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By H. Salomon-de-Friedberg

The amount of pyrite in copper concentrates fed to the CESL Process can vary appreciably. The fraction of pyrite that oxidizes influences both capital and operating costs and is therefore an important variable. The present paper explores operating conditions that influence the extent of pyrite oxidation and the probable overall reaction chemistry under CESL conditions.

Jan 1, 2014

By H. P. Pew

THE Pembina oil field is in west-central Alberta, about 88 miles west-southwest of Edmonton. The field, about 35 miles long by T HE Pembina oil field is in west-central Alberta, about 88 miles west-southwest of Edmonton. The field, about 35 miles long by 85 miles wide, is the largest in Canada in areal extent, in the amount of oil in place and in the current producing rate. The discovery well was completed in the middle of 1953. The field has grown until its present area is 369,820 acres. There are 74 working interest owners in the field. Early in the producing history of the Pembina field a committee of operators was formed on a permanent basis. The Pembina Operators' Committee has established a permanent staff, which compiles and distributes pertinent field information on a regular basis to all participants. The Alberta Oil and Gas Conservation Board has dealt with field-wide problems primarily through this committee. Expansion of the field was rapid as shown by the number of wells completed -from 135

Jan 1, 1961

By J. -F. Blais, M. -O. Simonnot, J. Mocellin, G. Mercier, J. -L. Morel

Large quantities of ferromanganese sludge are generated as waste material by blast furnace during the manufacturing of ferromanganese. These slags are very rich in manganese, zinc and lead (5 to 40 %). These residues have been deposited in a pond in periphery of the steel industry. Considering the market value of the metals, these brownfield sites can now be considered as secondary resources. We have developed a hydrometallurgical process for selectively leaching Zn, Mn and Pb in order to produce compounds of Mn and Zn pure enough to be economically recoverable and a residue rich in Pb. Batch laboratory experiments were carried out to determine appropriate leaching conditions to maximize zinc extraction (100 %) and manganese extraction (90.0 %) with sulfuric acid and to generate a residue containing 15 to 30% of lead. This Pb residue is recyclable by another process.

Jan 1, 2015

By Carlos Alberto Spier

The Águas Claras and Pico mines are two world-class, iron-ore mines hosted within Lower- Proterozoic banded iron-formations (locally known as itabirites) of the Minas Supergroup located in the Quadrilátero Ferrífero District, Minas Gerais, Brazil. The Águas Claras orebody consists of a 2,500 m long roughly tabular-shaped lens hosted within the dolomitic itabirite of the Cauê Formation. Dolomitic itabirite is the protore of the soft high-grade iron ore, which is the main ore type of the Águas Claras orebody, and represents more than 85% of the 284 Mt mined since 1973. Hematite is the main constituent of the iron ores. It occurs as martite, granular hematite and, locally, as specularite. Magnetite appears subordinately as relicts within martite and hematite crystals. Gangue minerals are very rare. These consist of dolomite, chlorite, talc and apatite and are especially common close to the contact with the protore. This virtual absence of gangue minerals is reflected in the chemistry of ores which are characterized by very high Fe contents (an average of 68.2% Fe). The Pico orebody is a continuous ~3,000 m long body of lenticular shape hosted within quartz itabirite, which is the protore of the soft high- and low-grade ores at the Pico mine. The soft high-grade ores, together with the low-grade ores, called iron-rich itabirite, are the main types of ores at the Pico mine, respectively representing approximately 51 % and 29 % of the reserves within the pit. The iron oxide mineralogy is the same as that of the Águas Claras mine, but in different proportions. Gangue minerals are very rare in the high-grade ores, but are slightly more common in the iron-rich itabirite. Quartz is the dominant gangue mineral, and is found with minor quantities of chlorite. The chemistry of the high-grade ores is characterized by high Fe contents (an average of 67.0 %) and low P, Al2O3, and SiO2 which are concentrated in the fines. Iron rich itabirites average 58.6% Fe and 13.5% SiO2.

May 1, 2003

By A. G. Lylie

Introduction At the Britannia Mining and Smelting Company's mill, the equivalent of 2,500 to 2,800 pounds of copper sulphate crystals per day is made from copper which is precipitated from the mine-water. This copper sulphate is used in the mill for the recovery of sphalerite by2 flotation. From 1932 until 1936 it was produced by exposing the precipitate to air for thirty days and then dissolving the oxidized copper with dilute sulphuric acid. In 1936, the flotation of sphalerite was discontinued and, when it was resumed in 1947, steps were taken to try to improve the former method. The present paper outlines the way in which this was done, and describes the plant and procedure by which copper sulphate is now being made, and by means of which an appreciable saving is being effected. Aboratory Tests The previous work had established that the precipitate, which consists mainly of metallic copper, must be oxidized before the copper would dissolve in dilute sulphuric acid. Various methods for oxidizing it were tried but in the early laboratory work the only suitable one found was to heat the precipitate to 600°C. and hold it at this temperature for two hours. When this was done, approximately 90 per cent of the copper became soluble in .acid. This percentage was considered satisfactory for practical purposes, but the cost of roasting was prohibitive because only a small amount of roasted precipitate was required each day.

