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By Zhou Yucai, Zhou Jing, Zhu Yimim

"In this article, research on the beneficiation process for a carbon containing copper-molybdenum deposit in Henan province has been carried out. The elemental composition, mineral composition and relative content, characteristics of embedded and symbiotic relationship, the forms of the copper-molybdenum particlesand their disseminated features, and particle size distribution have been worked out. Flotation behavior of copper-molybdenum mixed flotation and separate flotation in the systems of different collectors and depressants, and the influence of different flowsheets on the copper-molybdenum separation have been investigated by actual ore flotation tests, The separation problem of copper-molybdenum for a carbon-containing copper molybdenum ore has been solved.INTRODUCTION In this paper, technological mineralogy, small experiment of flotation recovery of copper Molybdenum ore, and expansion experiment of mineral recovery of copper Molybdenum ore are introduced. (1) The results of process mineralogyshow that the content of copper is 0.42%, molybdenum is 0.021% in the raw ore, they mainly exist in the form of sulfide, with low oxidation rate. (2) The results of flotation tests show that the combination of butyl xanthate and isopropyl ethylthionocarbamate reagents is effective collector of copper-molybdenum mixed flotation for carbon copper molybdenum, (3) When the grinding fineness is -0.074 mm taking 71%, and regrinding fineness is -0.038 mm taking 85%, the flowsheet of first copper-molybdenum mixed flotation and then regrinding rough concentrate and last separation flotation of copper and molybdenum was adopted, which realized the effective separation of copper and molybdenum for carbon-containing copper molybdenum ore. Good flotation indexes were gained with copper concentrate containing 20.96% copper and copper recovery 90.06%, and molybdenum concentrate containing 46.78% molybdenum with molybdenum recovery 72.68%. (4) The seven days average concentration index of scale-up the continuous dressing experiment is as follows, the copper content in copper concentrate is 20.16% and the recovery is 89.61%; the molybdenum content in molybdenum concentrate is 24.58% and the recovery rate is 74.09%."

Jan 1, 2018

By Felix M. Zhuravlev, Vitalij P. Lyalyuk

"While there is a large industry based on recovering platinum group metals (PGM) from complex sulphide ores containing Cu and Ni, there is little information on the thermodynamics of the matte phase formed on smelting the ore and in particular the behaviour of Pt in the matte.The equilibrium between metallic platinum and industrial mattes was studied in a series of experiments where a small quantity of matte (5g) and platinum foil of 150 µm thickness (0.5 g) were equilibrated in magnesia crucibles at 1400°C under conditions where the oxygen and sulphur partial pressures were controlled.The chemistries of the phases were determined from EDS analysis using a scanning electron microscope. Line scans were initially used to confirm that the foils had attained a uniform composition across their thickness. The composition of the matte was determined from analysis of an area of matte including the small metallic droplets and dendrites.The distribution of Pt in Cu-Fe-Ni mattes (Pt: 1.5 – 3%) and solid Pt alloys (Pt: 54 – 72%) was studied. For a matte of base composition 45%Fe, 11%Ni, 8% Cu, at a base temperature 1400°C, the following behaviour was observed for the Pt distribution ratio:Under the range of sulphur and oxygen pressure of this study (log pO2 from -15 to –12.2, log pS2 from – 4.6 to –2.2), the distribution ratio of Pt between matte and alloy was independent of the sulphur and oxygen pressure, having a value of 0.04.The Pt distribution ratio increased from 0.02 to 0.08 with temperature from 1340 to 1450 oC.For mattes where the proportions of Cu and Ni were kept constant, a slight decreasing trend was shown for the distribution ratio of Pt versus the iron content (37 to 53%) in the matte but was not confirmed because of experimental uncertainty."

