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By P. T. O'Kane

The PLATSOL® process, initially developed for the treatment of the NorthMet Cu/Ni/PGM concentrate, has seen over the recent years its applicability extended to include numerous other Cu/Ni concentrates of the same type, as well as other precious metals-containing feedstocks. However, several concentrates were found refractory to the typical PLATSOL® conditions, more particularly so the platinum. Attempts to extend those conditions, such as higher temperatures (250°C), longer retention time, increased oxidation conditions, higher chloride additions, were not successful. Detailed mineralogical investigation of those PLATSOL® leach residues indicated the main refractory mineral to be cooperite (PtS). Further metallurgical investigations showed that a thermal pre-treatment of the concentrate effectively unlocked the refractory platinum minerals for the subsequent leach. Temperatures between 400 and 750°C were tested, with the optimum being found around 650°C. The kinetics of the pre-treatment process were fast, and one hour at temperature proved sufficient. Under those conditions, PLATSOL® extractions were re-established around 95% for both platinum and palladium. From a mineralogical examination of the calcine, it was shown that the effect of the pre-treatment was to transform the cooperite and other refractory sulphides into metallic platinum and alloys, amenable to the PLATSOL®. The implications of the pre¬treatment step for the processing of PGM concentrates arc briefly discussed.

Jan 1, 2004

By M. W. Grabinsky, B. D. Thompson

ABSTRACT: Use of cemented paste backfill (CPB) offers economic and environmental advantages over other backfill methods. However, many operations have limited knowledge of how their CPB behaves in situ. Therefore, to avoid over-pressuring containment barricades, backfilling strategies necessarily tend to be conservative. In situ monitoring at Barrick Gold Corporation’s Williams Mine and Inmet Mining Corporation’s Cayeli Mine has been conducted and factors controlling barricade pressures are demonstrated, including rise rates, binder content, stope geometry, and tailings properties. The application of barricade pressure monitoring on a stope-by-stope basis can increase backfilling efficiency and, thus, reduce stope cycle times, while maintaining optimal safety.

Jan 1, 2011

By W. H. Gross

To pollute means to make impure or unclean. We tend to forget that man defecates, urinates, sweats, expectorates and exhales and in himself is a beastly little pollutor-but then so is Mother Nature! The object of this paper is to try to put what man and nature do into perspective. The facts indicate that although man may sweat a little, Ms. Nature is by for the greatest pollutor of all.

Jan 1, 1979

By T. Hofbauer, M. J. Dry, G. B. Harris, C. W. White

"Urban Mining is a term that is increasingly being used, and represents an appreciable source of secondary materials for the metals extraction industry, a source that does not incur mining costs, but does, at present, incur considerable disposal costs. Electric Arc Furnace Dust (EAFD) is probably the most common of these materials, with an estimated global production of 8 million tonnes annually, of which 1 million tonnes is generated in North America. The contained annual metal value in EAFD at current prices is of the order of $6 billion, yet, apart from the zinc, virtually none of this is recovered.Despite many attempts over the years, with pyrometallurgical, hydrometallurgical or hybrid processes, currently the only commercially viable method of treating these materials is smelting in a Waelz Kiln (or a Rotary Hearth Furnace), which essentially recovers only the zinc, in an impure oxide form, and generates a secondary slag waste, which is still toxic and requires disposal. This paper describes the development of a chloride-based treatment process to recover all components of the EAFD in a marketable form, which centres around the novel hydrochloric acid recovery and recycle operation. Laboratory, miniplant and pilot plant data are presented, leading to the definition of a viable process flowsheet enabling the recovery of pure iron and zinc products (the principal components of EAFD), together with secondary products such as copper, silver, lead, cadmium, magnesium and manganese. A rigorous mass-energy balance is used to examine the preliminary economics involved."

