Search Documents

By S. Steinlechner, S. Wegscheider

"In the past, the metallurgical industry was most of the time dedicated on their main commodity, recovering base metals like zinc, copper or lead but leaving other valuable side elements in the generated residues. As a result, these accompanying minor elements, like gold, silver, indium or also PGMs can be found in the dumps of the corresponding industry. Because of political unrest, strikes, economic reasons or decreasing primary resources leading to a high supply risk, also those mentioned minor elements moved into the focus of the recycling industry. Therefore, beside the base metals, first of all the recovery of those minor metals would be of high interest contributing to the economic viability of recycling processes, although they occur in much smaller quantities in materials. In this context, residues from zinc industry, like leaching residues or precipitation residues show high potential to carry silver as well as indium next to lead and zinc. Therefore, the paper summarizes carried out thermochemical calculations investigating a possible recovery of silver as well as indium by volatilization and the influence of zinc and lead on this process. Based on these theoretical investigations with HSC, trials in lab scale were done verifying the obtained results.INTRODUCTIONHuge amounts of iron precipitate, mainly jarosite get landfilled every year although there is a high content of valuable metals in this residue beside iron. Nevertheless, jarosite has to be dumped due to the presence of contaminating heavy metals. The accumulation of these residues takes up massive land on the one hand but also causes a series of environmental problems in ecosystems on the other. Moreover, some toxic ingredients such as arsenic and cadmium can be dissolved in rain water and are therefore harmful to the health of the aquatic systems. (Erdem & Özverdi, 2011; ÖzverdI & Erdem, 2010) Approximately 0.5 t of dry jarosite accumulate in the production of 1 t of zinc by the hydrometallurgical zinc-winning route (Svens, 2010). Jarosite is a precipitation residue formed during the iron removal. In general, the iron already exists in the zinc ore which is why zinc ferrite builds up during the roasting step of the zinc ore. Zinc ferrite is only soluble in strongly acidic solutions and during the hot acid leaching step it gets dissolved while zinc and iron enter the solution. It is necessary to get rid of the iron because otherwise it would deposit on the cathode first due to its precious character which would be harmful in the zinc-winning electrolysis. Nevertheless successful investigations were done by adding chlorine to the jarosite to recover silver. These findings leads to another residue which occurs in huge amounts – electric arc furnace dust (abbreviated with EAFD) from the iron and steel industry. In 2013 the annual electric steel production reached about 451 million tons. Around 15-20 kg of EAFD is produced per ton of steel in an electric arc furnace (EAF), creating approximately up to 9 million tons of dust per year. (Grabda, Oleszek, Shibata, & Nakamura, 2014; World Steel Association) Next to elements like zinc, lead and iron, chlorine and fluorine are present in this dust. While galvanized steel plates in the scrap act as a source for zinc, casting powders, flame retardants and synthetic coatings are responsible for the chlorine and fluorine contents in the dust."

Jan 1, 2016

By D. W. R. George, J. L. Stewart

Developments in the last decade, which have contributed to increased productivity and decreased coke rates in the iron blast furnace, are reviewed. Future progress in blast-furnace practice is also considered.

Jan 1, 1966

By L. J. Friedman

The recovery of sulfur dioxide from metallurgical gases for the production of sulfuric acid has been the primary means of reducing sulfur dioxide emissions from nonferrous smelters. Sulfuric acid has been produced from gas originating from fluid bed roasters, electric furnaces, reverberatory furnaces, flash smelting furnaces, Pierce Smith and flash converters, sinter machines, etc. The gas from each of these sources has a unique set of variables that affect the design and operation of the sulfuric acid plant. In addition, the sulfuric acid plant itself has been evolving, with new equipment designs and materials. This paper will review each of the unit operations in the gas cleaning and contact sections of the metallurgical sulfuric acid plant, discussing various equipment designs, materials and the handling of gas stream variables and impurities. The paper updates to 2007 previous works on metallurgical sulfuric acid plants by the authors, and analyzes new equipment and systems, including: FRP or alloy quench systems, alloy converters, towers and pump tanks, heat recovery systems, high efficiency mist eliminators, tower packing, etc.

