Search Documents

By Wei Sun, Xue-feng Cao, Lei Sun, Run-qing Liu

The flotation performance of kaolinite in laboratory micro-flotation was investigated with 3- (dodecyloxy) propan-1-amine (ON12) as the collector. Compared with dode cylamine (DDA), which is commonly used as the bauxite reverse flotation collector, ON12 shows stronger collecting ability for kaolinite than using the same amounts of DDA, when experimental pH value reaches more than 6. With the addition of ON12, the isoelectric point of kaolinite shifts to 6.1 from 3.6, which suggests a strong adsorption between kaolinite and ON12. Infrared spectra analysis indicates that the type of ON12 adsorbed on the kaolinite surface is mainly of electrostatic adsorption. Molecular dynamics simulation further indicate that electrostatic adsorption of ON12 cation on kaolinite (001) surface based on electrostatic interaction between NH4+ and O atoms. ON12 will be suitable for bauxite reverse flotation with the efficiency depressors of the diaspora.

Jan 1, 2014

By A. Gueciouer, A. Akkouche, K. Chalah, A. Benmounah

"Drilling solid waste is a typical industrial solid waste, and it is a major pollutant source to ecological environment. Generally, waste management dewatering systems separate solids and fine particles from the liquid phase of drilling fluid, thereby leaving a clarified aqueous solution and allow the cleaning of waste fluids. Typically, dewatering waste management systems clean drilling fluid through coagulation, flocculation and/or mechanical separation. Chemicals used in dewatering are based on the coagulation-flocculation process, which it facilitate the removal of suspended solids and colloidal particles. The factors which can promote the coagulation-flocculation are velocity gradient, contact time, and PH. The objective of this work is to optimize a formulation adequate for dewatering based on the coagulation-flocculation process used coagulant (Aluminum sulphate), anionic flocculants (Partially Hydrolyzed Polyacrylamide) and anionic polyelectrolytes (in solid form with linear chain with very high molecular weight). The results obtained show the good efficiency of the coagulant and flocculants. INTRODUCTION Rig site dewatering of drilling fluids with recycling of processed water can help an operator to comply with environmental rules by reducing volumes of waste and reducing long term liabilities. It can also reduce disposal costs and provide a cleaner drill site overall. Most of the environmental concerns during the 1980s involved hazardous materials and toxic wastes. Drilling fluids, many of which are chemically benign, have escaped many of the difficult-to-comply-with rules and regulations. During the 1990s, however, operators may be required to submit a written plan for liquid waste reduction for even nonhazardous materials. Many states and local agencies may institute total bans on oil field wastes. Drilling rigs typically produce about 1 bbl of liquid waste for every 1 ft of hole drilled. Thus, a typical drilling operation can produce a large quantity of waste [1]. To improve the dewaterability of sludge, different pretreatment processes have been widely studied and developed including thermal, chemical, magnetic, mechanical, acoustic, electric, electro-acoustic and their hybrid treatment processes [2]. Rig site dewatering (figure 1) is the process of injecting coagulants or flocculating chemicals into the mud entering a large clarifying centrifuge. Coagulation occurs when the solid and allowing it to be attracted to other solids by van der waals forces. Flocculation is the binding of individual solid particles into aggregates of multiple particles. It is physical, rather than electrical, and occurs when one segment of a flocculating polymer chain absorbs simultaneously onto more than one particle [3]."