Jan 1, 2014

By R. White, C. Doyle, B. Martin, C. Díaz, J. Hrepic, G. Cuthbert

"A program initiated to improve the service life of the magnesite-chrome refractory in the top blown rotary converters at INCO’s Copper Cliff Nickel Refinery identified slag corrosion as a major wear mechanism. Target slag compositions were established to produce a non corrosive slag. A plant program to achieve this target slag by the addition of controlled amounts of do lime and MgO was instituted. Addition to rates of the slag modifiers was optimized based on the slag composition assays achieved and the requirement to address corrosion effects on the high alumina content ladle refractory. A60% gain in TBRC refractory performance was eventually achieved and has been maintained yielding a net annual savings of $700,000. A significant gain in available converter operating time has also been realized.IntroductionINCO’s Copper Cliff Nickel Refinery utilizes two top blown rotary converters (Fig. 1) to smelt a blend of semi-refined nickel concentrates, producing a granulated nickel matte suitable for the adjacent carbonyl based nickel refining operation. The converter, or TBRC, operation is a batch process composed of feed charging and melting, oxidation of the excess sulphur in the matte, and reduction of residual nickel oxide. The final matte, containing about 78% nickel, is tapped at 1600°C from the converter and is granulated in a sluice equipped with high pressure water jets."

Jan 1, 1997

By The Staff

WE were requested to make a digest of our original grinding report, Fine Grinding Investigations at Lake Shore Mines. This digest is much easier to read than the original report, but it lacks the experimental 'evidence' found in the first report which, in many cases, is much more interesting and educational than the conclusions derived from it. In the course of rewriting the paper, we noticed several new angles on the test data which had not occurred to us previously. From the data included in the report and other tests not published, calculations were made which indicated a line of new test work. These tests, among other things, more than suggest a technique for designing the length of mills, the position and number of classifiers, and the total loads a mill should carry.

Jan 1, 1941

By S. Steinlechner, G. Schneeberger, J. Antrekowitsch

The recycling of steel mill dusts is getting more and more important. The costs and requirements of land filling are rising and companies are interested in new recycling strategies. The rising of sustaina¬bility hand in hand with the high rate of valuable metals in these residues supports new research activities on the recycling sector. Especially zinc but also iron and lead are economical factors due to the treatment of steel mill dusts. This paper gives a small overview of fundamental studies concerning the chemical and physical composition of these dusts. Furthermore aggregates for the reduction of these dusts in the liquid phase are introduced and compared. The Flash-Reactor, the TBRC-Technology (Top Blown Rotary Converter) and submerged arc furnaces and there use for melting and treatment of these dusts are in the center of interest of this paper. The final conclusion gives an overview of possibilities for reduction of filter dusts in the liquid phase.

Jan 1, 2011

By J. B. Hadaway

The operation at Phu Kham commenced design and construction in early 2006 and was commissioned in May 2008. This paper will examine and discuss the project from the inception of flow sheet development and equipment selection, equipment design and manufacture, construction, commissioning and ramp up to full production. The paper will touch on the strategies employed to achieve a short schedule and the efficient use of capital, but with the main emphasis on the grinding circuit. Various challenges during the early years of operation will be discussed including the effect of ore characteristics, including competency, on the performance of the grinding circuit. Actions to overcome these challenges and to enhance performance will also be discussed. Finally, current and future plans to improve the performance of the grinding circuit and the overall plant will be summarised.

