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By M J. Daniel

Comminution is the science of size reduction of brittle materials. It is integral to mineral extraction and is one of the most energy intensive processes in the mining industry. There are a number of tests used to quantify the strength of ore, which are then used to size the AG / SAG mill in circuit design. The calculated energy utilized for breakage in these devices is based on the assumptions that the materials treated are of average shape and that the processing equipment is designed to break the ore as efficiently as possible under the given operating conditions. In drop weight tests, it was found that shape significantly influences the measured rock strength. Controlled experiments with variations in blends of rock shape show that mill throughput increases with the addition of weaker shaped rocks.

Jan 1, 2012

By Mike McKevitt

We are trying to promote a concept and a change in management?s approach to the iterative process of grade control. This is important as grade control must routinely try and achieve the long term objectives set by the mine plan ??BackgroundBackground ??Factors contributing to variation from planFactors plan ??Basis of OptimisationBasis Optimisation ??Ore Block Optimisation processOre process ??Operating mine examplesOperating examples ??Chain of Mining. ??Intention is to highlight the need for repeatable and consistent materialand material-type classification to remain consistent with the Life of Mine Plan ??We can drill another hole or reWe re-optimise a plan, but once excavated, the final decision has been made ??The grade control decision is the last decision made in the resource exploitation sequence.

May 1, 2009

By Robert B. Parsons

"The customary onslaught of government budgets this spring offers lots of interesting reading to the mining industry.While the favourable changes tend to get all the fanfare, there are some ""sleepers"" in the host of proposed changes which will be bitter pills for some mining people to swallow.IntroductionOn a scale of one to ten, the Canadian mining industry will probably give this year's federal and provincial budgets a score that is pretty close to five. Although some budgetary proposals are generally perceived to be favourable to the industry, there are other provisions (and lack of provisions) which are considered to be negative.This month, Tax Notes examines in a summary manner the principal features of the 1985 federal and provincial budgets which are of particular interest to this country's mineral industry."

Jan 1, 1985

By S. Yannacopoulos, L. Bichler, P. Wanjara, J. Gholipour

Characterization of a virgin and in-service Inconel 718 alloy was undertaken to study the changes caused by the service conditions on the grain size, ?? phase, MN-type nitrides and MC-type carbides. The size, distribution and volume fraction of these phases and grain size were studied using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and electron backscattered diffraction (EBSD) analyses. A considerable difference in the grain size, as well as distribution and volume fraction of the precipitates was observed in the in-service material as compared to the virgin Inconel 718. As a result of these microstructural changes, a notable dissimilarity in hardness between the materials investigated was observed. The results presented in this study are important for proper development of repair parameters and heat treatment of in-service Inconel 718 material.

Jan 1, 2014

By H. R. Wilson

"This paper describes the evolution of the Waste Management Program at the Lupin Mine through the years 1982 - 1988. The program was developed in response to the terms and conditions of the Water Licence issued to the mine in 1981 by the Northwest Territories Water Board. Echo Bay Mines Lupin Mine is located on the western shore of Contwoyto Lake in Canada's Northwest Territories about 80 km. south of the Arctic Circle.The gold mine commenced production in 1982 and the Waste Management Program was based originally on the total containment concept. Due to an expansion of the mill circuitry and increased throughput, it was apparent that the total containment concept would require reevaluation since discharge from the pond would be required within a few years. During the initial years of production, an investigative program was established to determine the most effective means for treating the tailings pond water. This program incorporated both laboratory studies as well as monitoring of the tailings pond contents and environmental conditions as the impoundment area was filling. The program showed that natural degradation phenomena, if properly utilized, are effective in lowering the concentrations of all contaminants to within Licence limits with the exception of arsenic. To ensure compliance with arsenic limits, an iron salt was added to cause arsenic to precipitate from solution in the tailings pond.As a result of our studies, the tailings management system finally implemented at Lupin Mine includes the following components:Tailings pulp retention cells constructed by dyking off one end of the tailings impoundment area.Two tailings ponds in series operated in a sequential decant and fill fashion.An iron salt solution preparation and metering system.A syphon system into which the iron salt solution is injected as the contents of the first pond are decanted into the second pond.A second syphon system for decanting the contents of the second pond to the receiving streamThis paper discusses the findings and conclusions of the waste management investigative program, describes the civil work completed to reach our final operating scenario, describes the sequence of operating the treatment system, reviews performance data, and comments on abandonment and restoration of the tailings impoundment area."