Jan 1, 2018

By A. J. Lynch, L. Ergun, M. Oner

"A research program on modelling cement grinding circuits has been in operation at Hacettepe University, Ankara, for four years. It has concentrated so far on tube mill and air separator grinding circuits for cement clinker, with emphasis on plant sampling surveys, including axial sampling inside the tube mills. The methodology is to use plant data to build the models and to supplement this by laboratory data where necessary, for example the determination of breakage functions. The plant data come from comprehensive sampling surveys and so far 33 surveys of clinker grinding circuits have been carried out in 9 plants. The operating conditions have been• mill sizes – 3.2 to 4.8 metres diameter and 8.5 to 15 metres long,• mill feed rates – 46 to 158 tonnes per hour,• air flow through mills – 25000 to 125000 cubic metres per hour,• cement clinker work indexes – 10.3 to 18,• separator sizes – 2. to 3.1 metres diameter,• separator feed rates – 132 to 689 tonnes per hour,• separator speeds – 12.3 to 21 metres per second.The ball mill model is Whiten’s perfect mixing model and the separator model is the Tromp curve with a fish-hook. This paper emphasises on the importance of calculating the breakage rates and the discharge functions with three case studies at five different circuits which were selected for discussion because they show how particular features of circuit operation can be included in the general models. Size distributiongraphs are used to illustrate every aspect of the discussion.In case I the special emphasis on calculating the breakage rates and discharge rates separately is given in a high pressure grinding roll-ball mill-separator circuit. The tonnes of each size fraction in the mill and the calculated values of R/D, D and R are determined. The values of R per mw are also given to allow comparison with mills of other sizes. The circuit allows the comparison of the static type (V Sep) and dynamic type separators (SKS). Comparing the reduced efficiencies shows that the dynamic separator is slightly more efficient than the static one.In case 2 data are given from two compartment tube mills having the same diameter and the motor power but different ball size gradation. The breakage rate particle size variation of the second chamber of two mills indicate that having finer ball size distribution causes higher breakage rate values."

Jan 1, 2003

By Svetlana Krashenina, Nebojsa Petrovic, Oscar Lopez

"As easily mined gold deposits are becoming increasingly rare, gold producers are turning to the processing of ores with polymetallic and copper mineralization. These base metals can create metallurgical and waste handling/disposal challenges, which can render the project uneconomic. Base metals such as copper compete for the cyanide reagent used to extract gold, necessitating the need to increase cyanide volumes and consequently, cyanide consumption costs. Copper will also stabilize in tailings water as weak acid dissociable cyanide, a form that is both difficult and costly to destruct. SART (sulphidization-acidification-recycling-thickening) process technology can be applied to remove base metal interferences in gold projects. SART breaks the copper-cyanide complex and precipitates the copper as a saleable copper sulphide concentrate. With the copper removed, the cyanide can be regenerated as free cyanide for recycle to the gold recovery process. This improves cyanide utilization efficiency and mitigates copper presence in tailings. Additionally, copper recovery generates an incremental revenue source to further improve project economics. Engineering Dobersek GmbH together with BioteQ developed a SART and AVR testing program to recover cyanide and maximize operational efficiencies at a gold processing plant in Kazakhstan with high cyanide consumption in the leach circuit. Results from on-site testing demonstrated that up to 99.98% of copper can be removed and precipitated as copper sulphide and 60-90% of cyanide can be recovered from the AVR and recycled for leaching, reducing total overall cyanide use. This paper provides an overview of the testing methodology and results together with a discussion on the potential of SART to improve gold production operations to deliver both environmental and economic benefits."

Jan 1, 2014

By C. Suazo, N. Mora

"The bubble size distribution plays a fundamental role in flotation kinetics. Nowadays it is possible to measure the bubble size distribution, gas holdup and superficial gas velocity by using specialized equipment developed for this purpose. In this article a methodology is presented for estimating the kinetic rate constant using a known particle and bubble size distributions. The attachment and detachment probabilities were modelled from three matrixes. The first matrix represents particle size distribution, the second was named the probability matrix, and the third is the bubble size distribution. Using laboratory data, it has been possible to estimate the flotation rate constant as a function of operating conditions and both the bubble and particle size distributions. The model tested at laboratory scale achieved a quadratic correlation coefficient equal to 0.97. This methodology could be used in the operation and control of the flotation, when in the near future we have industrial equipment that allows in-line measurement, in real time, of gas dispersion and bubble size distribution. knowing particle size distribution, it will be possible to manipulate the operating flotation cell conditions, in order to modify the bubble size distribution and find the bubble distribution that maximizes flotation kinetics. Furthermore, knowing the bubble size distribution, the grinding operator will be able to look for the particle size distribution that produces the maximum flotation kinetics. In order to do this, the operator will have to modify the solids percentage fed to the hydrocyclone cluster, modify the apex/vortex ratio, etc. Finally, this article shows that the maximum flotation speed is reached when the particle size distibution slope is equal to the bubble size distribution slope."

