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By Oliver C. Ralston

DURING the development of froth flotation for the treatment of sulphide ores, a certain amount of information was collected about a few of the nonmetallic minerals, and occasionally the gangue minerals in the sulphide ores showed an embarrassing tendency to float. However, for many years efforts were expended to develop reagents that would cause wetting and depression of these minerals. Among the nonmetallics, the minerals sulphur, graphite, and talc probably should be classified as 'natural floaters', and perhaps sericite. They respond to almost any type of flotation reagent, and their beneficiation by flotation had been attempted years ago. Flotation of sulphur is now common practice, and graphite was concentrated during the World War in many mills, most of which have now closed down. A talc mill has just been constructed, and another may soon be erected. Second to the 'natural floaters' come the 'easy floaters', cassiterite, fluorite, barite, mica, colloidal gangue, and paper pulp from white water of paper mills. That these materials responded to some of the early flotation reagents, as oleic acid, has long been known; occasional references to their behaviour are found in the very early flotation literature and in that of today. In general, however, nonmetallic minerals, valued at $2.00 to $15.00 per ton, have for a long time been regarded as cheap products and not worth much beneficiation. Consequently, only high-grade natural deposits suitable for direct mining and sale have been gouged out. Furthermore, the mining of these minerals has too frequently been in the hands of 'super-practical' men-men of no technical or other training, willing to work for a very low compensation. From the social standpoint, nonmetallics has been the field for small, untrained enterprisers with little money to spend on plant or equipment. But times have been changing. The impact of technically trained men on the old industry has revealed appalling losses and inefficien-cies and proved the value of processing materials discarded or avoided by the old regime.

Jan 1, 1937

By J. Finch, Wei Zhang

In this paper we describe the synthesis of a new homologous series of linear Polyglycol-based frothers that consist of Ethylene Oxide (EO) and hydroxyl as hydrophilic groups and Propylene Oxide (PO) and alkyl chains as hydrophobic groups. The synthesized frothers were of two types: Alkyl-Ethoxy-Propoxylate (abbrev. CnEOlPOm) and Alkyl-Propoxy-Ethoxylate (CnPOmEOl) giving: (a) different number of groups and chain length, and (b) different locations of the groups. The identities were confirmed by proton nuclear magnetic resonance (NMR) spectroscopy and total organic carbon (TOC) analysis. The characterization of the products was carried out in a bubble column. At steady state, bubble size, gas holdup and water overflow rate were measured as a function of frother concentration. The results indicate that increasing number of PO groups led to significant decrease in bubble size, and increase in gas holdup and water overflow rate. Increasing the alkyl chain length, gave similar but less pronounced trends. There was no impact of increasing the number of EO groups on bubble size but there was an in increase in gas holdup and water overflow rate. Changing the location of the PO and EO group had a significant effect on all three parameters.

Jan 1, 2015

By John Plecash

This paper comprises a general outline of all of the developments, including the history, geology, mining, milling, power and transportation installations, at the gold mining operation of La Luz Mines Limited and the copper mining operation of its wholly-owned subsidiary, Rosita Mines Limited, both located in north-central Nicaragua. The low-grade, gold-bearing ore-bodies of La Luz Mines, contained in highly fractured and folded Lower Cretaceous sedimentary rocks, were from 1909 to 1928, mined and treated by primitive methods by the La Luz and Los Angeles Mining Company. The abandoned property was acquired by La Luz Mines Limited in 1936, and was equipped with modern machinery and put into production in 1939. Between 1939 and 1948, the daily rate of production was in-creased from 300 tons per day to 2,-000 ton per day. The ore reserves available for open-pit mining were depleted in 1954. Since then, the entire production has come from under-ground operations.

Jan 1, 1963

By J. E. Gill

"The name 'Canadian Shield' is used for a vast area; largely in northeastern; Canada; underlain by Precambrian rocks. The part in Canada has an area; of about 1; 790; 000 square miles. Extensions in Greenland; Labrador; Newfoundland; and the United States bring the total area to around 2; 800; 000; square miles. The boundaries of the Canadian part are shown in Fig. 1.; At its margins; the Precambrian rocks can be seen at many places to; extend beneath a cover of flat-lying Palxozoic or later sediments. Information; from borings in the Plains and natural exposures in mountain-built belts; show that similar rocks form a large part of the continental platform. The; Shield; therefore; is a large exposure of what may be regarded as the foundation; of the continent."