Jan 1, 2012

By Ben Habermann

"The object of the work described in this paper was to increase the understanding of the relation that capillary pressure of a rock, hydro-dynamics, and accumulation of oil in stratigraphie traps have to one an-other. The hydrodynamic oil-water tilt equation is derived by considering the two vector gradients involved: (1) buoyancy of oil in water and (2) hydraulic gradient.Recent theories show the necessity for oil to have a continuons phase in the reservoir rock in order to mi-grate; this fact applies to hydro-static as well as to hydrodynamic conditions. Hydrostatically, the displacement pressure of the rock deter-mines the amount of oil that can be trapped behind a permeability barrier. If the buoyancy of oil in water exceeds the displacement pressure, oil will migrate up-dip; an oil trap will be formed where displacement pressure is greater.In stratigraphie traps the pressure drop caused by moving water is positive when its direction is down-dip, helping accumulation; and it is negative when its direction is up-dip, forcing the oil into the tighter section of the reservoir. Theoretically, pro-vided we have data such as: (1) the displacement pressure of an up-dip permeability pinchout, (2) density difference between the oil and water in place, and (3) the direction and magnitude of the hydrodynamic gradient (if any), the possible extent of a stratigraphie oil accumulation down-dip can be predicted.To test the above theory sample cores from three wells in the Denver Basin were analyzed and the oil column that could be held under hydro-static conditions was calculated. After the hydrodynamic influence was considered, the results were compared with actual field data.The significant fact shown by this investigation is that the calculated oil column in one reservoir very closely approximates the actual extent of the oil column in a well. Also in accordance with the theory, the capillary pressure caused by the buoyancy of the oil column exceeded the measured displacement pressure on core samples from another productive field. For very tight shaly sand and questionable oil shows, the interpretation of data is very critical, as shown by experiments on core samples from a third field."

Jan 1, 1960

By B. Jin

Removal of fluoride and chloride by alkaline washing from direct lead smelting dust which originated from an Ausmelt furnace is reported. The results show that the fluoride removal efficiency increases with an increase of alkaline concentration, alkaline washing temperature and time. The L/S ratio has little effect on fluoride and chloride removal efficiency. A new flow sheet for removal of fluoride and chloride from the dust was successfully proposed according to the results. Fluoride and chloride removal efficiencies are more than 53.68% and 63.18% respectively using the flow sheet under the optimum parameters of temperature 338 K, L/S ratio 3:1 and alkaline washing time of 1.5 h. The contents of fluoride and chloride in the alkaline washing residues can meet the standard of zinc purity as hydrometallurgical materials for zinc processing.

Jan 1, 2014

By B. G. Cousins, L. Racine, R. S. MacPhail

"FLEX 31 is a chemically enhanced sodium isopropyl xanthate that has shown improved collection properties over SIPX for copper-bearing and copper-activated minerals. Characteristics such as improvement of recoveries with lower dosages and high pyrite and pyrrhotite rejection capabilities have all been exhibited by FLEX 31.The most improved results have been seen insphalerite flotation. Plant trial work carried out in the zinc circuit at the Louvicourt Concentratorin northern Quebec has produced data showing superior grade and recoveries from rougher concentrates that previously had not been attain-able with other reagents effectively. The improvement over SIPX adds up to an almost$1,000,000 annual improvement on the mine’s bottom line at present zinc prices.IntroductionSodium Isopropyl Xanthate (SIPX) is one of the most popular flotation chemicals on the market today. Somewhat more specific than amyl xanthates, SIPX is used in a variety of ores like copper/zinc, lead/zinc, arsenopyrite/pyrite, and many others (Melis et al., 1991). An investigation carried out by Tennants Research Technology Applications (TRTA), a division of Charles Tennant & Co. (Canada) Ltd., produced a chemically enhanced SIPX that has shown all the advantages of normal SIPX along with improved recoveries of copper and copper activated minerals. The new product has been named FLEX 31. Currently, FLEX 31 is manufactured at the Prospec Chemicals, another division of Charles Tennant & Co. (Canada) Ltd.A large amount of laboratory testing pro-grams have been carried out with FLEX 31 todate (MacPhail and Cousins, 1995; Cousins and MacPhail, 1996). One of the minerals that has a defnite affinity to improved fotation is sphalerite (ZnS). Once activated with copper sulphate, sphalerite has produced some of the most spectacular test work when FLEX 31 is compared directly to SIPX. Plant trials of FLEX31 at Aur Louvicourt Inc. carried out in 1995show that FLEX 31 is far superior to SIPX for activated sphalerite flotation."