Jan 1, 2014

By Hideki Yamamoto, Norihiro Murayama, Junji Shibata

"Hydrothermal syntheses of zeolite from coal fly ash were carried out by using various alkali sources. NaOH, Na2CO3, KOH, K2CO3 and their mixture were applied for an alkali source of zeolite synthesis. The various physical properties of the reaction product, such as the kind of zeolite crystal, cation exchange property, surface texture and so on, was investigated through the zeolitization reaction from fly ash. The mechanism of zeolitization reaction was considered from these results.Zeolite P(NaP), hydroxysodalite(HS) and chabazite(K-CHA) are synthesized as zeolite species, when fly ash hydrothermally reacts in various alkali solutions at 393K. The crystal structure of the products obtained in NaOH solutions for 3h changes from NaP to HS with increasing NaOH concentration. K-CHA formation in KOH solutions needs 10h of reaction time, which is longer than that of NaP or HS.Dissolution, condensation and crystallization steps exist in the zeolitization reaction from fly ash, and the particle surface of products remarkably changes in each step. The fly ash is spherical particles and the surface is smooth(Fig.1(a)). The dissolution of fly ash occurs in the heating process until 393K, and the particle surface changes like unevenness(Fig.1(b)). In case of NaP, the condensation of aluminosilicate ions takes place at 373-393K, and the amorphous aluminosilicate is deposit on the unreacted fly ash(Fig.1(c)). The crystallization of NaP already begins to occur at 393K and the surface is covered with fine zeolite crystals for 24h(Fig.1(d))."

Jan 1, 2003

By P. Banerjee, P. Dash, S. Sriramoju, A. Suresh, R. Lingam, T. Ray

"One single property that influences the quality and market value of coal to the maximum extent is the ash content. The lower the coal ash higher is the energy utilization and potential for different applications. Even though Indian coal washeries aspire to produce coal with low ash, the intimate distribution pattern of ash bearing minerals in the coal matrix becomes the real bottleneck, as it brings down the clean coal yield to the impractical value. Because of this fact, most of the Indian washeries are operated to produce coal with 14-15% ash content at the yield of around 40%. In this context, with an objective to produce low ash coal at higher yield, a novel chemical beneficiation route has been explored to demineralize the high ash containing Indian coals. In this present work, the production of low ash clean coal from high ash Indian coals using chemical leaching process has been studied at pilot plant level. The leaching process parameters such as reaction temperature, reagent concentration, reaction time, coal-liquid ratio and agitator speed have been optimized for the flotation tailings sample from a captive washery of Tata Steel. The results obtained show that 67% demineralization could be achieved in a single stage of leaching process with a product yield of more than 65%. For further demineralization, multistage leaching was carried out and the results showed that 75-85% demineralization could be achieved with significant reduction in alumina to silica ratio. Additionally, the phosphorus content is also significantly reduced from 0.20 % to 0.022 %. Further, it is interesting to note that there is no increment of sodium content in the product coal after chemical treatment."

