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By John Ralston

"Interfacial chemistry plays a pivotal role in bubble-particle capture, for it controls whether or not attachment occurs. Surface heterogeneity, degree of surface hydrophobicity, bubble nucleation and related phenomena influence the stability of the aqueous wetting film between a particle and an approaching bubble. The latter must be unstable if capture is to occur. Various techniques that may be used to quantify this interfacial, chemistry-dominated behaviour, are described.The efficient capture of specific particles by rising bubbles and the delicate control of interfacial chemistry that leads to selective capture are central issues in froth flotation. For efficient capture to occur between a particle and a bubble, they must undergo a close encounter, a collision process dominated by hydrodynamics. Should this encounter bring the particle and bubble within the range of attractive forces, the intervening liquid film between the bubble and the particle will drain, leading to a critical thickness at which rupture occurs. The liquid-vapour interface then retreats over the solid particle surface until a stable wetting perimeter is established. The particle and bubble are then joined after this attachment process. The particle may only be dislodged from this state if it is supplied with sufficient kinetic energy to exceed the detachment energy in this detachment process. These various events are now well documented and may be followed using high-speed videomicroscopy (Schulze, 1984; Nguyen et al., 2001).The process of collision can now be described quantitatively for single bubbles colliding with bubbles under various flow regimes (Dai et al., 1998) and appropriate scale up is possible for multiple bubble particle collisions occurring under turbulent conditions (Pyke et al., 2002). In this paper we will be concerned with the role of interfacial chemistry and how this influences the attachment process."

Jan 1, 2003

By Xingshi Yang, Ghislain Bournival, Seher Ata

"Particle-laden interfaces are a fundamental research topic in froth flotation since the process involves particle-coated bubbles in both the pulp and the froth phase. In most experimental studies the characteristics of the particle layer in multi-bubble systems are poorly defined. An experimental setup has been developed based on a Langmuir-Blodgett (L-B) trough. The modified trough allowed introducing an air bubble beneath the particle monolayer formed at the air-water interface which made the study of the interaction between the bubble and the monolayer under various pH values possible. The monolayer characteristics of the particles were also studied and compared in terms of surface pressure (?-A) isotherms and packing factor. On compression, the particles formed branched structure at high pH whereas a uniform monolayer was formed at lower pH. Observations related to the behavior of particles during compression and expansion cycles, and the coalescence of a bare bubble with the flat particle laden interface were provided and the implication of the results for flotation process was discussed.INTRODUCTIONFroth flotation is known for its versatility and ability to concentrate low-grade, complex ores. It is considered a physico-chemical process in which particles attach to air bubbles, depending on their hydrophobicity as well as other factors, and are carried to the surface to form a froth layer. Reagents are used to stabilize bubbles and the froth layer (Pugh, 1996). However, particles, which are carried by the bubbles or entrained, significantly contribute to the stability of the froth phase (Ata et al., 2003; Zanin et al., 2009; Bournival et al., 2015a). Their relevance in mineral processing has led to a number of fundamental studies on the effect of particles and their properties on the process of froth flotation.Flotation systems are particularly difficult to characterize due to the broad range of properties of particles (e.g. size, liberation, hydrophobicity, etc.) and inconsistent operational conditions (e.g. changes in water quality, reagent addition, etc.). Several studies have made the use of well characterized particles in laboratory conditions. Such studies allowed the finding of an optimal contact angle for the stabilization of the froth phase (Johansson and Pugh, 1992; Ata et al., 2002). Froths have a large number of bubbles so that individual interactions are not observed. The study of two bubbles allows to determine the stability of the bubbles, with particles, and to some extend the stability of the bubble-particle aggregate (Gourram-Badri et al., 1997; Bournival et al., 2015b). The removing of particles between two bubbles may also be studied from a Scheludko cell (Johansson and Pugh, 1992) or by observing a bubble with a flat interface (Sethumadhavan et al., 2002). However, these systems provide limited information on the arrangement of the particles."

