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By H. C. Cooke

"The Eustis mine, which was discovered in 1865, lies about 6 miles southwest of the city of Sherbrooke, Quebec, in lots 2, 3, and 4, range 9, Ascot tp. The mine was operated almost continuously from 1865 to 1937, under vanous owners.The ore was pyrite with varying amounts of chalcopyrite, a small amount of zinc blende and galena, and a low content in gold and silver. Parts of it ran quite high in copper, but the mine average would probably have been between 3 and 4 per cent. The high percentage of pyrite made it profitable to separate the ore into a copper concentrate and a pyrite concentrate. The latter was shipped away for manufacturing sulphuric acid, or was treated in a plant erected in 1887 at Capelton by the Nichols Chemical Company.The ore is a replacement of mica schist, which in turn was formed by the shearing of rhyolite flows. Ore also replaces the 'green rock', a term locally applied to carbonatized mica schists. The ore contained numerous 'horses' and smaller fragments of country rock, in all stages of replacement, ranging from those whose character was quite distinct to those whose ancestry could only be detected by an indefinite banding preserved in the sulphides."

Jan 1, 1954

By I. M. Santos Moraes

The control of minor impurities (mainly As, Sb and Bi) in copper refineries has been a great challenge. Caraiba Metais' copper refinery produces a very high quality copper, registered in LME as grade A, and recognized as amongst the top ten in the copper world. At Caraiba's Tankhouse Bi and Sb are controlled by means of electrolyte bleed-stream removal after partial decopperizing in a set of electro-winning cells (liberators). Another way of reducing the Sb and Bi content in the electrolyte is by means of the arsenate precipitation chemistry. It is well known that the use of high arsenic concentrations in copper refinery electrolyte has the advantage of causing most of the bismuth and antimony to report in the anode slimes. However, the use of such mechanism of control may contribute to other undesired problems such as antimony and bismuth precipitation in the bulk of the electrolyte, what may cause severe contamination problems. This paper describes a period when some cathode contamination with Sb occurred at Caraiba Metais' Copper Refinery. It also presents an analysis of several process parameters related to the problem, the possible causes for the contaminations as well as the actions taken to correct the problem.

Jan 1, 2007

By M. Stelter

Since the first years in copper electrorefining natural products have been used as so called "additives" in the electrolyte. Glue as one of these additives offers a lot of different reactions with the metal ions and also with other additives like thiourea in the electrolyte. For a deep understanding of the effect of these additives it is important to know the routes of possible reactions in the electrolyte as well as the basics of electrocrystallization. Using this knowledge the interpretation of nodulation or inclusions of electrolyte in the cathodes in copper electrorefining is easier than before. Setting up on physical and chemical properties of the electrolyte and the additives practical investigations of the effects of additives in copper electrorefining and their impacts on copper crystallization and cathode quality are presented in this paper. Chemical deposition of glue against time and temperature are only few of the effects that are mainly caused by the use of natural products. In fact parameters like anodic and cathodic polarization are strongly affected by the additives as well as the effects of the additives are strongly affected by current density. This second part of the paper presents results concerning interactions of the above mentioned parameters.

Jan 1, 2007

By H. T. Michels

Recent laboratory studies show that several bacteria, known to be human pathogens, die when they come in contact with copper and copper alloy surfaces. The amount of live bacteria drops by several orders of magnitude, to zero, on copper alloys in a few hours. In contrast, no reduction is seen in the concentration of live organisms on stainless steel during the six-hour test period. Aluminum painted and coated surfaces and plastics would show behavior similar to stainless steel and show no effect. Coatings and other surfaces claiming to be antimicrobial showed little to no effect. These results suggest the selection of copper alloys for surfaces exposed to human touch can materially assist in reducing the transmission of infectious organisms. In order to make antimicrobial claims in the United States, the approval of the US Environmental Protection Agency (EPA) is required. The EPA-required efficacy testing is described and the test results are summarized. It is anticipated, that once regulatory approval is obtained, that this will facilitate the introduction of antimicrobial copper alloys in hospitals, nursing homes and other healthcare facilities, as well as schools, and public buildings. Some of the application and barriers, to entry into the healthcare markets are mentioned.