Jan 1, 2014

By Graeme Lane, Yuqing Feng, Kaixi Jiang, Junwu Zhou, Zhengchang Shen, Tao Song

"Airlift reactors are used in a wide range of industries, such as hydrometallurgy, biochemical processes, chemical process industry and waste water treatment. With increasing superficial gas velocity three circulation regimes can be defined: no gas bubbles in the downcomer, gas bubbles remain stationary in the downcomer and gas bubbles in the circulating regime. In this paper a numerical modelling method was presented for gas-liquid flow in airlift reactors under different bubble recirculation regimes. Gas-liquid flow was modelled using the Eulerian two-fluid equations, and extra user defined subroutines were incorporated to consider the complex physics, such as bubble induced turbulence and turbulent dispersion force. Some alternative correlations of drag coefficient were used to capture the bubble distributions in the riser and downcomer of the airlift reactor, with consideration of the interaction between bubbles. As using constant bubble size is hard to describe global characteristics of the flow in airlift reactors for three circulation regimes, a model including multiple bubble sizes was presented to get more accurate simulation results of gas holdup and water velocity. Also, the inhomogeneous MUSIG model was used, as an exploration, to compute the complex flow regimes. The MUSIG model is a population balance method to predict the bubble sizes, taking break-up and coalescence into account. The modelling method was applied to a laboratory internal loop airlift reactor, and the simulation results were compared with the experimental measurements of Simcik et al. (2011) for gas holdup and water velocity. The three bubble circulation regimes were observed from simulation figures. Reasonable agreement was obtained over a range of operating conditions, and an improvement was demonstrated using the proposed methods."

Jan 1, 2014

By Janusz S. Laskowski

"Frothers offered by different manufacturers are marketed with some information on their chemical and physical properties (e.g. density, viscosity, color, water-solubility, safety/toxicity, etc.). But frothers are used in flotation to generate fine bubbles and to stabilize the forth, and this information is only provided in a very qualitative description of the visual appearance of bubbles and froths. The terms “powerful” and “selective”, which have been commonly used to characterize frothers, have intuitive rather than scientific meaning.This paper introduces the DFI (Dynamic Foamability Index) plotted vs. CCC (Critical Coalescence Concentration) diagrams to classify flotation frothers (Fig. 1). The frothers characterized by low CCC and high DFI values have properties of strong flotation frothers, while those with high CCC and low DFI values are more selective. The proposed frother classification system, based on simple CCC and DFI measurements, provides, for the first time, a solid ground-work for characterization of the flotation frothers."

Jan 1, 2003

By Ernesto de la Torre, Karla Velín, Alicia Guevara

"The following study shows the improvement and simulation of a gold recovery plant of 24 t/day of capacity by gravity concentration, flotation and leaching. The ore processed had grades of 6 g/t Au, 15 g/t Ag, and 0.69 %Cu with the mineralogy consisting of 2 %chalcopyrite, 12 %pyrrhotite, 7 %plagioclase and 50 %quartz. The recovery process starts with crushing the ore followed by grinding it further in a ball mill. The ground ore is then concentrated in a Falcon centrifugal concentrator with concentrate being processed by amalgamation process. Gravity tails are sent to a flotation circuit where the copper minerals and some gold are concentrated. Lastly, the flotation tailings undergo cyanidation for gold recovery. Currently, the overall recoveries are 82.8 %Au, 49.6 %Ag and 99.1 % Cu. The optimization was developed in the laboratory using a Wilfley table by gravity concentration. Flotation tests in the laboratory were performed using potassium amyl xanthate and pine oil. Lastly, cyanidation was then performed on the flotation tailings. The results showed the optimum concentration of sodium cyanide in cyanidation is 2 g/L, which produced an increase in gold recovery from 30% to 44%. The reduction of diameter particle from 132 to 80 µm also produces an incremental recovery of gold and silver from 11% to 21% Au and 0.4 to 3% Ag in gravity concentration. Likewise in the cyanidation the recovery of gold and silver has shown a rise from 44 to 62% and 8 to 32% for Au and Ag respectively. However, the flotation method the gold recovery is reduced from 68 to 30% Au by reducing the particle size. Computer simulations using the programs, Moly-Cop and ModSim were performed to determine optimum parameters for the recovery of precious metals at the gold recovery plant."