Jan 1, 2003

By Steven Wright, Sharif Jahanshahi, Shouyi Sun

"While there is a large industry based on recovering platinum group metals (PGM) from complex sulphide ores containing Cu and Ni, there is little information on the thermodynamics of the matte phase formed on smelting the ore and in particular the behaviour of Pt in the matte.The equilibrium between metallic platinum and industrial mattes was studied in a series of experiments where a small quantity of matte (5g) and platinum foil of 150 µm thickness (0.5 g) were equilibrated in magnesia crucibles at 1400°C under conditions where the oxygen and sulphur partial pressures were controlled.The chemistries of the phases were determined from EDS analysis using a scanning electron microscope. Line scans were initially used to confirm that the foils had attained a uniform composition across their thickness. The composition of the matte was determined from analysis of an area of matte including the small metallic droplets and dendrites.The distribution of Pt in Cu-Fe-Ni mattes (Pt: 1.5 – 3%) and solid Pt alloys (Pt: 54 – 72%) was studied. For a matte of base composition 45%Fe, 11%Ni, 8% Cu, at a base temperature 1400°C, the following behaviour was observed for the Pt distribution ratio:Under the range of sulphur and oxygen pressure of this study (log pO2 from -15 to –12.2, log pS2 from – 4.6 to –2.2), the distribution ratio of Pt between matte and alloy was independent of the sulphur and oxygen pressure, having a value of 0.04.The Pt distribution ratio increased from 0.02 to 0.08 with temperature from 1340 to 1450 oC.For mattes where the proportions of Cu and Ni were kept constant, a slight decreasing trend was shown for the distribution ratio of Pt versus the iron content (37 to 53%) in the matte but was not confirmed because of experimental uncertainty."

Jan 1, 2003

By P. Saha, D. M. Chakrabarti, J. P. Srivastavam, P. Bhattacharyya, B. R. Sarkhel, Banerjeem B.

The phosphatic soil deposit at the Sukulu hills region of Uganda contains 10-12% P2O5. The ore occurs as a naturally degraded soil deposit containing a very sticky slime composed of earthy lateritic minerals. Desliming of the ore, which is imperative for its further beneficiation, is an extremely difficult hurdle to overcome for its commercial utilisation. Earlier studies on samples of the same ore at the National Metallurgical Laboratory (NML) and abroad established that it was necessary to pass the ore through a series of three stages of desliming, each consisting of a step of vigorous attrition scrubbing followed by hydrocycloning, for effective elimination of the sticky slime. In the present paper an innovative use of the very strong shear-fields created inside a hydrocyclone has been discussed, that could effectively eliminate the stubborn slime from the ore. The standard design of the hydrocyclone was suitably modified to increase the shearing effect on the slurry. It was possible, through the application of this modified hydrocyclone, to not only totally eliminate all the stages of attrition scrubbing, but also to reduce the subsequent stages of hydrocycloning. The modified technique yielded a concentrate of grade comparable to that obtained by employing the earlier more complex flow sheet, with about 25% higher P2O5 recovery.

Jan 1, 2003

By Katsunori Okaya, Toshio Inoue

"Movement of mill charge in the centrifugal mill is essentially dissimilar from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. This dissimilarity is the reason for the substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Bradley et al. (1983) developed a math model regarding the mill charge as a lump. This model is presented in a simple equation with which motion of the mill charge can be predicted in terms of the parameters describing the specification and the operation of the centrifugal mill. This equation can be used to explain the power draft of the mill as well as the stability of mill operation. More recently, on the other hand, a numerical simulation technology called discrete element method (DEM) has become a vital vehicle for estimating the motion of the grinding media in the mill. The authors developed a mill simulator called ‘Mill Solver’. Mill Solver is designed to simulate various types of mills including centrifugal and vibration mills. The principle of this simulator is to calculate individual kinetic events of interaction of balls in the mill in a minute time interval, hence the mill performance can be constructed for estimation."

