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By M. A. Mahtab, A. S. Burgess, R. G. Charlwood, P. O. Sandstrom, J. L. Ratigan

"Addressing a current operating and environmental concern, this paper first presents an overview of the design program for an underground radioactive waste storage vault. It then reviews the construction, operational and thermal-mechanical aspects of such a project. The relevant experience from major underground construction projects is reviewed and the paper concludes with brief comments on the design-oriented research and development requirements . 1. IntroductionA program to develop techniques for the ultimate disposal of high-level radioactive waste into geologic formations was announced by AECL in 1975 (Tamrnernagi, 1976), and is discussed more fully in a later document (Boulton, 1978). Our paper summarizes the studies caried out, as part of the AECL waste management program, by the authors and associates on the development of design concepts for a vault situated in crystalline rocks of the type present in the Canadian Shield.The design studies have been carried out in three phases, the elements of which are described in Section 2.1 (also see Fig. 1). The general vault designs are presented in Section 2.2. These provide for emplacement of either immobilized fuel or solidified reprocessing wastes in a room-and-pillar facility at a depth of 1,000 m.Section 3 reviews the principal design considerations from the construction, operation and thermal-mechanical response aspects. The concepts have been studied in both temporal and spatial domains, and the requirements and responses assessed in each as appropriate.Section 4 briefly reviews the availability of relevant experience from previous major underground construction projects. Finally, in Section 5, brief comments are given regarding design-oriented research and development requirements."

Jan 1, 1980

By G. J. Kipouros, N. Dadvand

"In recent years coatings of alloys have been produced for a wide range of applications including many for wire bonding application. The main characteristic of the baths of electroless plating is the presence of sodium hypophosphite as a reducing agent and also as the supplier of phosphorus. In the electroplating of alloys the Watts bath is predominantly used. This presentation compares the two techniques, electroless plating and electroplating, and discusses the possibilities of cross utilization of sodium hypophosphite in an attempt to formulate baths that eliminate the waste disposal issue related to some components.INTRODUCTIONThe importance of surface characteristics and the linkage of surface coating process to surface characterization has given rise to the evolution of surface engineering. Not only the surface preparation and morphology has become very important to the coating technology but also the knowledge of surface area exposed to the process of coating or corrosion is absolutely essential in ascertaining the behaviour of coatings and their adherence to the substrate. The above concepts are not unknown to researchers involved in the protection of surfaces, particularly metallic, from corrosion and/or erosion corrosion. However, the complexity of the surface defects, roughness, porosity, interconnected porosity and other related factors have contributed to the uncertainty of the true surface area versus the nominal surface area. Therefore critical parameters such as current density and chemical surface intensity although have been studied extensively at the atomistic level by carefully prepared surfaces are very difficult to be determined at the practical scale required during the coating processes.The most pronounced case calling for an understanding the relationship between the surface area and the effective protection is the coating of surfaces of items produced by compression or consolidation of powdery materials. With the advent of nanomaterials and the additive manufacturing through 3D metal printing this issue is becoming more important. Certain experience in this field come from the accumulated knowledge resulted from the attempts to characterize the electrochemical behaviour of powder metallurgy metals and alloys. Powder metallurgy has been a well-established process for half a century on basic metals such as iron, copper and their alloys. Recently the development of powder metallurgy process for aluminum, titanium and attempts to develop powder metallurgy processes for magnesium and its alloys has brought to light another important issue that of the development of coatings on difficult to plate reactive metals such as aluminum and magnesium. Despite of many successes in the development of powder metallurgy alloys the exact characterization of the corrosion behaviour of the coatings and the substrates is difficult to determine because of the unknown morphology of the exposed area i.e. the exact morphology and area of the exposed surface (Samal, 2007)."