Jan 1, 2007

By R. T. McAndrew

Introduction Drinnan is situated in the Prairie Creek coal area in the Foothills belt of Alberta. It lies on the main line of the Canadian National railway from Edmonton to Jasper. The exact location is shown on the map (Figure I). Interest in the field was aroused by several circumstances: Its proximity to Brule and Pocahontas on the southwest and to Coal-spur on the southeast led to the belief that coal might be economically produced here. There was already at Hinton a 3 ft. 9 in. coal seam being mined by Seabolt. The coal was of very good grade, being black and shiny in appearance with well defined cleavage and a heat value of 12,000 B. t.u. Outcrops of coal had also been noticed on the north side of the Athabaska river and Fish creek. These facts led the Jasper Coal Company to investigate the field. This Company considered taking over the Seabolt property at Hinton, but, owing to the size of the seam, this plan was abandoned and prospecting by diamond drills and test pits was started two years ago in the district east of Hinton. After prospecting had been completed, the most favourable district was found to be in township 51, ranges 24 and 25, west of the 5th meridian. The Company's lease includes all or parts of sections 18, 19, 20, and 28 in range 24, and sections 10, 11, 12, 13, and 14 in range 25. The approximate boundaries of the property are the Canadian National railway on the north, Happy creek on the west, and Cache Percotte creek on the east. The lease comprises 3,100 acres, and the total amount of coal in sight is estimated at 100,000,000 tons.

Jan 1, 1931

By H. C. Gunning

DURING the past year the Cadillac-Malanie area in northwestern Quebec has been catapulted to the front as one of Canada's most active gold mining districts. Late in 1934 the area was lolling along in the doldrums, with one producing mine and a handful of active prospects. 1935 passed with only slightly increased activity, but saw the start of production at Canadian Malartic mine. Lightning struck in April, 1936, when a new and phenomenally rich ore-body was found in O'Brien Gold mine, and by midsummer the camp was ablaze with activity. An important new discovery on the Pan-Canadian property, and pleasing underground developments at Sladen Malarric, East Malartic, and Lapa Cadillac, in addition to other new developments, lent fodder to the flame, and at present several dozen properties are being actively developed. For the past three seasons, the Geological Survey of Canada has been engaged in a fairly detailed study of the geology and mineral deposits across Cadillac, Malarric, and Fourniere townships. Ir is the purpose of this paper to present a brief preliminary statement of the structural and economic geology and to discuss some of the more important problems that have been found to exist. The reader is requested to remember that the paper is a preliminary one and that therefore the conclusions presented are open to revision. It is impossible to make full acknowledgment for help received, for the writers are indebted to practically every operator and prospector in the area for generous co-operation in the work, and to several private, provincial, and federal geologists for data and frank discussion of problems encountered. Over a score of student assistants from McGill, Queen's, and Toronto have given excellent service. Published reports by Wilson, Cooke, James, Mawdsley, L. V. Bell, and J. J. O'Neill greatly facilitated the work. For adequate control surveys and a topographic base-map, the writers are greatly indebted to H. N. Spence.

Jan 1, 1937

By B. Panton, J. Carvalho, E. T. Brown

High-capacity, post-tensioned anchors have found wide-spread use in initial dam design and construction, and in the strengthening and rehabilitation of concrete dams to meet modern design and safety standards. Despite the advances that have been made in rock mechanics and rock engineering during the almost 80 years in which post-tensioned anchors have been used in dam engineering, some aspects of the rock engineering design of high-capacity rock anchors for dams have changed relatively little over the last 30 or 40 years. This applies, in particular, to the calculations usually carried out to establish the grouted embedment lengths required for deep, post-tensioned anchors. These calculations which involve a number of aleatory and epistemic uncertainties, usually make simplified assumptions about the distribution and values of rock-grout interface shear strengths, the shape of the volume of rock likely to be involved in uplift failure under the influence of a system of post-tensioned anchors, and the mechanism of that failure. The resulting designs are generally conservative. These aspects of the rock engineering design of large, post-tensioned rock anchors for dams could be improved by making greater use of modern, comprehensive, numerical analyses in conjunction with 3D models of the rock mass structure, realistic rock and rock mass properties, and the results of prototype anchor tests in the rock mass concerned.

