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By L. Becze, B. Pierre, S. Di Carlo, G. P. Demopoulos

From January to June 2007, the autoclave production at the Kidd Metallurgical Site was severely affected as a result of plugged discharge lines and extensive precipitation/crystallization of sulphates that caused massive scaling in different autoclave compartments. Work was performed at McGill University to understand the root causes. The crystallization of zinc and ferrous sulphate salts was investigated in terms of solubility measurements. Scale samples were characterized using chemical and mineralogical-spectroscopic analysis. In this paper, following a description of the Kidd zinc pressure leach operation, highlights from this investigation are presented and solutions used to overcome the problem are outlined.

Jan 1, 2008

By V. V. Severov, Z. Lafhaj

The flotation separation of salt type calcium minerals is problematic, due to the similarities in their formation properties and the same active Ca2+ related site for interaction with anionic collectors and similar physicochemical characteristics such as solubility, point of zero charge, surface speciation, Ca-site density. The work was performed to achieve effective and selective separation of the calcium-minerals using pure minerals samples: four calcite, two fluorite, and two apatite samples. The effect of pure and mixing anionic collectors such as oleic and linoleic acid to different ratio (2:1; 1:1; 1:2) as well as the role of nonionic collectors on the selective separation of Ca minerals were studied. All flotation tests were performed in self-aspirated flotation cell. The results obtained with the blend of anionic collectors with the molar ratio of 2:1 show a separation between apatite and calcite at pH 5 and a ratio 1:2 at pH 9. The enhancing of separation contrast using the sodium silicate as a depressant for calcite and apatite is also examined as a function of oleate/linoleate ratio. Additionally, this paper discusses the enhancing of the selective separation of Ca minerals when anionic collectors were blended with nonionic reagents. The surface reactions in aqueous mineral suspensions and the adsorption of anionic collectors blended with nonionic reagents were studied by FTIR spectroscopy. An unexpected synergistic effect was observed for some ratios between anionic and nonionic reagents. The mixture of fatty acids and nonionic reagent showed very high flotation efficiency in comparison with fatty acid alone for the flotation of an igneous low-grade phosphate ore.

Jan 1, 2016

By William C. Browning

An economic drilling programme is one which costs the !east in chemicals, equipment, and time. The basis for such a programme with rotary drilling techniques is a drilling fluid in which bentonites do not swell. This is recognized in the growing trend toward gyp and other inhibited mud systems. Therefore, even though the mechanism of thinner action is a subject of applied colloid ,chemistry, the understanding of this mechanism is of economic importance in controlling the flow properties of inhibited muds. In phosphate, or sodium tannate, conditioned muds that are relative-!y free of contaminating-electrolytes, the thinner, or dispersing agent, is adsor.bed, ?creating an electrical double layer about the clay particles. The mutual repulsion of these charged particles effects colloidal stabilization, or deflocculation of the suspended clays, as discussed by Norton and others. In inhibited muds, however, the electrolyte concentration in the filtrate is sufficient to collapse the double layer and flocculation of the mud solids occurs, as evidenced by increased viscosity and gel values. Chemicals to control the flow properties of inhibited muds, therefore, are vital to the successful use of these systems as it is not always economical to adjust flow properties by watering back. Flocculation of suspended particles, as indicated in the work of Vervey, Overbeek, and others, is due primarily to gravity-like, long-range Van der Waals forces. Prevention of flocculation may, therefore, be secured by the interposition of any barrier between the particles, the thickness of which approximates the extension of the Van der Waals at-traction. Organic polyelectrolytes, such as Kembreak, Rayf!o, and Q-Broxin, may act to increase the double layer charge when used in small amounts in fresh-water muds. More important, however, is the fact that in inhibited muds an increase in concentration of the polyelecholyte permits the formation of a condensed film adsorption layer of the polyelectrolyte about the clay particle. When this occurs, the extremely viscous condensed adsorption layer creates a mechanical. barrier that prevents flocculation of clays, even in the presence of inhibiting concentrations of elecholytes. Rheological evaluation of the degree of deflocculation, or colloidal stability, may be made by utilizing the known effects of particle inter-action and volume concentration on the flow properties of suspensions. Rheological evaluation should be supplemented by direct microscopic or ultra-microscopic observation.