Jan 1, 2016

By P. MacPhail, G. S. Dobby, I. M. Flint

"The objective of the laboratory work described in this paper has been to develop a method f or producing small gas bubbles at moderate to high gas rates in a flotation column. Small bubbles are particularly important for attaining reasonable flotation rates of fine particles. An ultrasonic aerosol generator has been employed to add frother solution directly to the gas stream. Using porous glass and filter cloth spargers, aerosol frother addition has produced bubbles at 1/2 to 2/3 the diameter of those produced by conventional frother addition to the liquid, at a lower frother consumption.IntroductionGas bubbles are generated in a flotation column most commonly by forcing gas through a porous medium called a sparger. Typical sparger material includes rubber (pierced with small holes) , fabric (such as filter cloth), fritted glass, or porous metal (steel or bronze) . Solid sparger material is suitable for laboratory use; however, for industrial applications a flexible sparger such as rubber or fabric is necessary to prevent the eventual plugging of orfices with solid particles and/ or precipitates. An exception to this is the use of a gas liquid contactor external to the column in combination with pressure release of gas in water, a method that has been demonstrated to produce very small gas bubbles. The typical objective of bubble generation for flotation column purposes is to produce bubbles with diameter of about 0.1 cm (and less) at a gas superficial velocity of 1 cm/s to 3 cm/s. In general, the smaller the bubble, the better. In man y cases, though, there is little , or nothing, gained by generating bubbles less than about 0.05 ern in diameter.Several factors affect bubble size when generated by a sparger: gas rate, orifice diameter, sparger surface area, surfactant type, surfactant dosage, and static head. At very low gas rates bubble diameter is independent of flow rate and is proportional to orifice diameter. At the moderate gas rates encountered in flotation columns bubble diameter, db' is related to gas flow by: db oc vg n, where vg is superficial gas velocity (rate of gas flow per unit column area). For porous steel and filter cloth, n has a value of about 0.25 for vg between 0.2 cm/s and 2 cm/s(2). The magnitude of the effect of orifice diameter at these gas rates is unclear. The effects of frother type and concentration on bubble size issuing from a single orifice have been measur ed by Miagkovaru , shown here in Figure I(IS). The reduction in bubble diameter upon surfactant addition is due to the lowering of interfacial tension created by adsorption of surfactant at the gas liquid interface."

Jan 1, 1988

By D. Seo, P. Au, S. Yandt, N. Tsuno, A. Sato

Nickel-base single-crystal superalloys are used for gas turbine airfoil applications due to their excellent high temperature properties. A good understanding of the mechanical response of these alloys under different temperature and loading conditions is essential for modeling their behavior. In this study, the low cycle fatigue behavior of CMSX 2 oriented with the loading axis along [001] was investigated under zero-compression strain-controlled loading at 1100°C. The experiments were performed with or without a two-minute dwell (hold) in compression. The microstructure before and after testing was analyzed to understand the deformation characteristics including the effect of dwell.

Jan 1, 2010

By Asbjørn Solheim

The service life for aluminium reduction cells is often limited by the cathode carbon, due to preferential wear along the periphery of the cell leading to the so-called "W" wear pattern. The reason for this preferential wear is not well understood. Two mechanisms are suggested in the present paper; 1) non-stationary dissolution of aluminium carbide into a layer of sludge that periodically forms and disappears, and 2) electrochemical formation and dissolution of aluminium carbide within an aluminium carbide layer containing bath-filled pores. The latter mechanism may be related to the high local current density at the periphery of the cathode.

Jan 1, 2011

By C. Sorel

The PAREX code has been developed since the nineties by CEA and AREVA to describe the PUREX process implemented in the French fuel reprocessing plants. It enables the calculation, either in steady or transitory states, of the behaviour of the different elements of interest at each process step. The high customized structure of the software allowed the implementation of various phenomenological models describing solvent extraction systems dedicated to uranium purification from crude ore to spent fuel. After qualification of the implemented models, the code was used to perform the design of flowsheets, for safety demonstration analysis or for operational assistance.

Aug 1, 2010

By Christopher H. Clement

The International Commission on Radiological Protection (ICRP) is an independent, international organization that advances for the public benefit the science of radiological protection, in particular by providing recommendations and guidance on all aspects of protection against ionizing radiation. This presentation touches on aspects of The 2007 Recommendations of the ICRP, a fundamental document that lays out the system of radiological protection for all exposure situations and types, and focuses on other recent publications relevant to the uranium industry. Of particular relevance are the 2009 ICRP Statement on Radon and the accompanying report on lung cancer risk from radon.

Aug 1, 2010

By B. S. Riess

A novel design for an automated uranium pellet stacking system is presented. This system is designed as a drop-in solution to the current production line to enhance the fuel pellet stacking process. The three main goals of this system are to reduce worker exposure to radiation to as low as reasonable achievable (ALARA), improve product quality, and increase productivity. The proposed system will reduce the potential for human error. This single automated system will replace the two existing pellet stacking stations while increasing the total output, eliminating pellet stacking as a bottleneck in the fuel bundle assembly process.