Jan 1, 2003

By Hakan Gürsoy, Kemal Bilir, Bahri Öteyaka, Ali Uçar, Oktay Sahbaz

"Jet diffuser flotation column (JDFC) is a flotation device resembles Jameson flotation cell (JFC) in terms of operational principles, but it has significant difference structural points of view. This difference is an essential change in the downcomer to provide an increase of performance of the cell for the coarse particles. By using the hydrodynamic and fluid mechanics principles (Sahbaz et al., 2013) downcomer was changed as a diffuser, therefore turbulence at the end of the downcomer was reduced to provide better aggregate stability and homogeneous dissipation of the bubbles in the separation tank. According to experimental results carried out in pilot scale JDFC, not only higher flotation performance comparing with Jameson cell was obtained specifically for coarse talc particles in a certain condition, but also quiescent froth layer was acquired. In these tests, vertical pipe of JDFC having inlet diameter of 6 cm and outlet diameter of 11.5 cm was used with separation tank having the diameter of 39 cm. By using the data, pilot scale JDFC having 410 cm vertical pipe integrated with separation tank was produced and flotation tests were carried out by using the naturally hydrophobic mineral (talc). Finally, the talc recovery obtained as 94% by the use of JDFC, while Jameson cell has the recovery of 77% for the particle size of 250 µm."

Jan 1, 2014

By Tsvetan Damyanov, Nikolay Hristov, Evgeni Kostadinov, Lubomir Kuzev

"The process of grinding in drum mills is directly dependent on the dynamic forces occuring in the free movement of the grinding bodies in the volume. The subject of discussion are the potential impacts between grinding bodies having different shape and equal weight in a drum mill that has a diameter of 1200 mm. The study utilised ball grinding bodies having a diameter of 120 mm and tetraballpebs having a conditional diameter of 120 mm. The study was carried out using the Solid Works Simulation software. The following cases were examined: • Impact between two identical grinding bodies; • Impact between a grinding body and the shell surface. The study provided numerical values for impact force, kinetic energy of impact, linear speed of impact, linear displacment of the center of gravity and duration of impact deformation. The impact force of the balls is approximately 179000 N. The impact force of the tetraballpebs with typical vertices, edges and spherical surfaces depending on the area of impact is 177000 to 185000 N. Upon impact between two spherical surfaces of tetraballpebs, the contact area is 263.55 mm2, which is more than twice the contact area upon impact between two balls, which is 114.39 mm2. This determines better conditions for the transmission of kinetic energy by reducing opportunities for overgrinding."

Jan 1, 2014

By P. Somasundaran, Tarun Bhambhani, D. R. Nagaraj, P. Patra

"Certain non-sulfide gangue minerals are known to have a detrimental impact on flotation performance. When present in large amounts, they can negatively affect recoveries, grades and throughput at current operations, and dictate the viability and economics of a greenfield project. While the problem has been investigated for a long period of time, a scientific understanding of the mechanisms by which these minerals affect performance has not been obtained, and no acceptable solutions have been developed. This study focused on the role of physical aspects (e.g. shape, size and morphology) of these minerals as the underlying factors for poor performance. Flotation tests were conducted using model mineral systems to understand the impact of one phyllosilicate mineral (muscovite) on flotation kinetics, recoveries and grades. The study reveals that there is minimal impact on flotation kinetics, no impact on recoveries, but a very strong detrimental impact on concentrate grade. The traditional mechanisms of transport such as true flotation and entrainment are not sufficient in describing the extent of transport. The transport is attributed to the unique platy morphology of muscovite, which allows for action of buoyancy forces. Data also shows that the muscovite transport to the froth phase depends on particle size; coarser sized muscovite (100-150@) report to the froth phase in much larger amounts than medium sized muscovite (50-100@). At finer size fractions (<50@) the transport is also increased, and this is likely due to entrainment."

