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By P. Chu, J. A. Finch, R. Li

"Bubble size plays a key role in flotation. In this paper, we examine the possibility of using passive acoustic sending to determine bubble size. Software was developed based on Short Time Fourier Transformation (STFT) to analyze the frequency of the acoustic signal emitted from the bubble formation event. Bubble size was determined from the Minnaert frequency. The acoustic-determined bubble size responded to reagent dosage, but was less sensitive than that given by imaging. The constraints of the current acoustic approach are discussed.INTRODUCTIONBubble size is an important factor affecting flotation performance. It determines the maximum available surface area for collecting and transporting mineral particles. Of interest for process control (Gorain, Franzidis, & Manlapig, 1995), it can be determined by several techniques, such as image analysis (Grau & Heiskanen, 2002; Hernandez-Aguilar, Gomez, & Finch, 2002); conductivity (Barigou & Greaves, 1992); drift flux analysis using gas rate and gas holdup measurements (Banisi & Finch, 1994); and optical sensors (Randall, Goodall, Fairlamb, Dold, & Connor, 1989). However, all these techniques have drawbacks.Acoustic analysis of the oscillatory behaviour of bubbles to extract bubble size is another possibility (Leighton & Walton, 1987; Pandit, Varley, Thorpe, & Davidson, 1992; Al-Masry, Ali, & Aqeel, 2005; Manasseh & Ooi, 2009; Leighton & White, 2012; Spencer et al., 2012). The fundamental basis is the work of Minnaert (1933) who first correlated the bubble size with its natural frequency, Equation 1:"

Jan 1, 2016

By Z. Liang, Z. Q. Liu, X. F. Li, H. L. Zhang

"Dynamic characteristics of frozen soil is important for the safe, effective and rapid construction in cold regions and artificially frozen engineering. In this paper, dynamic characteristics of frozen clay with various low temperature and different strain rate were studied by using Split Hopkinson Pressure Bar (SHPB) test and numerical simulation test. Variation of dynamical parameters and dynamic stress-strain curves of frozen clay were obtained and analyzed. The results of these test show that: Frozen clay exhibits temperature effect and strain rate effect that the failure type tends from plastic failure to brittle failure with the increase of strain rate or decrease of temperature; Under impact loading, frozen clay exhibits three typical dynamic stress-strain curves as strain rate increases, and the maximum strain of frozen clay only linear increases with strain rate.INTRODUCTIONArtificial freezing technology has been widely used in the construction of underground engineering, such as the coal mine shaft, the deep foundation pit, the urban metro and subsea tunnel, etc. Research on dynamic mechanical behavior of artificial frozen soil will provide supports for these artificially frozen engineering (Xu et al. 1998; Ma 2009). However, the dynamic mechanical research on frozen soil is mainly carried out at low frequencies or small amplitudes of the waves, behavior of frozen soil under impact loads or high strain rate loads has not been made clear."

Jan 1, 2015

By X. Cao, X. -G. Chen, K. Liu

Due to the detrimental effect of platelet iron-rich intermetallics on mechanical properties (particularly ductility) in cast alloys, it has been essential to transform these phases into Chinese script morphology. In the present work, the effects of Mn and/or Si addition and cooling rate on the phase transformation of the iron-rich intermetallics in 206 cast alloys with different Fe contents ranging from 0.15 % to 0.5 % were systematically investigated. The results obtained showed that platelet ß-Fe and Al3(FeMn), Chinese script a-Fe, Alm(FeMn) and Al6(FeMn) can be observed in the 206 cast alloys, depending on the Fe, Mn and Si contents as well as the cooling rate. It was found that the addition of either Mn or Si favors the formation of Chinese script iron-rich intermetallics but inhibits the precipitation of the platelet phases. In addition, the combined addition of both Mn and Si has a synergistic effect on the phase transformation. Furthermore, there exists a critical cooling rate to effectively suppress the formation of platelet iron-rich intermetallics for a given alloy. The threshold cooling rate decreases with increasing Fe, Mn and Si contents. Casting process maps are established to correlate the intermetallics precipitated with alloy chemistry and cooling rate for 206 cast alloys containing various Fe levels.