Jan 1, 1997

By M. Goto, F. Kubota

"In this study, we show the successful separation of rare earth metals, which are indispensable elements for the high-tech industry, from a solution containing a metal mixture by using a liquid-liquid extraction and liquid membrane based on ionic liquids. We employed newly synthesized N, Ndioctyldiglycol amic acid (DODGAA) as an extractant for rare earth metals. The DODGAA exhibited a high affinity for rare earth metals such as Y, Nd, Eu and Dy and the extraction efficiency was greatly enhanced in ionic liquids (ILs). Furthermore, stripping of the metals was readily achieved by using an acid solution. INTRODUCTIONRare-earth metals have important applications in cutting-edge technologies employed in the electronics, information technology, and automobile industries. As Japan does not have many natural metal resources, maintaining a steady supply of imported rare-earth metals is important. The total amount of rareearth metals imported into Japan was 19,000 tons/year in 1996, and this amount increased to 40,000 tons/year over the following decade (Kramer 2010). Japan is now one of the world’s major importers of rare-earth metals (Kramer 2010). However, more than 90% of the rare-earth metals imported into Japan come from China, the world’s leading supplier of rare-earth metal resources, due to their low costs. This situation made us realize the importance of a second resource of rare-earth metals: “urban mines” or discarded electronic waste. Rare-earth metals are generally separated from their natural ores by solvent extraction. However, since urban mines have different metals and the concentrations of rare-earth metals are usually low, highly efficient separation and recovery methods are required for rare-earth metals.Recently, ionic liquids (ILs), which are molten salts at room temperature, have attracted considerable attention since they are novel, environmentally friendly solvents (Kubota & Goto, 2006; Han & Armstrong, 2007). The use of ILs in liquid-liquid extraction of rare-earth metals has been reported (Kubota et al., 2012). In some cases, the IL-based systems showed better extraction ability and selectivity than those showed by the conventional organic solvent extraction systems(Nakashima et al., 2003, 2005; Hirayama et al., 2008; Fang et al., 2012). Therefore, more efficient solvent extraction processes by using ILs can be developed. In this study, we investigated solvent extraction processes in which ILs are employed and discuss the possibility of using ILs in the separation and recovery of rare-earth metals from electronic waste."

Jan 1, 2012

By T. H. Etsell, P. Kerr, Qi Liu

"The objective of this investigation was to study the reaction mechanisms during the reduction of iron oxides in the presence of calcium chloride and carbon black as a simplified iron segregation process. The gas phase was analyzed by mass spectroscopy and the solid reaction products were analyzed by scanning electron microscopy. Mass spectroscopy, combined with thermogravimetric analysis and differential scanning calorimetry, revealed the presence of several gases at elevated temperatures over time, and the scanning electron microscope in combination with energy dispersive X-ray analysis illustrated the growth of a metallic iron phase on or near the carbon substrate. The results correlated well with similar copper and nickel segregation processes, but also introduced new insights that challenge the simplicity of the current models. The formation and transport of gaseous iron species to the carbon substrate in the presence of steam and hydrogen were evident during the reduction process that was studied; however, there is more happening at a mineralogical level, based on evidence of a liquid phase resulting in substantial growth due to an apparent fluxing effect created by the calcium chloride.These results help to better explain the chemical reactions and, in turn, the thermodynamics and kinetics of iron segregation processes related to the beneficiation of low grade complex iron ores. The results are also applicable to the production of metallic iron and concentrated titanium dioxide from ilmenite ores. The benefit of this process is that it allows ores in which the iron minerals are intimately associated with gangue minerals to be processed in circumstances where conventional mineral processing techniques are unsuitable or incapable of upgrading the material."