Jan 1, 2007

By Manouchehr Oliazadeh

Talc is used as a gelating, diluting, antimould and softening agent in the pharmaceutical industries. This article reviews efforts made for producing pharmaceutical grade talc from a mine located in the west of Iran, called Masoud Abad. Reaching to the pharmaceutical standards, was the principal goal of the talc beneficiation. Methods such as flotation and leaching were applied to eliminate the impurities. Considering to the negligible Fe content of the ore, the major impurity was calcium carbonate and to some extent dolomite. Depressants used in froth flotation were dextrine, quebraco and sodium silicate. Variation of collectors such as oil petroleum, paraffin, stearic acid were also used. After optimization of the effective parameters, followed by two stages of flotation (rougher and cleaner) acid leaching process was also applied as a complementary step to remove the impurities. CaO impurities in the sample was 11.63% which reduced to 1.03% after two stages of flotation, and finally reached to 0.03% CaO by leaching process. This figure is more lower than the world pharmaceutical standards (i.e. <0.6 % CaO). The highest recovery was 55% at the best conditions. Other impurities (i.e.As, lead, heavy metals ,?) which were at standard levels, confirmed by the authorized health organizations.

May 1, 2001

By L. Byszynski

The results of a three month evaluation of the application of EMEW® technology at the KGHM Glogów II Smelter tank house bleed stream are presented. The current, conven¬tional electrolyte decopperization process has some limitations, including: only a fraction of its production is commercial grade cathode copper, significant operating costs, low current efficiency, low current densities resulting in low copper depletion rate, and arsine gas and sulphuric acid emission. The EMEW® cell technology developed by Electrometals Technologies Ltd. can overcome many of these limitations. Tests were performed on a pilot EMEW® installation comprising 30 cells at ambient temperature on electrolyte bleed, using current densities between 100 and 600 A/m2 , with copper concentrations between 45 and <1g/dm3. Results showed that a high grade copper can be obtained to the level of 7 g/dm3 of copper concentration in electrolyte. The use of EMEW® technology allows the direct and efficient recovery of over 85% of the copper contained in the bleed electrolyte. Glue & thiourea addition were tested in order to improve the parameters of the copper depletion process. The behavior of Arsenic and Bismuth was observed and a means for their elimination from the system proposed. On-line copper concentration monitoring is proposed to improve control and performance.

Jan 1, 2007

By P. Bonadia, A. Tabereaux

Nearly all aluminium smelters are increasing the potline amperage to achieve higher aluminium production. In some instances the higher amperage operation has a significant negative impact on shortening the lifetime of aluminum electrolysis cell cathodes due to loss of the protective sidewall cryolite ledge freeze and too rapid penetration of the cell bottom refractory lining by cryolitic bath components due to the higher temperature isotherms. Thus Cathodes require careful thermal modeling of the cathode relining designs and improved refractory materials to allow greater heat loss from the sidewall to preserve a stable sidewall ledge freeze at higher amperages, and the selection of optimum refractory barrier materials to control the penetration and reaction of bath into the cathode bottom refractory and insulation lining. This requires an understanding of the reaction mechanisms and product formation for molten NaF enriched bath and alumino-silicate refractories. It is desirable to use dense, low porosity refractory fireclay firebricks, or similar materials with a sufficiently high silica content to promote the formation the mineralogical phase albite, NaAlSi3O8, that significantly increases the viscosity of the melt which slows the diffusion of reactive species in the melt and thereby retards further bath penetration.

Jan 1, 2004

By M. Fooladi Mahani, M. R. Izadpanah

The knowledge of the thermal shock resistance of refractory materials is of outmost importance due to their wide range of applications in various industries, namely; ceramics, oil refinery, thermal insulation, nuclear power, chemical and petrochemical industries. Thermal shock resistance is measured in terms of the number of cycles that a refractory material can withstand when subjected to sudden temperature changes. This property is measured experimentally by heating a sample of the material and cooling it in a known environment then the number of cycles it withstands this treatment without spalling is a measure of its thermal shock resistance. Although this method of experimentation has long been the practice, but it is both expensive and time consuming. Various studies have been carried out to predict this vital property, however, the rang of applications are limited. The present study employs a test rig by which temperature distributions in magnesite samples are accurately measured. This information plus other results obtained from relevant tests on related properties are used to develop a model which predicts the number of quench cycles withstand by different materials when subjected to sudden temperature changes. The comparison of the theoretical values using the solution of the presented model with experimental data for different materials having different thermal resistance shows a closed agreement.