Jan 1, 1989

By Euler De Souza, Kyle Penner

"Booster fans play an important role in assisting main fans by boosting the air pressure of the ventilation air passing through it. The correct placement of underground booster fans in a mine is a critical decision since it not only influences the mine’s operational capacity in terms of costs and efficiency, but also affects safety and environmental conditions. There are many booster fan installations around mines that are inappropriate, in some cases resulting in system failure (fan stall) or in a major negative impact on mine production. Inadequate booster fan placement has resulted, in some cases, in extensive air leakage which has compromised the economics of the operation and, in other cases, in recirculation of contaminants which has seriously compromised safety. This paper provides guidelines for proper design and siting of booster fans underground, to not only achieve an economic ventilation system but to create safe work conditions and efficient atmospheric conditions. Procedures for the planning, installation, operation and maintenance of booster fans are also presented. A case study illustrating the design and siting of a major booster fan installation in a potash mine, supported by computational fluid dynamics analysis, is presented.INTRODUCTIONIn large underground operations with complex ventilation networks offering high resistances, the never ending increased required quantities of air can almost only be supplied through use of high pressure main fan systems. These fans may, in effect, induce significant leakage losses in the system, having a negative impact on safety performance. In such cases, booster fans can be designed to decrease the main fan pressures and reduce the leakage flows, improve system efficiency and reduce costs. In well designed systems, booster fans can thus be used to redistribute the airflow and assist the main surface fans.When the pressure supplied by the main fans is insufficient to meet the ventilation circuit pressure requirements, booster fans are placed in strategic locations where pressure boosting is essential. Booster fans are typically sited in sections of the circuit offering high ventilation resistance and requiring this form of ventilating air motivation. Booster fans are thus required when the mine expands, and so the resistance of the ventilation network, and the primary fans no longer can supply the required pressure and flow."

Jan 1, 2019

By Jerry Ran

When multiple levels are mined in open stope mining with delayed backfill, mining underneath fill is inevitable to achieve higher rate of recovery if no sill pillars are left for the purpose of fill separation or partial ground support. This is particularly true when the orebody has low reserves per unit vertical distance. Instability of the exposed fill back causes stope dilution, production delay and possible equipment damage and consequently increases the mining cost. Previous studies have concentrated on fill mat stability in cut-and-fill and stability of fill walls in open stope mining. Workers are exposed to the fill back in cut-and-fill and therefore smaller open spans are normally adopted and the fill mat is reinforced. In open stope mining openings with large spans are designed, workers are not exposed to the fill back and its stability has to be maintained by fill of sufficient strength. However, the required fill strength is normally determined by considering different modes of fill wall failure. The fill back stability is usually not analyzed in the fill design process. The lack of analysis on fill back stability for open stope mining is mainly due to difficulties in relating the fill properties to the fill and stope geometry. In this paper a simplified wedge model is adopted to analyze stability of the exposed fill back in open stope mining with consolidated backfill. The proposed method calculates the factor of safety of the fill back against shear failure under known fill and stope geometry and fill strength parameters in order to assess the fill back stability. It can also be used to determine the required fill strength with known fill and stope geometry. The proposed approach is indirectly validated by mining experience and observations at two operating mines. In addition there are many factors affecting the fill quality and stope configurations in an operating mine. These factors have to be considered in the analysis of fill back stability. This situation is highlighted by presenting an actual mining case where the fill back failed due to factors commonly encountered in mining operations.