Jan 1, 2018

By G. K. Nimal Subasinghe

The establishment of grind size that optimally liberates the valuable mineral for efficient down-stream processing is of great importance for most mineral processing operations. Reasonably accurate comminution models as well as models of downstream separation processes may be found in the literature but their use in optimizing grind size is limited without an associated liberation model. In this work, an attempt has been made to address the above shortcoming by demonstrating how the effective parameters of the downstream flotation process may be predicted from the liberation characteristics based on the ore texture data for a disseminated nickel ore. In this regard, the liberation model based on linear intercept distributions of mineral and gangue proposed by King (1979) and its application to predict the flotation performance of an industrial plant demonstrated by Schaap (1979) may be considered useful contributions. However, while the model proposed by Schaap is simplistic enough, it is based on several assumptions due to the non-availability of intercept length measurements on the parent rock, in particular, on the extent of mineral exposure on the surface of comminuted particles. In this work, the linear mineral and gangue intercepts on polished specimens of a binary ore, comprising darker pentlandite as the valuable mineral and lighter barren host rock were measured using an image analyser. The resulting intercept distributions followed negative exponential distributions. Using the mean sizes of mineral and gangue intercepts, the proportion of liberated, compo-site and mineral occluded particles of a given size, the extent of mineral exposure on the surface of particles and their mean mineral contents were calculated using principles of renewal theory. The rock was then crushed and ground and different size fractions were floated. It has been shown that the parameters of observed recovery data based on 1st order kinetics such as the associated rate constant and ultimate recovery agrees well with those predicted from the quantities calculated above. This work has important practical implications since it can indicate variations in flotation performance arising from changes in mineralization within a large ore body.

Jan 1, 2014

By Carlos de F. Gontijo

The flotation of quartz particles was studied over the particle size range from 0.5 µm to 1000 µm and for advancing water contact angles between 0º and 83º. Flotation was performed in a column and in a Rushton turbine cell. Particle contact angle threshold values, below which the particles could not be floated, were identified for the particle size range 0.5~1000 µm, under different hydrodynamic conditions. The flotation response of the particles, either in a column or in a mechanically agitated cell with a similar bubble size, was comparable. Turbulence plays a role, as does bubble-particle aggregate velocity and bubble size. The stability of the bubble-particle aggregate controls the maximum floatable particle size of coarse particles. For fine particles, the flotation limit is dictated by the energy required to rupture the intervening liquid film between the particle and bubble. Flotation of very fine and large particles is facilitated with small bubbles and high contact angles. These results greatly extend our earlier observations and theoretical predictions.

Jan 1, 2014

By Bulelwa Ndlovu, Saeed Farrokhpay, Dee Bradshaw

The effects of phyllosilicate minerals on the flotation performance and froth stability of a copper ore was investigated. It was found that various phyllosilicate minerals affect the copper recovery differently however they all caused the flotation grade to be reduced. The effect of different phyllosilicate minerals on the froth stability followed the order of talc >> montmorillonite > muscovite > kaolinite > illite. The results demonstrated that there could be a relationship between the deleterious effect of phyllosilicate minerals on the flotation and froth stability. Talc and montmorillonite have both shown the highest effect on the flotation recovery and grade as well as froth stability. On the other hand, illite has the least effect on the both flotation performance and froth stability. Kaolinite and muscovite also affected the copper flotation grade (but not the recovery) while they also affected the froth stability. Therefore it is possible to control the flotation performance when phyllosilicate minerals are present via monitoring and controlling froth stability which needs to be investigated further.

Jan 1, 2014

By L. J. Li, Q. Zhang, Z. H. Liu, Q. L. Chen

Phosphogypsum (PG) is an industrial waste from the production of phosphate fertilizer. The utilization of PG is restricted by its containing impurities, and the pretreatment is crucial to eliminating these impurities. The purpose of the research is to recycle pretreatment PG as raw material for preparation of a-calcium sulfate hemihydrate (a-HH) by salt solution method. The effect of pretreatment technologies of lime neutralization and washing on dehydration rate, phase composition and morphology evolution of a-HH were investigated by crystal water content analysis, XRD and SEM. Furthermore, the change of pH in the reaction process was also discussed in detail. The results show that the dehydration rate of conversion PG to a-HH increases and the corresponding induction period, crystal growth period and total time decrease with an increase in CaO dosage from 0.2% to 0.6%. In the presence of 0.4% CaO or 0.6% CaO, the a-HH presents a long hexagon-prism-shaped crystal with a purity of 94%, and the end face of a-HH presents polyhedron. The system pH sharply decreases with the reaction time under different CaO dosage, and the pH variation from the initial alkalinity to acidity. The main reason is that as the co-crystallized phosphorus dissolved and released HPO42-, and with the pH decreasing to 4-5, HPO42- transformed into H2PO4-. The dehydration rate of washing PG is lower than that of original PG. Compared with the original PG, a-HH with the larger width and smaller aspect ratio can be achieved from the pretreatment PG subjected to lime neutralization and washing, meanwhile the crystal surface is more smooth.