Jan 1, 1958

By Y. Wang

Phosphates and fluorides are used as regulators for the removal of silicates from diasporic-bauxite both in direct and reverse flotation. While using dodecylamine chloride as a collector, micro-flotation studies showed that sodium hexametaphosphate has stronger depressing power on diaspore than on silicate minerals with increasing sodium hexametaphosphate concentration at pH 6.5, but sodium fluorosilicate shows poor depression on diaspore with increasing sodium fluorosilicate concentration at the same pH. Zeta potentials of diaspore and silicate minerals become more negative both in the presence of sodium hexametaphosphate and sodium fluorosilicate. Adsorption density studies indicated that the adsorption density of sodium hexametaphosphate on diaspore is much higher than that on silicate minerals at the concentration of 75 mg/L. FTIR spectroscopy studies show that sodium hexametaphosphate interacted with the Al atoms exposed on the diaspore and silicate minerals surfaces to form P?O?Al bonds through the P02 groups. It is possible that sodium fluorosilicate interacted through F- or [SiF6]2- with silicate minerals surfaces based on the analysis by AES.

Jan 1, 2006

By Frank D. Shepherd

THE Gunnar Gold Mines property is on the west shore of Beresford lake, in the Rice Lake mining division, southeastern Manitoba. Gold was first discovered in place in the Rice-Beresford Lakes area in 1911 on the Gabrielle claim, now included in the San Antonio Mines property at Rice lake. Following an eastward trend of favourable prospecting ground, promising showings were next staked in the vicinity of Long lake during the years 1915 and 1916. At that time, William Walton and associates, among them Gilbert LaBine, staked the Eldorado vein, north of Long lake, and Eldorado Gold Mines, Limited, was formed to develop the property a Company that, later, was to become widely known through successful operation of its radium-silver mine at Great Bear lake, Northwest Territories. Continuing eastward from Long lake, Walton and his partners, Gunnar Berg, Leo Seaberg, and Wm. Quesnel, staked claims during the years 1920-24 in the vicinity of Beresford lake which, later, were to become incorporated into the Gunnar Gold Mines property. The presence of gold-bearing quartz on these claims had been known from the time they were staked, but an opportunity to consolidate them into a group was not forth-coming until early in the year 1933. Although promising gold showings had been disclosed during the performance of assessment work on individual claims, no continuous mineralization having mine-making possibilities was discovered until after the consolidation of the entire group. From this stage onward, progress was rapid. Active exploration was begun on August 1st, 1933, and late in October James Houston reported favourably on the property. On October 27th, Gunnar Gold Mines, Limited, was incorporated in the Province of Ontario to develop and operate the property. The Company is also registered in Manitoba. The authorized capitalization is 3,000,000 shares of $1.00 par value. Gilbert LaBine was appointed president of the Company, with James Houston as mine manager. Following completion of a diamond-drilling programme, planned in 1933, it was decided to install a mine plant capable of carrying development to a depth of 1,000 feet. A transmission line, 5 miles in length, was built to the Great Falls-Central Manitoba line of the Manitoba Power Company, Limited.

Jan 1, 1939

By Nelson Hogg

"THE NOR-ACME gold mine is located close to the north shore of Snow Lake, at 54°53' north latitude and 100°03' west longitude. It is about 75 air miles east of Flin Flon, and 36 miles by road from Wekusko at Mile 81 from The Pas on the Hudson Bay Railway.The claims which contain the Nor-Acme orebodies were staked in 1927 by C. R. Parres, who, with his sons, held the ground until 1938 when Nor-Acme Mines Limited was incorporated. In 194 l, on the recommendation of F. Ebbutt (1), this property was optioned by the Howe Sound Exploration Company, Ltd. A program of 50,000 feet of diamond drilling resulted in the outlining of two orebodies containing an estimated 5,000,000 tons with an average grade of 0.15 ounces per ton to a depth of 1,000 feet.A period of inactivity during the war years was followed by the construction of a mining plant capable of treating 2,000 tons of ore per day. Milling started in March 1949, and to the end of 1954 has resulted in the production of 383,793 ounces of gold and 32,906 ounces of silver from 3,331,403 tons of ore.General GeologyThe general geology of the Snow Lake area is described by J. M. Harrison (2), and will not be discussed here except insofar as it affects the Nor-Acme orebodies. The orebodies occur in rocks of Precambrian age that have been classified by Harrison as the Snow group, comprising meta-morphosed sediments interbedded with acid and basic volcanic rocks. The volcanic rocks include pyroclastic types which are unique in the region, a fact which led to their classification in the Snow group rather than the more widespread Missi group that generally occupies the same stratigraphic position above the Amisk group (Figure 1)."