May 1, 2003

By R. A. Sudisman, T. Yamabe, M. Osada

"Geological material can be subjected to some different loading conditions, mainly due to three inter-related physical processes which are mechanical, thermal, and hydrological. Freezing and thawing process of rock that occurs in sub-zero temperature condition may contain some or all those three physical processes depended on its initial condition. Those inter-related physical processes may lead the ground into failures. Therefore, understanding the physical properties such as deformation process of geological material under freezing and thawing condition is required for the artificial ground freezing projects and engineering construction activity in the natural cold region.In order to study the strain characteristic of rocks during freezing and thawing process, a series of freezing and thawing experiments of core samples of three different rock types and mortar has been conducted under varying temperature from -20 °C to +20 °C. Four core sample types are Sandstone, Granite, Tuff, and Mortar with 50 mm diameter and 50 mm height, which were naturally dried before the freezing-thawing experiment. Freezing-thawing experiment was conducted by submerging the vinyl covered core samples into a temperature-controlled liquid coolant box. Firstly, temperature of liquid (brine solution) was set at -20 °C so that the temperature of subjected sample was decreasing to as low as -20 °C. And then the temperature of brine was returning to initial room temperature after the coolant system was stopped. Strain gauge and thermo couple were attached on the core’s perimeter to measure strains and temperature changes.Sandstone and Mortar samples show relatively similar results than other two samples. Both presents linearly shrink with the temperature decrease and expand almost to its initial condition with the temperature increase. Granite shows less-linear strain-temperature relationship during thawing process, while the Tuff sample shows abrupt strain increase during thawing process on the temperature higher than +10 °C. Thermal expansion value of each rock types were obtained by fitting the major strain-temperature relationship on -19 °C to +10 °C temperature range. Overall, anisotropic deformation was observed on the entire samples and possible mechanisms for each hysteresis characteristic are discussed, which need to be confirmed by further experiments."

Jan 1, 2015

By Roderick C. McDonald

Great Bear lake, the fourth largest body of water on this continent, comprises an area of approximately 12,000 square miles, and is set astride the Arctic circle, with a large portion of it witnessing both the Arctic winter night, and the Arctic summer day with its midnight sun. The very name itself, Great Bear, suggests an Arctic region. The seasonal contrasts at Great Bear lake are very marked by the cold and darkness of winter, and the warmth and brightness of summer. Signs of winter such as low clouds, snow, sleet, fog, and night frosts, generally appear the latter part of August, while ice forming on bays during the last two weeks in September ends boat travel on the lake about September 30th.Early in June the ice leaves the river mouths, during the last ten days of the month it disappears from small bays, and at some time during the last two weeks of July the main body of the lake becomes navigable. In 1916, the ice disappeared earlier than usual, and the lake was navigable on July 5th. Great Bear river generally breaks up about June 1st, but, on account of ice cliffs and floes, it is not navigable with safety until early in July. Even then, the traveller is confronted with the Charles rapids, but these might be overcome by a wagon or motor road, such as the one from Fitzgerald to Fort Smith: However, in 1931, Mr. A. W. Boland, Fort Norman, N.W.T., carried with scow and motorboat practically all freight between Fort Norman and LaBine point and Hunter bay, at the east end of the lake. During July and August, two types of clothing are required, for, although the days are mainly ones of warm sunshine, the nights are cloudy and cold. In the winter season, fur clothing is used exclusively. Considerable timber, mainly white spruce, suitable for fuel and building purposes, borders the lake and extends eastward to the Coppermine river. North of the lake, no timber is found except in the river valleys, but with oil and coal possibilities near Fort Norman, the fuel situation might be solved.

