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By A. Suzue, T. H. Okabe, Y. Taninouchi

Methods for the physical separation and enrichment of platinum group metals (PGMs) from autocatalyst scrap were studied in order to develop an environmentally friendly and efficient recycling process. In general, an autocatalyst has a honeycomb-structured ceramic substrate that is coated with a catalyst layer containing platinum (Pt), palladium (Pd), and rhodium (Rh). Therefore, physical separation of the PGM-containing catalyst layer directly from the ceramic substrate is favorable for upgrading the autocatalyst scrap. In this paper, the authors present a scrap-upgrade process consisting of electroless iron plating and magnetic separation techniques. Iron was plated on the surface of a catalyst sample used to represent an autocatalyst, which was then crushed and magnetically separated. The Pd in the catalyst sample was successfully extracted and concentrated in the magnetic powder. Under certain conditions, the process increased the Pd concentration by a factor of 4 and recovered 89% of the Pd in the autocatalyst sample.

Jan 1, 2014

By K. E. Waters, J. E. Nesset, F. Rosenblum, J. A. Finch, S. Moon

"Some materials when exposed to various conditions can exhibit a rise in temperature without requiring an external heat source. Generally referred to as pyrophoric or self-heating substances, they challenge the safety of materials handling, storage and transportation. Reliably assessing the self-heating potential of materials is thus essential. Over the years a number of test protocols have been developed. A widely accepted method is that recommended by the United Nations to certify the safety of shipping pyrophoric goods. Our test work on sulphide materials has shown that the U.N. test can give false negatives if the sample oxidation history is not considered. Depending on the degree of oxidation (“weathering”), the same sulphide material can exhibit self-heating ranging from safe to hazardous. For concentrates, oxidation can occur during storage and transport making the sample weathering history an important consideration in the test work. To make the U.N. test, and other single-stage self-heating procedures, more reliable in assessing self-heating potential when testing sulphide materials, it is suggested that a weathering step be incorporated in the test protocol. This test work for two sulphide samples, an ore and a concentrate, demonstrates the impact of incorporating a weathering stage in the test protocol. INTRODUCTIONSelf-heating occurs when exothermic reactions produce heat faster than can be dissipated to the surroundings. Numerous substances self-heat, ranging from wood chips and powdered milk to coal and sulphide minerals (Beever & Crowhurst, 1989; Hudak, 2002). Mixtures of sulphide minerals, most notably those containing the iron sulphide pyrrhotite (Fe(1-x)S), commonly encountered in the extraction of base metals (e.g., copper, zinc, lead, and nickel), are particularly prone to self-heating (Rosenblum, Nesset, & Spira, 2001; Payant, Rosenblum, Nesset, & Finch, 2012). In the mining and subsequent processing stages, the minerals are progressively liberated and finely ground, then separated, usually by flotation, with the resulting concentrates stored and transported to smelters for metal extraction. At most of these stages the sulphides are exposed to both moisture and oxygen, conditions that promote partial sulphide oxidation and the formation of elemental sulphur. Studies have shown that pyrrhotite, in particular, readily oxidizes to form elemental sulphur (Bernier & Li, 2003; Belzile, Chen, Cai, & Li, 2004; Somot & Finch, 2010). The elemental sulphur becomes fuel for further self-heating as the temperature of the mineral mixture increases above 100 oC (Rosenblum & Spira, 1995; Somot & Finch, 2010). It is believed the propensity of pyrrhotite to self-heat is a result of its iron-deficient, and hence somewhat unstable structure. It is worth noting that pure metal sulphides (with the exception of pyrrhotite) do not exhibit appreciable self-heating. A mixture of minerals sufficiently different in their electrochemical rest potential is required to initiate self-heating at ambient temperatures (Payant et al., 2012)."

Jan 1, 2016

By Marc Bétournay

This article examines how fuel cell technology and related power distribution system fits within mine operating requirements. Considerations for improvement of power plant architecture and functions to yield production advantages are presented. Improvements to conventional mining approaches are also discussed.