Jan 1, 2014

By Rogerio C. Guimarães, Antonio E. C. Peres

The production of phosphate concentrates (phosphate rock) from slimes represents a challenge to the phosphate industry worldwide. In Brazil, this challenge is particularly relevant due to the consistently low P2O5 grades and the igneous origin. The first industrial experiences of producing phosphate rock from slimes (-44µm or -325#) fraction started at Arafertil, currently Bunge Fertilizantes SA, in Araxá, in the 1980.s. This production corresponds, nowadays, to 35% of the total production of concentrates in the company (830,000t/year) in a circuit consisting of desliming in 40mm microcyclones and concentration in flotation columns, corn starch and fatty acids being utilised as reagents. The performance of slimes flotation and the process control, at Bunge´s concentrator, were improved after the introduction of column flotation technology, in the first half of the nineties. The column flotation technology for slimes recovery was expanded to other Brazilian concentrators still in the nineties: Ultrafértil (Catalão - GO), Bunge (Cajati - SP), Fosfértil (Tapira - MG) and Copebrás (Catalão - GO). At present the Brazilian production of phosphate rock is approximately 4.5Mt/year, with a strong trend for a market increase. Genuinely Brazilian technology is utilised for the processing of slimes, the concentrates representing 11 to 13% of the overall production. The production of apatite concentrates from slimes was relevant to increase phosphate recovery and reduce costs, contributing to the growth of the fertilisers industry.

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Tetsuo Ikejiri, Abel Bissombolo, Yoshitsugu Koga, Masamichi Hata

In Japan, the increasing number of automobiles newly put into circulation is followed by a larger amount of end-of-life vehicles from which valuable metals are being recovered in shredder and related plants. Nevertheless, the processing of these scrapped automobiles which has reach a recycling rate of about 75%, generates a huge volume of waste, locally known as .shredder dust., which is commonly dumped on landfills. The saturation and depletion of valuable disposal sites in the near future, as well as the social and environmental problems related to the accumulation of these residues disposals are a major challenge for the automobile shredding industry. To promote an alternative way for the management of these disposals, the authors have initiated and developed a system for their processing, on the basis that more than 90% of these residues are combustible materials that could be used as refuses derived fuel. The developed processing system points out the mechanical/physical separation of shredded automobiles residues into two streams by means of an ascending airflow passing through a vertical zigzag separator and, the compaction of the light-density fraction of materials (that is about 60% of auto shredder residue recovered as float products and mainly composed of cotton, sponges and light plastics) to form a refuse derived fuel (RDF), the density, calorific value and ignition loss of which are 1.19 g/cm3, 4470 kcal/kg and 60.7%, respectively.

Jan 1, 2003

By Rod Hocking, Nenad Djordjevic, Randolph A. Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures from standard operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill. Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulate the assemblage of a physical mill.By modelling the assemblage of steel balls in a 1 m pilot mill and duplicating the experimental arrangement exactly with the PFC3D model, it was possible to replicate the pattern of falling balls in the experimental mill. Furthermore, the key features of the acoustic emission spectrum that was calculated compared favourably to the measured spectrum at low frequencies. The experimental spectrum is shown in Figure 1."

Jan 1, 2003

By M. Pelser, Lorenzen L.

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.A review of literature has proven that there is no conventional method for the control of calcium and or magnesium, although a number of potential processes have been identified. The technologies investigated included precipitation, ion exchange and solvent extraction, for which at least one method was found under each. To make the reader aware of these processes a short description was provided of each within the text.Of these processes, fluoride precipitation was selected for experimental investigation based on the low solubility of calcium and magnesium compared to the base metals. This process involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments were designed to investigate the equilibrium of the system at varying parameters of which the level of fluoride addition, the ratio of calcium to magnesium, and the identity of the soluble fluoride was reported. In all of the instances the process showed high selectivity towards calcium and magnesium over the base metals. The experiments proofed the process to have a higher affinity towards the removal of magnesium at compositions where the molar ratio of calcium to magnesium was higher than 1:3. It is often the case that the calcium to magnesium ratio is in the region of 1: 10. From this it follows that the fluoride addition has to be stoichiometric or greater for calcium and magnesium combined, if the calcium is to be precipitated. This was demonstrated as well. On the identity of the soluble fluoride hydrogen fluoride was compared to ammonium fluoride, of which the latter was found to be preferred."