Jan 1, 2004

By Par G. Jönsson, Joachim von Scheele, D. S. Sarma, Mukul Goyal

Dust from flue gas cleaning systems at iron and steel production is frequently considered as a waste problem, but it is actually a potential raw material source. By using a technology like the oxyfuel based OXYFINES technique, it can be melted into a suitable form. The product from this processing, however, needs to meet the requirements of a recyclable raw material, here particularly a top-charged blast furnace feed. The present work has been focused on characterization of the product produced from these dusts by OXYFINES technology. The investigation has been carried out on samples of processed dusts from a European integrated steel mill. It was done by means of chemical analysis, density measurement, light optical microscopy, X-ray diffraction, scanning electron microscopy combined with energy dispersive spectroscopy, and micro indention hardness measurement. Special attention was paid to the presence of zinc, an element that might be harmful while recycling the material (e.g., in a blast furnace). The results show that the product contains four different regions with different morphologies and properties in the material, which are discussed in detail. The overall conclusion is that by processing the dusts in this way, a raw material suitable for recycling in a blast furnace can be obtained.

Jan 1, 2004

By Jamal Asfahani

Abstract - Natural gamma ray well logging, an effective tool in geophysical prospecting, is used to investigate the radioactive and phosphatic layers in the Khneifiss mine in Syria. The interpretation of the gamma ray measurements, using numerical methods of analysis developed previously and applied successfully in some phosphatic areas in Syria, make it possible to define precisely the phosphate thickness from place to place in the study area. This technique has been successfully applied while studying seven boreholes in the area. Sixty-three core samples from phosphatic layers in the boreholes have been analyzed, using gamma ray spectrometry for the determination of P2O5 , U, Th, and K. Good correlation between P2O5 content and U concentration has been found. The total count gamma logs correlate reasonably well with the U core analysis, suggesting that radioactive equilibrium exists in the U decay series. These gamma logs can be therefore used effectively to quantitatively map the distribution of P2O5 and U. The characteristics of both subsurface phosphatic sand and phosphatic rocks have been investigated and outlined using a statistical approach. The affinity of uranium to some trace elements such as V, Sr, Cu, and Ni has been verified using correlation matrices of these elements.

Jan 1, 2002

By A. Jeffkins

Visibility is restricted when operating load haul dump vehicles resulting in a number of serious accidents in the Ontario Mining Industry. One of the leading causes of these accidents is the inability of the equipment operator to see clearly people, objects or hazards around the machine. Previous line of sight testing by the research team found specific machine characteristics were responsible for blind spots and impaired visibility. In order to identify feasible design modifications a computer simulation program, Classic JACK 3.1, was utilized. Program features include human factors analysis, which allows evaluation of line of sight and operator posture in order to decrease risk of musculoskeletal injury. Research within the virtual computer environment consisted of a Visibility Audit and a Target Audit in order to quantitatively determine how certain components of the LHD design affected the line of sight around the vehicle. Results indicate that modifying the LHD light brackets, engine profile, cab posts and other components will enhance visibility. The addition of cameras located on the front and rear of the vehicle were able to enhance the operator?s sight lines to previously obstructed areas. Modifications to seat height and the operators orientation both improved sightlines and decreased risk factors associated with back and neck musculoskeletal disorders.

May 1, 2003

By Anna Maria Venezia

Bimetallic Au-Pd catalysts supported on amorphous silica-alumina (ASA) with vary amount of alumina (0, 8, 14, 28 and 100%) were prepared by the simultaneous reduction of palladium and gold precursors by ethanol in the presence of the polyvinylpyrrolidone (PVP). X-ray diffraction and X-ray photoelectron spectroscopy analyses indicated formation of alloyed Au-Pd particles. Ammonia temperature programmed desorption measurements were performed to monitor the acid strength and the amount of acid sites on the catalysts after their reduction with 10%H2/Ar at 573 K for 1h. The effect of the support acidity on the catalytic activity was investigated in the simultaneous hydrogenation (HYD) of toluene (T) and naphthalene (NP) in the presence of dibenzothiophene (DBT). Coke formation was also determined. Under the selected conditions (P = 5.0 MPa, T = 523 K, WHSV = 41.2 h-1), all the catalysts were resistant to poisoning with 113 ppm of S (as DBT). The hydrogenation activity of toluene and the HDS activity of DBT were found to correlate with the concentration of the medium strength acid sites. The enhancement of the HYD activity and the S- tolerance was related to modifications of the electronic properties of the metal atom upon interaction with the Brönsted acid sites and upon intermetallic interaction.