Jan 1, 1932

By Frank Ebbutt

Introduction The property of the Britannia Mining and Smelting Company, Limited, is situated on the east side of Howe sound, about six miles from its head. It is roughly thirty miles by water from Vancouver, one of the important ports of the Pacific and the industrial and financial centre of British Columbia. Howe sound is navigable for ocean-going vessels and Britannia Beach is a daily port of call for the commodious boats of the Union Steam-ship Company, sailing from Vancouver. Few mines are so ideally situated or have so many or varied natural advantages. Copper was first found on Britannia mountain in 1888, by Forbes, but it was not until 1898 that five claims were staked here by Oliver Furry, a trapper. It is from these claims that the major production during the past thirty years has come. In 1900 the Britannia Copper Syndicate was formed and development of the property was commenced. In 1903 the late Grant B. Schley obtained control, and through his efforts the Britannia Mining and Smelting Company was organized in 1908 as a subsidiary of the Howe Sound Company. Since that time, a persistent and progressive policy has been followed, which has resulted in a prolonged and profitable operation. The country in the immediate vicinity of the mine is marked by strong relief, with mountains rising abruptly from tide-water to elevations of 5,000 feet and more. Two broad transverse valleys deeply dissect the area. These are the valleys of Britannia creek and Furry creek. The region has under-gone prolonged and relatively recent glaciation. Over much of the surface there is deep overburden and dense vegetation. The geology of the mine and vicinity has been described in reports by S. J. Schofield (1), H. T. James (2), J. G. Barry, and others (3). The present writer is in accord with much of this literature on Britannia, but during recent years, extended observations made underground have shown that the 'quartz porphyry', or 'mine porphyry', of several of the earlier writers is not the host rock to the commercial mineralization; and he contends that the mineralization occurs in highly altered phases of a complex series of ruffs, flows, and pyroclastics and their autoclastic metamorphosed products.

Jan 1, 1935

By L. Wolofsky

"The Candego property is in Boisbuisson and Christie Townships, Quebec, about 13 miles south of Marsoui, a village on the north coast of the Gaspe peninsula, 80 miles east of the railhead at Matane. It was the first producing mine in the peninsula. Production to October 1954, when operations were suspended, totalled 68,497 tons of ore, which yielded concentrates containing 8,706,535 lb. lead, 5,870,272 lb. zinc, 355,526 oz. silver, and about 1,000 oz. gold. The property was acquired by the present company in the summer of 1955.The mine has been developed by seven adits, driven into the west slope of the valley of the Marsoui River. The river here is at an elevation of about 1,600 feet, and is roughly 1,500 feet below the level of the adjacent upland. Adit elevations range from 1,760 to 2,330 feet. Five of them are in one vertical zone, on what was originally believed to be a single vein. Past production has come from Nos. l to 5; the chief present high-grade ore reserves are in No. 7.The author's observations were made in adits Nos. 3 to 6, in several of the old pits, in the surface trenches, and on drill core, at various times between December 1952 and September 1953. Much of the surrounding area has been mapped by Jones (I) and McGerrigle (2) for the Quebec Department of Mines. H. M. Kingsbury served as consulting geologist to the mining company for several years.General GeologyThe Candego veins occur in Lower ( ?) Ordovician sedimentary rocks which form a strip about 15 miles wide along the north coast of the Gaspé peninsula. The series includes limestones, shales, and sandstones, mildly metamorphosed in places. Three miles south of the mine is the north contact of the granitic intrusive, regarded as Lower or Middle Devonian, which underlies the Tabletop Mountains area. This batholith is about 10 miles long, in a north-south direction, and about 4 miles wide. At Mount Albert, about 5 miles west of the Tabletop intrusion, is a group of basic rocks, amphibolites and serpentinized peridotites, thought to have been intruded at the close of the Ordovician."

Jan 1, 1949

By T. W. Cavers

The Dwight-Lloyd sintering machine was the answer to the flue-dust problem of the copper blast-furnace smelter. Then came concentration by flotation, which threatened to eliminate the blast furnace from the smelting field altogether, and again the sintering process solved the problem. As is well known, the sintering process is dual in its function; it expels sulphur from the charge and it converts a powdery material into nodules or chunks that hold together. The charge is ignited on top just as it passes over the edge of the first suction box, and the oxygen of the air that is drawn downward through the charge breaks up the sulphide and oxidizes about fifty percent of the sulphur. The heat produced by this reaction in the upper stratum of the charge ignites that lying immediately below, and, when the pallett has travelled the full length of the machine, the tire has reached the graces and the fine concentrate has changed its characteristics by being partially fused and has become a more or less solid mass. When the Granby Company was smelting its ore as mined, one small D-L machine was adequate for the treatment of the flue dust, but as soon as the policy of smelting the concentrate was adopted, it became necessary to add two large machines to the sintering plant. The three sintering units, of which two are 42 in. by 396 in. and the other 42 in . by 264 in. in hearth area, have a combined capacity of from 370 to 450 tons (dry) of charge per day. The capacity varies directly as the hearth area. The sinter produced is about 88 per cent of the dry charge, or 325 to 400 tons per day. The sintered fines returned for resintering average between 30 and 35 per cent of the charge, but this is not as great a disadvantage as might appear, since the addition of hot fines improves the burning qualities of the mixture. From 50 to 54 per cent of the sulphur is eliminated in the sintering operation.