Jan 1, 2014

By M. Kosugi, M. Kawata, J. V. Satur, K. Mitsuhashi, R. Kawarabuki, W. Kracht, Y. Ebisu

Copper concentration is becoming more difficult because remaining copper ores are more complex and of finer copper mineral grain size, making copper minerals harder to float because of the fine particle size required to liberate the valuable species. The purpose of this work was to study the flotation behavior of fine copper sulfide ores at different conditions of agitation and aeration. The experimental campaign was carried out in a laboratory Denvertype flotation cell of 1 L volume modified to be operated with forced air that allows decoupling air flow rate and agitation speed. Four ore samples from Chile were used, all of them containing copper sulfides such as chalcopyrite, bornite, chalcocite, and tennantite, but with varying grain sizes and compositions. Preliminary flotation tests for establishing the flotation conditions of grinding size and collector dosage were conducted before the kinetic flotation tests that were carried out at different agitation speeds varying from 900 to 1300 rpm for gas flow rate ranging from 1.6 to 7.2 L/min. The flotation products were analyzed by ICP-MS and MLA (Mineral Liberation Analyzer). The results showed that high agitation speeds with corresponding air flow rates resulted in better recovery than moderate agitation speed and air flow rate, and an excess in gas flow rate resulted in bad performances. The flotation rates of the fine copper minerals were improved despite the different improvement rates among the fine size fractions. The impact of these operational variables, however, was different when comparing the results for the four ore samples. While it was found that the order of floatability in the four samples was the same, that is, chalcocite > tennantite > bornite > chalcopyrite, the kinetic constants of the copper minerals in the samples were different, indicating that mineral composition in the sample affects the flotation kinetics.

Jan 1, 2018

By Gustav Hawlitschek, Henrique Kahn, Carina Ulsen, Renato Contessotto

"The problems related to waste dumping increased with the growth and development of large cities. In the U.K., more than 50% of landfill waste comes from construction use and the U.S. alone produces around 200 to 300 million tons of CDW annually. The exhaustion of natural sand deposits close to large urban centres stimulates the recycling of construction and demolition waste for the production of recycled aggregates as a construction material. This paper presents a flowchart for the production of recycled sand with low porosity and regular shape by the selective removal of the cement paste attached to recycled aggregates. The products characterization was carried out by the determination of the particle size and shape distribution, chemical and mineralogical composition, heavy liquid mineral separation and quantification of all present phases using a scanning electron microscopy with automated image analysis (SEM-MLA). The comminution of CDW by vertical shaft impact crusher made possible the production of a lower porosity recycled sand. The heavy liquid mineral separation showed that the proportion of low porous phases (d>2.5 g/cm3) is very high, exceeding 70% of the weight, encouraging further mineral processing separation to obtain a fine recycled aggregate with less cement paste content. The mineralogical characterization by XRD and SEM indicates that the main phases are tectosilicates, phyllosilicates and calcite which one can be attributed to both calcareous aggregate and cement paste. The precise quantification of cement paste and calcite/dolomite alone is just possible by automated image analysis. The characterization results demonstrated that proportion of phases with no cement paste attached increases progressively in denser products. The results of heavy liquid separations and image analysis are comparable and automated image analysis can be used for the characterization of phase content and their main associations."

Jan 1, 2014

By Henrique Kahn, Daniel Uliana, Juliana Antoniassi, Viviane Shimizu

"Mineral exploration and geometallurgy require a large number of samples for physical, chemical and mineralogical assays. The combination of all these data and their spatial distribution define the ore variability. This is important in exploration programs and crucial in feasibility studies as well as at the production operation level. Ore mineralogical composition and its associations, characterizing the geological formation and mineralization, are the main keys to define the ore domains and its variability, which can be quickly assessed by cluster analysis and by modern automated mineralogy tools. One hundred and ten copper ore samples from Sossego mine, in Brazil were compared and classified by X-ray diffraction cluster analysis based on the position and the intensity of the diffracted peaks. Initially four ore types were categorized based on content of major minerals: quartz, feldspar, amphibole, iron oxides, mica and chlorite. Results showed a strong correlation between the grouping and the samples location in Sequeirinho and Sossego orebodies, with a straight link to types/intensities of hydrothermal alteration prevailing in each body, which reflects the mineralogical composition and thus the X-ray patterns. Samples from four recognized ore types were submitted to detailed automated mineralogical studies by electron beam image analysis and differ strongly from each other regarding their chemical and mineralogical compositions and relevant parameters for mineral processing. Chalcopyrite is essentially the only valuable mineral, occurring both as submillimetric grains included in other minerals and as larger crystals. Except for pyrite, other sulfide minerals occur as traces. Chalcopyrite liberation curves indicate that samples from Sossego have higher liberation degree than those from Sequeirinho. The proposed method proved to be very efficient and accurate to classify a large number of samples within a short time frame, allowing the distinction of the ore types regarding their mineralogical composition as well as the mineral processing parameters."