Jan 1, 2003

By Markus A. Reuter, Bernardete Castro, Antoinette van Schaik, Han Remmerswaal

"INTRODUCTIONThis paper describes the inseparable relation between product design, liberation, and metallurgical recovery in the optimisation of the recycling of passenger vehicles. This is illustrated by the use of an optimisation model that uses among others a material combination matrix based on metallurgical process data, which depicts the consequences of the quality of intermediate recycling products on the metallurgical material recovery and final alloy metal quality. Various simulations will illustrate the effect of changes in product design and hence liberation on the recycling of end-of-life vehicles. Although this paper focuses on cars, the discussion is equally valid for any end-of-life product. Calibration of the model will be discussed with reference to experiments carried out in order to study the optimal recovery of aluminium applications used in passenger vehicles.OPTIMISATION MODEL FOR LINKING DESIGN TO RECYCLINGImproving the efficiency of the material cycle of the car is essential to ensure a sustainable development of our society as well as e.g. to comply with the recycling targets imposed by EU legislation. In the design of the car various materials are combined and connected in many different ways, making up the complex 'mineralogy' of the car and its components, which is changing rapidly and continuously over time. The liberation of materials during shredding plays an important role in the composition (and quality) of the intermediate recycling streams. In order to include the influence of product design (mineralogy), liberation, and particle composition (quality of the intermediate recycling streams) in the optimisation of the recycling of end-of-life vehicles, a systems engineering tool for optimisation of the recycling of end-of-life vehicles was developed, including a liberation model. The optimisation model predicts the recovery rate as a function of product design (in this case a car), liberation, efficiency of the different process steps, economy and legislation based on a developed recycling flow sheet for end-of-life vehicles. Optimisation can only be achieved through the combination of the knowledge areas of product design, shredding, mechanical separation technology linked to pyro- and hydrometallurgy, composing a complex interconnected network of unit operations."

Jan 1, 2003

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

"As native gold resources are depleted, gold-sulfide ores consisting essentially of pyrite, arsenopyrite, chalcopyrite and pyrrhotite become one of the major precious metal sources, being presently estimated to account for more than 40 % of total world gold reserves.The prime objective of flotation of gold-bearing sulfide minerals is to increase precious metal recovery and to reduce the product cost through achieving maximum selectivity of the separation process. Separation of Fe and As sulfides in selective flotation of gold-bearing ore products helps reduce the amount of ore mass being sent to hydrometallurgical processing, and permits of recovering gold from As-free gold-containing pyrite concentrate by using a lower-cost pyrometallurgical procedure.An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study.Comparison of the elemental composition, non-stoichiometry and flotation activity of different monomineralic pyrite varieties revealed that samples with negligible impurity content are nearly stoichiometric, and show similar flotation properties. Samples with high Cu, As and Au contents are highly non-stoichiometric and readily floatable, even in a highly alkaline environment. Samples with high surface sulfur content and the most defective crystal lattices, with iron atoms substituting for sulfide vacancies, are most sensitive to depressive action of the alkali.A correlation between the type of conductivity, impurity content and amount of xanthate compounds on the surface and in the liquid phase of monomineralic pyrite and arsenopyrite suspensions detected by the extractive spectrophotometric analysis has been identified and analyzed. Experiments showed that the proportion of cuprous xanthate in sorptive collector layers on sample surfaces increases with increasing Cu content of the samples. In general, pH for pH, overall xanthate sorption on pyrite is greater than on arsenopyrite, with the difference increasing in passing from an acid environment to an alkaline one. A significant decrease in xanthate sorption on arsenopyrite is observed at pH greater than 9, whereas sorption on pyrite markedly decreases at pH greater than 11."