Jan 1, 1954

By D. L. Cluff

Ventilation Air Methane (VAM) is a high volume low concentration methane source. The capture or use of methane from VAM is challenging, which results in the routine discharge of methane into the atmosphere. Mitigating VAM has the benefits of providing an energy source and reducing the atmospheric Greenhouse Gas (GHG) burden. The GHG radiative forcing effect of methane is 17?23 times as potent as carbon dioxide on a 100-year time horizon. Thus, any reduction in atmospheric methane would be beneficial. The calorific value of methane is 55.5 MJ/Kg; therefore, a 100 m3/s flow with VAM concentrations from 0.1?1% can provide 3.8?38 MW of exploitable power. Strategies to mitigate VAM such as: Thermal Flow Reverse Reactors (TFRR), Catalytic Flow Reverse Reactors (CFRR), Lean Burn and Catalytic Gas Turbines, Biothermica Vamox®, Megtec VOCSIDIZER©, and Vamcat? are briefly reviewed. The review of VAM mitigation technologies reveals disadvantages such as the need to maintain a minimum internal heat capable of oxidizing the methane. This requirement uses all of the available methane up to the point of reaction sustainability and up to half at the highest methane concentration in VAM. Some systems may introduce a pressure drop to the ventilation system, which would impinge on the existing ventilation system design. These impediments necessitate the development of a more amenable technology. In the proposed system, gas turbines (GT), coupled to a combustion chamber with an external fuel supply, assist the combustion of the VAM. The combustion-chamber coupled system provides electricity, while the heat contained in the GT exhaust gases increases the temperature of the VAM, encouraging the development of a flame inside a combustion chamber. The flow from the combustion chamber streams through a primary air/fluid heat exchanger capable of producing steam of a high enough quality to generate electricity using conventional steam turbines. The residual heat after primary extraction, directed through other equipment, provides additional heat based products such as industrial scale dry air, chilling by an absorption chiller or hot water. The overall design of the system is scalable for low to high VAM flows or variations in concentrations and is capable of providing the company or community with heating, chilling, hot water, electricity or motive force as needed by the particular site or community. The Multi-generation system uses heat from three sources to provide clean efficient energy while mitigating the atmospheric emissions of methane. These sources are heat from the GT, often considered waste heat, heat from fuel injected into the igniters and heat from the VAM. The opportunity to collect carbon credits may improve the economics. In order to design a system with this capacity, a detailed analysis of the combustion characteristics of three separate flows is required. VAM is the main airflow, having the highest volumetric effect, while the GT exhaust and the additional fuel added to the hot exhaust flow of the gas turbine are lower flows, but have a higher velocity and temperature. The aim of the modeling undertaken in this work is to establish the combustion dynamics, degree of pre-heating required and the geometry essential to the design of combustion based VAM mitigation multi-generation systems.

Aug 1, 2013

By W. Hrynewich

"The Central Canada Potash facility, a division of Noranda Metal Industries Limited, is located 3 kilometres south of the junction of Highways 16 and 2, about 75 kilometres south-east of Saskatoon, Saskatchewan. The site occupies 26~ hectares of land and includes well-equipped machine and electrical _shops, a 325,000-tonne muriate storage and reclaim warehouse, a stores warehouse, processing plant (mill), two mine shafts (one for production, the other for servicing and personnel transport), as well as a two track product loading complex. Access to the site is by road and railway (CN and CP Rail). Suppliers of operating and maintenance use both means of transportation, whereas muriate shipments are entirely by railway.Currently five continuous mining machines - one a Goodman 526 borer and four Marietta 911-A units produce some 10,500 tonnes of ore per operating day. A smaller Voest-Alpine Af.1-100 boom type miner is used for floor cutting which was previously done by a production unit. In order to maintain safe, competent ground conditions only 35 percent of the total ore is extracted. At this rate mine reserves are deemed adequate for about 100 years. The plant has operated since August 1969 and has a current practical annual capacity of 1,270,000 tonnes of muriate. As of June 30, 1981, some 11.9 million tonnes of muriate had been produced from 31.4 million tonnes of ore. Of the total muriate, 6.1 million tonnes was granular, 4.8 million was coarse, and 1.0 million was standard. No standard product has been made since August 1978."