Jan 1, 2014

By H. Asgari, A. G. Odeshi, J. A. Szpunar

In the current research, the role of grain size on the texture formation and mechanical behavior of rolled AZ31B Mg alloy is investigated under shock loading conditions. The grain size of the original asrolled sample was 8 µm and different grain sizes, e.g. 25 and 46 µm, were produced by heat treatments at temperatures in the range of 400-500 °C. In order to evaluate the effect of grain size on the anisotropy of mechanical behavior, the samples were cut along the rolling direction (RD), transverse direction (TD) and normal direction (ND) and tested at strain rates of 900 and 1200 s-1 using Split Hopkinson Pressure Bar. Texture measurements showed that initial texture of the samples cut from the as-rolled sheet is a weak rtype texture. However, a stronger texture was observed for samples with large grains. After shock loading, a (00.2) basal texture developed in all samples and the intensity of the basal poles was higher in samples with coarser grains. This observation is corroborated by high twinning activity and possible activation of pyramidal <c+a> slip in coarse grained samples. Besides, the strength of basal texture increased with increase in the strain rate. Furthermore, the samples with larger grain size showed lower strength and higher ductility, and this was observed for all investigated strain rates.

Jan 1, 2014

By Te Gao

It is a general expectancy that in most of the construction and renovation project, the contractor is going to hand over the as-built documents to the owner or the facility management team at the completion of the project. The main challenge for the handover process is to ensure the completeness of the captured building information and the accuracy of it in terms of how well it represents the reality. Building information models (BIMs) can be used as an information repository to store and deliver as-built information. However, due to changes made in the construction and renovation phases and errors made in the design and modeling phases, discrepancies can exist between BIMs created in the design phase (asdesigned BIMs) and actual building conditions. Laser scanning technology is able to efficiently capture accurate geometric information, which provides an opportunity to identify and quantify discrepancies and update as-designed BIMs into as-built BIMs. This paper presents a case study, within which the asdesigned BIM of a newly renovated research lab was updated into an as-built BIM using laser scanned data captured in the renovation phase. This paper introduces the challenges associated with the updating process for the as-designed BIM. In order to address these challenges, this paper introduces a framework that supports the update of an as-designed BIM by incorporating point clouds captured by the progressive laser scans.

Aug 1, 2013

By C. Diaz, S. W. Marcuson, K. I. Burgess

Deep roasting in fluid bed roasters is the first unit operation in Inco&apos;s "roast-reduction smelting" process for the treatment of nickel sulphide concentrates. The roaster product, a low sulphur calcine, is reduction smelted with coke in an electric furnace to yield a sulphur-deficient matte which is then converted to low (<1%) iron matte in Peirce-Smith converters. Due to the deep roasting, a minimal amount of sulphur dioxide is evolved in the smelting and converting stages. Sulphur is eliminated from the concentrate almost exclusively in the roasters in a single, continuous, strong, gas stream suitable for treatment in an acid plant. This paper discusses the commercial scale testing of deep fluid bed roasting of nickel concentrate at Inco&apos;s Thompson Smelter as part of two commercial scale campaigns on roast reduction smelting conducted in 1981-1982. Slurry feeding, practised during the second campaign, permitted excellent control of the air/concentrate ratio in the roaster and, in turn, good control of sulphur elimination (about 80% of input). Smooth autogenous operation with high oxygen efficiencies (about 95%) was promoted by operating at bed temperatures of830°C to 850°C with calcine recycle. High throughputs and the desired metallurgy were achieved. The extensive testwork conducted during the two experimental RRS campaigns demonstrated thot deep fluid bed roasting of nickel concentrate at high oxygen efficiency is a technically viable operation.