Jan 1, 2003

By F. L. Mentg

The utilization of acid leaching tailings was studied. It is obvious that the Fe in acid leaching tailings can be leached into solutions as Fe2+. In this paper, the influence of conditions, including the concentration of ferrous sulfate, pH, temperature and velocity of air flow was investigated. The optimum conditions for preparing seed crystal are as follows: the concentration of ferrous sulfate is 20 g/L; pH is 9.5~10; reaction temperature is 10~20?; velocity of air flow is 0.4m3/h. The optimum conditions for preparing iron oxide red are as follows: the concentration of ferrous sulfate is 5 g/L; reaction temperature is 80~85?; velocity of air flow is 0.13m3/h. At last, the product of iron oxide red could be prepared by ammonia method.

Jan 1, 2014

By Gabriel C. Aguilera, Juan Arismendy

"The effect of rheological factors inside of a hydrocyclone is very relevant for the fluid mechanics and for the classification of materials on suspension, since parameters such viscosity and thixotropy are intrinsic variables that depend of the particulate system and the continuous phase; they determine the efficiency of classification. Nevertheless, the exact knowledge of the main characteristics and magnitudes of them inside the hydrocyclone is very difficult because of the geometry of the hydrocyclone, even more if the hydrocyclone is of small diameter. Hence is not possible to make a hydrodynamic study with effects over classification regarding these variables. This work studies the rheological variables inside a small diameter hydrocyclone that works at high pressures, using the information given by a model of Computational Fluid Dynamics (CFD). The model used includes the Reynolds Stress Model (RSM) for the evaluation of turbulence, and the Volume of Fluid (VOF) to study the interaction between water and air, which is very important to obtain regarding the effect of the air core over the performance of the equipment. The validation of the CFD model was done with a kaolin suspension at several conditions of solids contents below the critical volume fraction, without chemical additive aid. These conditions are representative of current work parameters on plant. As result it could be established the ranges of evaluation of rheological variables on specific regions inside the hydrocyclone, and through a rheometric study, based on the mechanic characteristics previously obtained, the main rheological characteristics of the mineral suspensions were determined."

Jan 1, 2014

By Shuji Owada, Yang Geng, Natsuko Kuroki

Micro-bubble flotation is considered to be an ideal method for the separation of fine or ultra-fine particles, which are difficult to be separated with conventional flotation and other solid separation technologies. Micro-bubble flotation can increase the probability of bubble-particle collision more than conventional milli-bubble flotation. However, there are also some problems. For example, it is known that the rising velocity of micro-bubble is quite low; therefore, the flotation rate reduces. And also, the bubble-particle adhesion probability becomes lower than that of milli-bubble flotation, which is proved in our prior research. In this paper, we applied ultrasonic irradiation to the micro-bubble flotation system in order to solve the above problems and focused on the bubble-bubble and bubble-particle interactions. For clarifying the behavior of bubble-bubble interaction, bubbles behavior was recorded by high-speed camera under irradiation of various ultrasonic frequencies. As a result, in the case of bubble-bubble interaction, it is proved that bubbles are highly coalesced by ultrasonic irradiation especially in the lower frequency and it can enhance more precise separation. In the case of bubble-particle behavior, it is found that the floatability become higher with the ultrasonic irradiation of higher frequency, and it is indicated that ultrasonic irradiation might improve the bubble-particle adhesion probability. Additionally, it is also found that the apparent CMC of the micro-bubble flotation under the ultrasonic field become much lower with higher frequency than with lower frequency, and it is suggested that the dramatic improvement of hydrophobization is achieved.