Jan 1, 2015

By H. C. Gunnings, C. O. Swanson

"The Sullivan mine; at Kimberley in southeastern British Columbia; is the largest silver-lead-zinc mine in the Empire and one of the largest in the world.The original discovery was made in 1892 by four prospectors. Until 1899, when the branch line of the Canadian Pacific railway from Cranbrook to Kimberley was completed, little work was done on the property. In 1900, systematic development was started, and during the next 3 years 5,000 tons of ore was shipped to the smelters at Nelson and Trail. By 1903, some 300,000 tons of ore was developed, and a smelter was started at Marysville, about 5 miles from the mine. However, this smelter closed down in 1907 because of metallurgical difficulties after treating 75,000 tons, and the property came under the control of the American Smelting and Refining Company. An option on the property was taken in 1909 by the Consolidated Mining and Smelting Company of Canada, who exercised their option in the following year. During the next 5 years by selective mining and sorting 188,000 tons of high-grade ore was produced and shipped to Trail. This tonnage came from the upper levels, about 4,600 to 4,800 feet in elevation. At the same time, deep drilling down to the 3,900-foot level showed the presence of an immense body of complex ore. In 1915, the main adit-the 3,900-foot level-was started, and by 1919 this had been driven a distance of 2 miles to develop the ore above this level. Meanwhile, progress was being made in overcoming the milling problems. An interesting account of this work was written by the staff ( 4). In 1923, the first unit of the present concentrator was erected, with a capacity of 2,500 tons a day, and thereafter the rate of production increased rapidly. In 1934 it was around 8,000 tons a day, and to date a total of about 30,000,000 tons of ore has been sent to the mill. In recent years, a considerable part of the production has come from levels between the 3,900-and 3,350-foot, which were opened by an internal incline shaft started in, 1930. In 1942, tin was added to the products separated at the concentrator."

Jan 1, 1954

By M. B. McClenaghan

"The Matheson area of northeastern Ontario is of great interest for mineral exploration because of its geological similarities with the adjacent Timmins, Kirkland Lake and Larder Lake gold camps. Exploration in the area, however, is hampered by the presence of an extensive and thick cover of glacial sediments. For this reason, till geochemistry has become an important exploration method. The Ontario Geological Survey&apos;s Black River-Matheson (BRiM) reconnaissance till sampling project, carried out between 1984 and 1988, was designed to aid exploration in the Matheson area by documenting the Quaternary stratigraphy and providing a database of till geochemistry. Till samples were collected by backhoe trenching of surface pits in areas of thin drift (< 5 m) and by sonic overburden drilling in areas of thicker drift. This paper summarizes the results from the shallow till sampling component of the BRiM project.Two hundred and eighty-two surface samples were collected from Matheson Till, the youngest till sheet in the area, which was deposited during the Late Wisconsinan. For each sample, the non-magnetic heavy mineral (> 3.3 S.G.) and fine (- 250 mesh) till fractions were analyzed geochemically. In addition, visible gold grains were recovered by panning the heavy mineral fraction. Five areas that display multi-element anomalies in both till fractions warrant further investigation: (1) western Egan Township, overlying the Bradley Lake Syenite; (2) around and south of the Munro and Croesus mines, in Munro and Guibord townships; (3) central Garrison Township overlying the Garrison Stock; (4) south of Ore Car Lake in northern Thackeray Township; and (5) southeastern Harker Township. In these areas, Matheson Till has a local provenance and the bedrock sources for these anomalies are nearby in the up-ice (north northwest) direction. Due to the fine-grained nature of gold in bedrock deposits in the BRiM area, the small size of most gold grains recovered from till samples (< 50 um) and the variable distribution of gold in the heavy mineral concentrate and fine fractions, the fine fraction in addition to the more commonly used heavy mineral concentrate should be used for gold exploration.Surface till samples have been affected by weathering to a depth of = 3 m. Weathered till is characterized by a very low carbonate content in the matrix fraction, the absence of sulfide grains in the heavy mineral concentrate and higher concentrations of copper, nickel and zinc in the fine fraction than in the heavy mineral concentrate. As a result of the weathered/ oxidized nature of the surface till samples, the fine fraction is a better sampling medium for base metal exploration."