Jan 1, 1949

By S. B. Mishra

Ni-20Cr metallic coating was deposited on a Ni-based Superalloy (3Fe-19.5Cr¬0.3Ti-Balance Ni) by a shrouded plasma spray process; NiCrA1Y was used as a bond coat. Erosion studies were conducted on uncoated and plasma-spray coated superalloy specimens using an air-jet erosion test rig at a velocity of 40 m/s and impingement angles of 30° and 90°. The coating has been characterized for porosity, microhardness and microstructure and X-Ray Diffraction (XRD). An electron probe micro analyzer (EPMA) was used to obtain X-ray elemental mappings of the coating along the cross-section. Scanning electron microscope (SEM) with EDAX attachment was used to analyze the eroded surfaces.

Jan 1, 2005

By J. J. O?Neill

Introduction The Beattie mine is the first of its character to be exploited in Quebec. It is primarily a large low-grade gold deposit containing values which a few years ago would not have been considered as ore. Much interest is attached to this development as its success may mean a greatly enlarged scope to gold mining in Canada on deposits which have formerly been considered worthless. Because of its potential importance as a pioneer in low-grade gold mining, the Quebec Bureau of Mines decided to make a careful detailed study of the Beattie in the hope not only of assisting in its development, but of stimulating the search for similar essential geological conditions in other parts of the Province. This paper is a summary of the results obtained during two months on the property in 1932, supplemented by a few trips underground in 1933. The full report will appear in the Annual Report of the Quebec Bureau of Mines for 1932, Part C. Location and Means of Access: The Beattie ore-body is situated two miles west and one half mile north of the centre of Duparquet township, and approximately 22 miles north 28° west of the town of Noranda. Until the fall of 1932, access to the property was from LaSarre, on the Canadian National railway, over a thirty-mile water route with one portage 600 feet long; about 2,000 tons of machinery and supplies were taken in by that route. An automobile road, nine miles long, now connects the property with the Makamik highway, and a narrow-gauge railway, without ballast, gives outlet for concentrates from the mill to the C.N.R. tracks of the Rouyn-Taschereau line, nineteen miles distant.

Jan 1, 1934

By R. E. Phelan

Introduction The Flin Flon deposit was discovered by Tom Creighton, an experienced prospector and trapper, who in 1914 made his headquarters at The Pas, Manitoba, and still lives there. The discovery was made in the fall of 1914, and Creighton and his associates spent the next summer in investigating the find. In August of 1915 the first claims were located. The property was optioned to Hayden Stone & Company, and in the spring of 1916 they started a diamond-drill campaign. Hayden Stone spent $50,000 on the property and, among other things, completed over 7,500 feet of diamond drilling. The ore not being as high grade as expected, and also being complex in character, Hayden Stone then abandoned their option. In the spring of 1917, Messrs. Earle, Faskin and associates took an option on the property and started an extensive drilling campaign. This campaign accomplished approximately 18,000 feet of drilling and secured for the Faskin interests a 32 per cent interest in the property. In 1920, W. B. Thompson and The Mining Corporation of Canada secured an option, and, while this option was in force, sunk two shafts in the ore-zone and did a considerable amount of drifting and cross-cutting in the ore to study the manner in which it occurred in place, and, by actual channel sampling, to check the grade indicated by the previously accomplished diamond drilling. All of this work had indicated that an ore-body existed on the property containing at least 18,000,000 tons of ore, assaying as follows: gold, 0.074 oz./ton; silver, 1.06 oz./ton; copper, 1.71 per cent; and zinc, ). 45 per cent (1). Complete analyses of composites from the drill holes showed that the ore was very complex in character. It contained the above values in gold, silver, copper, and zinc, as well as large amounts of sulphur and iron, and traces of lead, arsenic, antimony, cobalt, and various other metals. Although the ore was obviously pyritic in character, pyritic smelting, the usual method of treating this class of ore, could not be used to beneficiate the ore with any reasonable expectation of making such a venture a financial success, since coke and coal landed at Flin Flon would be expensive, and siliceous flux was known to be scarce locally and low in grade. The property therefore lay idle until 1925.