Jan 1, 2014

By K. Saberyan

Zirconium and hafnium are two important elements in nuclear industries. Zirconium is used in fuel rod for its low neutron absorption. Hafnium should be separated from zirconium, because it has higher neutron absorption cross section. In this research, separation process of the mentioned elements from (Zr+Hf)Cl4 mixture produced in the Zirconium production plant (ZPP) of Iran (Esfahan) was studied employing solvent extraction method in the nitric acid medium by using tributylphosphate (TBP) as solvent, and kerosene as diluent. The effects of nitric acid, sodium nitrate and amount of extractant, zirconium concentration in aqueous phase, phase ratio, agitation time, and mixer agitation rate were investigated on the separation process. The process was optimized at 5 M nitric acid, 1 M sodium nitrate, 60% (v/v) TBP. The optimum values for phase ratio, agitation time and agitation rate were 1.5 min and 500 rpm respectively. In this condition, the zirconium extraction efficiency, and separation factor were 65.1% and 205.59, respectively. Finally, we accessed to nuclear grade in this research.

Jan 1, 2014

By K. H. Luo, J. Y. Liu

An experimental study on interparticle breakage of three iron ores was carried out by compressive stressing of particle-bed in a piston-die device. The feeds to the particle-bed stressing were five narrow size fractions in the size range of 0.2~3.2 mm respectively and a wide size fraction of 0/4.0 mm. The pressures applied were in the range between 30 and 360 MPa. The results show that the energy absorption of the particle bed increases linearly with the pressure; the increase of the product fineness with the pressure declines as the pressure goes up; and the product size distributions resulting from interparticle breakage of different narrow size fractions have no self-similarity. Using data obtained from the piston-die compressive stressing test, the suitability of a previously-developed material-characterization model for interparticle breakage was verified for these ores. It is shown that the particle-bed compression test conducted with piston-die device in lab-scale may provide a cost-effective way of studying and modelling size-reduction of ore materials by interparticle breakage.

Jan 1, 2014

By Rodney J. Hundermark, Sharif Jahanshahi, Shouyi Sun

"The major platinum producers in South Africa make use of electric furnaces for the melting of platinum group metal (PGM) bearing nickel – copper concentrates. To gain better understanding of the furnace operation, research was conducted at CSIRO Minerals in Melbourne, Australia. One aspect of the research project was the investigation of the factors affecting the electrical conductivity of melter type slags.Electrical conduction in slags can occur through two mechanisms: ionic and electronic. There is good understanding of the ionic mechanism. In slags containing high levels of iron, the dominant mechanism is electronic as a result of charge hopping (electrons or holes) between ferric and ferrous ions. There is limited understanding of the electronic mechanism and one of the aims of the research was to investigate this mechanism further.Experimental work was carried out at 1450 °C on Al2O3–CaO–FeOx–MgO–SiO2 slags similar in composition to the melter slags (typical composition range (wt%): Al2O3: 5, CaO: 5-15, FeOx: 10-30, MgO: 15-25, SiO2: 40-60). The approach was to vary the oxidation state of three different basicity slags and measure the conductivity response. The slags had molar (CaO+MgO)/(Al2O3+SiO2) ratios of 0.43, 0.64 and 0.94 and FeOx contents of up to 40wt%. A twoelectrode technique was employed with a shallow layer of slag contained in a magnesia crucible. The small amount of slag facilitated relatively quick equilibration (up to one hour) with the gas atmosphere. Experiments were typically started in air and sequentially reduced using different ratios of CO and CO2 gases.Conductivity increased with increasing basicity and increased significantly with iron oxide content. Above 20wt% FeOx, electronic conduction was significant and the conductivity varied with the oxidation state of the slag. The typical response of the conductivity to the change in oxidation state was the following: starting in air, as the slags became more reduced, the electrical conductivity increased to a maximum at around pO2 = 10-7 to 10-4 atm and then decreased with further reduction. The value of the pO2 at which the maximum occurred was dependent on the total iron oxide content and basicity of the slag. The magnitude of the conductivity of the slags increased with increasing FeOx content in a range of 20 to 170 S/m for 20 to 40wt% FeOx. For a given FeOx content in the slags, the oxidation state dependence of the conductivity varied with slag basicity. The trend observed was that the maximum in the conductivity occurred at higher oxygen partial pressures for the lower basicity slags."

