of tests were conducted using the first two systems; only limited experiments were carried out employing the third decomposition procedure. All decomposition was done at temperatures of 370 -4000C I the higher temperature being used in the stagnation burner. It has to be stressed that the nature of the products and the relative product concentration are temperature dependent. Thermogravimetric and differential thermal analyses were performed to supplement and extend the above delineated studies and to explore the feasibility of using these analyses as a method for material differentiation.

Jan 1, 1973

By G. P. Houston

This is the final, report submitted for the Contract No. H0220002 with the U. S. Bureau of Mines for the design and development of a Permissible Automatic Data Acquisition System (PADAS) to measure and record roof stresses in underground mines Basically the PADAS is a portable, battery powered, 24-channel data acquisition system designed for safe unattended operation of up to 30 days duration in explosive environments. The unit will accommodate twenty-four pressure transducers or eight borehole deformation gages (or any combination) at distances up to 300 feet from the PADAS to measure pressures up to 10, 000 psig. All 24 channels as a selected group are scanned sequentially at one of several selectable rates.

Jan 1, 1973

By John H. Johnson

This report covers research which is directed toward the measurement and control of underground mine diesel emissions. The report consists of three separate reports presented as Sections 1, 2, and 3. Section 1 "Emissions Measurement Apparatus" (EMA 1) discusses the selection and evaluation of instruments and procedures to be used as part of a diesel tailpipe emissions dilution and measurement apparatus. The instruments selected for gaseous pollutants are the Energetics Science Inc.* E.S.I.) 2000 for CO, the E.S.I. 7000 for NO and N02, and the Fuji ZFP5 for C02. Particulate matter is presently measured with the Celesco 1013 Smoke Opacity Meter. The raw exhaust concentration of one of these constituents is used Lo calculate the dilution ratio. Either a modified high range E.S.I. 2000 CO instrument or a Daco Products Cobra C02 instrument can be used, but neither is totally satisfactory. The study also indicated that it may he possible to increase the sample collection time from 15 seconds to the total 30 seconds over which the engine can be loaded without increasing the probability of damaging the vehicle hydraulic systems. Section 2 "The Effect of Fuels, Catalysts and a Filter Trap on Drift Pollutant Concentrations" discusses research in the Mine Air Quality Laboratory. A Wagner ST5D LHD with a Deutz F8L714 engine was used to compare three exhaust aftertreatment devices and a muffler-only system. The effect of these four systems on CO, C02, NO and N02 and on total, soluble, sulfate, and solid particulate matter was measured in the drift and on the LHD. The filter trap successfully reduced particulate matter for both fuels without significantly increasing the concentrations of any of the other constituents. The PTX catalyst was effective in reducing CO, and soluble particulate, but significantly increased N02 and solid and sulfate particulate matter. The Oxy Cat catalyst tested didn't seem to he working on the gases, and it significantly increased sulfate, soluble arid solid particulate concentrations. Section 3 "Diesel/Coal Particulate Matter Characterization by Laser Raman Spectroscopy" covers basic research on a method for determining the percentage by weight of diesel particulate on a filter containing a diesel-coal mixture. Signal-averaged Raman spectra provide the necessary precision. The method developed is non-destructive and uses as-received filters requiring no sample manipulation. Particulate with diesel contents in the range of 10 to 50% by weight have been analyzed with accuracies better than 6%t of the mean value. A number of samples containing diesel-coal mixtures were characterized by the procedures developed and the results are analyzed in light of various spectral and other system variables including coal rank and form and diesel engine operating conditions.

Jan 1, 1982

By Harold A. Watson

A method for measuring leakage of vapors into a chemical-cartridge half-mask facepiece during simulated use is described. The respirator, fitted with high efficiency cartridges, is worn in a dichlorodifluoromethane (CC12F2)--air test mixture while a series of timed activities (facial movements, varied breathing, exercise, etc.) is performed. Complementing other tightness tests, this method is useful particularly for studying face fit and the effect of facial movements on leakage. The concentration of CC12F2 within the facepiece is monitored continuously to observe the immediate effect of physical activity on leakage. A composite sample is collected simultaneously in a plastic bag as a measure of average leakage during the 18-minute test period. Leakage, reported as percent, is calculated from the concentrations of CC12F2 within the facepiece and in the test atmosphere.

Jan 1, 1970

By J. Torma-Krajewski, C. Hipes

Although many mining companies apply ergonomic principles, it is usually done either informally and/or reactively. An example of an informal approach is replacing worn equipment (such as seats) with models that have ergonomic features. Another example is modifying a task to eliminate safety hazards. Such approaches reduce risk-factor exposures that can lead to musculoskeletal disorders (MSDs). A reactive approach is followed when modifying a task/ equipment after an MSD occurs. However, neither of these approaches involves a systematic method of proactively applying ergonomic principles to actually prevent injuries or illnesses. This paper discusses how Vulcan Materials Company applied ergonomic principles and implemented interventions to reduce risk-factor exposures.