Jan 1, 1935

By J. Dupre, A. Gontcharov, H. Pepin

Produced by the conventional TIG welding CMSX-4 welds had been studied. It was demostrated that microstructure of welds depended on filler materials, welding parameters and joint design. Epitaxial solidification of CMSX-4 clad deposits produced a directionally solidified structure while welding with the similar filler material. Defects free clad welds were obtained by TIG welding without preheating using similar and dissimilar filler materials.

Jan 1, 2006

By J. D. Zhu

A numerical model for predicting microporosity formation in aluminum castings has been developed, which describes the redistribution of hydrogen between solid and liquid phases, the transport of hydrogen in liquid by diffusion and Darcy flow in the mushy zone, One of the key features of the model is that it uses a two-stage approach for porosity prediction, In the first stage, the volume fraction of porosity is calculated based on the reduced pressure, whereas, in the second stage, at fractions solid greater than the liquid encapsulation point, the fraction porosity is calculated based on the volume of liquid trapped within the continuous solid network, which is estimated using a correlation based on the Niyama parameter, The porosity model uses thermal data calculated using the commercial finite element package ABAQUSTM. The model has been applied to examine the evolution of porosity in a series of experimental samples cast using unmodified A356 in which the initial hydrogen content was varied from 0,048 to 0.137 [cc/100g], A comparison between the model predictions and the experimental measurements indicates good agreement in terms of the variation in porosity with distance from the chill and the variation resulting from initial hydrogen content.

Jan 1, 2005

By J. Béland

"Three stages, each characterized by a particular sedimentation, magmatism, mineralization and deformation, are recognized in the geological history of Gaspe. The first stage led to the formation of the Taconian orogen, the second to that of the Acadian orogen and the third stage to the accumulation of a post-orogenic cover. The Taconian orogen includes volcanic and detrital rocks of Late Precambrian or Cambrian and Lower to Middle Ordovician ages in which ultrabasic intrusions have been emplaced. Folding is severe. Mineralization is of the Cr-Ni-Cu type, related to the igneous facies.The rocks constituting the Acadian orogen include two distinctive sequences corresponding to two successive sub-stages. The second substage began in Early Devonian time with the first pulses of the Acadian orogeny. The rocks of the first substage grade southward from a nearly platformal sequence to an assemblage implying less stability and spotty volcanism. The second substage was one of synorogenic deposition of elastic rocks, first in a marine environment and later under terrestrial conditions. Granitic intrusions, surrounded by aureoles of skarn and hornfels in which Cu-Pb-Zn mineralization is found, accompanied the Acadian deformation. The second-stage"