Jan 1, 2003

By Glaser. C., J. Balz, F. Logsch, R. Heiduschke, M. Leiker, P. Ay

The treatment of iron-hydroxide-containing water from ground water and surface water is achieved by a combination of the process steps of flocculation and subsequent mechanical dewatering. The aim is to create solid pellet structures by extending the structure forming flocculation process with a build-up pelletizing process which can be transferred directly into a drying unit. A Taylor-Couette-reactor (diameter of the inner cylinder – 40 mm, gap width – 5 mm) was used for these experimental studies. To produce the necessary flow profile the inner cylinder was rotated at a speed of 230 rpm. The iron hydroxide-containing suspension (dry matter content: 2 mass %) was added simultaneously with the addition of a cationic high-molecular flocculant in various flocculant dosages and residence times of 5 to 15 min. The pellets were examined for parameters such as geometric dimensions, dry substance content and dewatering behaviour. As the results show, there is a direct relationship between the residence time and the geometric dimensions of the pellets. After a residence time of 5 min, round pellets with an average diameter of 6 mm were formed. With an increase in the residence time up to 15 min, a compaction of the pellets could be observed, which resulted in an increase in the dry substance content of 8.0 to 11.2 mass % on average. After completion of the pelletizing process, the pellets were mechanically dewatered by filtration. By applying this innovative wet pelletizing of iron-hydroxide containing suspensions in a Taylor-Couette-reactor, it is possible to carry out the process of flocculation combined with the pellet formation with simultaneous pellet compaction in a single process step. The resulting pellet structures are distinguished from conventional floc structures by an improved water discharge capacity. After classification the pellets can be marked directly as easy-to-handle bulk material, suitable as feedstock in percolation columns for the purification of contaminated fluid streams

Jan 1, 2018

By Peter Ay, Elena Geldt, Satyanarayana Narra, Claudia Glaser

"As part of an extensive research and development project, the technical and technological implementation of the patents DE 10 358 245 B4 and WO/2006/056172 was developed with the goal to present a system for the innovative roll- agglomeration method exhibiting a) a modular setup, b) high productivity and c) suitability for the use of fibres of different applications and product qualities (high technical availability). The processability of the rarely adapted raw fibre materials into high-value intermediates brings forward their application in various processing industries dealing with the production of fibre reinforced plastic composites, heat and sound insulation materials as well as with the gas and liquid cleaning systems. The innovative fibre agglomeration presented in this work is performed by a combination of rolling and pressing the fibres inside a geometrically pre-defined roller table, in which the fibres are forced to bound through entanglement / interlocking and develop into agglomerate. The agglomeration process is carried out in a circular roller path with a rectangular cross-section. For improving the adhesive properties, and thus the quality of the agglomerates, the boundary surfaces can be covered / patterned / lined / coated with various materials. The resulting roll-agglomerates are characterized by different quality parameters such as mass, shape, porosity and stability. The properties of the agglomerates can be modified based on the end-product requirements by slightly modifying the process parameters such as filling ratio, residence time, roll-geometry, procurement of the boundary surfaces, etc. as well as the input material properties such as fibre type, fibre fineness, fibre length, etc. This work carries extensive work on the roll-agglomeration system to assess the effectiveness and the variability based on the product specifications. Agglomerates were produced with wide variations of system parameters with varying roller table liners and based on evaluation of the produced agglomerates with respect to their mass, the geometrical dimensions, their porosity and stability."