Jan 1, 1994

Concentrator Improvements -1990-1995Back to Basics ?pilot plant versus plant opportunities identified ?understand process fundamentals & baseline -1996-2000Point ?C?Projects ?strategy to improve global competitiveness ?structure implemented to generate & drive ideas ?capital investment for life of mine asset renewal - 2001-200?Six Sigma Methodologies ?emphasis on data, measurements & analyses ?dedicated, highly trained personnel on projects 1990-1995 Improvement Phase??Philosophy??back to basics?approach?understand what each piece equipment needed to do?understand reagents, control variables?confirm operating strategies ??probe, stabilize, institutionalize??test theories, confirm with lab and plant trials?process stability (equipment reliability, controls)?enhanced operator guidelines, operator training?focus on continuous improvement?optimize existing equipment capability?stop looking for ?magic?solutions 1990-1995 Improvement Phase??Technical?finer grind, same equipment?optimize media size/shape to grinding application?balanced available ball mill power to applications?lowered cyclone feed densities where possible?improved selectivity, same equipment?balanced available cells to applications?streamlined process (eliminate process steps)?added cleaning stages where required?understanding pulp/mineral surface chemistry?lowered flotation pulp densities 1990-1995 Improvement Phase??Effort?numerous studies to understand process?liberation and mineralogical characterization?pulp and mineral surface chemistry?flotation kinetics and entrainment?extensive internal and external manpower?Brunswick, Noranda Technology Centre?CanMet, AMTEL, MinnovEx, Lakefield Research, McGill University?small capital expenditure

May 1, 2002

By H. Langlois

"Included in the Mines Gaspe mining complex located at Murdochville, Quebec, is a copper smelter which comprises a reverberator furnace, two Peirce-Smith converters, an anode furance, and a sulphuric acid plant.The 50% smelter capacity available is supple mentedby custom concentrates for treatment. As these concentrates can be varied and extremely complex many modifications and improvements have been brought about to optimize and make the process more flexible since its inauguration in 1955.IntroductionThe copper smelter of the Mines Gaspe mining complex is located in Murdochville, a small municipality in the heart of the Gaspe peninsula, 90 km northwest of the town of Gaspe .This metallurgical installation has a daily smelting capacity of 650 tonnes of concentrate and an output of 250 tonnes of copper and 900 tonnes of sulphuric acid. Its main components are: a reverberatory furnace, two Peirce-Smith converters, one rotary anode furnace and one acid plant. The gases, which are produced by the converters, are treated at the acid plant then combined with gases from the reverberatory furnace before being vented through a 152 metre high stack .From the beginning of its operation until the present day (1991), the smelter has treated 7 million tonnes of concentrate and 100 thousand tonnes of scrap for a production of 1.8 million tonnes of copper and 2.2 million tonnes of sulphuric acid."

Jan 1, 1993

"Technological innovation is an extremely complex activity. The author presents his interpretation of innovation and the innovative process. He reviews the strategy used by participants in coal mining innovation in the past and discusses changes required to meet the challenges of the future.Introduction if an industry is to be successful and viable in today&apos;s world, the companies active within the industry must remain close to the frontiers of knowledge. The coal mining industry is no exception. Technological problems facing the coal mining industry are basically economic and social. Economic problems are those concerned with the long-term growth and profitability and social problems, with the health and safety of the mine worker and the impact of the mining operation on the environment.Technological innovation can be a key factor in meeting these problems successfully. The general belief is that the information base for technological innovation exists within mining companies and governmental agencies but current industrial and governmental strategies and structures impede the transformation of this knowledge into the mining products and processes required for growth.The purpose of this paper is to determine where Canada is in terms of coal mining on the innovative ladder. The paper as presented: defines innovation and innovative process; gives an historical ""broad brush"" review o f innovation in the industry; and suggests the challenges to be faced in the future."

Jan 1, 1985

By 13409, B. Arjang

"Ground stresses are one of the significant factors in the context of rockbursts and underground instability at some hard rock mines in Canada. Overcoring strain relief measurements using triaxial strain cells were performed at several mine sites to provide stress data for stability evaluations and mine design. Pre-mining stress determinations carried out at depths between 60 m to 1890 m resulted in the following average stress gradients:Maximum horizontal stress, s Hmax = 8.18 + 0.0422 MPa/m depthMinimum horizontal stress, s Hmin = 3.64 + 0.0276 MPa/m depthAverage horizontal stress, s Ha = 5.91 + 0.0349 MPa/m depthVertical stress, a; = 0.0266 ± 0.008 MPa/m depthThe maximum and minimum horizontal compressive stresses, with an average ratio of J.75 ± 0.45, prevail in east-west and northerly directions, respectively. Horizontal compressive stresses in excess of vertical overburden load were determined, indicating large variations in ratios to a depth of about 1000 m with decreasing trend toward depth.From present data, a particular regional zoning for the magnitude and direction of horizontal stress fields cannot be outlined.A common feature at mines with near vertical orebodies is that the maximum horizontal stress acts perpendicular to strike while the minimum horizontal stress is aligned on-strike. The vertical stress components approach the gravitational overburden load."