Jan 1, 2016

By N Robb

This paper gives an account of the laboratory testing, plant testing and final inclusion of the two-stage sulphuric acid leaching process in the Milliken mill. Operational results for September, 1962, are presented, showing a uranium extraction of 95.5 per cent, with a saving of some 16 lbs. of 100 per cent H~S04 and some 9 lbs. of lime per ton milled. Methods for effecting further improvements in the process are indicated. HISTORY P RIOR to the incorporation of two-stage leaching, the process for the treatment of uranium ores at Milliken consisted of a single-stage sulphuric acid leach, followed by a solution recovery step involving washing in thickeners and two-stage filtration. The thickener overflow solution was subsequently concentrated and purified by ion exchange, and the uranium was recovered, by two-stage precipitation, as ammonium diuranate. Figure I illustrates this flowsheet. For satisfactory extraction of uranium from the. Milliken ore, a high residual acidity, of the order of 40 grams per litre of free acid in the discharge solution, must be

Jan 1, 1963

By P. Amelunxen

It is well-known that the particle breakage mode that occurs in a semi-autogenous mill is significantly different from that which occurs in a ball mill, enough so to warrant very different lab scale breakage tests and scale-up models. This phenomenon, at the plant scale, leads to changing process constraints depending on the particular properties of the ore. For example, hard or coarse ores might bottleneck the SAG/AG mill throughput, while the ball mills might constrain throughput when milling soft or fine ores. Because the power draw of a ball mill is fairly constant compared to that of a SAG/AG mill, periods of SAG/AG mill bottlenecks lead to increased ball mill circuit specific energy consumption and a finer grinding circuit product size, which together constitute a loss of efficiency of the overall process. Because HPGR circuit throughput is less sensitive to changes in ore hardness, this situation is less common or severe in those circuits. Furthermore, the ball mills are somewhat decoupled from the upstream crushing circuits through the use of surge bins, which also helps to mitigate this effect. As a result, ore hardness variability constitutes a significant cost penalty that should be applied to SAG mill/ball mill/pebble crusher SABC circuits when evaluating the relative economics of different grinding circuit configurations. Nevertheless, the issue is by-and-large ignored, because most current HPGR trade-off studies are based on averaged ore hardness parameters. This paper provides an estimate of the magnitude of this penalty for a typical operation by using Monte Carlo simulation methods and plant data from Freeport-McMoRan?s autogenous, semi-autogenous, and HPGR-based comminution circuits. A case study from an in-house 96K t/d sulphide project is presented to illustrate the concept. It was found that by including variability effects, the trade-off NPV of the HPGR circuit over that of the SAG mill circuit increases to $84 million from negative $33 million, effectively reversing the original decision of selecting a SAG mill circuit for the fixed hardness case.

Jan 1, 2012

By J. O. Pitts

"Background The preponderance of Canada's coal resources is located in areas remote from high demand domestic users and at some significant distances from deepsea ports. This places great demands on the transportation system and has forced the coal and the transportation industries to adopt highly efficient methods of handling the product and hauling it to market position. Most of the coal not consumed in minemouth thermal power stations is carried by rail over lines operated by the two transcontinental railway systems, Canadian National and Canadian Pacific. These rail networks are extensive and have the advantage (as compared to most other North American railways) of being able to handle coal movements from origin through to destination without interchange to other rail carriers. Coal SourcesWith exception of the coal produced in Cape Breton, Nova iScotia, all the significant shipping volumes in Canada emanate ifrom mines located in the three most westerly provinces. Figure I ishows the geographic distribution of the major mining operaitions shipping coal to domestic and export markets. The prinicipal routes and the tonnages carried (1980 calendar year) are ialso indicated. iThe 1980 shipping data are summarized in Table I. Saskatchewan lignite began moving from Bienfait to Thunder Bay by CP Rail unit trains in mid-1981 at the rate of one million tonnes per year. The product is handled through Thunder Bay Terminals and delivered directly to a nearby Ontario Hydro electrical generating station."