Jan 1, 1992

By D. J. Cheung, V. N. Kazakidis

ABSTRACT Seismicity and rockburst problems in hard-rock mines negatively impact safety and profitability. The authors propose a design risk methodology as a relative risk assessment for underground excavations vulnerable to rockburst damage. It considers rock mass conditions relating to mininginduced stress, geological structure, rock mass properties, and mining influence. Application of the methodology to rockburst cases involving seismically active fault zones at the Craig mine in Sudbury, Ontario, Canada, demonstrates that design changes can reduce exposure and economic risks. Mines with high geotechnical risk can use the design risk methodology to evaluate design alternatives as a risk management strategy.

Jan 1, 2014

By Jim Richard

Introduction Electric Vehicle Controllers (EVC) and the Northern Centre for Advanced Technology (NORCAT) have created two generations of Lunar Highland Simulant ?Simulant preparation techniques and equipment resulted from drilling activities in support of Regolith and Environment Science and Oxygen and Lunar Volatiles Extraction (RESOLVE ) ?The purpose of defining the compaction process was to minimize the effect of density on drill testing This allowed other variables including drill bit geometry, auger, RPM, and thrust to be evaluated independent of density ?Density of Highland Regolith falls within a range of 1.40 to 2.29 g/cm3 (p484 Lunar Source Book)

May 1, 2013

By Robert B. Parsons

"As the 1981 annual reports of Canadian mining companies one by one see the light of day, it becomes clear that softer metal prices and rising costs are the main problems which beset the industry today. These problems are certainly not lightened by that familiar monster lurking in the shadows-taxation! Recent taxation trends in Canada, and the existing tax regimes for the mining industry, continue to be a major bugaboo.This examination by ""Tax Notes"" of the impact of current taxation trends on the mining industry is based on a speech delivered recently by Robert D. Brown, senior tax partner of Price Waterhouse, Canada, to the annual meeting of the American Institute of Mining, Metallurgical and Petroleum Engineers in Dallas.IntroductionThe purpose of this paper is to tell a story-and it is a story with a moral. The first thing to recognize is that, with depressed metal prices and weakening western economies, high taxes, in and of themselves, are not really the cause of the Canadian mining industry&apos;s present doldrums. However, the character and level of mining taxes in Canada has had a profound influence on the development of the industry over the past decade, and the expectations of what the future holds for mining men in Canada will equally play an important role in the future development of the Canadian industry. Our tax system has, in the past, served as a negative and destabilizing influence in the mining industry: it has contributed to a major short-fall in investment commitments and hence in the contribution which the mining industry can make to the Canadian economy, and the adverse effect on the industry of previous high marginal tax rates was made far worse by the confusing, contradictory and perverse nature of the tax system itself."