Jan 1, 2018

By Fiona Sofra, Briony C. Ruse, David B. Boger

"The sustainability of the mining industry must be addressed through improving tailings management. The use of thickened tailings and pastes stems from a paradigm shift towards designing tailings disposal sites to suit their surrounding environment, rather than manipulating the environment to accommodate the tailings. Thickened tailings and pastes usually exhibit non-Newtonian behaviour, so a thorough understanding of the rheological characteristics of the material is required in order to determine the disposal plant operating conditions.Full Cost Accounting techniques may be used to provide financial justification for the implementation of alternative tailings disposal techniques through the calculation of a disposal cost per tonne of tailings over the life of the facility. Improved disposal methods such as thickened tailings disposal involve additional initial capital expenditure but reduce environmental impacts. The cost savings associated with environmental impact mitigation are reflected in Full Cost Accounting outcomes.Rheological characterisation is significant as a design basis that may be analysed using Full Cost Accounting to justify the initial capital expenditure of dry disposal systems for improved environmental performance."

Jan 1, 2003

By Fu Ping-Hao, Sergio Mauricio Vianna, Ewen Silvester, Emmy V. Manlapig

"Over the last 5 years, an ambitious project has been undertaken at the Julius Kruttschnitt Mineral Research Centre (JKMRC) aiming to isolate, study and, if possible, model the effect of particle size, liberation and collector adsorption density on the floatability of mineral particles. As part of this project, we have conducted highly controlled flotation test-work, combined with state-of-the-art solution and surface analytical techniques such as High Performance Liquid Chromatography (HPLC), Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) and detailed mineralogical analysis to fully characterize the flotation behavior of a natural ore.The flotation tests were undertaken using a high-grade lead-zinc ore from BHP-Billiton’s Cannington mine (Australia) in a specially designed continuously operated laboratory scale flotation rig. Solution and adsorbed collector concentrations were measured independently during the course of the flotation tests using HPLC based ex-situ techniques. Liberation studies were performed using the JKMRC Mineral Liberation Analyser (MLA) on selected size intervals of different streams to estimate the specific surface area of galena. These results were used to calculate the collector adsorption density (collector coverage) on galena particles, with the eventual aim of developing a mathematical model describing the relationship between pulp chemistry, feed mineralogy, and floatability of galena particles."

Jan 1, 2003

By Di Liu, Yongjun Peng

"It was identified that clay minerals adversely affect fine coal flotation through slime coatings. In the study, it was interesting to find that an anionic polymer dispersant, lignosulfonate, successfully mitigated the negative effect of clay minerals in coal flotation using fresh water, but in saline water, it exacerbated coal flotation.In order to understand the mechanisms underpinning the different behaviour of lignosulfonate in coal flotation using fresh and saline water, the adsorption isotherm, and dynamic light scattering (DLS) measurements were conducted in this study. While DLS monitored the molecular conformation change (swelling or shrinking) of the polymer in fresh and saline water, adsorption isotherms enabled polymer adsorbed amount on clay and coal mineral surfaces to be determined. It was found that lignosulfonate adsorbed on the coal and clay mineral surfaces providing effective electrostatic repulsions and resulting in a mitigation of clay minerals from coal surfaces in deionised water. In the presence of saline water, however, polymer molecular conformation changed. Polymer molecules were compressed and adsorbed in form of aggregates. The adsorption amount of lignosulfonate on clay minerals increased in saline water. A low dosage of lignosulfonate could not provide sufficient electrosteric repulsion to disperse clay minerals. Moreover, the high adsorption amount of the polymer on coal and clay surfaces led to a more hydrophilic coal surface, and coal flotation was therefore depressed in saline water. This study provides a new insight into understanding the role of anionic polymeric dispersants in mineral flotation using different quality water."