Jan 1, 1982

By F Kelly

"A central composite experimental design was used to determine empirical relationships between the operating variables of a ball mill and the characteristics of the ground products. The independent variables selected for the study were the work index and size distribution of the feed material, the feed rate and the pulp density. The measured responses included product size distribution, product surface area, viscosity of pulp discharge, weight of dry solids in mill, mill time constant and emitted sonic vibrations. The ball mill was operated continuously in open circuit during each experimental run.Multivariable regression techniques were used to derive linear empirical models from the experimental results. Of the four factors studied, the grindability of the feed material significantly affected every measured response. The size distribution of the ground product was affected significantly by the feed rate and the size distribution of the feed, but not by the pulp• density. Feed throughput capacity and pulp density were significant to the viscosity of the pulp discharge, the weight of solids in the mill and the mill time constant. Significant first-and second-order models are given for the above relationships. The relation-ships between the characteristics of the sonic vibrations of the operating mill and the various dependent variables have not as yet been established."

Jan 1, 1970

By Wayne D. Goodfellow, William M. Luff, Steven J. Juras

Abstract-Brunswick No. 12 is a vent-proximal massive sulfide deposit that formed above a feeder pipe with associated hydrothermal alteration. Because of the replacement of bedded sulfides deposited above the hydrothermal vent, individual sulfide lenses show the following vertical and lateral zoning outward from the vent complex: massive pyrite-pyrrhotite-chalcopyrite core - interlayered pyrite-sphalerite-galena (Pb-Zn ore zone) - bedded pyrite. The feeder zone which underlies the Cu-rich core consists of an anastomosing network of pyrite-pyrrhotite-chalcopyrite­ quartz veins with variable and generally minor contents of ferroan carbonate, Fe-rich chlorite, sphalerite, galena and arsenopyrite. Hydrothermal alteration of felsic igneous rocks hosting and adjacent to the feeder pipe is represented by an inner zone (zone 1) characterized by sulfide stringers, Fe-rich chlorite, muscovite, quartz, and ferroan carbonate that formed at the expense of feldspars and what was probably glass; outer zones (Il and III) are represented by Mg-rich chlorite and muscovite formation, and the albitization and silicification of K-feldspar. Accompanying these alteration trends is a marked decrease of Na + Ca, and an increase in Fe + Mg + C03 in zone 1, and increases in Mg + Na in the outer zones. The classic zoning of metals within the sulfide lenses, the formation of a feeder pipe below the vent-proximal sulfide core, and the hydrothermal alteration of felsic volcanic rocks cut by the feeder pipe all support a vent-proximal origin for the Brunswick No. 12 deposit. Furthermore, restriction of sulfide stringer mineralization to the footwall sequence, the folding of the stringer zone by an F1 fold, and the difficulty of long distance mass transfer of metals from the sulfides into the host rocks all argue against a tectonic origin for the stringer zone. All of the evidence indicates that the feeder pipe formed during the ore forming hydrothermal event, but has been distorted and in some areas detached from the overlying massive sulfides during subsequent deformation.