Oct 1, 2003

By J. K. Van Beek

The Deep Underground Science and Engineering Laboratory (DUSEL) is a scientific facility that will be placed in the deeper reaches of the Homestake mine, Lead, SD. Our team of geologists and engineers is carrying out the first scientific project awarded to the site ? Towards a Transparent Earth. Taking advantage of the thousands of open exploratory and sand-line holes, we are installing the beginnings of a seismic observatory. Each installed station consists of a 3-D accelerometer package and a 1 nanoradian 2-D tilt meter. In order to allow for a variety of monitoring and characterization studies, the array instruments are sensitive over the frequency bandwidth of 0.2 - 1 KHz. Three, three component accelerometer stations are currently installed ? in a 140 m deep bore beneath the slurry pump house, and in 12 m deep bores on the 2000-foot level, 800 and 400 m from the Ross shaft. There is a tilt-meter installed at each 2000 level station. These installations are in 150 mm diameter sand-holes. From the currently installed tilt sensors we are investigating solid earth deformation as a response to tidal potential. The accelerometers are being used to locate and characterize events associated with mine dewatering and rehabilitation.

May 1, 2009

By J. H. Pateson, D. C. Comrie, D. J. Ritcey

"Geopolymers are inorganic semi-amorphous three dimensional silico-aluminates of the poly(sialate) type (-Si-O-Al-0-) or of the poly(sialate-siloxo) type (-Si-O-Al-O-Si-0-). Polycondensation occurs at low temperatures with geopolymers being stable up to 12oo0 c. Research, development and application technology pertaining to geopolymers is being undertaken jointly with Dr. Joseph Davidovits of The Institute for Applied Archaeological Sciences of Florida, U.S.A. This joint focused upon the chemical Barry University in Miami Shores, research and development program has stabilization and solidification of various waste products through geopolymerization. Of particular interest is the geopolymerization of mine wastes including tailings and waste rock derived from the processing of base metals, precious metals, potash, coal and uranium deposits.INTRODUCTIOND. Comrie Consulting Ltd., in cooperation and technical liaison with CANMET, Ottawa has been testing the application of geopolymers to mining wastes. Corporate efforts to date have concentrated upon reactive acid tailings, principally from the abandoned Kam-Kotia Mine site, and dewatered paint waste sludges. Test work conducted to date has successfully yielded geopolymer treated materials and wastes with increased chemical and structural stability. Wastes containing heavy metals, cyanides, arsenic and sulphur dioxide have been successfully geopolymerized."

Jan 1, 1988

By Tyson C. Birkett

Initial indicator mineral sampling covering 425,000 square km of northern Quebec and subsequent follow-up of positive results convinced the Ashton ? SOQUEM joint venture to acquire mineral rights to 380,000 hectares prospective for diamond in late summer, 2000. Drilling in 2001 and 2002 identified eight kimberlitic bodies, all significantly diamondiferous. Commercial size stones (retained on a square mesh sieve with openings 0.85 mm) and encouraging grades have been returned by several bodies tested to date: The Renard bodies are formed by steep-sided breccia pipes with kimberlitic matrix surrounded by irregular outboard breccia zones within country rock. These bodies were emplaced in high-grade metamorphic rocks of the Superior Province of Archean age. Orthogneiss with lesser tonalite hosts the breccias, although regionally paragneiss is also present. Diatreme facies portions and nearby country rock are intruded by minor to major (Renard 1) amounts of hypabyssal-facies kimberlitic rock. Renard bodies are macrocrystic, with large olivine crystals set in a groundmass of olivine, phlogopite, monticellite, spinel, carbonate, apatite and serpentine. Proximity of various Renard bodies, with most in a core area of 0.5 square km will allow planning of an efficient mining operation. Geophysics, especially magnetic surveying, has contributed to identifying bodies of kimberlitic rock.

May 1, 2003

By A. Putz, F. Vincent, A. R. Laplante

"This paper briefly reviews some of the gravity research done at McGill University and current Canadian operating practices, with emphasis on results of interest for operators. The following topics are addressed: security, economics, predicting recovery, circuit optimization, unit selection and final upgrading. Emphasis is placed on the Knelson Concentrator.The topic of security and economics are addressed jointly, in terms of the place of the gravity circuit in the mill flowsheet. Actual plant experience is drawn upon to identify potential problems and actual solutions.Predicting primary recovery is linked with a characterization of the ore, the choice of a circuit, and the fraction of the bleed used. Factors such as feed preparation, preliminary upgrading, fraction of recycle treated, ability to recover fines and location of the bleed are discussed.Final upgrading is achieved almost only by tabling and smelting. This can lead to fine gold recovery problems when more effective units are used upstream. Alternatives are discussed.IntroductionResearch on gold recovery by gravity over the past eight years has associated McGill University with a number of gold producers. This paper attempts to review the information gathered from a practical perspective. Some of the information was generated in McGill University's labs, some gathered at plant site, and some was shared by operators."