Jan 1, 1991

By W. W. Muir

"The Baker Mine used a 100-ton per day conventional cyanide leach mill located in northern British Columbia. A production decision was made in early 1980 and the mill was on fine in April 1981.Ore reserves had been estimated at 100,000 Ions averaging 0.9 oz gold per ton and 18 oz silver per ton . Mineralization consists of electrum (Au/Ag) and acanthite (Ag2S).This paper will review plant design and focus on some problems associated with start-up and early operation with the intention of assisting other mine operators by indicating potential problem areas.IntroductionThis paper will discuss operating strategies employed at Baker which improved over-all mill performance. Also included are some ideas which could be steps toward a more efficient operation in a similar setting.Actual dore production by mine life was 37,606 oz gold and 742,117 oz silver.Figure 1 illustrates the relative stability attained over the mine life. Metal recoveries for gold and silver were 92% and 85% respectively.Safety at Baker was of prime importance because of its remote location. Baker received the Mine Safety Association ""Small Mines Award "" in two of its three operating years. At shutdown in late 1983 the mill had operated for over 850 days without a lost-time accident."

Jan 1, 1985

By A. Sutherland Brown

"The ProblemMany science activities receive substantial funding from governments without much direct economic benefit accruing to state or individuals. In contrast, the search for knowledge has never been an acceptable so le justification of geoscience activity, perhaps because of its utility right from its inception. William Smith&apos;s geological activities were embraced because of their usefulness in building canals. Utility has been expected ever since.For decades it has been accepted at senior level s of government, without much understanding of the process, that geological surveys are necessary as a basis of resource evaluation and utilization. Recently, government treasury board s, staffed with economist s, have questioned these near axioms and in many cases the budget s of geological surveys have reflected their stone y-eyed appraisal s. Are government surveys necessary? Can their functions be reduced? Can some or all of their functions be privatized?Government geologists have been muted in trumpeting their successes outside their own ranks. Companies have been reluctant to give specific public feedback on the work of government surveys that have truly aided or guided them toward discovery. Lack of acknowledged linkages between survey work and discovery has dogged survey managers in budget reviews. Impoverished surveys cannot perform adequately so the circle is completed and the doubters&apos; prophecy fulfilled. This is the genera l problem; British Columbia is the archetypical province."

Jan 1, 1986

By D. MacGREGOR, VERA TUREK

The Badgeley Island quartzite deposir in Georgian Bay is worked by lndusmin Limired and was developed in 1969 to produce a high-qualiry silica for use in rhe ferrosilicon and glass industries. The quartzire is part of the Precambrian Bar River Formarion, and is a generally whire, fine-grained rock containing rhin sericire seams. Primary sedimenrary features wirhin the deposit are bedding and ripple marks. Amphibolite and diabase dykes cur the quarr zire body.