Jan 1, 1992

By Fabian Mohr

The methyl substituted binuclear cyclometallated gold(I) complexes [Au2(?-n-MeC6H3PPh2)2] [n = 4, 5 and 6] all undergo oxidative addition reactions with halogens and, in the case of the 4- and 5-methyl substituted analogues, with dibenzoyl peroxide to give metal-metal bonded digold(II) complexes [Au2X2(?-C6H3-n-MePPh2)2]. The 4- and 5-methyl substituted digold(II) compounds on warming or exposure to light undergo carbon-carbon coupling reactions to give gold(I) complexes containing the corresponding 2,2'-n,n'-biphenylyldiphenylphosphines. The 6- methyl substituted digold(II) complexes rapidly isomerise above ca. -20° C to binuclear heterovalent gold(I)/gold(III) compounds [XAu(?-2-Ph2PC6H3-6-Me)AuX{?2-(6-MeC6H3-2-PPh2)}], containing a fourmembered cyclometallated ring on a gold(III) centre. Surprisingly, no carbon-carbon coupling could be induced for any of the 6-methyl substituted compounds, even under forcing conditions. This difference in reactivity of the 6- methyl derivative, compared to that of the 5-methyl and unsubstituted analogues was studied by ab initio calculations using a series of model compounds. The results are in excellent agreement with the experimental findings and suggest that the key-step in the C-C coupling reaction is the partial opening of the Au(III)-P bond in one of the transition states. In the 6-methyl system this transition state is energetically inaccessible and hence no C-C coupling occurs.

Oct 1, 2003

By J. J. Brummer

"A reconnaissance geochemical survey, using the stream sediment technique, is described. The survey covered an area of about 400 square miles, in the Seal Lake area of central Labrador, underlain by basaltic flows, diabase and metadiabase sills, and sedimentary rocks. Previous work had indicated numerous small copper occurrences within the Seal Lake group of rocks. Stream sediments were tested for the readily extractable copper content and total heavy metal content. The results of the copper survey did not yield any new data on the distribution of copper mineralization. Results of the total heavy metal survey attracted attention to a remote portion of the area (Ten Mile Lake), which had hitherto been regarded as having no economic interest. The anomalous values found, suggested that zinc mineralization should occur in this region. Geological mapping indicated that the rocks exposed belonged to the Letitia Lake Group, which is older than the Seal Lake Group exposed to the east, which contains the copper mineralization of the district.Investigation of the area lead to the discovery of: (1) uneconomic lead-zinc mineralization; (2) radioactivity extending over a considerable area. Evaluation of the radioactive rocks led to the discovery of columbium-thorium mineralization in amphibolite and in diopside-actinolite schists along a contact with intrusive alkali syenite.Thus a geochemical survey, which was planned to evaluate a copper province, resulted in the discovery of lead-zinc-columbium-thorium mineralization."

Jan 1, 1960

By The Staff

"IntroductionThis paper lists typical liner performance data for various grinding mills at the Noranda, Waite-Amulet, Pamour, and Hallnor mines, and concludes with a comparison of these data, based on wear per square foot of lined mill shell area. Flow-sheets for each of these plants will be found in the reference cited.General InformationTwenty-eight ball-mills and one rod-mill are used by the Noranda organization for grinding ore. These mills, which are shown in general outline in Plate IV, are all of the overflow type and have a cylindrical shell attached to dished heads.Most of them are serviced by hand-operated cranes and none by power cranes. During re-lining, portable tugger hoists are employed to lift the liners and, frequently, to install them in place.The mills vary in length and diameter and the ratio of end liner area to breast liner -area consequently ranges from 1. 6.75 in a 5 ft. by 14 ft. mill, to 1:2.28 in an 8 ft. by 8 ft. mill."

Jan 1, 1950

By Jürgen Antrekowitsch, Gerardo R. F. Alvear Flores, Mehmet Ayhan, Christoph Zschiesche