Jan 1, 2014

By lves Matiolo, Jorge Rubio, Carlos Perez Guerrero, Denise G. Nunes, Fabiano Capponi

The problem (very old) of processing by flotation, the fine (“F”, 38-13 µm) and ultrafines (“UF”, < 13 µm) mineral particles continues to be a major technical challenge in the area of mineral processing. Many different processes have been proposed over the last three decades but, unfortunately, most of them have not found practical applications yet. This paper describes some advances in flotation research in fines (“F”, 38-13 µm) and ultrafines (“UF”, < 13 µm) mineral recovery by two different techniques. Extender flotation (EF) and flotation with bubbles with a wide size distribution-SB of copper sulphide ore fines (1 % Cu) were compared with a “standardised” (STD) mill laboratory procedure. Comparative evaluation was made through concentrate grade and recovery (size by size results included), “true” flotation recoveries and process kinetics. Copper porphyry samples, containing about 1/3 of the mass and about 37 % of the total copper content in the fines and ultrafines fractions were used. In the EF tests diesel-in-water emulsions were used as an extra reagent, added after the collector and frother addition. In SB tests, drawing air through an aspiration nozzle, directly in the pulp, generated bubbles sized about 50-200 µm. Both techniques yielded higher metallurgical efficiencies than the mill standard but better results were obtained with the extender flotation, with emulsified diesel oil (90 gt-1). Concentrate recoveries were of the order of 85-90 % (84 % in standard conditions), 14-17 % Cu grade (15 % Cu in the standard) and 3.5-4.5 min-1 for the Klimpel rate constant (3 min-1 in the standard). Size by size and true flotation results proved that metallurgical and kinetic gains, obtained with the two techniques, might be attributed to fines and ultrafines enhancement. Data obtained are discussed in terms of physical and physicochemical parameters related to aggregation and capture (of particles by bubbles) phenomena and the practical potential of these techniques are envisaged. The following figure shows size-by-size copper recoveries results, after classification of produced concentrates and tailings using micro-sieves. Results clearly show that flotation of the F and UF fractions is highly improved with injection of small bubbles (SB) and with the addition of an extender collector. It is believed that the techniques presented here will establish shortly a new basis for the flotation enhancement of the F and UF, aimed at solving a very old problem. This work is being continued, now at pilot plant scale, and results will be published en the near future.

Jan 1, 2003

By I. H. Mukhametshin, E. N. Baranova, I. B. Fadina, E. A. Ashirbaeva

The purpose of the research is the development of a complex of solutions for the maximum extraction of non-ferrous and precious metals from persistent mineral raw materials by heap bioleaching from spent heap leaching (HL) stacks. Methodical recommendations for assessing the suitability of primary and technogenic refractory mineral raw materials for heap bioleaching are developed. Active associations of microorganisms have been created for the conversion from various types of ores to the solution of S, Fe, As, Sb, Cu, Zn, Mn, Ni, Mg, P and other elements, as well as methodologies for their storage, immobilization and preparation of bioreagents in industrial conditions. On a pilot scale, tests were carried out on samples weighing 15-17 thousand tons of refractory gold-sulphide ores (more than 50% of gold is associated with sphalerite), gold-quartz ores with colloidal gold (74% associated with quartz and pyrite) and gold-silver ores with elevated copper and zinc content (1.5 and 3,5%, respectively), as well as man-caused material lying for 4-5 years of spent quarry material of oxidized gold-silver ores. In the pilot-industrial tests of heap bioleaching of gold-sulfide ores, gold recovery of 84-85% and silver was achieved to 89-90%, the possibility of obtaining high-yield solutions of copper and zinc, suitable for hydrometallurgical processing, from gold-silver ores, and the possibility of obtaining waste with a dump content of valuable components, suitable for deep disposal in the construction industry. When comparing two technologies for processing refractory ores after biooxidation under HL conditions, when 1000 tons of ore processed by the bioreagent were re-milled from a size of 40 mm to 0.1 mm and cyanated under the conditions of the factory process, the same results were obtained for gold recovery (85%) and silver (90%), as with the heap version. The copyrights of the development are protected by a patent.

