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The corrosion of aluminosilicate refractories by soda from three different sources has been studied by microscopic methods. Sodium sulphate from oil ash, sodium chloride used in glazing structural clay products, and sodium borate from borax-impregnated wood ash have fundamentally the same effect on the refractories. The soda is the chief medium of reaction and fluxing, the sulphur, chlorine, and boron being volatized as sulphuric, hydrochloric, and boric acids.INTRODUCTIONBecause of their strong fluxing action, alkalis are one of the main causes of corrosion and slagging of refractories.The action of potash and soda on refractories follows somewhat similar lines, although it is common for one alkali to be greatly in excess of the other. The course of the reaction in a number of cases of alkali attack has been studied by microscopic and chemical methods. For example, the action of potash on blast furnace refractories was studied by Kraner (1942) and Rigby and Richardson (1947), who described the occurrence of various potassium aluminium silicates. Its action on cement kiln refractories was described by Brisbane, Segnit, and Weymouth (1957). The action of soda on glass tank refractories has been studied by many people, for example Bisby (1956) and Resch (1954). Clews, Hugill, and Green (1940) made a microscopic examination of the attack by soda on silica bricks from a gas retort.Some recent cases of corrosion of aluminosilicate refractories which were brought to the attention of the Division of Building Research, C.S.I.R.O., illustrate phenomena which occur under conditions different from those...

Jan 1, 1964

By S. Nikolic, G. M. Stieper, D. P. Mallah, B. J. Hogg, P. B. Voigt

Copper feed materials processing is becoming more challenging, due to an incremental increase in the mineralogical and compositional complexity of these feeds. These complex and polymetallic feeds are now becoming more common and many sites have been forced to re-evaluate their operating strategies to process these materials at cost competitive rates, whilst meeting ever more stringent environmental regulations. Most operations must first evaluate the merits of pyrometallurgical and hydrometallurgical treatment routes. Although there are multiple copper smelting technologies available, only top-submerged lance (TSL) technology, supplied by Glencore Technology as ISASMELT™, has been applied in the real world to consistently and successfully smelt complex materials in integrated metallurgical facilities such as Glencore’s Kazzinc Ltd. operation in Kazakhstan, Umicore Precious Metals Refining in Belgium and Aurubis AG in Germany. Glencore Technology also offers hydrometallurgical processing, through the Albion Process™ technology, opening up viable flowsheet options previously not possible for these complex feeds. This paper describes a number of real world process flowsheets at global operations and Glencore’s own operations at Mount Isa and Kazzinc Ltd., which process complex feeds. These flowsheets integrate the ISASMELT™, Albion Process™, ISACONVERT™, ISAKIDD™ Tank house, and bottom blown oxygen cupel (BBOC™) technologies to provide an effective process solution for the treatment of complex polymetallic feeds to produce metallic copper and associated by-products. INTRODUCTION Traditional smelters and those built in recent times within the bulk smelting hubs of the world have been designed to treat standard/clean concentrates. In recent years the processing of complex polymetallic sulfide concentrates and the recycling of secondary copper and derivatives of waste electrical and electronic equipment, such as e-scrap, have become a focus for numerous companies (Alvear & Nikolic, 2013). Processing of these complex feeds, characterized by relatively high levels of minor elements (over 5% of elements such as arsenic, antimony, bismuth, lead and zinc) is more challenging. Facilities not designed for these types of materials may require significant modifications or a change in smelting technology to treat them. Often operations find themselves re-evaluating the merits of pyrometallurgical and hydrometallurgical treatment routes for their sites through a number of factors:

Jan 1, 2019

By W. Stumpf

Mean flow stress analyses from plant mill logs for the conventionally produced hot rolled low carbon steel from the Ispat Iscor Vanderbijlpark strip producing plant, indicated a higher temperature sensitivity than that found for the equivalent SAE 1006strip steel produced in the compact strip plant of Saldanha Steel. This was confirmed quantitatively through detailed hot deformation studies on an as-cast structure as well as on a finer grained condition on the same steel. In the conventionally produced steel, activation energies for hot deformation of 309 kJ.mol-1and 388kJ.mol-1for the two respective starting structures were found, both values extending over the entire normal hot deformation temperature range of 1140 to 900°C. These and other experimentally determined constitutive hot deformation constants were applied to the hot rolling austenite grain size development model used earlier. From this, it is predicted that dynamic recrystallization occurs only in the first two break-down passes at the Vanderbijlpark plant and thereafter static recrystallization occurs after exiting from all of the remaining ten or eleven roughing and finishing passes. This is significantly different from what was predicted earlier for the Saldanha Steel plant with its lesser number of passes where static recrystallization is predicted to occur only in the last three passes. The effects of this process difference and other observed product differences between the two types of product are discussed. Keywords: Low carbon steel, hot rolling of strip steel, rolling mill log analyses, austenite grain size, grain size modelling.

Jan 1, 2004

By E. J. Haug, K. L. Clifford, K. L. Purdy

St. Joe Minerals Corp.'s Southeast Missouri Mining and Milling Division produces lead, zinc and copper sulfide concentrates at three of its operations. The Viburnum and Fletcher mills have been described in previous papers. The new Bushy Creek mill, dedicated in May of 1973, is an updated version of the Fletcher mill incorporating 8.5 m3 (300 cu ft) lead and zinc

Jan 2, 1979

By Andrés Gonzalo Reyes Unda

Este trabalho de investigação foi realizado com a intenção de obter uma rota alternativa de lixiviação de ouro para minérios de baixo teor para uma planta industrial que adsorve ouro atualmente pelo processo CIL (Carbon in Leaching) na região da Ilha Cristalina de Rivera (ICR). Foram realizados testes em garrafões de 20 litros para estabelecer critérios de operação e dimensionamento de uma planta de lixiviação em pilhas permanentes para tratar 1.000.000 toneladas de minério por ano de minério de baixo teor (0,45 - 0,65 g/t) com granulometria menor que 12mm e com produção anual podendo alcançar de cerca de 455 kg de ouro.

Aug 16, 2017

By E Claridge

There are a number of major infrastructure tunnelling projects currently underway or proposed in New Zealand, including construction of new road and rail facilities and the refurbishment of existing road tunnels. These new projects have triggered a rethink of traditional practices in underground fire and life safety and local regulation.While there is a current surge in activity, tunnels have been a signifi cant part of New Zealand’s transport infrastructure for over a century. Despite this background, the new projects commonly face challenges that are symptoms of a national regulatory environment that has aspects that are inappropriate for underground environments. There are inconsistencies in local regional regulation and an absence of national guidance and standards relating to tunnel design. Historically, New Zealand has looked across the Tasman for guidance. Although recent overseas tunnel designs present learning opportunities, the adoption of international best practice and standards may not necessarily address local expectations or needs.This paper explores a number of specific matters affecting the design of road and rail tunnels in the New Zealand context, namely; the Building Regulations and associated local consenting processes and parties, and the responsibilities and needs of the New Zealand Fire Service.The discussion highlights the importance of a collaborative approach involving the designer, asset owner, regulators, emergency services, and other parties, and ensuring up-front clarity in design responsibility and ownership of residual risk.

Mar 8, 2011

Improving the Sustainability of Primary Metal Production - The Need for a Life Cycle Approach

Sep 13, 2010

By M. Matema

Paper written on project work carried out in partial fulfilment of BSc (Eng.) Metallurgy and Materials Engineering Small and large welded aluminium specimens were tested in fatigue and the results compared with design curves for aluminium in specification BS8118. Metallurgical tests were also performed on the specimens in order to correlate microscopic and macroscopic phenomena. The small-scale fatigue test results were in reasonable agreement with results in BS8118, whereas the large-scale fatigue tests showed that BS8118 is conservative.

Jan 1, 2005

By D. Whittles, C. J. Lea, T. X. Ren, A. Kelsey

A methodology for the simulation of methane drainage combining geotechnical modelling and computational fluid dynamics (CFD) will be described. Geotechnical modelling was used to predict the development of stress and strain due to mining. The results from the geotechnical modelling were combined with empirical expressions for the variation in permeability with stress of coal measure rocks and assumptions on fracture behaviour. This allowed the permeability, as affected by mining, to be specified in CFD simulations. Flow of methane through strata, with and without methane drainage, was then simulated to examine the effects of methane drainage.