Jan 1, 1951

By Jun Deng

The aim of this paper is to study the scientificity and reliability of three coal gas indices used to predict coal fire disasters, namely Graham?s ratio, CO/CO2 ratio, Litton ratio and their different characteristics and service conditions. Data from a programmed temperature experiment were applied to check their veracity and accuracy. Each index performed well in detecting the level of a fire. We conclude that it is better to redefine the definition through experimentation before applying a given index. Integrated analysis of the results can provide reliable reference data for predicting spontaneous combustion of coal.

Aug 1, 2013

By R. E. Martin

"The Westerose Leduc (D-3) pool, a Devonian reef reservoir situated in Central Alberta, Canada, has now been producing for over seven years. As a unit operation, the pool pro-vides an interesting example of the full exploitation of gravity segregation tendencies. The reef has a 238-foot oil column, underlain •by bottom water and over-lain by a substantial gas cap. The original hydrocarbons in place were 147.96 million STB oil and 94.4 MMMCF of Taw gas cap gas. Nine-teen producing wells on 80-acre spacing have been completed, most of which are highly productive. Gas injection operations return solution gas to the gas cap. A study of the rock and fluid properties of the pool show it to be conducive to production by gravity segregation at high rates. Monthly average producing rates have varied between 800 B/D and 8,000 B/D and have recently totalled 3,000 BID to 5,000 B /D. Recovery and performance predictions under partial pres-sure maintenance at 10,000 BID indicate an ultimate recovery of 66 per cent of the original oil in place. In the absence of pressure maintenance, recovery would be only slightly less."

Jan 1, 1960

By F. R. Ploeger, J. H. Crocket

"IntroductionRocks in the Kirkland Lake district form part of the Timiskaming Group, a south-facing homoclinal sequence of wackes, conglomerate, trachytic flows and pyroclastic rocks and syenitic intrusive rocks. Hewitt (1963) indicates that the thickest section, about 5 km, of the Timiskaming Group rocks is attained in Lebel Township. Several writers (Thomson, 1948; Hewitt, 1963; Hyde, 1978; Jensen, 1978; and Downes, 1979) have observed that the Timiskaming Group unconformably overlies the Keewatin volcanics, particularly along the northern contact. Recent work by Downes (1979) in McGarry and McVittie townships to the east of Kirkland Lake has shown that much of what had formerly been classified as Timiskaming actually belongs to an older group of rocks, the Larder Lake Group (Jensen 1978).General GeologyA series of fluviatile, braided-stream sedimentary rocks (Hyde, 1978) form the oldest of the three major rock suites at Kirkland Lake. Conglomerates constitute a large proportion of these sedimentary rocks and typically contain a large percentage of a variety of locally derived alkalic rock clasts as well as the distinctive red jasper iron-formation pebbles (Fig. 1a). The associated wacke units can be massive to finely bedded and are interbedded with the conglomerate. They also contain a large alkalic tuffaceous component.Interbedded with these sedimentary rocks are alkalic extrusive rocks, including tuffs, agglomerates, breccias and flows, which represent episodes of fissure and explosive crater eruption (Cooke and Moorhouse, 1969). The tuffs, although dominantly alkalic in composition, are commonly reworked and contain sedimentary features such as graded bedding, scouring and crossbedding (Fig. 1 b). The trachytic flows are massive to porphyritic and outcrop mainly east of Kirkland Lake in the adjoining townships. Altered leucitic porphyritic flows, locally referred to as red and green spotted trachytes, commonly occur."