Jan 1, 1982

By Eric Johnson

"IntroductionHistoricalCyanidation is a leaching process, in world-wide use, to extract gold (and silver) from ores and concentrates. The process has many inherent advantages on account of its adaptability:a. to any scale of operation;b. to a wide range of ore types and mineral associations;c. to a wide range of physical characteristics of the gold particle size, alloy (electrum) or mineral (telluride);d. to relatively simple plant controls and operating procedures;e. to simple marketing procedures and quick cash return.The basic idea for cyanidation was first described and patented by a German chemist, L. Elsner, in 1846. Some forty years later, J.S. McArthur, a metallurgical chemist and R.W. and W. Forrest, medical doctors, all of Glasgow, Scotland, came to realize the import of the discovery and accordingly, registered patents in Great Britain in 1887 and in the United States in 1889. The keystone of the McArthur-Forrest patent registration was the use of weak (0.05o/o) instead of strong (1.0%) solution.The years 1890-1910 saw much progress in equipment design and the advance from batch to continuous processing to increase efficiency and reduce operating costs.In later years, technological progress followed advances in materials of construction and control systems. Current innovations include large-scale equipment, high-capacity thickeners, belt type filters and Steller, candle-type filters for plants using zinc dust precipitation. As well, environmental protection is increasingly a major concern.The technology of gold adsorption from cyanide solution onto activated carbon has made rapid strides in recent years. This has followed the initial efforts of Potter, Salisbury, Zadra and their colleagues of the U.S. Bureau of Mines Research Station in Salt Lake City, Utah, and the field work of Homestake Mining Company personnel, in Lead, South Dakota."

Jan 1, 1989

By S. Goodman

Successful exploration for and exploitation of a mineral deposit requires an accurate understanding of the deposit architecture in 3D, and of the development of the mineralizing system through time, which requires a thorough comprehension of the structural framework of the deposit. The integration of geological, geophysical and geochemical datasets to arrive at a 4D structural framework is well-established and has been successfully applied by SRK Consulting in projects from deposit to regional scale. In some cases, we can go beyond this, applying the SEEBASETM technique, which utilizes a ?bottom-up? approach to basin analysis. SRK?s approach primarily relies on the interpretation of magnetic and gravity data, calibrated with many other datasets including mapped geology, topography, event histories, wells/drillholes and seismic data. The SEEBASETM model is a culmination of this data integration and is produced through an iterative process of structural interpretation and geophysical modeling, where an interpretation of basement composition and 4D structure is used to constrain depth-to-basement geophysical modeling, and the modeled depths are then used in conjunction with the structural interpretation to constrain contouring of the basement topography. The result is a rigorously calibrated, 3D view of the basement surface, which can be used to understand the basement and basin architecture, and thus serves as a predictive exploration model. This technique, which was developed for use in the petroleum industry, is now finding success as a predictive tool in mineral exploration.

May 1, 2003

By A. G. Ballachey

Introduction This paper will describe the mining plant and underground operations at Quemont. Details of geology and milling are beyond its scope. Papers on these subjects will be prepared and presented separately. A detailed account of the exploration and development, 1944 to 1947, has been given by W. L. Brown (1). Location The mining concessions of Quemont Mining Corporation, Limited, are in Rouyn township, Rouyn-Noranda county, northwestern Quebec. These concessions total about 640 acres in area. They lie within the limits of the City of Noranda, contiguous to, and directly north of, the Horne mine of Noranda Mines, Limited. A large area in the southern part of the property is covered by the north arm of Osisko lake. Production The present operating rate is about 2,100 tons per day. Three flotation concentrates are produced: copper, containing a large proportion of the gold and silver in the ore; zinc; and pyrite, which carries an appreciable additional proportion of gold. The copper and zinc concentrates are shipped to smelters as produced. The pyrite concentrate is cyanided to recover additional gold, after which it is filtered, dried, and shipped for the manufacture of sulphuric acid. The principal revenue metals are copper, gold, and zinc. Silver and pyrite are important by-products.