May 1, 2007

By C. R. Edwards, D. R. G. Watt

"Equity Silver Mines Ltd. a member of the Placer Development group of companies operates Canada's largest silver mine near Houston in north-central British Columbia. Initially, the silver-gold-copper flotation concentrate contained excessive levels of antimony and arsenic, so a leach process was installed to remove undesirable metals and provide improved smelter terms for the leached concentrate. The leach plant which has been fully described elsewhere (1, 2, 3), was forced by deteriorating process economics to shut down in April 1984. Equipment was mothballed and alternate uses sought.The Endako Mines Division of Placer Development Limited, located some 150 kilometres east of the Equity mine site, shut down its molybdenite mining and milling facilities in the spring of 1982. Endako has continued to produce molybdic oxide (molybdenum trioxide or MTO) via intermittent roaster runs, and also a high purity, lubricant grade molybdenum disulfide in the Ultrapure Plant. With the steel industry in the doldrums, molybdenum chemicals present an alternate and growing potential for molybdenum sales. In 1982 Placer Development began testing this market. Molybdenum chemicals were produced in the United States on a toll basis using Endako MTO as process feed. The transfer of this production to Canada was being considered when Equity's leach plant shut down, and it was noted that most of the equipment and skills necessary could be provided by the leach plant. See Figure 1.A careful investigation of process requirements was completed by engineering and production staff at Equity and Endako. A provisional capital and operating cost estimate was made, and it was decided to perform a test run during July 1984. There were strong reasons to proceed with this project. A positive cash flow was expected for both Endako and Equity. Endako would have product to continue to expand in the molybdenum chemicals market with the added selling point that now the complete production process would be under direct control of Placer Development companies. Equity would further benefit since a portion of the leach plant would continue in operation thus maintaining and exercising our hydrometallurgical engineering and operating skills. Finally, Equity would have a base from which to search out other processes adaptable to the idled leach plant equipment."

Jan 1, 1986

By D. Y. Kim

This paper shows an approach that a gondola-typed robot recognizes walls on building facades. It is applicable for autonomous or teleoperated building façade painting robots. The robot may react based on the wall classification data. This approach is based on 2D LRF(two-dimensional Laser Range Finder). The robot acquires relative distances to walls, and a Kalman filter decides correspondence of walls. An ARS(Attribute Reference System) sensor helps convert LRF coordinate to global coordinate. The experimental results demonstrate the conversion of LRF data.

Aug 1, 2013

By F. Urekar, R. B. Pankhurst

"Air spaces and air gaps in an explosives column are known to allow greater distribution and cushioning of explosive energy from the rock mass. This energy distribution is enhanced if the explosives ' gases can be confined in the borehole for as long as possible by plugging and stemming above the air space.Power Plug is an inflatable plug which can seal a borehole at any point to separate the stemming from an air gap and explosive toe load.IntroductionThis paper will discussion-going work by C-I -L Inc. and operators of two open pit mines to study the results of using Power Plugs:I. Pit wall stability - the authors have found the Power Plug effective for wall control blasting in open pit mines.2. Selective mining of coal seams - the authors work shows the Power Plug allows mining selective coal seams by predrilling underseam waste wedges.Pit Wall StabilityWall stability in an open pit mine is essential for safety. Good wall stability can be achieved with wall control blasting techniques which cushion the effect s of the explosives charge by decoupling the charges from the borehole wall. The usual method of decoupling a charge in a large-diameter rotary borehole is to load the explosives in tubes (Fig .I) . We now believe the air deck system is effective in sea ling a borehole above the explosive charge to create an air deck within the borehole which will cushion the blast.In a linear decoupled charge, an air annulus surrounds the explosives charge and cushions the effects of detonation genera ted gases on the pit wall. In an air deck, i.e. with the hole plugged at the collar, the gases genera ted by an explosive toe load are sealed in the empty borehole column. After a period of time, these trapped gases produce radial cracking between holes along the entire length of the borehole.It is common practice to employ de coupled explosive charge columns in the borehole to limit blast damage to surrounding rock. The exact mechanism of energy transfer in such blasts, however, is not well understood. Interruption of the continuous explosive column in a borehole by means of stemming, or air decks, may also be viewed as another form of decoupled blast. Decoupling of the explosive charge from the borehole wall affects both explosive energy release and explosion pressure developed in the borehole."