Synergies between copper and lead extractive metallurgical processes enable the processing of a broad range of polymetallic materials. However, this complexity also brings some challenges expressed in terms of complex intermediates and final products. For instance, based on the limited solubility of Cu and Ni in crude lead bullion additional phases will appear during the crystallization of the melt. Beyond the need for continuous optimization of metallurgy the control of phase solidification is a further important pillar to achieve a more efficient process by minimizing the amount and cycles of reverts. This paper describes the microscopy study of one of the most relevant intermediate in the Cu and Pb metallurgy, the Cu based alloy and highlights the importance of applying a well-controlled cooling sequence to improve the overall process efficiency. INTRODUCTION One of the key aspects in Aurubis’s 2025 vision is to move towards the implementation of a multi metal recovery strategy. The implementation of this new multi metal vision is supported by the long tradition of the company, founded in 1866 as Norddeutsche Affinerie, and further developed by adopting modern copper smelting and lead smelting technologies for the processing of primary and secondary materials. The combination of these assets have already build the basis for processing of complex materials in the copper and lead circuits implemented in Aurubis’s facilities. The addition of a new smelting facility, will enhance these capabilities. Aurubis current flowsheet combines Cu, Pb and Zn metallurgy. This includes primary smelting of copper concentrate, processing of secondaries (residues, slimes, slags) and recycling materials (scrap, shredder material, e-scrap). These broad range of materials contain not only the mentioned base metals but also a number of minor metals that requires to be properly managed to ensure efficient recoveries and quality of the targeted metals.

Jan 1, 2019

By W. B. Boggs

The Noranda smelter was built by Noranda Mines, Limited, from the designs of A. E. Wheeler, consulting metallurgist, New York, for the reduction of ores and concentrates from the Horne mine, and to treat, on a custom basis, ores and concentrates from other mines in the Rouyn district. The smelter is situated at Noranda in western Quebec, about 330 miles directly north of Toronto. Ground was first broken for construction in November, 1925, before the completion of the branch railway into the district, which was not finished until October, 1926. After many difficulties and delays due to the Jack 'of transportation and the severe weather during the winter months, the smelter was started in December, 1927, and the first blister copper was poured on December 17th. The smelter was built throughout in two duplicate units, each with a rated capacity of 500 tons of ore per day. Operations were started with only one unit, and after several months it was found that one unit alone would smelt 1,000 tons of ore per day. At this time only one shaft, No. 3, existed, and its hoisting capacity and the capacity of the original crushing plant were insufficient to supply ore for two units at the increased tonnage. Accordingly No. 4 shaft was sunk and a new crushing plant provided to handle the ore hoisted there. This work was completed in the latter part of November, 1929, and since that time both smelter units have been operating.

Jan 1, 1930

By Stephan I. Zajac, Roger A. Blais, John B. Stubbins

THE iron deposits of central Labrador occur within a relatively small area, herein called the Knob Lake Iron Range, in which a northwest-trending series of low hills and ridges defines the height-of-land at the boundary between provinces of Quebec and Newfound-land. Approximately two-thirds of the deposits are in Quebec and the remainder in Labrador, with several deposits straddling the inter-provincial boundary. These deposits are being exploited in open-pit mines by the Iron Ore Company of Canada centered at Schefferville, Quebec. Since 1954 this company has produced more than 56 million tons of iron ore to become Canada's leading iron ore producer. With indicated reserves of more than 375 million tons of direct-shipping ore and large tonnages of iron formation amenable to beneficiation, this mining district is assured of a long life. This paper describes the Knob Lake iron ores and their geological settings and stresses the features that lead to a better understanding of their origin. The

Jan 1, 1961

By J D. McDonald

This paper outlines the function of the Safety and Compensation Division of the Mining Association of British Columbia. After a general discussion of safety and the safety program now being followed in B.C., the author goes on to describe the wide-ranging aspects of compensation payments and company assessment rates. Special attention is also given to the problem of silicosis in mining operations. In appendices to the paper, the experience rating plan of the mining industry is compared to that recently adopted for the construction industry. Introduction The Mining Association of British Columbia consists of fifty-five member companies, including virtually all the producing mines as well as the larger exploration, contracting and development companies. On completion of an extensive study of safety and compensation in the mining industry, the Mining Association of British Columbia instituted a Safety and Compensation Division in 1954. The director of the Safety and Compensation Division reports to the Executive Committee of the Association. There are two main functions of this Division. First is the prevenion of accidents by encouraging

