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By L. G. Stolarczyk, J. Duncan

"SynopsisLong before the environmental movement, coal miners were suffering from occupational diseases that became apparent in the later years of service, and especially during the retirement years. Chronic exposure to micro-fine dust in the respirable range (‘float’ dust) causes various lung diseases, referred to as coal mine dust lung disease. In the USA alone, 76 000 miners have died of coal mine dust lung disease since early legislation recognized the issue in 1969. Researchers believe that reducing float dust exposure limits alone will not reverse the increasing incidence of coal mine dust lung disease seen in the current generation of miners. Trace and radioactive metals are concentrated in the thin boundary layers of the coal seam (Roberts, 2013), and hence float dust includes silica and toxic trace metals. The production and quality of coal is also significantly impacted by the presence of these contaminants in the coal. In the combustion process, the trace metals are oxidized and become incorporated in the fly ash and flue gas. Since they are extremely water-soluble, they represent a significant danger to health and the environment. Coal preparation plants and power stations need to mitigate these contaminants as far as is practical, but the simple fact is that most contaminants should have been left un-mined.This paper describes an innovative coal-cutting solution to the longstanding technology gap in mining – the ability to measure uncut coal layer thickness to the boundary rock layer. Because of constant changes in geology, seam thickness, and seam undulation, the horizon sensor must be located in the bit-block of the rotating cutter drum of the mining machine. Contaminants in ROM coal must be minimized at the source – that is, at the rock/coal crushing cone directly under the bit-tips of the cutting drum. Bittip distances to the rock boundary layer must be automatically controlled in real time when mining in a complex and undulating coal bed. Horizon sensing (HS) technology enables the mining machine’s cutting picks to stop at a specified distance from undulating horizons of the boundary rock. The thin contaminated coal layer can be left in situ, significantly reducing the toxicity of the float dust. Preventing the metal picks from striking quartz-containing boundary rock also reduces the occurrence of methane ignitions. HS technology equipped with pick force vector sensing can allow optimization of the cutting pick lacing pattern for minimum coal and rock crushing, thereby reducing float dust. This technology may enable the mining industry to convert from automated machine control to autonomous during coal cutting and loading."

Jan 1, 2015

By Z. van Zyl

The southern African coal industry is facing the reality that coal reserves are becoming deeper and harder to mine than before. Alternative visions need to be considered to offset the impact of these challenges on productivity, cost, and profitability. One of the main challenges is to maintain current production levels under more difficult conditions, and improve productivity where conditions allow. There is a need to move from the reactive event-based management system towards the more adaptable and flexible process-based management system. This paper focuses on underground coal mining, but the principles are also applicable to other commodities and mining methods. This paper is based on research undertaken by the personnel from Mining Consultancy Services Pty Ltd (MCS) on trends in the underground coal mining sector, as well as practical experience over a period of 16 years in the field of electronic monitoring of mining machinery and productivity optimization.

Jan 1, 2015

By Brian Heer, David Young, Randall Essex

The Manapouri Power Station is New Zealand’s largest hydroelectric facility located on the South Island of New Zealand. Constructed in the 1960’s, it includes a 700 MW under-ground power station and a 9.8 km (6.1 mile), 9.2 m (30 ft) diameter tailrace tunnel. The output of the power station is currently limited due to excessive head losses in the tailrace tunnel. To remedy this situation, the Electricity Corporation of New Zealand (ECNZ) retained Woodward-Clyde to design a second tailrace tunnel and appurtenant facilities and prepare Contract Documents for construction. The Project will involve the construction of a 9.8 km(6.1 miles), 10 m (33 ft) diameter, TBM-mined tunnel, hydraulic control structures at the upstream and downstream ends of the tunnel, an underground dewatering shaft and station, and tailrace channel improvements. This paper summarizes the key design and construction issues addressed during the planning and design phases, outlines the risk management provisions incorporated in the Contract, and overviews the Interactive Tender Process (ITP)that was implemented during the pre-tendering and tendering periods.