Jan 1, 1984

By M. Tadie, J. Wiese, K. Corin

The use of potential control in the flotation of ores has been applied in a variety of operations and presents an opportunity for improvement of selectivity and recovery of valuable minerals. Although it is possible to vary the redox potential (Eh) using chemical additives such as sodium hypochlorite or hydrogen peroxide this is more commonly done by varying the pH and dissolved oxygen (DO) concentration. The present study involves an investigation into the effect of varying dissolved oxygen concentration, ionic strength (IS) and pH on the flotation response with the aim of application to a South African lead-zinc ore. In all cases the Eh is measured as a function of the different DO, IS and pH values. The main objective was to achieve selective flotation of galena from sphalerite. The first part of the work was micro-flotation tests conducted on single minerals with galena used as the basis for effect of the factors studied on redox potential and ultimately recovery. The DO was varied by alternating between the use of air and nitrogen as the gas source to the micro-flotation cell. PH was varied between pH 9.2 and pH 11.8 using sodium hydroxide. In the first part of this study a factorial design approach was used to determine the interactive effects of the variables tested, viz. DO, ionic strength and pH, on the Eh and on the recovery. Redox potential was measured using a combination electrode made up of platinum wire and Ag/AgCl reference combination. Recoveries indicated that pH had the most significant effect on recovery and Eh. The influence of redox potential on recovery was found to be of relevance to the condition of high dissolved oxygen concentration and less so at low dissolved oxygen concentrations. It was also noted that that the combined interaction between ionic strength and dissolved oxygen concentration had a positive effect on recoveries, however this was not so with Eh. The chemistry of the ions in solution was observed to play a dominant role on the recovery due to changes in solubility arising to pH modification. The longer term objective of this work is to determine the optimal Eh conditions for the separation of galena from sphalerite.

Jan 1, 2016

By David Dreisinger

Arsenic occurs in nature in association with many valuable metals including copper, nickel, cobalt, gold and platinum group metals. The recovery of these valuable metals is of course complicated by the need to extract and stabilize arsenic in a form suitable for disposal. In this paper, a review of some recent developments related to hydrometallurgical treatment of arsenic bearing materials is provided. The key aspects of metal dissolution, arsenic stabilization and disposal are discussed.

Jan 1, 2014

By Chunlin Chen

Published data on thermodynamics of tin in liquid copper, matte and slag have been reviewed, assessed and used in development of thermodynamic solution models of melts. The developed model/database was applied in modelling the Sn deportment in primary copper smelting and e-waste melting processes. The results show that Sn can be removed from the matte through evaporation of various volatile Sn species (with SnS the most volatile) and slagging during copper smelting. The Sn removal increased with increasing matte grade due to the increased gas and slag volume. In the e-waste smelting process, fluxing strategy was developed for smelting e waste to produce a slag with reasonable liquidus and viscosity. Modelling results show that very low amounts of Sn reported to the gas phase due to low S, hence low SnS partial pressure in the system. The black copper produced could contain a few percent of Sn depending on the oxygen potential. The Sn in the black copper could be removed to the slag phase during anode refining. INTRODUCTION Tin is an impurity element commonly found in copper ores, which will be dispersed into various solid, liquid, and gaseous streams during the pyrometallurgical processing of copper. Tin alloy is widely used in electronic soldering due to its low melting point. The growth in treatment of recycled e-waste through primary and secondary copper smelting has led to an increased tin input to the smelting system. Therefore, the deportment of tin between phases is of great interest to the operators of modern smelters. Multi-Phase Equilibrium (MPE) is a thermodynamic package developed by CSIRO for simulating reactions between phases in multi-component and multi-phase systems (Zhang et al., 2002). Over the years the capability of the MPE model has been extended to cover the behavior of a large number of elements in high temperature system (Chen, Zhang, Wright, & Jahanshahi, 2006). In the present paper, the thermodynamic data on tin in liquid copper, matte and slag have been reviewed, assessed and used in the development of a database for Sn slag, alloy and matte phases. The model/database was applied in modelling the tin deportment in primary copper smelting and e-waste smelting processes. The aim of this study is to provide a better understanding of the chemical behaviours of tin in high-temperature copper processing and e-waste smelting.