Jan 1, 1982

By Leroy C. Stewart

Owing mainly to the use of ethylene dibromide in the production of tetraethyl lead for gasoline treatment, there has been a tremendous increase during the past decade in the demand for bromine. In the United States, production, derived mainly as a by-product from the treatment of brines from salt wells, rose steadily from about two million pounds in 1924 to nine million pounds in 1931. In 1936, production amounted to between 20 and 21 million pounds. Much of the increase during the past four or five years has been due to the operation of the Ethyl-Dow Chemical Company's plant, which extracts bromine directly from sea water. The process employed by the Ethyl-Dow Company is somewhat similar to that in use on salt-well brines at their plant at Midland, Michigan, but whereas these brines contain around 1,300 parts per million bromine, sea water contains only 65 to 70 p.p.m.-about as much as the waste effluent in the brine process. By intensive research, however, a process was developed whereby a very considerable percentage of the bromine content of sea water could be recovered, and at a satisfactory operating cost. In its essentials, the process consists in liberating the bromine from the sea water by treat-ment with chlorine, blowing the bromine out of the water by a current of air, and finally absorbing it in a solution of soda-ash.

Jan 1, 1938

By Yong-neng Feng, Xiao-ping Chen, Wei Guo

"While the uniaxial compressive strength of rock has been extensively investigated, the relation between the saturation and natural compressive strength is relatively unexplored. This paper studies on 1865 statistical data of Chongqing Rail Transit Line 1 and Line 6, which located in the Middle Jurassic of Shaximiao formation. The research focuses on the relation between the saturation and natural compressive strength. The statistical data are categorized and quantified in order to ascertain the softening properties of sandstone and sandy mudstone. The findings suggest that the saturation compressive strength is significant effected by its natural compressive strength, and an empirical formula is introduced to explain the relation. These findings have implications for researchers and engineer who concerned with Chongqing rail transit construction.INTRODUCTIONIn the engineering construction and surrounding rock classification, the uniaxial compressive strength index (Ministry of Water Conservancy, 1995; Ministry of Railways, 1999) is one of the essential parameters of rock mass. Usually, there are two types of the uniaxial compressive strength index, natural and saturation compressive strength, and the ratio of them is the softening coefficient. Most of the previous studies on rock strength had focused on the influence factors (Liu et al., 2008; Liu et al., 1998; Liu et al., 2013; Wang, 2013; Zhang et al., 2008; Zhang et al., 2010; Zeng & Lin, 2003) with experiment and in-situ tests. But few publications that reports a long and formal research project on the relationship between natural and saturation compressive strength. In order to figure out this issue, this study investigated the distribution of Solidity Classification of Rock Mass and softening coefficient based on the statistical data of Chongqing Rail Transit Line 1 and Line 6. Based on the analysis, an empirical formula was proposed to explain the relationship."

Jan 1, 2015

Mining Equipment Challenges Equipment Availability Unplanned downtime Maintenance Costs Secondary damage and catastrophic failures (T282 $750k) Emergency work is 4x the cost of planned work Inspections Troubleshooting time Incorrect repairs (parts, labor, lost production) Equipment Life Mis-operation of equipment

May 1, 2013

By S. W. Asihene, K. Osseo-Asare

The thermodynamic data necessary for the quantitative treatment of Metal-NH3- H2O systems at elevated temperatures are lacking in the literature. As a result discussions of the chemical basis of high temperature processes, such as leaching and hydrogen reduction, have tended to rely on low temperature thermodynamic data. In this paper a critical review is presented of the available high temperature data for metal ammine formation in aqueous systems, and methods are suggested to enable extrapolation of elevated temperature stability constants from low temperature thermodynamic data. Predictions of the Van't Hoff Lsobar, the simple cation Correspondence Principle (whereby metal ammine complexes are treated as simple cations) and Helgeson's Electrostatic-Nonelectrostatic Model are compared with the available high temperature stability constants for nickel ammines. Up to 80 °C all three estimation methods yield results which are in agreement with experimental data. However, serious deviations occur at higher temperatures; the various models overestimate the stability constants in the order Van't Hoff Isobar > electrostatic-nonelectrostatic model > simple cation Correspondence Principle. Using the experimental nickel data as a basis, a method is presented which permits reasonable estimates to be made of the stability constants of metal ammine complexes for temperatures above 80 °C.