Jan 1, 2014

By Tingting Li, Guodong Li, Dezhou Wei, Cong Han, Shuling Gao, Yanbai Shen

"The aim of this study is to solve the problem of tungsten leaching from scheelite concentrate using sodium hydroxide in the presence of phosphate by an autoclaving process, which is one of main development techniques for tungsten recovery. To understand the applicability and leaching performance of tungsten leaching from scheelite concentrate, the main work is to investigate the effects of leaching parameters such as initial concentrations of NaOH and Na3PO4, reaction temperature, stirring speed, liquid-to-solid ratio and reaction time on WO3 dissolution rate to obtain the optimal leaching conditions. The chemical composition and phase composition of the samples were evaluated by means of XRF and XRD. The content of WO3 in the leaching residue obtained via washing, filtering and drying was analyzed by thiocyanate spectrometric method. The optimal leaching conditions were found to be NaOH concentration of 6.76 mol·L-1, Na3PO4 concentration of 1.35 mol·L-1, reaction temperature of 180°C, stirring speed of 400 rpm, liquid-to-solid ratio of 2.0 and reaction time of 90 min. The results showed that tungsten leaching rate of 99.20% was reached under the optimal conditions. The technology exhibited superior leaching performance, which not only reduced the consumption of sodium hydroxide but also greatly decreased reaction time in comparison to a conventional autoclaving process. INTRODUCTION Tungsten is an important strategic metal, which is widely utilized in a variety of industries due to its high melting point, superior mechanical properties and heat-resistant performance [1-3]. The chief raw materials for the production of tungsten in nature are wolframite and scheelite [4, 5]. Among them, approximately two-thirds of the tungsten reserves contain scheelite deposits in the world [6, 7]. With the progressive exhaustion of high-quality wolframite resources, scheelite has become a predominant primary resource for the production of tungsten [8, 9]."

Jan 1, 2018

By M. Özer, G. Önal, F. Arslan

"The use of ultrasonic in industrial processes has increased during the last few years. Ultrasonic vibrations are used in sieving, grinding, ore washing, cleaning, and flotation in mineral industry. There are also some attempts for the utilization of ultrasonic treatment in separation and removal of fine particles from gases and liquids. In Kalemaden A.S. (Turkey) four different types of clay mixtures (1. A mixture of clays from Balikesir-Düvertepe and Istanbul-Sile, 2. A mixture of clays from Ukrania and Balikesir-Düvertepe, 3. Sögüt-Kadikelimesi, 4. A mixture of clays from Sögüt and Istanbul-Sile) and kaolin from Balikesir-Düvertepe (Turkey) are concentrated before their use in ceramic production. Dewatering is the important step in those types of concentration plants. Sedimentation of concentrated clay has always been difficult and taken long times due to their nature and having small particle sizes. Flocculants can be used to enhance the sedimentation, but they are not preferred by the ceramic industry since they affect the quality of ceramic products. For this purpose, ultrasonic treatment is used in the sedimentation of clays mentioned above for solving the problems encountered related to the ceramic industry and promising results were obtained.Kaolin sample, subjected to this experimental study, from Balikesir-Düvertepe region of Turkey was brought from the plant as a pulp in containers and throughly mixed with a stirrer before sedimentation experiments. A two liter graduated cylinder and an ultrasonic bath (with 25 kHz frequency and 0.5 KW power) were utilized in the tests. Superfloc A-120 (1% concentration) was used as a flocculant. The settling distance was reported against the settling time during the experiments. Initial and final pulp densities were also determined. The effects of several parameters such as pulp density, flocculant addition, and ultrasonic treatment on the sedimentation of kaolin were investigated and the results are represented in terms of settling distance versus settling time."

Jan 1, 2003