Jan 1, 1965

By Alfred W. G. Wilson

THE state of development of its iron and steel industries serves as a 1eading index to the general condition of a nation's business affairs. In this paper, the authors present an economic study of the progress of this group of industries in Canada for the decade 1927-1936. The statistical data and most of the tables which accompany this article have been com-piled by John Casey, Statistician, Bureau of Mines; the text and some of the computations have been prepared by the seni0r author. The principal source of statistical information has been the publications of the Dominion Bureau of Statistics; where other sources have been consulted, they are noted in the text. All weights are given in short tons. Records for the years 1913 and 1918 are also presented in the group of tables dealing with iron ore and pig iron; they will serve as a basis for comparison with nearly normal years in the two decades prior to 1927-36, which included the abnorma1 years of the Great War. GENERAL REVIEW At the beginning of the decade under review, this group of industries had returned to almost normal production, as determined by pre-war conditions. Iron ore consumption showed a steady increase between 1927 and 1930; a marked decline began in 1930 and reached its culmination in 1932, when the recorded consumption of ore was 293,353 to11s, about 16 per cent of the average consumption during the first four years of the decade; the last four years of the decade show a gradual increase in consumption; the amount of ore used in 1936 was still slightly below the amount used ten years before, in 1927 (see Table 1, top).

Jan 1, 1938

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By Hevina S. Dashwood

This paper proposes to build on my previous research (Dashwood 2012), which analyzed how and why the norm of sustainable development became institutionalized in the global collaborative corporate social responsibility (CSR) initiatives of major mining companies. Since the late 1990s, the majority of major global mining companies have employed the norm of sustainable development to frame their individual CSR policies and to inform industry collaboration at the global level through the International Council on Mining and Metals (ICMM). This paper proposal seeks to address lingering questions from that research, by developing an explanation for how the normative frame of sustainable development has translated into specific CSR standards adopted by the mining industry. Preliminary findings suggest that, although the global mining industry has reached broad consensus on the meaning of sustainable development in the context of mining, there remains considerable variation between mining companies in terms of which specific global standards they adopt. As members of the ICMM, major mining companies are required to report according to the Global Reporting Initiative (GRI) indicators relevant to mining, and there has been wide-spread up-take of the ISO 14,001 environmental management system standard. However, other global standards, such as the International Finance Corporation (IFC) Performance Standards and the Extractive Industry Transparency Initiative, have not been uniformly adopted by the mining industry. What explains this variation? The paper employs a three-level institutional framework (rational choice institutionalism, historical institutionalism and the ?new? institutionalism in organization theory) to explain the influences on the adoption of CSR standards in the global mining sector. Existing research confirms that institutional context is an important factor in explaining CSR adoption in the mining sector (Dashwood 2012). Are similar forces at work in explaining the variation in adoption of specific CSR standards? A three-level institutional analysis lends itself to uncovering influences both external to mining companies (such as pressures from stakeholders), as well as internal company dynamics (such as managerial discretion). Furthermore, the framework can incorporate dynamics operating at the global level (such as isomorphism), the national level (such as the regulatory regime) and the local level (such as community needs and environmental challenges). The theoretical significance of this framework is that the influences on CSR adoption are more complex than can be explained in a single approach (such as narrow rational choice/cost benefit explanations). On a practical level, insights into how global standards get interpreted and acted upon by individual companies could lead to the development of more appropriate and effective global standards.

Aug 1, 2013

By R. U. Seneviratne, B. K. Ahlgren

In this paper we follow various technological discoveries and developments in the purification of minerals and metals in the mining industry by ion exchange. For approximately 100 years, ion exchange has been a known and variously applied purification and separation technology used by scientists and producers. It would seem obvious that the producer’s objectives have always been to achieve the highest quality products and the lowest operation costs, but also with the least amount of technological complexity. As a strategy to reach these goals, much effort has been expended in the quest to improve continuous ion exchange (CIX) systems by reducing utility needs and resin degradation or loss while at the same time improving productivity and reliability. Recent developments from a number of companies have pushed equipment boundaries, resulting in a variety of unique commercial equipment designs each with a varying degree of success. The challenge set forth for all new designs has been a truly continuous process with no sacrifice in the afore mentioned benefits. One very recent equipment design based on system symmetry appears to meet many of these objectives with greater flexibility and less complexity resulting in better economics for the producer.

Jan 1, 2014

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015