Jan 1, 1952

By Erik Richer La Fleche

LEGAL RISKS LEGAL RISKS ARE COUNTRY RATHER THAN PROJECT RISKS OTHER COUNTRY RISKS ARE POLITICAL AND MACRO-ECONOMIC RISKS COUNTRY RISKS ARE EXAMINED AFTER PROJECT RISKS COUNTRY RISKS COUNTRY RISKS INCLUDE: WAR AND ARMED CONFLICT TERRORISM AND SABOTAGE CURRENCY INCONVERTIBILTY AND TRANSFER NATIONALIZATION AND CREEPING EXPROPRIATION GOVERNMENTAL BREACH AND REPUDIATION OF CONTRACT CHANGE OF GOVERNMENT CORRUPTION COUNTRY RISKS FIRST NATIONS AND LANDOWNER CLAIMS LABOUR UNREST SINGLE CAUSE ACTIVISTS REGULATORY AND BUREAUCRATIC DELAYS CONFLICT BETWEEN GOVERNMENT LEVELS ETHIC AND RELIGIOUS TENSIONS INTERNATIONAL SANCTIONS TAXATION CHANGES CHANGES IN LAW

May 1, 2013

ABSTRACT The inevitable uncertainty in modelling spatial variables decreases as more data become available. This reduction depends on the properties of the variable being modelled. Spatially continuous variables show less uncertainty for a given spacing than erratic variables. A geostatistical simulation based approach is developed to quantify the relationship between uncertainty and data spacing. Reference realizations are sampled to condition additional realizations and quantify uncertainty. The procedure is automated, making it straightforward to consider sensitivity and different geological domains. A case study of the relationship between uncertainty and data spacing for net oil sands thickness data from northern Alberta is presented. _ KEYWORDS Simulation, Sampling,

Jan 1, 2013

By A. Boehm

"For recycling LD slag into the steel making process, the phosphorous containing calcium silcate phases have to be removed from iron oxide phases. One possible technical solution could be magnetic separation in a wide range of susceptibilities from ferromagnetic to paramagnetic. To check the feasibility of magnetic separation the distribution of the magnetic susceptibility in size classes as well as the liberation of the phosphorous containing phase were evaluated by a new method combining two dimensional physical property analysis with QEMSCAN analysis. The particle size classes of energy controlled comminution products were subdivided into fractions of defined magnetic susceptibility using a hand magnet of well known field properties (pick up method). On the one hand the susceptibility classes were wet assayed on the other hand analyzed by QEMSCAN followed by data evaluation using iDiscover 5.3.1(FEI), which was adapted to the data structure of two physical properties (size and magnetic mass susceptibility). The results allow the comparison of mass based (3D) cumulative distribution of grades from the wet assays with the area based (2D) distribution from QEMSCAN analysis, in order to control a systematic (size dependent) stereological error for this special type of material. As the physical separation property forms a crucial parameter the results from the liberation analysis by QEMSCAN can be interpreted more profound with respect to an expectable separation result. Once the various mineral compositions of the particles are assigned to the physical properties the Henry Reinhardt chart serves to predict the best possible separation result and thus the feasibility of a separation technique.INTRODUCTIONThe two Austrian steel plants operated by voestalpine AG produce about 650,000 t (voestalpine 2014) of LD slag in the course of steel production from pig iron according to the basic oxygen process blowing oxygen in the converter by an oxygen lance. The process is also known as the Linz Donawitz (LD) steelmaking process. By the addition of lime (CaO), carbon, phosphorus, silica, manganese and sulfur, which are present in the molten pig iron, shall be oxidized and bound in the slag either as oxide or silicate phases, or leave the slag in the gaseous phase (CO). The average chemical composition of the investigated LD slag is given in table 1."