Jan 1, 2003

By Robert L. Parsons

This paper describes the results of a detailed analysis of a loess deposit at the deep foundations test site established by the Kansas Department of Transportation. Multiple CPT, SPT, and pressuremeter tests were conducted as part of the investigation. This paper includes an evaluation of the effectiveness of common correlations used with the CPT, SPT when used for classification of loess and estimating its properties. Results show that common correlations must be used with caution as significant errors in estimation may result from using methods developed for other soil types. Laboratory testing included direct shear, triaxial, collapse, and consolidation testing, with many of the tests conducted on both vertically and horizontally oriented samples to evaluate anisotropic behavior. The results showed that strength properties could be considered to be isotropic.

Jan 1, 2009

By L. Holappa

Ferroalloys like FeCr and FeMn are mostly produced in submerged electric arc furnaces. Typical of these processes is that the amount of slag is quite high. The role of slag for the process is thus essential and specific chemical, physical and electrical properties are required. Slags in FeCr process are Al2O3-MgO-SiO2 based with minor contents of CaO and CrOx. Slags in the FeMn process are principally similar, originating from silicate minerals but can have quite large composition range depending on the manganese ore and its gangue minerals. Characteristic of the FeMn process is that the slag is rich in manganese oxide up to above 30%. A common feature is that the ?ore oxides?, CrOx and MnOx in slag are not only divalent oxides but also contain some higher valent of Cr3+and Mn3+, respectively. In FeMn production conditions the slag consists mainly of Mn2+. This is a clear difference from CrOx containing slags in which both two and three valent coexist in slags in FeCr process conditions. Oxidation state of the slag depends on the ambient oxygen partial pressure and temperature in the examined process. The thermodynamics of slags in ferroalloys, production are discussed in terms of phase diagrams, activities and oxidation state of chromium and manganese oxides. Further, slag properties influencing reduction kinetics and furnace operation i.e. viscosity and electrical resistivity are discussed. Keywords: review, slags, ferroalloys, ferrochromium, ferromanganese, thermodynamics, physical properties

Jan 1, 2004

By R. L. F. Kay, T. A. Fletcher, A. J. Boyce, C. M. Rice

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The synorogenic, mafic Ordovician intrusion comprises orthopyroxene-rich xenoliths and mafic-ultramafic cumulates with low-grade pyrrhotite, chalcopyrite and pentlandite mineralisation. Despite abundant textural, mineralogical and O isotope evidence for significant assimilation of country rocks, S isotopes indicate only a modest uptake and suggest that mineralisation is dominated by magmatic sulphur. The preferred explanantion is that the magma was close to S saturation on emplacement. Uptake of elements such as Si and O led to early crystallisation of orthopyroxene, resorption of olivine and early segregation of a sulphide liquid. Post-magmatic interaction with a high-temperature, surface-derived fluid, whose movement may have been controlled by regional shear zones, reset biotite and whole-rock O isotope values but not those of orthopyroxene. This model identifies the presence of olivine-rich rocks and evidence of extensive assimilation as guides to prospectivity

Jun 19, 1905

By P. J. K Leeuw, E. Uludag, M. J. Nong

Efficient drill-and-blast performance is pivotal to the profitability of deep-level mines, where high operating costs and declining grades demand maximum throughput. This study investigated persistent fragmentation problems at a longhole stoping operation that suffered from simultaneous oversized rock blockages in 300 mm × 300 mm grizzlies and excessive fines. Fifty-one muckpile images from five blasted stopes were analysed with Split-Desktop. Although the overall F₈₀ was 287 mm, nominally suitable for the grizzly aperture, the Rosin- Rammler uniformity index of 0.80 revealed a highly inconsistent size distribution containing both boulders and fines. Existing drill patterns were then evaluated with the Aegis underground software, which showed negligible crack overlap at the toe owing to inadequate spacing and burden. Insufficient energy overlap between blastholes, particularly at the toe, was found to contribute to the coarse fragmentation, while excessive fines were attributed to the crushing and severely fractured zones of blastholes. Optimisation simulations demonstrated that an 89 mm blasthole diameter on a 2 m × 2 m pattern would overlap, aligning with Aegis requirements of balancing powder factor, break angle, and energy distribution. Implementing this revised pattern is expected to reduce secondary breaking, prevent ore-pass blockages, lower fines, and ultimately improve overall production efficiency. The methodology illustrates how integrated image analysis and modelling software can effectively diagnose and address fragmentation issues, particularly in underground longhole mining, where challenging blasting conditions require a balance between achieving optimal fragmentation and maintaining stope stability. This approach offers a cost-effective pathway to improving comminution performance in deeplevel mines.