Aug 1, 2010

By Nathan Deisman

Coupled reservoir geomechanical simulations have become a key component of caprock integrity assessments for SAGD operations. This work demonstrates the differences of stress evolution when considering coupled versus uncoupled reservoir simulation. Coupled simulation involves the use of a reservoir and a geomechanical simulator with feedback to each simulator to update reservoir or geomechanical variable (permeability, porosity, relative permeability, pressure, temperature, saturations). Uncoupled simulation only passes the pressure and temperature to the geomechanical simulation with no reservoir simulator updating. Therefore, it is possible to complete uncoupled simulations exclusively with no knowledge of geomechanical flow property evolution. However, it is important to understand the differences between the stress evolution in each model for caprock integrity analysis. A single geological model was selected and parametric analysis was completed while varying the geomechanical the production injection pressures (1600 kPa, 1900 kPa, 2200 kPa) for a reservoir with an initial pressure at the injector of 1300 kPa. The results of the six uncoupled and coupled models are compared through the changes in mean stress, shear stress, and strength with focus on geomechanical assessment of caprock integrity.

Jun 1, 2012

By T. Yalcin, S. Brunet

The flocculant-assisted hydrocyclone involves the addition of a flocculant to the cyclone feed for the purpose of obtaining a clear cyclone overflow, and thereby eliminating or reducing thickener requirements in tailings disposal operations. This paper describes the testing of this concept on the iron ore tailings of Quebec Cartier Mining Company's Mount Wright Concentrator. The current practice at Mount Wright makes use of conventional hydrocyclones and thickeners for the disposal of their tailings, which are generated in a spiral gravity separation circuit. The test work was conducted primarily on their cyclone overflow product which becomes the feed to the thickeners. A detailed study was carried out to determine the sedimentation properties of these tailings in terms of their response to a variety of flocculating reagents, and to varying conditions of pH, pulp density and flocculant dosage. The tailings were then processed in a laboratory hydrocyclone with the aid of flocculants. The use of a shear resistant flocculant, in particular, was found to yield cyclone overflows with low solids contents. Based on the test results obtained, a conceptual flow sheet has been proposed for the treatment of the iron ore tailings at the Mount Wright Concentrator.

Jan 1, 2004

By W. Beres, R. E. Miller, B. Shiari, L. R. Zhao

A dynamic multiscale (MD/FE) method has been used to study dislocation generation and plastic deformation during a nanoindentation process which is physically associated with the generation of heat within the specimen and as a consequence with a temperature rise. Two different techniques are applied to study the temperature effect on the nanoindention process. In the first technique, a global Nose-Hoover thermostat is applied to the entire atomistic region to keep temperature constant during simulation (finite temperature approach). In the second method, the thermostat is applied only on a damping region along the MD/FE interface. Both techniques are able to effectively and efficiently absorb high frequency reflected waves from atomistic/continuum interface. The temperature profile of the atomistic region beneath the indenter is reported and discussed at four different initial substrate temperatures for both techniques. The loaddisplacement (load/unload) curves for different temperature-controlling techniques are compared and discussed. The nucleation and propagation of dislocations in the atomistic region are investigated for both techniques. Correlations between the observed features in the load-displacement curves with the motion and pile-up of dislocations are reported as a function of temperature.

Jan 1, 2006

By A. Innus, R. Pelletier, C. Allaire

Refractory used for molten aluminium confinement is typically assessed separately for thermo-physical properties and molten aluminium resistance. This present work provides a case study comparison of four commercial refractory products that were subjected to a test procedure that combines mechanical impact, thermal shock with molten aluminium contact. The main conclusion of this work is that physical and mechanical property values by themselves do not, and cannot, predict the response of refractory to potential interactions between molten aluminium contact and thermal shock and mechanical impact. Adequate physical simulation is imperative to quantify the effect of such interactions.

Jan 1, 2004

By Murray W. Grabinsky

This paper considers thickening mine tailings to dense non-segregating slurry or paste for surface disposal. The driving motivation for this initiative is the elimination of ponds, reduction in containment dams and significant decrease in water being sent to the tailings basin. This inherently reduces risks of environmental and structural failure. Some of the engineering challenges in creating a stable stack of thickened or paste tailings are identified, and possible field and laboratory testing techniques in support of design are discussed. Finally, the integration of monitoring activities into the ongoing management of the surface disposal site is considered.