Jan 1, 2016

By N. Melnyk

"FOREWORDThis paper provides a unique description of a method devised for mining a very thick steeply dipping seam of soft gassy coal which was prone to spontaneous combustion. The editors con¬sider that the information in this paper should be important to those who may have to consider mining such seams again at some time in the future and therefore believe that the paper warrants reprinting in the present volume. The author was ask¬ed to review the paper and to add any additional relevant in¬formation. He provided the accompanying footnote, only a month before his death on April 22, 1982.IntroductionIn the past, the Cadomin Coal Company has opened four mines, all in the same coal seam or its folds. Three of these were opened from river level by horizontal entries or rock tunnels. and the fourth, the present working mine, by vertical shafts. This paper deals largely with some operating phases of this fourth mine, with which the writer has been associated.The seam worked here is a thick, steep, bituminous seam, and the writer feels there is a paucity of published data on the mining of such seams. Possible reasons for this are that such seams do not lend themselves to intensive development or mining, there is little chance to mechanize because of the extreme pitch, and operations are fraught with many problems. In addition the present operations in this particular' seam are being carried on at a level below the former workings, introducing new problems, not encountered on the upper level.Coal will, without question, long continue to be an impor¬tant factor in the national economy, and some of the best coal is to be found in thick, steep seams. But with the exhaustion of the easily-mined coal near the outcrops, future coal will have to come more and more from lower levels. At Cadomin there is still considerable coal on the second level, below the old river-workings, and there is a possibility that, in the future, still lower levels will be worked. It is the purpose of this paper to indicate some phases of such lower-level operations and to invite discussion."

Jan 1, 1985

By E. S. Moore

In order that a logical conclusion may be reached regarding the possible occurrence of commercial iron deposits in Canada it is necessary to consider some important producers found elsewhere on this continent. A study of such deposits reveals the fact tl:~at a number of distinct types are producing large tonnages of ore. These types may be classified according to origin and occurrence as follows: (1) Bedded sedimentary deposits. (2) Contact metamorphic deposits. (3) Residual ores. (4) Lenses in metamorphic rocks and m some cases of uncertain origin. In addition to the types listed there are other deposits which have contained or do contain considerable ore and they either have not been worked on a large scale or they have been nearly exhausted. These include the following types: (1) Magmatic segregations. These are mostly titaniferous magnetites. (2) Dikes of magnetite of igneous origin. (3) Bog and lake ores in glacial drift. (4) Black sand placers.

Jan 1, 1925

By M. Tanaka, H. Narita, K. Morisaku

"The selective separation of palladium (Pd), platinum (Pt), and rhodium (Rh) from a hydrochloric acid solution by solvent extraction was investigated using amide-type extractants, i.e., N,N,N’,N’-tetra-n-octyl-thiodiglycolamide (TDGA) and N-n-hexyl-bis(N-methyl-N-n-octyl-ethylamide) amine (BisAA). The separation experiments employed two separation schemes: (1) extraction of Pd with TDGA and that of Rh and Pt with BisAA; and (2) extraction of Rh, Pd, and Pt with BisAA. Separation scheme 1 achieved the highly selective separation of each metal. For separation scheme 2, Rh can be recovered prior to Pd and Pt, despite having a lower selectivity for Pd/Pt than separation scheme 1. INTRODUCTIONThe recent increase in the use of platinum group metals (PGMs) in industry (especially auto catalysts containing palladium (Pd), platinum (Pt), and rhodium (Rh)) has lead to their increasing waste; therefore, improvements in the recovery techniques for PGM have received significant attention. In metal refineries, PGMs are mainly separated and purified by solvent extraction (Cox, 2004). The extraction process used in INCO’s Acton precious metal refinery is one of the most famous commercial processes and is utilized worldwide. In this process, silver is first removed as a residue (AgCl), and then gold, Pd and Pt are extracted from hydrochloric acid (HCl) solutions using dibutylcarbitol (DBC), dialkylsulfide (DAS), and tri-n-butylphosphate (TBP), respectively. Finally, Rh remains in the raffinate (Barns & Edwards, 1982).The development of a successful solvent extraction process depends on the choice of the appropriate extractants. We have studied the extraction of PGM using N,N-disubstituted amide compounds (Narita, Tanaka, Morisaku, & Abe, 2004; Narita, Tanaka, Morisaku, & Tamura, 2006; Narita, Tanaka, & Morisaku, 2008a, 2008b). They are relatively stable against acids, and their metal extractability can be improved by changing the side chain length and/or introducing additional donor atoms like sulfur and nitrogen. We have recently found that thiodiglycolamide and an amide-containing tertiary amine have good extractabilities for Pd and Rh, respectively."

Jan 1, 2012