Jan 1, 1994

By Victor A. Sowa

"Abstract - In 1938, a body of goethite and hematite was discovered beneath Steep Rock Lake near Atikokan, northwestern Ontario. This was at the time the largest and richest undeveloped iron ore body in North America. Mining began in 1944, fast-tracked by the needs of World War II, and through 1979 produced 79 Mt of 56.5% Fe. Production required the diversion of the Seine River, draining of Steep Rock Lake, building of a railroad, and a 25-fold increase of the local population. The mining project, at the time, was the largest project of its type undertaken in Canada. The current concepts of sustainable mine development and mine closures have advanced considerably since the period of operation and closure of the Steep Rock mines, and those operations would probably not have met current expectations of sustainability. However, some of the post-closure aspects of the mines provide illustrations of components of sustainability, which could form part of a basis for a post-mining sustainable land use plan. It is concluded that some of these components were successful in meeting current expectations of sustainable use, and although some aspects are unique to the circumstances at the Steep Rock mines, others could be applicable at other mine sites."

Jan 1, 2003

By P. Woo, N. Brodusch, R. Gauvin, H. Demers

The scanning electron microscope (SEM) was primary developed for imaging applications. With the introduction of the Si(Li) energy dispersive spectrometer (EDS), simultaneous imaging and x-ray microanalysis became possible. However, long working distance and high current were needed because the position and small solid angle of the EDS detector. The high spatial resolution is generally obtained at short working distance with a SEM. Unfortunately x-ray microanalysis is never performed in the best imaging conditions. The annular silicon drift detector system is inserted below the objective lens which gives a higher solid angle (up to 1.3 sr). In consequence, a lower working distance and probe current can be used. An improved spatial resolution becomes possible during x-ray microanalysis. With this x-ray detector installed on a cold-field emission scanning electron microscope, quantitative x-ray microanalysis with high spatial resolution at low beam energy and low current becomes possible with the possibility of using the various different type of imaging at the same time. Also, since the count rate can be as high as 1,500 kcps, which lowers significantly the detection limit of elements as well as the minimum feature sizes of different phases that can be distinguished.

Jan 1, 2014

By Dwayne D. Tannant

The Fox Pit at EKATI Diamond Mine reached a depth of approximately 150 m as of September 2005. The pit is designed with 11 m wide benches excavated using a double benching technique leaving 30 m high bench faces. A series of blasting tests were conducted to improve catch bench reliability and increase the percentage of benches that meet an 11 m catch width. The design changes focussed on reducing damage to the bench crest because maintaining the bench crests is the most important factor in achieving good bench reliability. The most significant improvement was obtained by raising the bottoms of the lower trim blastholes by 0.5 m. This change decreases the depth of broken rock below the final bench elevation, and consequently reduces damage to rock that forms the bench crest below. Another improvement was the use of smaller diameter (165 mm vs. 270 mm) blastholes in the A and B rows for the upper trim blast. This change reduces the charge per delay during detonation, reduces the powder factor slightly, and reduces the energy affecting the final pit wall and crest. As mining and the blast testing progressed, the portion of the bench with crest achievements (>11 m) increased from 57% to 75%.

May 1, 2006

By S. Zakaria

"Inco&apos;s Automated Haulage Truck System (AHT) is a revolutionary automatic guided vehicle that performs all load, haul and dump operations without human intervention. The high level of sophistication and the short period it has been in operation has only allowed a select few Inco personnel to become familiar with the ART operation and maintenance. As an aid to operations an expert system using the knowledge gained from the experienced specialists was implemented in the field.The AHT operating and maintenance assistance expert system will reason through the information given, arrive at conclusions and give advice to operations, technical and management personnel. It will provide comprehensive real-time troubleshooting assistance for the hydraulic, electrical and mechanical subsystems of the ART. The ART expert system has many benefits to Inco which include increased skill levels of ART operations and maintenance personnel, reduction in ART downtime, standardization of troubleshooting procedures and reduction in ART operating and maintenance costs. In the future, the expert system application will be linked to SCADA (Supervisory Control and Data Acquisition), maintenance and statistical software to display current and historical trends of variables from a centralized historical database. As well, a wide variety of features will be integrated into the system including AutoCad drawings, graphics, photographs, voice and video capabilities."

Jan 1, 1994