Jan 1, 2018

By Z. K. Liu

Production of the amines collectors and cation surfactant gives out the liquid waste containing high COD (Chemical Oxygen Demand) and ammonium & nitrogen, which is difficult to be treated with conventional biological method to reach waste water discharge standard. In this paper an engineering practice of treatment on the liquid waste by the technology combined high effective microbe with A/O (Anaerobic& aerobic) process is presented. The quality of treated water comes up to class A national standard for discharging.

Jan 1, 2014

By Hugo Barrientos

"The growing need to optimize the mining processes produces a need for users to have a simple, reliable, secure and cost-effective method to monitor the values of the variables measured in field. The solutions described in this paper, we will demonstrate how the implementation of Emerson Smart Wireless technology helps to optimize the leaching and electro winning processes. An effective monitoring of the variables involved in the operation of a heap leach, such as pressure, flow rate, pH, water level control and regulator valves can improve production and optimize the use of sulfuric acid, which results in a more effective management of resources and helps reducing input costs. Moreover, the constant monitoring of variables prevents the risk of landslides, reducing maintenance costs. In electro winning cells, the wireless solution measures variables such as pressure, flow rate, temperature and voltage provides a performance indicator for the entire operation, capable of detecting and predicting shorts, and monitoring the overall functioning of a cell or group of cells. As a result of the applications studied, users can monitor variables in real time, optimizing the use of resources, quickly detecting possible flaws in the process and reducing the risks in the operation. All these factors have a direct impact on company results."

Jan 1, 2014

By Christopher Davey, Professor Emeritus, Marian Mazurkiewicz, Peter Kanjorski

The concept of a high pressure liquid jet mill with highly unsteady flow, has been developed and recently patented by Cornerstone Technologies LLC (CsT), for the purpose of micron and sub-micron particle production. The mill accepts feed sizes up to 15mm for some materials and is capable of sub-micron production. Successful material range from precious metals such as silver and palladium to dielectric components and substrates such as Barium Titanate slips, zirconia, titania and silica. The process has also succeeded in adequately reducing the size of materials for both composite and coating uses such as anthracite coal, graphite, chrome metal, wollastonite and more than 100 others. A unique design approach has been taken to highly maximize the energy flux in the mill’s chambers to create extremely high turbulence and destructive cavitation. This is assisted by shock waves, which cause particles to undergo ultra high frequency pressure pulsations, high frequency collisions and then abrasion, shattering, hydro-wedging, and cleaving. Due to these extreme properties the processing occurs in just fractions of a second allowing throughputs up to 1000 kg/h on a machine that would fit inside a 60 cm box. The technical solution and technological advance, as well as the environmental and economic benefits indicate rapid and wide spread acceptance of high-pressure liquid jet milling in modern industry.

Jan 1, 2003

By Bern Klein, Givemore Sakuhuni

Flotation is the dominant base metal extraction technique and it requires ore to be ground below the liberation size for effective recovery due to its dependence on mineral surface properties. For a poly-metallic ore, differential hardness of constituent minerals leads to over grinding of softer minerals before the harder minerals are fully liberated, which makes selection of a target grind size complex, and the complexity increases when treating leaner ores. Flotation recovery deteriorates above 100 and below 10 microns causing significant loses of valuable minerals in most flotation circuits. Although enhanced gravity concentration is known to be effective at recovering particles above 100 microns, which are difficult to hydro-dynamically transport, exploiting differential specific gravity for base metal separation was not an option in the past. This was partly due to the absence of high mass yield gravity techniques. The advent of continuous gravity concentrators with flexible mass yields, in the past two decades, has necessitated investigation of possible base metal applications. The Knelson CVD, one of the continuous discharge centrifugal concentrators, has an established application niche for sulphides associated with gold. However, its base metal applications have never been rigorously tested. Considering the dependence of flotation recovery on particle size, continuous discharge centrifugal concentration can be integrated in flotation circuits to capture flotation non-recoverable coarse particles. This paper explores how particle size, liberation and mineral hardness influence application of continuous centrifugal technology to regulate galena deportment in a polymetallic base metal plant. The results show that particle size affects galena recovery more than liberation. In view of these results, the CVD can be integrated in the primary grinding circuit to pre-concentrate the heavy sulphides at a coarser grind size with potential grinding energy savings.