Jan 1, 1985

By D. S. Robertson

More than 700,000 feet of diamond drilling was completed in the Blind River area between 1953 and 1958. Much of this drilling was at depths which are still not usual in North America. However, as the tendency is to deeper holes, factual data from the Blind River operation may well provide information of value in future programs. Rates of drilling decreased with in-creasing depth, but uncommonly good rates (an average of over 50 feet per day over more than 4,000 feet of hole) were achieved with proper engineering and care. Costs varied as contractors and geologists became familiar with the area Hole deviation in the Blind River area was locally severe and control of the hole trace became a major problem. Careful surveying was necessary and found to be highly re-liable. It was found that control of the hole trace above 1,500 feet was much more difficult than at depths below 1,500 feet. This is explained by the mechanics of the drilling operation. Various methods of controlling hole deviation were attempted and,

Jan 1, 1962

By K. Turgeon, D. Larivière, L. Whitty-Léveillé, J. -F. Boulanger, C. Bazin

"The processing of ore containing rare earth elements leads to the production of an impure solution of these elements. The separation of the rare earths from the impurities and the production of individual elements is usually carried out by solvent extraction. The effectiveness of the extraction conditions and of the reagents is generally tested in the laboratory. This paper deals with the processing of results from solvent extraction laboratory tests planned to generate data redundancy. A method is proposed to take advantage of the data redundancy by accounting for the pH variation during the extraction. The parallel processing of several tests also allows estimating the equilibrium constants for the extraction. The proposed method produces equilibrium constants that are more reproducible than values estimated using conventional approaches. The method is illustrated with solvent extraction tests conducted on synthetic solutions of rare earth elements.INTRODUCTIONThe processing of ores containing rare earth elements (REE) usually includes the production of a concentrate of the minerals carrying the REE. These minerals, for instance monazite and bastnäsite, contain the 14 elements from La to Lu plus yttrium and scandium. As an example monazite has the general formula of (La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy…Lu)PO4 with a typical lanthanum content of 20-26%, cerium content of 40-50%, praseodymium of 4-6%, neodymium of 16 to 20%, and decreasing concentrations of heavier elements (Gupta & Krishnamurthy, 2005). During the processing of a REE mineral, it is generally not possible to isolate and separate a single REE from all the rest. The mineral molecules need to be broken (usually via a heat treatment followed by leaching with a base and/or an acid) to produce an aqueous solution of the REE of the ore. After purification of the solution, the REE can be precipitated as a bulk concentrate and sold to a refinery that separates the REE into particular groups of REE such as the light versus heavy REE or into individual elements such as lanthanum, neodymium, or europium oxides to yield value-added products."

Jan 1, 2016

By J. M. Cummings

CONSIPERABLE information on the industrial or non-metallic mineral resources of British Columbia has been published. For a general resume of the subject, reference may be made to a paper presented by A. M. Richmond before the Annual General Meeting of the Institute in 1935 (1). To avoid duplication, the present paper is confined to a discussion of the existing industrial mineral industry of the Province and of the factors governing its present and future development. British Columbia's mineral production in 1936 had a value approximately 15 per cent of that for the whole of Canada. Preliminary estimates for 1937 indicate that this proportion has been maintained, although the totals have increased about 25 per cent. The following table presents comparative figures, for the year 1936, illustrating the relative importance of the major divisions of the mineral industry in British Columbia and in Canada as a whole.

Jan 1, 1938

By G. M. Ritcey

The recovery of copper from low-grade solutions res ulting from dump leaching is well known, whereas the recovery from highly concentrated copper solutions has not been practiced. This paper discusses the use of Ashland Chemical's Kelex 100, a substituted quinoline, for the recovery of copper from solutions resulting from leaching copper-nickel concentrates. A flow sheet is described, and an economic comparison shows Kelex 100 to be superior to either the LIX 64N or LIX 70 reagents of General Mills for the recovery of copper.

Jan 1, 1973