Jan 1, 1969

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By Etienne Roy Grégoire

Since the early 1990s, the Canadian mining industry has been increasingly defined by the signing of Impact and Benefit Agreements (IBAs) between mining companies and Aboriginal peoples. While these agreements are intended to complement the legal system, they also serve to establish the legitimacy of mining projects and to encourage the harmonious integration of these projects into their social and environmental contexts. Beyond their practical implications, what are the effects of such agreements on the ability of Aboriginal communities to access the institutional space where the authorization of mining projects and the conditions of their implementation are decided? Can we view IBAs as a preliminary step towards the operationalization of the principle of Free, Prior and Informed Consent? This paper aims to explore the potential of IBAs as a sustainable solution to the legitimacy issues that result from the implementation of the formal regulatory framework governing mining activities in this jurisdiction. We highlight what constraints and opportunities the James Bay and Northern Quebec Agreement (JBNQA) engenders for local communities and draw attention to the ways in which the negotiation of the Raglan IBA and the environmental evaluation processes act upon each other. We find that certain structural problems - and problems of legitimacy ? related to mining in Northern Quebec cannot be solved by the sole signature of an IBA, which suggests the need for caution when considering such agreements as a panacea. The Raglan case demonstrates that IBAs, like other modes of regulation relying on the direct interface between companies and communities, would benefit from a stricter framework and more explicit ties with official regulation channels.

Aug 1, 2013

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By S. Mamonov, V. ?shikhin

"The purpose of work was the significant increase of copper recovery from slag at a concentrating plant. Analysis of study of slag phase composition showed the perspective of a slow slag cooling method due to its recrystallization and transition of primary copper minerals to secondary.Copper content in base slag varied between 0.71 and 0.96%. The study of a degree of copper minerals release of the slowly cooled slag in comparison with a yielding slag showed that in a flotation size grade –0.071 mm of yielding slag the weight ratio of released copper minerals grains is 58.95% against 86.73% in samples of slowly cooled slag. The process flotation sheet consists of three main, one control and two cleaner flotation operations with aftergrinding of middling products. A reagent mode was differed from a factory one by decreasing the slurry pH from 11–12 to 8–9. This paper shows research results of the slurry alkalinity impact on technological indexes of beneficiation (flotation).Industrial testing of a resulted batch of slowly cooled slag at “SUMZ” concentrating plant showed the efficiency of such processing: copper recovery to a copper concentrate increased by 15–19%.INTRODUCTIONIntensive development of mining and metallurgy industries within a 250-year period in the Ural region led to forming of approximately 315 man-made mineral formations at the territory of the Sverdlovsk region. The region contain over 32.5 billion tons of barren rocks and out of balance ores, over 1.5 billion tons of tailings, over 115 million tons of slimes, and over 100 million tons of metallurgical slag (Demin et al., 2000). Latters, at average, contain 407 thousand tons of copper, 2519 thousand tons of zinc, 7 tons of gold, and 150 tons of silver (Rudoy et al., 2011). Wastes generated in mining processing and metallurgical sector of economy contain not only thousands tons of copper and zinc, but cause significant damage to the environment where they are located. The reduction of negative impact of anthropogenic wastes on the environment as well as the storage volume reduction of valuable metals from dump slags is possible by improving the efficiency of the melting and further flotation of slags formed during this process."

Jan 1, 2016

By Erol Yilmaz

This poster presents results obtained from an experimental test set-up called CUAPS (curing under applied pressure system) allowing to assess the performance and quality of cemented paste backfill (CPB) materials. CUAPS can be used for carrying out a series of tests: one-dimensional consolidation, saturated hydraulic conductivity, pore-water pressure dissipation, and curing under uniaxial stress. The poster presents CUAPS testing preliminary results including uniaxial compression tests (UCS) and mercury intrusion porosimetry (MIP). It was demonstrated that CUAPS-consolidated CPB materials cured under time-dependent stresses provide higher UCS values than standard mould (undrained and unconsolidated) CPB samples. This may be explained by the release of excess pore water within backfill that gives rise to a significant reduction in the total porosity of fresh CPB materials prior to hardening and thus, to higher mechanical strength (UCS) gain. The results obtained from MIP highlighted a good correlation between CUAPSconsolidated and mould-unconsolidated CPB samples. MIP results were also related to UCS values in order to predict the final CPB mechanical strength.