Jan 1, 1988

By A. J. Hyett, R. D. Reichert

"A laboratory and field research program was conducted to investigate the major factors influencing bond capacity of grouted cable bolts. The results indicate that cable bolt capacity most critically depends on the grout uniaxial compressive strength (UCS), the radial confinement, and the embedment length.In the laboratory &apos;split-pipe&apos; tests were conducted using P VC, aluminum and steel pipes to provide radial confinement, and field test sites were chosen in granite, limestone and shale rock masses. For both datasets higher capacities were obtained under conditions of higher radial confinement. A correlation between the two was obtained through a comparison of the radial wall stiffness of the laboratory pipes with that of the field boreholes as measured using a high pressure dilatometer. Cable bolt capacity was found to increase with embedment length though not in direct proportionality.The use of low water cement ratio grouts (<0.40) can increase cable bolt capacities by 50% to 75%. This effect is maximized under conditions of high radial confinement. However, the use of super thick grout paste (0.30 and less) may be both impractical and undesirable, first because of their limited pumpability and second because of their inconsistency in strength. Grouts with a water cement ratio of between 0.35 and 0.40 are recommended for practical cable bolt applications."

Jan 1, 1992

By D. Xia

Pt-Bi intermetallic Nanoparticles was prepared by the polymer-anchor method. The electron micrographs shows that the dimensions of particles sharply distribute in the range of about 3-6 nm. The elemental ratio of Pt/Bi in the bimetallic particles is estimated by the electron probe microanalysis method. Pt-Bi intermetallic Nanoparticles shows a higher activity for the ORR than pure Pt. No significant dependence of the oxidation currents on the rotating speed of the electrode could be observed in the presence of methanol. This clearly indicates that the Pt-Bi is inactive to methanol.

Jan 1, 2005

While this paper is directed towards the ?Bellambie? type of rope attachment, the principles can be applied to any brand of rope fitting however, it is a only a broad outline and the specific installation and maintenance procedures can be obtained from the attachment supplier. The types of attachment to be discussed are:- ?Thimble Type rope cappel ?Wedge Type cappel ?WRC Rope Clamp ? (Rope Glands) ??Hoist and Balance Rope Sockets In each case, the assembly and stripping (disassembly) plus the basic maintenance procedures is briefly described. A guide for Risk Assessment is also included but because of his familiarity with the installation, the end-user is in the best position to draft the final version.

May 1, 2003

By A. Kraly, M. Complojer, P. Paschen, K. Gamweger, H. Antrekowitsch

Increasing quality of aluminium alloys and continuous optimization of the production process leads to an improvement of the gas purging systems. The application of porous plugs for the treatment of liquid aluminum is nowadays not widely used in the aluminium industry especially in Europe. The Department of Nonferrous Metallurgy and the Christian Doppler Laboratory of Secondary Metallurgy of Nonferrous Metals intensified the research and development of refining and alloying processes by gas treatment during the last years. CFD-modeling supports these experiments, which should lead to lower hydrogen content, lower suspended particles and a better distribution of alloying elements in the melt. Different parameters such as temperature, bubble size, gas amount and which kind of gas is used influence the quality of the products.

Jan 1, 2006

The Rabbit Lake In-Pit Tailings Management Facility contains frozen layers of tailings due to subaerial deposition during the coldest periods of winter. Thawing is required to ensure full consolidation of the tailings and to regain disposal space presently occupied by ice. Electric resistance heating has been used to heat soil for bitumen extraction and remediation of volatile contaminants. A preliminary evaluation of the application of electric resistance heating to thaw about 0.3 cubic metres of frozen tailings was conducted using tailings frozen at about -2 oC. Visible thawing of the tailings mass was observed after 25 hours, demonstrating the feasibility of this approach.

Aug 1, 2010

By K. Mayhew, A. Lossin, H. Salomon-de-Friedberg

"The proportion of arsenic-bearing copper concentrates that supply the copper industry is on the increase. The current strategy of miners and smelters to blend feeds to reduce average arsenic levels is rapidly becoming unsustainable as more concentrates with even higher arsenic levels enter the marketplace. In addition, the capability of smelters to manage increasing arsenic levels to more stringent and restrictive environmental standards is limited by available process technologies.CESL Cu-As Technology is a viable technical and economic alternative to traditional smelting. It offers the advantage of simultaneous leaching and precipitation of the arsenic in a single processing step while achieving high copper extractions. The process has been piloted in six separate, fully-integrated pilot campaigns for feeds ranging from ~1% to 12% arsenic in concentration. This paper will focus on the behaviour of arsenic in CESL’s leaching/precipitation step and operational factors that influence it, and on the chemical and physical characteristics of the subsequent iron-arsenic residue that represents today’s best available technology from a long-term sustainable (capital/operating costs, metal recovery, safety, environmental) perspective.The examples provided will demonstrate copper extractions approaching 99% and arsenic deportment to residue of 99%. Instantaneous settling rates of the residue were measured at 15+ m/hr. Data from subsequent short and long-term stability testing of the residue confidently support the view that the scorodite-bearing residues from the process will be stable and provide an acceptable arsenic management practice. The technology offers increased revenue and environmental certainty for miners, smelters & refiners to support the development of metallurgically challenged copper-arsenic deposits. Furthermore, results will be presented demonstrating the technology’s ability to successfully incorporate hazardous arsenic containing smelter by-products such as dust into the process feed and simultaneously extract copper value while fixing the arsenic in a stable residue."