Jan 1, 1934

By O. S. Perry, D. F. Kidd

"BEAVERDELL IS IN the Interior Plateau of British Columbia, 25 miles east of Penticton, B.C. In 1897, small but rich silver-bearing veins were found on Wallace Mountain, 2 miles east of Beaverdell. Production from the camp, at first of a modest character, started in 1901 and has never ceased. Over 90 per cent of the values in the ores have been in silver. Remaining values present are in lead, gold, zinc, and cadmium.There have been four principal mines in the camp. A fifth is approaching production. The four mines lie within a northeasterly trending rectangle about 5,000 feet long and 2,000 feet wide, the fifth mine being at the northeast end. From southwest to northeast the mines, with their silver production to Sept. 30, l 955, are: -Wellington Mine - 1,463,948 oz.Sally Mine (includes Rob Roy claim) - 1,930,124 oz.Bell Mine - 3,460,815 oz.Lass Mine - 12,557,956 oz.Other production - 331,252 oz.Total, Beaverdell Camp - 19,744,095 oz.The camp is near the centre of an area geologically mapped in 19 l l by L. Reinecke for the Geological Survey of Canada (1). The rocks of the camp comprise:1. Beaverdell stock of porphyritic quartz monzonite;2. Westkettle batholith of quartz diorite;3. Wallace formation of tuffs and lavas.The Wallace formation borders the east edge of the camp, and has been intruded by the Westkettle batholith. The batholith is the host rock for the orebodies. The Wallace-batholith contact dips gently east. Some of the Beaverdell ores at depth, while in the batholith, are under Wallace formation mapped on the surface above.West of the camp, Reinecke mapped a stock one by one and one-half miles in size, of porphyritic quartz monzonite, which he considered much younger than the Westkettle quartz diorite (I). Recent petrographic work by White and Dolar-Mantuani (3) suggests that in the vicinity of the camp the Westkettle batholith is more quartz monzonite than quartz diorite, and little different in composition from the Beaverdell quartz monzonite. They suggest a consanguinity with the Westkettle batholith."

Jan 1, 1949

By A. Rahimi

The smelting plant at Sarcheshmeh Copper complex commenced working with two reverbatory furnaces, four pierce smith converters, two anode furnace and one holding furnace having a known capacity of 420 metric tons of anodic copper according to the initial design in 1982 (1361 Iranian calendar). During the period from the commencement date up until now, the smelting plant has undergone changes for improvement and enhanced production by substituting holding furnace with another anode furnace, installing the fifth converter and utilizing oxyfuel burners on the ceiling of the reverberatory furnaces. According to the different operational processes in reverberatory, converter and anode furnaces different types of corrosion mechanisms and degradation can be observed in the refractories of copper smelting furnaces. In the case of reverberatory furnaces, the corrosion and degradation of refractories may be factors such as hot corrosion by melt, corrosion attack by the constituents of burning fuel, degradation of sidewalk exposed to mechanical stresses of the feed charge and the hydrostatic pressure exerted by the melt inside the furnace, all of which are due to the unique operational condition governing the reverberatory furnaces environment, i.e. burning fuel atmosphere, charge concentration and combination, furnace temperature, calm melt condition, etc. In the case of converter furnaces, the most likely corrosion and degradation of refractories may be due to the chemical reaction between the melt and degradation of tuyere zones due to sever movement of the melt and mechanical strikes of the punch rod. Also the most essential corrosion reaction occurs around the mouth of the converter because of the mechanical strikes by the cleaning device and thermal heat shock. Other parts inside the furnace are corroded due to the reactions between the fayalite slag and the furnace refractory. In anode furnaces the degradation mechanism is mostly related to the gaseous corrosion (penetration of natural gas or liquid gas inside the refractory structure due to the long period of reduction processes and refining stages. Finally another important factor responsible for destruction of refractories in these furnaces is the copper oxide slag together with the fume constituents of burning fuels.