Jan 1, 1997

By B R, R Brooks, R Simcock, R Stewart

As environmental costs incurred by the mining industry become increasingly subject to critical analysis, new technology is necessary to ensure the further development of good relationships between the industry and community. Phytoremediation and phytomining are technologies that have the potential to capture the imagination and approval of the public. Phytoremediation , the in situ use of plants to extract heavy metals from a contaminated substrate, could offer an environmentally and cost-friendly alternative to traditional remediation techniques. Phytomining is the in situ removal of metals from a contaminated site or subeconomic orebody with the additional aim of recovering from the plant an economic amount of metal. Plants used in such operations, hyperaccumulators, accumulate large quantities of one or more target metals in their above-ground herbage. Upon harvesting and incineration, this plant material yields a low-volume, sulphide-free æbio-oreÆ, which can either be safely disposed of, or if the metal is of sufficient value, smelted. Investigations into the economics of phytomining nickel from ultramafic (serpentine) soils, showed that Alyssum bertolonii and Berkheya coddii could remove over 100 kg of nickel per hectare per annum from land with nickel concentrations well below the cut-off grade for conventional mining. It also appears possible to æinduceÆ the hyperaccumulation of gold into plants growing on gold tailings, or on stockpiled, low-grade gold ore. The plants used for phytoremediation and phytomining are useful colonisers as they are necessarily hardy and withstand extremes of salinity, metal toxicity and water stress that hinder the success of current revegetation procedures. As part of a rehabilitation operation, these plants may alter the geochemistry of a substrate making it more amenable to the growth of native species that should be used to restore a mining site to pre-operating conditions.

Jan 1, 1999

By Arthur D. Silber

The economic success and growth of any metropolitan region depends on mobility. Today, mobility between New Jersey and New York is threatened by a transportation system that cannot meet 21st century travel demands. The transportation bottleneck created by the Hudson River threatens the viability of one of the world?s great centers of commerce and culture. Fortunately, there is a solution: The Access to the Region?s Core Mass Transit Tunnel. The US$8.7-billion Mass Tran-sit Tunnel?s (MTT) new two-track line will double commuter rail capacity under the Hudson and create a new, state-of-the-art cavern station in Midtown Manhattan, with wide platforms, high-speed escalators and other features to improve riders? travel experience. The capacity and other benefits of the MTT project will launch a new era of prosperity for the region, just as the Pennsylvania Railroad did almost 100 years ago when it built the existing two, single-track rail tunnels that now form the sole commuter rail link between New Jersey and New York. The existing tunnels run from North Bergen, NJ, under the Hudson River to Pennsylvania Station at 33rd Street in Manhattan. Construction on the MTT, the largest public works project in the United States, is scheduled to start this year and continue through 2017. The MTT is ready to go to construction thanks to a major commitment of financial, engineering, project management and other resources from NJ TRAN-SIT, New Jersey?s statewide mass transit agency, and the Port Authority of New York and New Jersey, a bistate agency that operates the Holland and Lincoln tunnels, the George Washington Bridge and other major transportation facilities in New York and New Jersey. The project is also strongly supported by the state governments of New York and New Jersey, as well as that of New York City. The MTT is New Jersey Governor Jon Corzine?s number one transportation priority.

Jan 1, 2009

By D J. Black

Ventilation modelling is used to evaluate ventilation system performance. This paper describes modelling to assess potential changes to a single entry longwall ventilation circuit to improve ventilation and gas management. The longwall panel is extracting a 215 metre face in a 1.5 metre coal seam at a depth of 900 to 1000 metres below surface. The 1.5 metre B seam is located approximately 25 metres below the main 3.0 metre A seam and the gas content of both coal seams is approximately 20 to 25 m3/t. The B seam is extracted prior to the A seam and the mine relies on fracturing of the overlying strata to induce gas emission from the A seam to reduce the gas content prior to mining. Longwall operations in the B seam are constrained by limited ventilation and high gas emissions. Due in part to statutory limits on gas concentration and air velocity, the average longwall production rate is approximately 700 t per day.Gate roads in the B seam are single entry, developed using road headers and supported with steel arches. Additional timber cog support is installed to reduce roadway closure from abutment loading. Due to the slow advance of gate road development, mine management were reluctant to consider significant mine design changes, such as two heading gate roads; therefore, the investigation focused on determining the extent to which ventilation and gas emission impacted on longwall production performance, while recommending short-term, low-cost actions to improve ventilation and gas management to support increased longwall production.CITATION:Black, D J, 2017. Application of modelling to improve ventilation and gas management in a single-entry longwall panel, in Proceedings Australian Mine Vent Conference 2017, pp 239–244 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By J. A. L. Napier