Jan 1, 2014

By Peter Rubie, John Russell

"For many years, optimizing the relining of hard rock grinding mills has been complicated by the large number of variables, the low frequency of relines (resulting in a slow relining experience assessment and review cycle), and the potential economic risk associated with some changes to relining equipment or work practices. A technology that has its roots in the automotive manufacturing industry is being utilized to construct a statistically accurate, configurable, and dynamic simulation of the mill relining process. The detailed effects of various mechanization and process changes can be rapidly modeled and compared. Application of this discrete event analysis technology in the mineral processing industry delivers a range of benefits to many industry stakeholders. For example, mill maintenance managers and contract relining companies can embrace the opportunity to benchmark current performance against world’s best practice. Concentrator plant designers and mill manufacturers, informed by this technology’s scientifically defensible data set, can accurately plan for maximum plant efficiency when designing an infrastructure and equipment combination that truly maximizes annual plant availability. Time-motion studies of grinding mill reline data at mills of varying dimensions, liner configurations, mill relining equipment, operator and tool variables, have been integral to the development of this dynamic simulation tool and its associated data set. Access to mill relining simulation technology will enable mineral processing industry professionals to take advantage of an increased capacity to develop mineral concentrator performance optimisation initiatives within the given financial, physical and technological constraints of the individual concentrator plant."

Jan 1, 2014

By Naoki Hiroyoshi, Hajime Miki, Tsuyoshi Hirajima, Masami Tsunekawa

"Acidic solutions for chalcopyrite leaching contain cupric, ferrous and ferric ions, and the oxidizing power of the solutions is indicated by a redox potential, determined by the concentration ratio of ferric to ferrous ions. This paper reviews our previous studies on the redox potential dependence of chalcopyrite leaching in sulfuric acid solutions. Leaching experiments indicated that copper extraction rate was accelerated by cupric and ferrous ions , and was higher at potentials below a critical value (critical potential) in the presence of these ions. This was in good agreement with the results of electrochemical measurements, i.e. in the anodic polarization curves for a chalcopyrite electrode, active-passive behavior was observed when cupric and ferrous ions co-exist, but the activation at low potential did not occur without these ions (Figure 1). The analysis of the AC impedance spectra for chalcopyrite electrode indicated that a high-resistance passive layer grows on the chalcopyrite surface without cupric and/or ferrous ions, and that coexistence of these ions causes a formation of another product layer and inhibits the passive layer growth at low potentials.These results are explained by a reaction model assuming the formation of intermediate Cu2S due to chalcopyrite reduction and the subsequent oxidation of the Cu2S. The critical potential corresponds to the redox potential of the Cu2S formation and the predicted values matched with the experimental results. Catalytic effect of silver ions on chalcopyrite leaching was also discussed based on experimental results and the above model."

Jan 1, 2003

By Tom Leistner, Urs A. Peuker, Martin Rudolph

"It is well known, that for conventional froth flotation techniques the processing of ultrafine mineral particles is generally inefficient and results in rather low-grade concentrates and relatively high losses of valuable minerals. Therefore, the investigation of other possible methods, which can selectively separate such fine particle systems effectively, is of considerable interest. In this study, the application of two-liquid flotation, a flotation-related process using oil droplets instead of air bubbles, is investigated as a possible processing strategy for the separation of ultrafine particle systems. The investigation involves the testing of the two-liquid flotation technique as simple laboratory-scale batch trials and moreover, the up-scaling to a semi-continuous process by using a modified lab scale flotation column. Magnetite and quartz particles, with particle sizes below 10 µm respectively, as academic mineral mixture and iso-octane and water as the two immiscible liquid phases are chosen for the experiments. To manipulate the wettability of the magnetite particles as well as the interfacial tension of the oil/water interfaces, surface active reagents of fatty acid basis are introduced in the system. The selectivity of the process is characterized by determining the removal of magnetite particles from the aqueous suspension through selective accumulation at the oil/water interface or extraction into the oil phase, respectively. Operational parameters including pH of the aqueous suspension, additional electrolyte addition and surfactant type as well as dosage are varied in order to maximize the efficiency and stability of the process."

Jan 1, 2014