Jan 1, 2019

By R. P. Viljoen, A. L. Sokolov

"The distribution of mineralized provinces is analyzed on the basis of their genetic link with specific blocks of the earth&apos;s crust including ancient platforms, mobile belts and zones of tectonicmagmatic activation. Mobile and fold belts surround the Siberian platform in Russia and the Kaapvaal craton in South Africa, with decreasing age zoning away from ancient platform margins. The main differences in the geological development of the two cratonic areas are: (1) the long period before the final stabilization of the Siberian platform (3600 Ma to 1600 Ma) and the comparatively short period of time for the stabilization of the Kaapvaal craton (3600 Ma to 3050 Ma) and (2) the intensive multiple activation of the marginal zones of the Siberian platform and the tectonicallycontrolled, magmatic sedimentary, intracratonic activity, typical of the Kaapvaal craton. Mineralization of the Siberian platform is largely characterized by marginal reactivation zones of differing ages although mineralized intracratonic Cu-bearing basins of Proterozoic age are also known. Mineralization of the Kaapvaal craton is mainly related to the formation of the intracratonic basins i.e., Witwatersrand (Au, U) and Transvaal (Au). The latter is characterized by multi-age volcanic-intrusive activity including the emplacement of Bushveld Complex (Cu, Ni, Pt, Cr, Au, V). The Siberian platform is characterized by the prolonged development of inherited mineralization from Archean until the late Mesozoic. The main period of mineralization in the Kaapvaal craton is restricted to the middle Proterozoic.The Baykal-Patomskaya and Namaqua-Natal mobile zones occupy similar positions adjacent to the Siberian and Kaapvaal cratons, respectively, and demonstrate similar modes of metallogenic development: i.e., the early formation of exhalative Pb-Zn-Cu deposits during the early stage and magmatic Cu deposits during the late stage. The more remote mobile belt near the Siberian platform, the Trans-Baykal, is characterized by intensive multi-age mineralization (Wo, Mo, Sn, fluorite), related to a period of tectonic-magmatic activation. The Saldania Belt occupies a similar position near the Kaapvaal craton but is known for its poor Au, and Cu mineralization. It does, however, have some similarities with Trans-Baykal Belt in regard to Mo-W bearing granitoids.The phenomenon of interference of geosynclinal, orogenic, platform, and tectono-magmatic activation regimes is known for the Russian section of the Pacific Ocean Volcanic Belt."

Jan 1, 1994

By N. Moelans, I. Bellemans, K. Verbeken

In this work, we present a phase field model to simulate the facetted crystallization of Fe3O4 in a quaternary FeO-Fe2O3-Cu2O-SiO2 melt under different partial pressures of oxygen. An important focus in creating more realistic phase field models is the incorporation of the thermodynamic driving forces in multicomponent multiphase-field models by coupling to thermodynamic databases. The diffusion of FeO, Fe2O3 and Cu2O is considered. The ratio of FeO/Fe2O3 at the upper boundary is in equilibrium with the oxygen fugacity of the atmosphere, while conserving Fe. Two-dimensional simulations are performed with different varying oxygen fugacity in the atmosphere. For the considered composition range, the growth velocities of the spinel crystals increase with decreasing oxygen fugacity. INTRODUCTION Crystallization of silicate melts has its applications in geology, pyrometallurgy and glass making. In pyrometallurgy, the solidification of slags influences the freeze lining behaviour (Campforts et al., 2007) and the cooling of slag after tapping (Durinck, Jones, Blanpain, & Wollants, 2008). Modeling of silicate melt crystallization is frequently done on the macroscopic level, using thermodynamic equilibrium calculations to determine the fractions of all phases as a function of temperature. The Factsage software and database package (Bale et al., 2016, 2009, 2002) already proved its usefulness in pyrometallurgical applications, for example to model the phase mixture after solidification of a stainless steel slag (Durinck et al., 2008). Crystallization of phases typically results in complex morphologies on the mesoscale, e.g. dendrites or facetted growth. On this mesoscale, the phase field concept has proved to be a very powerful tool (Moelans, Blanpain, & Wollants, 2008) for modeling crystallizing microstructures, because it can treat arbitrarily complex interface shapes with minimal mathematical complexity. In contrast to macroscopic models, the diffusion profiles and crystallization kinetics can be described as well as the morphology of individual crystals. First, Kobayashi (Kobayashi, 1993) simulated a growing dendrite in a pure undercooled metallic liquid. Then, Warren and Boettinger (1995) simulated a dendrite in an isothermal system considering a binary alloy. The extension to multi-phase systems was done by Steinbach et al. (1996). This was further extended by Tiaden, Nestler, Diepers, and Steinbach (1998) to a framework with coupled diffusion and phase field equations in multi-component systems.