Jan 1, 2004

By L. R. Fyffe, D. R. Lentz, S. H. Mcclenaghan

"Abstract - The Eel River area in the southwestern Miramichi terrane of New Brunswick contains a complete calc-alkaline suite of volcanic rocks that are interlayered with intervals of sedimentary and polylithic fragmental rocks, and are overlain by a thick sedimentary sequence. This package, collectively referred to as the Meductic Group, was deposited in a submerged volcanic arc setting interpreted to be part of the Popelogan arc. Rifting of this arc led to the development of the Tetagouche-Exploits back-arc basin, and formation of volcanogenic massive sulfide deposits in bimodal volcanic rocks of the Bathurst Mining Camp in the northeastern Miramichi Terrane. Unlike the Bathurst Mining Camp, volcanic rocks in the southeastern Miramichi Highlands form a continuous calc-alkaline suite characterized by increasing Zr/TiO2 with increasing SiO2, in part resulting from progressive coupled assimilation and fractional crystallization of nested magma systems. Slumping of semi-consolidated volcanic and sedimentary rocks in topographically unstable areas resulted in numerous slumps and debris flows that are preserved throughout the Eel River area. In the early 1990s, the discovery of a large sulfide clast in a road cut along the Benton road sparked interest in the volcanogenic massive sulfide potential of the Eel River area. Subsequent drilling intersected smaller fragments, one clast of which graded 16.7% Zn, 5.6% Pb, 90 ppm Ag, and 220 ppb Au. The intersection of thin lenses of stratiform sulfides in another drillhole indicates favorable conditions for the preservation of massive sulfides. Their subsequent incorporation into synvolcanic debris flows resulted in the transport and deposition of sulfide clasts from hydrothermal vents to more distal locations. Similar to the Buchans deposits of Newfoundland, tracing these debris flows back to their source would be beneficial from an exploration perspective. Approximately 15 km to the southwest of the Eel River area, gold-bearing base metal sulfide clasts (11.1% Zn, 6.13% Pb, 0.19% Cu, 108 ppm Ag, and 1100 ppb Au) occur within intermediate-composition volcanic rocks at Monument Brook in eastern Maine. Sommaire - Le secteur d’Eel River dans le sud-ouest de la terrane de Miramichi au Nouveau Brunswick contient une séquence complète de roches volcaniques calco-alcalines interstratifiées avec des roches sédimentaires et fragmentaires polylithologiques, sous une épaisse couverture sédimentaire. Cet assemblage constitue le Groupe de Meductic, et a été déposé dans un environnement d’arc insulaire interprété comme une partie de l’arc de Popelogan. Le rifting de cet arc à mené au développement du bassin d’arrière-arc de Tetagouche-Exploits, et à la formation de gisements de sulfures massifs volcanogènes dans les roches volcaniques bimodales du Camp Minier de Bathurst dans le nord-est de la terrane de Miramichi. Contrairement au Camp Minier de Bathurst, les roches volcaniques des hautes terres du sud-est de Miramichi constituent une suite calco-alcaline continue caractérisée par un accroissement du rapport Zr/TiO2 à des valeurs croissantes de SiO2, résultant en partie de l’assimilation progressive et de la cristallisation fractionnée de systèmes magmatiques superposés. L’effondrement de roches volcaniques et sédimentaires semi-consolidées dans des secteurs topographiquement instables est à l’origine des nombreux slumps et coulées de débris qui sont préservés dans le secteur d’Eel River. Au début des années 1990, la découverte d’un large claste de sulfures le long de la route Benton provoqué un intérêt pour le potentiel en gisements de sulfures massifs volcanogènes dans les secteur d’Eel River. Des forages ont par la suite recoupé des fragments plus petits, dont un claste qui a retourné des teneurs de 16.7% Zn, 5.6% Pb, 90 ppm Ag et 220 ppb Au. Le recoupement de minces lentilles de sulfures stratiformes dans un autre forage indique des conditions propices à la préservation des sulfures massifs."

Jan 1, 2006

By A. Ojaghi, A. R. Mohammadi

"The Marvast monazite deposit is located 35 kilometres south - southwest of Marvast in Yazd province of Iran. A representative sample weighing approximately 10 tons was prepared to study the amenability of the ore to physical beneficiation. The size fraction of +1000 µm was removed due to low monazite content and the –1000 µm size fraction was concentrated by the gravity-classification-magnetic methods. According to the results of sample characterization, the representative sample contains 220 ppm REO that is contained in monazite. It was concentrated to 41.5% REO by the above mentioned methods. The recovery of REO in the monazite concentrate was 41.5%.INTRODUCTIONRare earth elements are critical metals in many countries (Gupta, 2005; UK Geological Survey, 2011). Increasing application of these metals in hi-tech industries and price fluctuation caused by Chinese production policy has led other countries to focus on their local resources (UK Geological Survey, 2011). In this case, Iran is not an exception.REE mineralization in Iran is mainly located in the central zone. Regarding the exploration data, these deposits are divided into two categories. The first group is iron ore deposits in which the REE are carried by phosphate minerals. The other group is placer deposits where monazite is the major mineral of the deposit. The Marvast placer deposit is one of these types of deposit (Daliran, 1990; Mokhtari, 2008; Torab, &Lehmann, 2007; Alipour, 2014)."