It has been established that significant time-dependent stope convergence may occur over time periods of hours and days in certain hard-rock gold and platinum mines. The source of this time-dependent behaviour appears to be associated with both pre-existing discontinuities and with mining-induced fractures that form near the stope face. These induced fractures may be associated with blasting processes and may also be formed in response to high stress concentrations in the unmined regions immediately ahead of the stope face. In shallower platinum mining operations, time-dependent behaviour is, however, observed to be much less marked unless some form of specific mining-induced fracturing occurs. One particular case of considerable interest is the time-dependent behaviour that is found to be associated with the formation and deployment of crush pillars. The purpose of the paper is to present a simple limit-equilibrium computational model of this behaviour that is sensitive to both the formation sequence and the size of planned crush pillars in a mine layout. This model provides a useful means to optimize the sizing of crush pillars, and at the same time may be used to identify potentially hazardous circumstances in which pillars may not crush in a stable manner.

Jan 1, 2012

By Michael H. Wysockey

The load test program for the pile foundation at Soldier Field included static and dynamic load tests at four locations around the site. The dynamic tests were run with no knowledge of the static results, and comparison between the two is very good. It was necessary to use a special testing hammer (not the production hammer) to demonstrate capacity with dynamic testing. Over 90% of the piles were HP14x89 with a design load of 230 tons (18 ksi). The load tests showed a capacity in excess of 590 tons for all tests where sufficient set up time was allowed. The remainder of the piles were mostly HP 12x53 with a design load of 100 tons (13 ksi). The measured capacity of these piles was typically about 250 tons. One experimental HP12×74 pile with a nominal yield of 65 ksi held 730 tons (67 ksi) before failing.

Jan 1, 2002

By J R. Manuel, J M. F Clout

The importance of goethite to Australian iron ore production is steadily increasing as the proportion of goethite-rich, martite-goethite bedded and channel iron deposits increases at the expense of declining production from high-grade microplaty hematite deposits. For this reason, an improved understanding of goethite in iron deposits, its genesis, goethite types and their physical and metallurgical properties is vital to maintaining optimum sintering and blast furnace performance in Asian steel mills.The terminology used to describe goethite in Australian iron deposits is currently highly variable. The discredited mineral name ‘limonite’ is still in widespread use as a field term for goethite and there are many misconceptions concerning goethite chemical grade and downstream physical and metallurgical properties. The goethite classification proposed here is based on geological and physical properties from which three types are recognised including brown goethite, dark brown-black vitreous goethite and highly microporous, friable yellow ochreous goethite.In practice, typical vitreous goethite with highly reflective surfaces and conchoidal fracturing, characteristic of the hard cap zone appears from X-ray fluorescence (XRF) and electron microprobe analysis to be significantly higher in Si (up to 18.7 wt per cent), Al (up to 3.5 wt per cent) and S (up to 0.14 wt per cent) compared to the generally very low (<1 wt per cent for Si and Al) levels of these elements in ochreous goethite and brown goethite. The data dispels the common misconception that friable earthy or yellow ochreous goethite is high in Al and Si and other chemical impurities. However, P was found to be consistently higher (mean of 0.112 wt per cent and up to 0.296 wt per cent) in ochreous goethite than brown goethite (mean of 0.011 wt per cent) or vitreous goethite (mean of 0.031 wt per cent). The highly porous microstructure of ochreous goethite is thought to have a much higher surface area, which may aid in preferential adsorption of P onto the ochreous goethite mineral surface.CITATION:Manuel, J R and Clout, J M F, 2017. Goethite classification, distribution and properties with reference to Australian iron deposits, in Proceedings Iron Ore 2017, pp 567–574 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

Pipe Flow Stability of Concentrated Coal-Water Suspensions in the Presence of an Electric Field