Oct 2, 2025

By David Schlain

The Bureau of Mines investigated methods for electrodepositing platinum-group metals from molten cyanide baths. The preparation of thick, protective coatings on molybdenum, Inconel, graphite, stainless steel, copper, and other structural metals were studied, as well as the electroforming of platinum and iridium crucibles. Iridium, rhodium, and ruthenium can be electrodeposited under an inert atmosphere, while platinum and palladium require the presence of air. Electrolytes may be prepared by direct-current electrolysis in NaCN or mixtures of NaCN and KCN using anodes of the particular platinum-group metal. When the concentration of metal increases to about 0.3 or 0.4 percent, the deposits become bright, adherent, and coherent. Current densities may be 10 to 25 ma/cm2, and plating rates are often 0.5 mil/hr. Platinum and palladium baths deteriorate because of the oxidation of cyanide to cyanate and carbonate, and the precipitation of metal. Changes in the platinum cyanide bath are relatively slow. The protection against oxidation afforded by the platinum-group metal coatings is evaluated by testing encapsulated specimens in a thermogravimetric balance. Surface pretreatment and the use of undercoats are discussed.

Jan 1, 1977

By Paul Kunze

When a new bridge was needed across the upper reaches of the Yellowstone River in Montana, removing the old concrete bridge piers became an environmental concern for the highway department engineers. The location is about fifty miles downstream from the north edge of Yellowstone Park. The determination was made by the federal and state agencies charged with protecting the resource, that the old piers had to go but the river bed had to remain unchanged. Concerns were expressed that removing the concrete presented the potential for environmental damage to this protected portion of the river. These concerns prompted the state to place stringent restrictions on the contractor in the way they carried out the demolition and disposal of the piers. The reinforced concrete masses had to be removed to an elevation at least fifteen feet below the river bed and every bit of concrete debris had to be removed from the river channel. Explosive removal was discouraged, but the only other options: saw cutting, mechanical or chemical breaking, were not viable.

Jan 1, 2014

By William H. Schiffbauer

The Bureau of Mines is conducting research that is aimed at making the mining industry more efficient in term of both productivity and the health and safety of the worker. As part of this research the Bureau of Mines has integrated a testbed composed of computer and related peripheral hardware to form an intelligent base for performing autonomous mining machine experiments. Although this particular application was con- figured for use on a Joy 16 CM mining machine, its generic structure facilitates its attachment to a variety of mining machine types. The multitasking multiuser computer can be set up for other applications by changing a bubble memory cartridge. The Joy 16 CM implementation includes 96 digital input-output (1-0) ports, 32 analog inputs, 8 analog outputs, 2 serial data channels, and 1 printer port. Operation of the machine can be performed either through a local terminal or remotely through a modem hookup. This report describes a testbed for autonomous mining machine experiments (TAMME)--its hardware, software, and complete system integration--so that it can be used as a foundation for other applications.

Jan 1, 1988

By Kenneth C. Ko

An engineering investigation was carried out on the technical and economic feasibility of implementing flexible liner/backpacking support systems In an advancing tailgate longwall mine. The system for a model mine consists of a circular tube constructed of liner plates and flyash backpacking. Flyash is pneumatically stowed into the tailgate. Small amounts of cement may be mixed to improve the support capability of the fill In difficult local ground conditions. Water is added inside the nozzle immediately prior to spraying. Results of theoretical analyses and a field test show that the designed system is technically feasible, can be cost-competitive, provides more stable ground conditions, and can Increase productivity and coal recovery, when compared with existing retreat longwall systems. In certain mine layouts, the new system can reduce the direct mining costs by a significant amount. The system would be particularly applicable to deeper coal beds with bad ground conditions.