Jan 1, 2004

At 14%, the representation of women working in the mining industry is the lowest among primary industry categories in Canada1. With reference to mining operations and senior leadership, the gap in the industry is even more pronounced. In an effort to narrow the gender gap, recent industry, education, and policy efforts have been made to increase the number of women entering the industry through career awareness and early career recruitment strategies. These strategies implied that by increasing the numbers of women entering the industry there would be a natural progression of women into the hierarchies of organizations. Efforts to retain women in the industry have focused around removing career barriers such as reviewing flexible work practices and programs directed at work life balance. At this time, these efforts have resulted in negligible fluctuations to the gender gap within the industry. This research investigates the under-representation of Highly Qualified Women (HQW), and the interaction of workplace culture on their career advancement and retention within the industry. HQW (women with a bachelor?s degree or higher) are the focus of the work as they represent an essential source of leadership and technical capacity for mining organizations. This paper is based on the results of a survey of 170 HQW working in the Canadian mining sector. The findings from this research suggest that HQWs careers in mining are stalled, despite a strong indication by respondents of interest in their professional career advancement. With regards to workplace culture, respondents indicated that blatant forms of gender discrimination have been reduced in mining workplaces; however, exclusion from informal networks, implicit bias and subtler forms of workplace discrimination persist. Utilizing a framework to assess the workplace culture for women in attracting and retaining their employment, respondents provided detailed information on the aspects of workplace culture that are most problematic in relation to women?s career development in mining. Women consistently identified problematic workplace culture as a significant barrier to the career advancement and retention of women within the industry. The representation of women within the labour force will likely remain stagnant until the industry addresses workplace culture within the industry, and makes strategic efforts to develop inclusive cultures throughout mining and supportive organizations.

Aug 1, 2013

"Chairman - To start this discussion off, I wonder if Mr. Dave Livingstone or Mr. Jeffrey of Granisle Copper would give a description of the crushing plant at Granisle since it is somewhat different from the usual plant, W. N. Jeffrey - Granisle Copper The main difference between the Granisle crushing plant and many others is the Livingstone method of putting the screens under the crushers instead of above them. This method allows a more compact arrangement and eliminates the heavy superstructure required to take care of the screen vibration when the screens are mounted above the crushers. There is a small surge bin above the tertiary crusher which takes care of the variation in circulating loads.All three crushers are gyratory crushers. There is no grizzly ahead of the primary crusher but the fines are removed from the primary crusher discharge at the first screen and sent directly to the fine ore bins. E, Thornton - Sullivan GroupDo you have any coarse ore storage outside?w. N. Jeffrey - Yes, there is about 6000 tons live storage, We have very little trouble with freezing even though it is open storage.E. Thornton - Sullivan GroupDoes rain cause any problem?w. N. Jeffrey - It sometime creates a problem because the storage area is on a slope. It is mainly a problem of keeping the drainage ditches open.Question – What is the size of the primary gyratory crusher and how does it work on run of mine size materials, in other words, do you have a problem with oversize material and how do you handle the oversize rock?w. N. Jeffrey - The primary gyratory is a 42 x 65 with a nominal open side setting of 61'. We do at times get a run of oversize material. For anything too large for the crusher to handle, we use what is known as the Esco hook, which is a type of grapple used to remove oversize rocks.The disadvantage with this equipment is that the crane is too slow. I am sure there must be better arrangements than the one we have,"