Three complete connector assemblies and ten separate contacts were submitted to a series of tests to establish the connector permissibility and compliance with the Bureau of Mines' research Contract H 0110423. Test Procedure TPC-0100 was coordinated, and the test plan approved by the Bureau as fully complying with the intent of the contract for the low voltage, medium voltage and high voltage A.C. connectors. The components and connector assemblies have been demonstrated in testing that they meet or exceed all the requirements of the test procedure.

Jan 1, 1972

By J. L. Holman

The Bureau of Mines, at its Rolla Metallurgy Research Center, has devised methods for separating and reusing the major portion of waste plastics discarded in urban and industrial refuse. Waste plastic concentrates from a local collection drive, recycling center collections, urban refuse pilot plants, and the secondary metals industry were separated into three major thermoplastic families--polyolefins, styrenes, and vinyls--based on differences in density using a Bureau-designed sink-float-elutriation hydraulic separator. Other separation methods and systems such as air classification, jigging, liquid media, screening, and electrostatics were studied. Vinyl plastics contain up to 50 percent HC1. It was found that over 90 percent of the HC1 in vinyls can be recovered as usable hydrochloric acid by pyrolysis at 350° C. The remaining pyrolysis products which had heats of combustion in excess of 12,000 Btu/lb, could become valuable as a future source of energy. A characterization study conducted on eight chopped wire insulation wastes from secondary copper and aluminum processors showed that most wastes contained 2 to 7 percent residual metal and large percentages of vinyl. The residual metal content of some of these wastes was lowered to 0.1 percent and the vinyl portion segregated using various separation techniques. The research also suggests ways in which reclaimed thermoplastics may be fabricated into useful products.

Jan 1, 1974

By Claude W. Sill

In the usual volumetric determination of uranium, the solution containing uranium is reduced in a Jones reductor, yielding a mixture of trivalent and tetravalent uranium; the trivalent uranium is oxidized to the tetravalent state by bubbling a stream of air through the solution. The resulting solution of. Tetravalent uranium is titrated with a standard oxidant, generally sulfatoceric acid, dichromate, or permanganate; It seemed likely that the, same general procedure could be used in determining semimicro quantities of uranium if the conditions affecting the variables involved were understood more clearly than at present. In the method described below, the use of ferric sulfate to oxidize tetravalent uranium allows the titration to be made at room temperature in an essentially colorless solution with sulfatoceric acid. The latter oxidant its turn permits the use of the very stable indicator, ferroin, with its sharp color.., change and exactly reproducible blanks. Solutions of uranyl sulfate were prepared by diluting a stock solution that had been standardized gravimetrically according to the method of Lundell and Knowles (8).3/ Solutions of sulfatoceric acid were prepared according to the directions of G. F. Smith (12) and were standardized against arsenic trioxide in the presence of osmic acid according to the directions of Gleu. The cerium solutions were stored in 18-liter carboys fitted with siphon arrangements so that the bottles did not need to be opened and protected from light in a dark cupboard. Under these conditions, even the 0.01 N solution changed by less than 1 part per thousand over a period of about 6 months.

Jan 1, 1952

By Frank C. Townsend

Centrifugal model embankments with varying geometries and materials were constructed of- coal waste material, accelerated From 100 to 120 times earth's gravity, and subjected to various throughflow rates until failure occurred. Complementary laboratory tests were performed on the waste materials to obtain strength and permeability parameters for analytical calculations to predict observed centrifugal model behavior. Failures in the form of deep.-seated failure, or erosion and sediment transport or a combination of both, occurred in model embankments with 1V:1-1/2H and 1V:2H slopes when the phreatic surface due to seepage exited on the downstream slope: Positive seepage control, i.e., a toe drain successfully prevented sloughing and failures. Slope stability analyses agreed well, albeit conservatively, with observed model performance. Factors of safety ranged from 0.7 to 1.02 at the instant of failure for models with retrogressing slips as compared with 1.05 to 1.7 for stable embankments, These models verified existing criteria of a minimum safety factor of 1 3 and the necessity of positive seepage control.

Jan 1, 1980

By F. Fraas, J. E. Conley

"The problem of recovering potash from the mineral polyhalite (K2SO4.MgSO4.2CaSO4.2H2O), occurring in large quantities in the salt beds of Texas and New Mexico, has been under investigation at the Nonmetallic Minerals Experiment Station of the U. S. Bureau of Mines continuously since 1928. Most of the results previously obtained have been published in technical journals and in a series of Bureau of Mines Reports of Investigations.The experiments described in the present report were performed to ascertain whether a continuous countercurrent extraction of calcined polyhalite by hot water would yield satisfactory recoveries and concentrations of sium sulphate in the top liquor. Previous investigation by Storch 4 had shown that the rate of solution of uncalcined polyhalite was too slow to be of value in an industrial process, and Storch and Clarke 5 had demonstrated that calcination of the polyhalite greatly, accelerated the rate of solution in hot water, allowing most of the potassium sulphate to be readily extracted."

Sep 1, 1933