Jan 1, 2016

By V. C. Pandolfelli, P. Bonadia, F. A. O. Valenzuela, L. R. Bittencourt

Refractories for aluminum cells, if not properly selected, can lead to increased energy consumption and even shorten the pot life. Based on recent advances in understanding the deterioration mechanism of cathode materials, several commercial bricks in the SiO2-Al2O3 system were compared to the one used by an Alcoa smelter. Both physical and chemical properties were considered in the selection of the refractories. A more reliable method of permeability measurement, which takes into account inertial and viscous effects during the fluid flow, was applied. Additionally, the traditional cup test and other characterization techniques, such as thermal conductivity, X-ray diffraction, and mercury porosimetry, indicated that a brick with a relatively low alumina/silica ratio, presenting low open porosity and low permeability, far exceeded the performance of the brick currently in use.

Jan 1, 2004

By Simon D. Handelsman, Malcolm Scoble, Marcello Veiga

"Abstract - In many mining areas, potentially profitable mineral projects can be at risk because local people do not trust their governments and mining companies on many issues, including human rights. Projects will continue to be vulnerable to potential failure, delays, and higher costs. This paper suggests that geoscientists need to be aware of the global challenges they face from issues of corporate social responsibility, sustainable development, and human rights. These are not areas in which geoscience education has traditionally focused.This paper examines the types of conflict concerning human rights that are encountered by geoscientists involved in mineral exploration and development. It provides a background to human rights issues and presents a classification of the types of issue encountered. It reports on a survey of case studies that provide examples of the breadth, complexities, and consequences of such issues. The paper then concludes by outlining the development of codes and standards to improve performance, and suggests approaches for positive, practical engagement."

Jan 1, 2003

By J. Beddoes

The various microstructural factors that influence the creep resistance of y-titanium aluminides are presented and discussed. Titanium aluminides have potential for a variety of intermediate temperature applications in both gas turbine and reciprocating engines. While it is well established that the &apos;fully lamellar&apos; titanium aluminide microstructure offers superior creep properties, the particular influence of lamellar morphology, third phase precipitation, and grain boundary structure in controlling both the primary and tertiary creep behaviour is presented. The results are primarily based on tensile creep experiments undertaken using several titanium aluminide intermetallic compositions processed via powder metallurgical techniques, investment casting and Bridgman directional solidification. The results indicate that lamellar structure and precipitate formation have a major impact on primary creep, while microstructural degradation through both lamellar and precipitate coarsening influence on the onset of tertiary creep leading to fracture. The results are used to design a creep resistant microstructure produced by directional solidification and the effectiveness of this designed microstructure is demonstrated through 10,000 hour creep tests.

Jan 1, 2004

By R. D. MacEchern, M. C. Rockwell

"This paper describes the research and tests carried out to recover the readily available barite from the tailings produced by the Nystone Chemical Ltd. operation at Debert, N.S. The tailings comprised 70-80% of the original feed and contained about 20-25% Baso4 .The objective of the research, undertaken during 1982, was to produce a barite concentrate which would meet the American Petroleum Institute (API) barite requirements for use in drilling mud. Samples from the tailings pond were examined and analysed to determine the tailings characteristics.Preliminary test work was performed on the tailings samples using a Haultain Superpanner, Wilfley tables and Humphrey's spirals. The grade of the barite concentrate retrieved did not satisfy the API barite requirements.The fineness of the tailings and the fact that approximately 80% of the barite was contained in the -200 mesh (0.074 mm) size fractions, indicated that flotation of barite from the tailings might be successful."