Jan 1, 1971

By Shinji Shirakawa

The gold wire bonding technology is widely used for electrically connecting aluminum pads on IC devices to external terminal of semiconductor. In 1960?s, the tensile strength of gold bonding wire was about 100 MPa only. However, recently the wire with 300 MPa in strength has been developed. Since the gold bonding wire was started to use for IC package in early 1960?, the many types of gold bonding wire has been developing continuously in order to meet market?s needs, such as high density, small size and thin type of IC packages. Moreover, electronic equipments were used in automobile applications and also demanded good reliability under severe temperature environment. Thus Au-Pd alloy wire has been introduced instead of the wire with 4N(99.99wt%) purity gold to provide excellent reliability in Au-Al bond interface. The phenomena at Au-Al interface in the high temperature storage have been already explained by several studies as follows. There are five phases of inter metallic compound (IMC) between gold and aluminum. Just after bond gold ball on aluminum pad, Au5Al2 phase was formed and occupied almost all of IMC area. During high temperature storage test, Au5Al2 phase transformed to Au4Al phase, then this phase was corroded by Bromide (Br) ion that was isolated from molding resin. Thus the reliability between Au and Al degraded. In case of Au-Pd alloy wire, the concentrated palladium phase (Au-Pd-Al) was formed at the interface between Au alloy ball and Al pad. The Au-Pd-Al phase prevented from transforming between Au and Al, therefore Au5Al2 phase was hard to transform to Au4Al phase. Consequently the reliability at the interface between Au alloy ball and Al pad was less degradation. However, in recent study using several advanced analysis technique, Au4Al phase was found at the interface between Au alloy ball and Al pad same as the case of conventional gold wire (4N purity gold bonding wire). It was suggested that the formation of concentrated palladium phase (Au-Pd-Al) related the excellent reliability at ball bonding process.

Oct 1, 2003

By Benoît Plante

La mine Tio (QIT Fer et Titane Inc.) exploite à ciel ouvert un gisement d?ilménite massive depuis 1950, générant jusqu?à maintenant plus de 70 Mt de roches stériles potentiellement génératrices de drainage neutre contaminé (DNC), dont une partie est submergée dans le lac Petitpas, au nord de la mine. Si généralement l?ennoiement des rejets miniers a un effet bénéfique pour limiter la contamination des eaux, cela reste à prouver pour ce qui est des stériles générateurs de DNC. Des essais en réservoirs ont été réalisés afin d?évaluer la réactivité de trois différents types de stériles submergés, qui ont été choisis en fonction de leur teneur en ilménite. Afin d?évaluer l?impact de la matière organique sur la réactivité des stériles submergés, chaque type de stérile est étudié en immersion simple ainsi que combinée à des sédiments prélevés au lac Allard, à proximité de la mine, d?où l?eau utilisée dans les essais a aussi été prélevée. L?évolution des teneurs en Ca, Mg, Si et Ni durant les 8 premiers mois d?étude démontrent que les stériles immergés sont réactifs, mais l?impact de la matière organique demeure pour l?instant difficile à préciser. Tank tests on Tio mine waste rock The Tio mine (QIT Iron and Titanium Inc.) exploits a massive ilmenite ore as an open pit since 1950, producing over 70Mt of potentially contaminated neutral drainage (CND)-generating waste rocks. While the underwater disposal of mine wastes generally show a beneficial effect on water contamination, this method still needs to be approved for CND-generating waste rocks. Tank tests were realized in order to evaluate the reactivity in underwater conditions of 3 different waste rock types, chosen with regards to their ilmenite content. In order to evaluate the impact of organic matter on the reactivity of underwater waste rock, each waste rock type was studied in simple immersion and in combination with sediments sampled at Allard lake, located near the mine, where the water for the tests was also sampled. The evolution of Ca, Mg, Si and Ni during the 8 first months of testing show that the waste rocks are reactive underwater, but the impact of the organic matter is till hard to define.