Jan 1, 1980

By Steven E. Mischler, Jon C. Volkwein

A diesel particulate matter analyzer capable of direct, real-time measurement of engine exhaust particulate is necessary to effectively institute source control technology currently being used on diesel equipment and to ensure that the control measures are working. To investigate the potential of a differential pressure monitor to measure diesel particulate matter in undiluted exhaust, samples were collected from three different diesel engines-Kubota, Isuzu, and Deutz-running under 12 different RPM and load scenarios. These measurements were compared to elemental carbon concentrations in the sampled exhaust as determined by using the NIOSH 5040 analytical method. Elemental carbon is used as a surrogate measurement for diesel particulate matter. The results of the two data sets were then compared using a linear regression analysis. The coefficient of determination (or R2) was calculated to be 0.98, 0.94, and 0.74 for the Kubota, Deutz, and Isuzu engines, respectively. R2 values of this magnitude indicate that this method can be successful in estimating elemental carbon emissions in the engines tested. In addition, for replicate samples, the coefficient of variation ranged from 7.1% to 10.2% with an average of 8.5%. These data indicate that this method could prove useful to mechanics as they work to maintain engines and DPM control technologies.

By Erin Legault Seguin, Mike Rylatt, Curtis Mohns

"With energy costs increasing and ore grades diminishing, the role of pre-concentration in hard rock mining operations has been gaining greater interest. To maximize energy conservation, the pre-concentration process should be conducted at as coarse a crush size as possible while minimizing losses of pay metals. Dense medium separation (DMS) is a robust process that can be conducted at particle sizes as coarse as 300 mm and as fine as 500 µm with high separation efficiency, depending on liberation characteristics of the value minerals. The DMS process involves three steps: feed preparation, dense medium separation, and ferrous-based media recovery. This paper discusses each of these processing steps, but focus will be given to the dense medium separation stage. Various types of DMS equipment are reviewed. Pilot plant campaign case studies conducted at the SGS Lakefield site are presented, which have included a variety of mineral systems such as spodumene, sulphide-bearing gold ores, and complex sulphide ores. These case studies demonstrate that for amenable ores, mass rejection of 20-60% is possible while maintaining recoveries of greater than 90% in most cases.IntroductionPre-concentration is a process of rejecting mass of gangue while ensuring recovery of valuable minerals prior to more intensive, downstream processing. Pre-concentration has been practiced in industry for many years, and is gaining greater interest as the industry copes with processing lower grade, more difficult ores, typically requiring finer grind sizes and higher energy costs."

Jan 1, 2016

By Chuck Edwards

"The development of two large, high-grade uranium projects has been proposed for northern Saskatchewan. The projects are now under review by a joint federal/provincial panel. The McArthur River project is owned by the McArthur River joint venture (Cameco Corporation 53.991 %, Uranerz Exploration and Mining Limited 29.775%, Cogema Resources Inc. 16.234%) and operated by Cameco. Cameco proposes to mill the McArthur River ore at the existing Key Lake mill. The Cigar Lake project is owned by the Cigar Lake joint venture (Cameco Corporation 48.75%, Cogema Resources Inc. 36.375%, Idemitsu Uranium Exploration Canada Ltd. 12.875%, Korea Electric Power Corporation 2.000%). The Cigar Lake joint venture proposes that Cameco operate the Cigar Lake mine for the owners, and that Cogema mill the ore at their McClean Lake mill, now under construction. Proposed systems provide safe mining and ore handling, and allow the milling of McArthur River ore at Key Lake and Cigar Lake ore at McClean Lake. This avoids the disturbance of new sites for milling and tailings disposal.The McArthur River and Cigar Lake deposits are the largest known high-grade uranium deposits in the world. The ore grades at McArthur River and Cigar Lake are at least 100 times those that are mined elsewhere. It is proposed to mine these deposits using remote underground mining methods, to crush and grind the ore underground, to pump a thickened ore slurry to surface, and to transport it in special containers by truck to the mills.During all mining and processing stages the ore is fully contained. Radon emission is controlled by positive ventilation of all process vessels, with the process ventilation backed up by the primary mine ventilation system. Radiation is controlled by heavy steel pipe and vessel walls, concrete walls and sometimes lead sheeting."

Jan 1, 1997