Jan 1, 2019

By L. Beiza, L. Velásquez-Yévenes

Chalcopyrite is by far the most abundant copper sulphide on Earth, but it has proved to be problematic in its processing by leaching, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface during leaching. This study is focussed on the electrochemistry of chalcopyrite dissolution in acidic chloride system, which has recently gained attention as a feasible alternative to conventional sulphate media for chalcopyrite leaching. It is well understood that chalcopyrite dissolution from mineral grains depends strongly on the solution redox potential at the mineral surface as well as the composition of the product layer that may form on its surface. The chloride ions in solution support the Cu(II)/Cu(I) couple as the primary oxidant, as they can form complexes with the cuprous ions formed, increasing the dissolution rate. Additionally, these ions increase the potential range where chalcopyrite can be oxidized. The chemical reaction that occurs on the surface of chalcopyrite in chloride solutions in the presence of cupric ions will be characterized and the coulometry of the reaction will be reported to understand what is happening on the surface of chalcopyrite. Electrochemical experiments have been carried out to investigate the behaviour of mixed potential by open circuit potential (OCP) measurement for 30 minutes using sulphuric acid at pH 1 under nitrogen at 25⁰ C. The effect of chloride was analysed at 0, 20, 50 and 100 g/L and cupric ions from 0 to 50 g/L. The potentials obtained were then used to carry out chronoamperometry tests for a period of 30 minutes in absence of cupric ions. The mixed potential did not show a significant difference with an increase in cupric concentrations in the absence of chloride. Increased mixed potentials and current densities were observed at higher chloride and cupric concentrations. Chronoamperometry tests at those potentials were used to construct a voltammogram trace which has the same trend as a normal cyclic voltammogram but with much lower current densities. INTRODUCTION As a result of the depletion of copper oxides, the leaching of copper sulphide minerals has become the focus of many studies. Chalcopyrite, (CuFeS2) which is the most abundant of copper minerals, has proved to be challenging to process via hydrometallurgy, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface, during leaching.

Jan 1, 2019

By G. Sedelnikova, D. Kim, N. Ibragimova

"The object of this study was three samples of sulfide old tailings, which were obtained after Cu- Zn ores processing. Fine metal dissemination in sulfides as well as fine mineral intergrowth determine the refractory nature of material and low metal extraction using simple methods: gravitation 1-6%, flotation 32-48%, cyanidation 10-37%, and cause the need to use sulfide bio-oxidation to liberate gold and to recover it by heap leaching. The gold is the main valuable metal in the tailings with content 1-1.5 g/t. Heap bio-oxidation with mesophilic and moderately thermophilic bacteria was used for pre-treatment of tailings before gold heap leaching from bio-oxidation solid residues. The tailings have a low permeability < 0.3-1.2 m/day, which is caused by migration of fine particles, decreases recovery rates, and is poorly suited to heap bacterial leaching. Therefore, preliminary gold sulfide tailings with permeability < 0.3 m/day were pelletized using copper containing flotation tailings of converter slags and calcium oxide. The most gold extraction was obtained for pelletized tailings. The base metals (copper and zinc) were precipitated from bacterial solutions. Experiments have demonstrated effective bio-oxidation of all third gold sulfide tailings samples and enough high gold extraction 60-82%.INTRODUCTIONIn Russia, as everywhere, there is a trend toward deterioration in the quality of mineral resources, including non-ferrous and precious metals, manifested in lower grade and higher complexity of ores. The proportion of refractory ores is increasing, characterized by fine dissemination of metals in sulfides, intergrowth, and poor liberation of minerals during concentration, resulting in loss of base and precious metals to flotation tailings.Over the operation period, huge reserves (hundreds of million tons) of ore processing waste have been accumulated at mining and concentration operations. Because of the imperfections of the previously used ore concentration technologies, the content of precious and base metals in flotation tailings is comparable with the grades of the ores being currently processed. Therefore, old tailings can be viewed as an additional reserve of non-ferrous and precious metals. The works (DEN, 1997; Lyman, Johnson, & Guerney, 2000) demonstrate that, tailings containing sulfides (sulfur, copper, zinc, and other metals) are a potential environmental hazard since they produce acid drainage water containing toxic components. Processing those tailings would require designing an effective technology for recovering useful components and protecting the environment."

Jan 1, 2016