Jan 1, 1984

By Lindsay A. Robertson

The long term management of acid generating tailings at mine closure is a common issue, however, management of ARD is significantly impacted by local conditions, including climate. Acid generating tailings, over time, will produce acid rock drainage (ARD) if left exposed to water and air, which both contribute to the sulphide oxidation process. The long term closure of tailings storage areas is a concern from both environmental and engineering perspectives, with long term acid generation and dam stability the main risks. Several approaches can be taken to minimize ARD from tailings facilities using cover systems. Three tailings facility cover case histories, in areas of net positive water balances, were investigated using unsaturated flow modelling software to determine the long term potential for limiting ARD by increasing saturation of the tailings and decreasing oxygen ingress. Each case study demonstrates the importance of integrating the tailings dam engineering into tailings cover closure design. Model predictions are compared to measured saturation levels to assess the accuracy of the calculations.

May 1, 2011

By T. R. Eger

The Load-Haul-Dump (LHD) vehicle is a trackless, free-steered vehicle used in underground hardrock mining to move large quantities of ore/rock to haulage trucks, ore dump locations, or crushing stations. The purpose of this paper is to show, through case study examples, how principles of human factors can be applied to improve the overall design of the LHD vehicle to enhance line-of-sight (LOS), improve posture and decrease whole-body vibration exposure (WBV). Vehicle modifications (larger cab windows, lower engine profile, smaller buckets, angled radiator profile) can lead to improved line-of-sight. The use of secondary viewing devices, such as cameras, can also improve line-of-sight and allow the operator to adopt a more neutral sitting posture. Seating systems that are suited to the underground mining environment can result in vibration attenuation and less vibration transmitted to the LHD operator. The connection between vehicle design, line-of-sight and driving posture needs to be considered in order to continue to improve the design of the LHD and enable the operator to work in a neutral posture with minimal vibration exposure. Changes leading to improved line-of-sight, vibration reduction, and a neutral sitting posture will lead to fewer LOS related accidents and decreased risk factors for musculoskeletal injury.

Aug 1, 2013

By J. Bhattacharya, S. K. Mukhopadhyay, S. K. Pal

"While time and again many authors have categorically stressed the restoration of the environment, very little effort has been made in the mineral industry to develop the economy of environmental control. There are many abatement procedures that search a maze of variants. Among them pricing environmental damage seems to be more logical and easily implementable.IntroductionMining as an operation has a severe impact on the Earth&apos;s natural resources. While economical environment control is much sought after, solutions are often varied and complex, and can differ in the problems of single or multiple mine sites.Determination of Optimum use LevelsIn “mining environmental control"" it is required to strike a balance to find optimum use levels. The solution is to find where the welfare benefits equal the cost involved to curb the degree of environmental damage (Fig . I) . In the mining industries this can be done by modifying the production/extraction process itself. For most pollutants, the marginal costs of control will exceed the benefits from further reduction of damage long before the zero pollution damage point is reached (Fig. I). From an economic perspective the optimal alteration of environment by mining would occur at z; pollution continues to be caused by ""zy"" control units, but it would be inefficient to pursue the redemption efforts further because the marginal cost involved would exceed marginal welfare benefits."

Jan 1, 1992

By Sheila E. Daniel

"Since 1989, the Mine Environmental Neutral Drainage Program (MEND) has sponsored research into ways of reducing the environmental impact and financial liabilities associated with Acid Mine Drainage from tailings and waste rock. Toward this overall objective, Kilborn was contracted to review the use and applicability of passive treatment systems for acid mine drainage.Experimentation using passive systems to treat acid mine drainage has been ongoing since the early 1980's in North America. Passive treatments are generally considered an attractive alternative to active lime treatment, since they require minimal human involvement, no power, and only seasonal or periodic care and maintenance after establishment. Most attractive is that initial capital cost to implement a passive treatement system is generally low to moderate. Ongoing operating costs are similarly low when compared to active treatment systems.Passive treatment systems currently used, or under investigation to treat acid mine drainage include: anoxic limestone drains, aerobic wetlands, reed bed wetlands, compost wetlands, microbial systems and bioabsorption systems. These wastewater treatment systems utilize the chemical, biological and physical removal processes that occur naturally in the environment to improve wastewater quality, including: oxidation, reduction, coagulation, adsorption, absorption and precipitation; microbial activity; and, gravity aeration and dilution. The rates at which these processes occur determines the loading which can be treated and the effectiveness of the system.The results of our literature review will be summarized, and insight provided into the applicability of passive systems to treat acid mine drainage from Canadian Mines."

Jan 1, 1995