Jan 1, 2014

By K. Malysa

Bubble collisions with ore grains and a selective formation of the bubble-grain aggregates are necessary steps for flotation separation of useful and gangue components of an ore. For the attachment of valuable mineral grain to the colliding bubble a liquid film, separating the bubble and the grain needs to rupture during short time of their collision. High hydrophobicity of the grain surface is favorable because stability of the separating (wetting) film is much lower at such surfaces, that is, the film ruptures faster and at greater thickness. Simultaneously, it needs to be kept in mind and taken into consideration that high affinity to air is a typical feature of hydrophobic surfaces. Thus, when the hydrophobic surface is immersed into aqueous phase the air can stay attached to such surfaces and affect kinetics of the bubble attachment. The paper presents results and analysis of dynamic phenomena occurring upon the collision of the rising bubble followed by its attachment to hydrophobic (Teflon) plates of different roughness. The influence of the Teflon surface roughness, solution concentration, bubble size and impact velocity on bouncing of the colliding bubble, time of the three phase contact (TPC) formation and drainage time of the liquid film, formed between the solid and bubble surfaces, is described. High hydrophobicity, as showed earlier (Malysa et al, 2005), does not assure that each collision leads to the TPC formation and attachment of the colliding bubble. Roughness is the parameter of crucial importance for kinetics of the bubble attachment to hydrophobic surfaces (Krasowska and Malysa, 2007; Krasowska et al, 2009; Kosior et al, 2011). Enlarged roughness of the Teflon plate, from ca. 1 to 80µm, results in shortening the time of the TPC formation (bubble attachment) by over an order of magnitude - from 105 to a few milliseconds only. Higher surface roughness means that larger amount of air can be entrapped in bigger scratches and cavities of the Teflon plate during its immersion into aqueous phase. Results documenting importance of the air presence are showed and mechanism of the air facilitated TPC formation and bubble attachment to hydrophobic surfaces is described. Keywords: bubble collisions, hydrophobic surfaces, teflon plate roughness, TPC formation

Sep 1, 2012

By Yu. Gurevich, M. Teremova, I. Prokopev, A. Razvjaznaya, N. Algebraistova

"The objective of this work is the scientific justification and development of efficient and environmentally-friendly method of bulk concentrate preparation for selection with application of microbiological practices. This research suggests to apply Pseudomonas Japonica bacterial culture to the bulk concentrate before the selection circuit in order to clear the surface of sulphides from the xanthate skin. It is also suggested to apply bacterial consortium Ochrobactrum ?nthropi and Pseudomonas aeruginosa JCM 5962 for desorption of diesel residual concentrations. High-efficient and environmentally friendly method of copper-molybdene and lead-zinc bulk concentrate selection was developed based on theoretical and experimental research work with application of microbiological practices. In comparison with conventional methods (steaming, sodium sulphide washing) the above suggested bio-technological method of bulk concentrate preparation before selection cycle will allow to reduce material and power expenditures, and it is also environmentally friendly. INTRODUCTION High-efficient selection of sulphide bulk concentrate is gained exclusively after collecting agent is removed from mineral surface. Therefore, the problem of bulk concentrate preparing before the selection cycle is acute, since the further technological parameters of the subsequent separation depends on the effectiveness of pulp preparation. Existing traditional ways of bulk concentrate preparation. such as washing or steaming, are characterized by high energy and material costs in industrial conditions [1,2]. The microbiological treatment before separation of the bulk concentrate into different kind of concentrates appear one of perspective processes for treatment of bulk concentrates [3,4]. At the present time, the world practice of processing mineral raw materials demonstrates the wide application of technologies using microorganisms: bacterial leaching and oxidation, purification of industrial wastewater. This is due to the fact that biotechnological methods are environmentally safe, low-cost, and suitable for refining complex ores and raw materials of industrial origin."