Nov 1, 2002

By P. R. Warner

This paper reviews the development of certain aspects of the electrical specifications of Anglo American?s suite of specifications for gearless mill drives (?GMDs?). These specifications are based on experiences in both Anglo American?s and others? operations, benchmarking against large hydro generators, the advice of industry and university experts, and continuous close co-operation with OEMs. To achieve a step change in availability additional final testing and electrical protection have been implemented, insulation requirements have been specified for machines to be operated at high altitude and clean area and access control systems have been developed.

Nov 1, 2011

By P. R. Warner

This paper reviews the development of certain aspects of the electrical specifications of Anglo American’s suite of specifications for gearless mill drives (“GMDs”). These specifications are based on experiences in both Anglo American’s and others’ operations, benchmarking against large hydro generators, the advice of industry and university experts, and continuous close co-operation with OEMs. To achieve a step change in availability additional final testing and electrical protection have been implemented, insulation requirements have been specified for machines to be operated at high altitude and clean area and access control systems have been developed.

Jan 1, 2012

By Nirmal Weerasekara, Jochen Franke, Malcolm Powell, John Favier

Mill liners serve the dual purpose of protecting the shell from wear and transferring the rotary motion of the mill to an effective grinding action. As the liners wear, the efficiency of energy transfer changes, so there is balance between liner profile for wear and for milling efficiency. A tool that can simultaneously predict the evolution of the liner profile and the associated change in milling efficiency should prove most useful in optimal liner design. This paper presents such an approach, based on measured 3D liner profile data informing 3D DEM simulations of charge motion and liner wear modelling.

Jan 1, 2012

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007

By Masakazu Daté

Moisture effect has been studied for the CO oxidation over Au/TiO2, Au/Al2O3 and Au/SiO2, in the range of H2O concentration over four orders of magnitude. It has been found that the catalytic activity is generally enhanced by moisture in the reactant gas. The enhancement is as large as two orders of magnitude. Response to the moisture concentration, however, depends on the support oxide, indicating different contributions of the support to the reaction steps. The moisture effect is reversible and the activity is mainly determined by the amount of moisture absorbed by the catalyst. The apparent activation energies are not significantly influenced by moisture for Au/TiO2 and Au/Al2O3. On the contrary, non-uniform conversion curves versus temperature observed for Au/SiO2 are drastically changed, which indicates that the reaction over Au/SiO2 does not take place at low temperatures without moisture. The moisture effect may be probably attributed to the decomposition of carbonate species accumulated during the reaction, while the ?OH group might directly participate in the reaction pathways as a promoter.

Oct 1, 2003

By Selvia Tourn, Liliana Castro

"Abstract - Argentina, a large country with an important agriculture industry, needs an ever-increasing amount of phosphorus and potassium, as essential elements for plant growth. Current requirements are met from imports, but potential resources exist in Argentina. For example, several phosphatic occurrences are known in paleo-marine basins, the most significant of which are in Tertiary units in Patagonia. In addition, two types of potassium deposits are also known in Argentina: evaporite deposits in the Neuquén Basin at depths of 750 m to 1500 m contain 22 to 25 wt% K2O equivalent; and glauconitic sandstone containing about 6 wt% K2O has been identified in Patagonia.Several experiments were undertaken to test unprocessed phosphate rocks as slow-release, direct-application fertilizers, with good results. In addition, it is proposed that direct application of glauconitic sands would provide an efficient and economic alternative source of potassium. Tests with glauconite samples are still in progress. The existence of both phosphate and glauconitic rocks in Patagonia suggests that development of an extractive industry for these materials would not only help Argentina approach self-sufficiency in fertilizer usage, but also assist in the socio-economic development of this region."

Jan 1, 2003

By Edmond Chow

Shovel bucket blast fragmentation analysis is an alternate way to assess blast performance and its effects on downstream mining processes. A camera is installed on the boom of cable shovels, and the stick of hydraulic shovels. Images are captured automatically as the shovel digs, and are processed to acquire rock size information. The automatic data acquisition makes this method safe to use with minimal manual labour. It also allows for a large set of sample data to be captured from both the surface and the interior of a bench face. The system has been deployed in several mines to provide an objective assessment of blasting performance. Images are captured from their cable or hydraulic shovels. The images are grouped into sets based on the shovel location and time to match the fragmentation to specific blasts. Blast fragmentation reports are created for each blast after reviewing the results. Measuring blast fragmentation from the shovel bucket proves to be an effective alternative for blast performance assessment with unique advantages. The blast fragmentation information has been valuable to the mines, and the mines have begun adopting it into their operations.

May 1, 2011