Nov 1, 2008

By A. Miura, R. Winarko, D. B. Dreisinger

Chalcopyrite leaching in acidic ferric sulfate media at ambient temperature exhibits slow kinetics and poor leaching efficiency, which is typically attributed to surface passivation. Recently, the presence of small amounts of iodide in the leaching media has been reported to significantly accelerate chalcopyrite dissolution. To further explore the behavior of chalcopyrite leaching in the presence of iodide, it is essential to determine the factors that control the leaching kinetics. In this study, we investigated the effect of initial solution potential, iodide concentration, particle size, and temperature on the kinetics of copper extraction from chalcopyrite. The key in the experimental setup was to minimize iodide loss by iodine evaporation and precipitation as cuprous iodide. The former was achieved by performing the leaching tests in fully sealed leaching systems. The latter was achieved by maintaining the solution potential higher than 420 mV (versus Ag/AgCl electrode), where formation of CuI precipitate is possible. The experimental results show that higher solution potential and higher iodide concentration had a pronounced positive effect on the rate of chalcopyrite dissolution. There was no effect associated with particle size, which might be due to the narrow size range tested. The positive effect of increasing temperature only manifested itself when the solution potential was sufficiently high. INTRODUCTION The main challenge of chalcopyrite leaching using ferric ions as the oxidant at ambient temperature is the slow kinetics and poor extraction. The reason for this leaching behavior has been attributed to passivation resulting from formation of insoluble passivating layers on chalcopyrite surfaces, which could be metal-deficient sulfides, elemental sulfur, polysulfides, and iron precipitates (Klauber, 2008). To overcome passivation, technologies using higher temperature and pressure have been developed to leach chalcopyrite concentrates, such as the CESL process (Mayhew, McCoy, Mean, & Woeller, 2013), FLSmidth Rapid Oxidative Leach (ROL) process (Mulligan et al., 2017), Galvanox (Dixon, Mayne, & Baxter, 2008), Albion process (Hourn, Turner, & Hourn, 2012), HydroCopper (Hyvärinen & Hämäläinen, 2005), TPOX (Dreisinger, 2006), and AAC/UBC process (Dreisinger, Dempsey, Steyl, Sole, & Gnoinski, 2003). Even though they are effective in accelerating copper leaching kinetics, those technologies typically have higher capital and operating costs associated with production of concentrates and application of autoclaves. This makes them unsuitable for treating low grade primary copper sulfide ores.

Jan 1, 2019

By J. Lu, M. Mohammadi, C. Pelletier, B. Wassink

Chemical reduction of selenate by chromous ions is proposed as a novel method to remove selenate from sulfate-bearing solutions Chromous ions were generated by electrochemical reduction of chromic ions using an electrochemical cell. The investigation was conducted in sulfate medium and under various concentrations of chromous ions (0.0062 to 0.05M), pH 1 to 2.2 and temperature 10 to 60°C. Selenate ions were rapidly reduced by chromous ions to hydrogen selenide. The overall reaction at a chromous/selenate molar ratio of 8 or higher can be expressed by the following reaction. At an initial chromous/selenate molar ratio below 8, the products are hydrogen selenide and elemental selenium. At a lower chromous/selenate molar ratio and pH, more elemental selenium and less hydrogen selenide are produced. The reduction kinetics is controlled by both chromous ion and hydrogen ions concentrations. The reaction rate is first order with respect to selenate, hydrogen ion and chromous ion concentrations. It was found that the selenate reduction rate with chromous is independent of the concentration of sulfate present in the solution. The general rate equation was proposed and the rate constant was calculated as k= 0.38 M-2s-1. An activation energy of 58.7 kJ/mol was obtained in the temperature range from 10 to 50°C. Nearly 100% of selenate can be reduced to H2Se from solution containing 17 ppm selenate in less than 30 minutes at pH 2.2 and 60°C. Various strategies have been tested to remove the produced H2Se from solution. INTRODUCTION Selenium in nature is mostly associated with metal sulfide minerals such as copper, iron, zinc, and lead sulfides (Zingaro & Cooper, 1974). The extraction of metals from ores has the potential for selenium contamination of ground and surface water which can pose an environmental and health concern. Therefore, selenium contamination in the receiving environment is a key issue for many industries (specifically copper industry) and the treatment of wastewater contaminated with selenium is a growing challenge. The effective removal of selenium from contaminated water is very important to support sustainability in the copper industry and the other industries with selenium pollution issues.

Jan 1, 2019