Jan 1, 2018

By Bern Klein, Givemore Sakuhuni, Libin Tong

The use of continuous discharge centrifugal concentrators introduced in the early 1990’s for recovery of gold associated with sulphides has introduced a novel application niche for gravity concentration which could not be realized with the low mass yield batch and semi-continuous concentrators. A typical application is scavenging gold associated with sulphides from flotation tails which has potential to increase productivity by reducing gold loss to tailings and lower grinding cost by using a coarser grind. However, the full potential of this technology has not been fully exploited partly due to the lack of reliable small sample procedures to demonstrate applicability. This paper introduces a bench-scale procedure developed to characterize the Knelson Continuous Variable Discharge concentrator (CVD) for scavenging gold from flotation tails. The procedure code named gravity release analysis was derived from standard flotation release analysis. It is a modification of the gravity recoverable gold and gravity amenability test in order to best simulate continuous centrifugal concentration. Based on this iterative procedure, a gravity release index similar to the flotation rate constant, for measuring individual mineral gravity susceptibility for an ore is introduced which can be a useful quantitative measure to both predict application of centrifugal concentration and for plant design. The gravity release analysis procedure was tested on a polymetallic flotation plant tailing at Myra Falls, BC, Canada and results show that it can predict CVD performance. The gravity release index for gold was observed to decrease with each successive cleaner stage showing that the initial stages recover liberated gold whilst successive runs recover gold associated with sulphides and or gangue. The difference in magnitude of the gravity release index for different mineral species shows the species separable by centrifugal concentration.

Jan 1, 2014

By J. R. Cui

The production of electric and electronic equipment (EEE) is one of the fastest growing areas. This development has resulted in an increase of waste electric and electronic equipment (WEEE). In view of the environmental problems involved in the management of WEEE, many counties and organizations have drafted national legislation to improve the reuse, recycling and other forms of recovery of such wastes so as to reduce disposal. Recycling of WEEE is an important subject not only from the point of waste treatment but also from the recovery of valuable materials. Consumer electronic equipment (brown goods), such as television sets (TV), radio sets, and video recorders, are most common. However, recent work on recycling of waste electric and electronic equipment (WEEE) primarily focused on personal computer and printed circuit boards scraps. Based on a detailed characterization study of consumer electronic scraps, recycling of TV scraps oriented to recovery of metals is highlighted by utilizing air table separation, eddy current separation, and optical (metal) sorting process. The result indicates that a high recovery of copper could be obtained by utilizing an effective gravity separation process. The separation results reveal that air table separation is an effective technology to recover metals from consumer electronic scraps. By using a DGS table, approximately 90% of non-ferrous metals were recovered in the heavy product with a purity of 40%. Printed circuit boards and cables in TV scrap cause metals loss due to the fact that metals in printed circuit boards and cables are not liberated from plastics and ceramic materials. The study shows that eddy current separation and optical (metal) sorting process provide alternatives for recovery of metals from shredded TV scraps.

Jan 1, 2014

By Kazutoshi Haga, Atsushi Shibayama, Kosuke Nishioka, Yasushi Kihara, Altansukh Batnasan

The aim of this study was to investigate the feasibility studies of seawater in flotation of a 1.5 mass % of copper containing copper sulfide ore. Effects of seawater, various frothers, and different distilled water/seawater ratio on flotation of copper sulfide ore were studied. Surface properties of native copper ore and sea water soaked were examined by using FT-IR spectrometry. Chemical contents of the copper sulfide ore and after flotation were identified using XRD studies. XRD pattern showed that the main constituents of the copper sulfide ore are chalcopyrite (CuFeS2), bornite (Cu5FeS4). Flotation experiments were carried out using mechanical agitation flotation equipment with a mineral separation type flotation cell. Froth flotation experiment was conducted using calcium hydroxide was used as a pH adjuster, using methyl isobutyl carbinol (MIBC), dow froth 250 (DF 250) as frothers and potassium amyl xanthate (PAX) as collector for the copper recovery from the copper sulfide ore containing chalcopyrite and bornite. The results showed that the copper recovery by flotation was dependent on the flotation medium and frother. The main results showed that the copper recovery by flotation was dependent on the process water and frother. The copper recovery reached 97 % and 87 % in the distilled water flotation and seawater flotation with MIBC, respectively. For seawater flotation with DF 250, the Cu recovery achieved near 95 % and grade of Cu in the froth product after 5 min flotation was reached 29.8 mass %.

Jan 1, 2014