Nov 1, 2008

By S. C. Livanou, S. P. Tampouris, E. N. Zevgolis

In ferronickel (Fe-Ni) production from oxidized nickeliferous ores, mechanical losses of ferronickel in the slag are reduced by magnetic separation. Slag from the electric furnaces (E/Fs) contains 0.16% Ni. Its magnetic separation gave a pre-concentrate with 0.76% Ni, weighing approximately 6.5% of the feed. Nickel recovery was 29.7%. This pre-concentrate was then treated in a second (concentration) plant. Concentration treatment involves screening, crushing and magnetic separation. A pre-concentrate with 0.76% Ni gave a magnetic concentrate with 2.58% Ni and a non¬magnetic part with 0.35% Ni. Smelting of the non-magnetic part without the addition of a reduction agent in a laboratory electric arc furnace, gave a ferronickel alloy with approximately 20% Ni and a slag with 0.16% Ni.

Jan 1, 2005

By Y. H. Hatzor

"This is an extended abstract for a keynote lecture delivered by the author during the 2015 ISRM congress in Montreal on the application of the numerical discontinuous deformation analysis (DDA) method in rock mechanics practice. Due to the large scope of the topic this lecture will focus on studies performed by the rock mechanics group at Ben-Gurion University, alone or in collaboration which other research groups, and is not intended to provide a comprehensive review of everything that has been done on the subject worldwide during the past two decades. A forthcoming textbook (Hatzor et al., in preparation) will attempt to provide such comprehensive coverage.DDA has been developed by Dr. Gen-hua Shi while he was doing his PhD studies under the supervision of Professor R. E. Goodman at U. C. Berkeley (Shi, 1988). Dr. Shi has invented a new numerical discrete element method which provides a solution for dynamic deformation of block systems, hence its applicability to rock mechanics practice. The method is similar in essence to the finite element method in its implicit formulation of the time integration scheme and where in every time step the minimum potential energy of the entire system is sought, but here every element is a finite block with six degrees of freedom. The blocks are assumed to be stiff (simply deformable) so that most of the energy is consumed by slip along pre-existing discontinuities, the frictional resistance of which is assumed to obey the Coulomb-Mohr failure criterion for rock joints. The greatest advantage of DDA over alternative numerical discrete element methods is its robust area (volume) integration which ensures great accuracy even when the blocks are of irregular shapes, including non-convex blocks which may contain holes. The greatest disadvantage is the necessity to solve in every time step very large matrices of unknowns, imposing great CPU demand when the block system involves a large number of blocks. Another disadvantage is the sensitivity of the solution to the choice of the penalty parameter which is implemented in DDA in the form of stiff springs that are attached to contacts once detected automatically.The inherently dynamic formulation of the DDA method lends itself to solution of dynamic problems in rock mechanics. Dynamic analysis with DDA can be performed in different ways corresponding to different rock mechanics problems and loading conditions. Three main classes of loading conditions which are relevant to rock mechanics applications are discussed here: 1) dynamic loading of a single bock which rests on a stationary foundation, 2) response of a block to dynamic loading of the foundations, 3) wave propagation through a block system.The most common approach is to introduce the dynamic force to a specific block in an otherwise fixed block system and check the resulting deformation, typically the time dependent displacement or rotation of the loaded block. This approach is particularly useful for dynamic rock slope stability studies when a stability of a specific rock block against earthquake vibrations is in question. The first 2D-DDA benchmark test of this approach was performed by Hatzor and Feintuch (2001) who introduced harmonic acceleration functions into a block which rests on an inclined plane. The analytical solution proposed for this problem by Hatzor and Feintuch (2001) was later generalized by Kamai and Hatzor (2008). The first 3D-DDA benchmarking for this approach was presented by Bakun-Mazor et al. (2012) who studied single and double face sliding of blocks which rest on stationary foundations and subjected to harmonic input acceleration functions."

Jan 1, 2015

By C. A. Pickles

Nickeliferous limonitic laterite ores contain considerable free moisture. In this research, the application of microwave radiation for the drying of this ore was investigated. The effects of sample mass, initial moisture content and porosity on the microwave drying rate were studied and the results were compared to those obtained with conventional drying. Microwave drying rates of two to three times the conventional values were achieved. Further enhancement of the microwave drying rate was realized by increasing the flow rate of air over the sample or by operating at reduced pressure. The high microwave drying rates were attributed to the inverted temperature gradient which resulted in internal heating and boiling and this in turn promoted movement of the water, both as liquid and vapour, to the surface.

Jan 1, 2005