Jan 1, 2016

By R. L. Every, A. G. Fonseca

"Sulphur deposition on the internal wall of a pipeline is caused by the temperature effect on the solubility of sulphur in the carrier fluid and is not due to particulate sulphur present. Deposition can be completely eliminated by proper insulation of the pipeline to prevent ""cold-spots"" and the resultant temperature gradient necessary for sulphur to precipitate from solution. Friction head losses for sulphur-condensate slurry systems are quite acceptable from a technical and economic standpoint and, in fact, are less than many present commercial slurry systems. Slurry transportation of sulphur in a hydrocarbon pipeline is a viable possibility and promises to have economic advantage over currently accepted transportation modes."

Jan 1, 1972

By Paul Guliov

Coal-bearing Tertiary sediments of the Ravenscrag Formation in southern Saskatchewan host numerous deposits of clinker resulting from in situ coal combustion. Clinker deposits form when sediments of relatively low temperature firing properties overlie coal seams which are undergoing prolonged spontaneous combustion. The resulting fired material is useful for decorative landscaping aggregate, rock gardens, driveways, mud control and others. Predicting the occurrence of clinker deposits requires a knowledge of the spatial distribution of coal seams and the nature ofoverlying sediments. Knowledge ofpaleotopography at the time of coal combustion can assist in locating more highly-fused material which can yield greater block sizes. Coal data bases can be used as a predictive tool by outlining areas where coal is or was at or near surface and therefore may have been susceptible to spontaneous combustion.

Jan 1, 2001

By M. Lghoul

Acid mine drainage (AMD) remains one of the major environmental problems for the mining industry particularly for many abandoned mine sites. The production of AMD as is commonly known can significantly affect the surrounding groundwater and surface water of the mine site. With the objective to investigate the impact of the AMD produced at the abandoned Kettara mine site (Morocco), groundwater sampling campaign was performed at this site. The sampled waters were analyzed to determine the hydrogeochemical composition, and then results were analyzed using different studied methods such as multivariate statistical analysis and geochemical modeling techniques. Investigation results show that the hydrochemistry of sampled waters is characterized by the relatively significant enrichment of Ca2+, Mg2+ and SO4 2-. The typical mine waters belong to the (Ca2+ +Mg2+)-SO4 2-type. Seasonal variations in major ion concentrations were partly attributed to dissolution/ precipitation processes. The saturation index (SI) calculation of the representative dissolved minerals in waters show that groundwater samples are undersaturated with respect to most potential sulphated secondary minerals.

Aug 1, 2013

By G. G. Richards, Y. Oyediran, V. Chow

The oxygen softening process for partial removal of arsenic and antimony from lead bullion has been in use at Teck Cominco's Trail smelter since 1986. In this process, industrial oxygen is injected into bullion to remove As and Sb with the formation of an oxide slag. In Trail, the levels of these elements are reduced to concentrations suitable for processing in the Betts electrorefining plant. Recent moves toward the treatment of higher arsenic-bearing feeds have necessitated an increase in the process capacity to meet the specifications for drossing plant bullion. Process intensification trials were conducted in-plant to develop an operating strategy for higher bullion processing rates. This was preceded by a study conducted with McGill University to develop a fundamental understanding of the therm ochemistry and kinetics of the process. The results have yielded more effective control of the operation, and identified opportunities for further improvements.

Jan 1, 2008

By H. C. Rickaby

The Bannockburn gold area covers the four townships of Bannockburn, Argyle, Hincks, and Montrose, lying in the western part of the Matachewan district of Ontario (see Figure 1). The geology of these four town-ships was studied by H. C. Cooke of the Geological Survey, in 1917-18, and is shown in his map of the district. In the fall of 1930, a rich gold-bearing quartz vein was discovered in the northwest part of Bannockburn by B. S. Ashley. A prospecting rush followed the discovery; many claims were staked in the Bannockburn area, and, during the summer of 1931, a considerable amount of prospecting was done.

Jan 1, 1932

By V. Gregoire

THE DEVELOPMENT by the Iron Ore Company of Canada of the Quebec-Labrador mining project, which eventually led to 'Iron Ore in 1954', involved, from the start, several distinct undertakings. Among them, the most important were: The construction of a 360-mile railway, linking Knob Lake with Seven Islands. The erection of a railway terminal, and harbour facilities, at Seven Islands itself. The building of an entire townsite at Schefferville (formerly Knob Lake) The construction of two hydroelectric plants; and, finally, The development of a sufficient number of orebodies to enable a production of 10 to 15 million tons of ore a year. Since these phases of the project have already been the subject of previous discussions, this paper will not elaborate further on them but will rather concern itself with a brief outline of the Company's current mining practices.

Jan 1, 1958