Sep 13, 2010

By John C. Machisak

INJURY DATA and experience at coal mines in the United States for 1956 and 1956 are presented in this publication with a minimum of interpretation and comment because of the numerous tables required to afford detailed comparisons between the 2 years. Corresponding table., for 1955 and 1956 follow in consecutive order under the following general sections: (A) General injury experience: Tables I to II: contain current data on number of fatal and nonfatal injuries, frequency and severity rates, and average severity. (B) Selected injury data: Tables 12 to 77: Contain current data on causes of injuries, distribution of injuries by part of body injured, clays of disability, extent of hand and machine loading, experience by employment and production groups, and various other operating factors and physical conditions related to the occurrence of injuries at the Nation's coal mines. (C) Injury experience, by States: Tables 78 to 87: Contain data on injuries, injury rates, employment, cause of injuries, aid severity rates by States. (D) Major disasters: Table 88: Contains data on major disasters, 1947 -56. A major disaster is defined as a single accident in which, or as the result of which, five or more persons are killed instantly or died at any time thereafter. (E) Historical coal-mine-fatality experience: Tables 89 to 93: Contain data on fatalities and their causes at bituminous-coal and anthracite mines from the earliest records through 1956.

Jan 1, 1960

By Holger Witthaus

There is more than a century of experience in multiple seam mining in Germany. In several mines up to 20 seams had been excavated within the last decades. Due to the nature of the deposit and the history of technical development the older panels cause a complex stress distribution for the lower seams and the current longwalls in descending order of mining. The depth of the longwalls reaches up to 4000 ft. This causes a maximum vertical stress that reaches between 30 and appr. 60 MPa. To handle these conditions several support systems are applied for roadway heading. A central knowledge management system for ground control is used for design and dimensioning of support within the DSK. This paper gives an overview to the nature of German multiple seam mining and the solutions in matters of panel layout and support design. It describes the full lifecycle for roadways in the seam starting with the geological and geotechnical evaluation, the basics of roadway deformation in great depth, the development of planning tools and standards for German coal mines, the range of alternative of support systems and roadheading techniques, as well as the reinforcement measures and the processing of support at the T-junction of the face entry. This paper uses exemplary descriptions that are consolidated in a specialized reference book ?Gebirgsbeherrschung von Flözstrecken? ? ?Ground Control in Roadways? which summarizes the standards of ground control based on the development of the past 25 years in German coal mines.

Jan 1, 2007

By Y. Mitani, M. Xie, G. Zhou, T. Esaki

The assessment of landslide instability and risk has become a topic of major interest for both geoscientists and engineering professionals as well as for local communities and administrations in many parts of the world. In this paper, based on a new developed Geographic Information Systems (GIS) grid-based 3D deterministic model and taken the slope unit as the study object, the landslide hazard is mapped by the index of the 3D safety factor. Assuming the initial slip as the lower part of an ellipsoid, the 3D critical slip surface in the 3D slope stability analysis is obtained by means of a minimization of the 3D safety factor using the Monte Carlo random simulation. The failure probability of the landslide is calculated by an approximate method in which the distributions of f,c and the 3D safety factor are assumed to be in normal distributions. The assessment of the earthquake triggered landslide hazard is done by the dynamic displacement analysis using the index of the Newmark displacement. All the calculations are implemented by a computational system call 3DSLOPEGIS in that a GIS component is used for fulfilling the GIS spatial analysis function. Besides the results of 3D safety factor and probability, the possible landslide body and boundary can be three-dimensionally quantitatively identified. L’ estimation des glissement de terrain et des risques impliqués est devenu un des principal sujet de préoccupation pour les géotechniciens, mais aussi pour les ingénieurs specialisés ainsi que pour les communautés et administrations locales dans de nombreuses région du monde. Dans cette étude, basé sur un modèle de maillage 3D et une approche déterniniste couplée au Système d'Information Géographique (SIG), étudiant la stabilité des versants , le lieu d'étude à risque est maillé suivant le facteur de sécurité calculé en 3D. En supposant que le glissement initial soit la partie inférieure d'un élipsoïde, l'analyse de stabilité pour le glissement critique 3D d'un versant 3D est obtenu grace à une minimisation du facteur de sécurité en 3D utilisant la méthode de simulation aléatoire de Monte Carlo. La probabilité d'un glissement de terrain est calculée par une méthode approximative, supposant la distribution de c, f et du facteur de sécurité 3D normale. L'estimation d'un risque de glissement de terrain causé par un tremblement de terre est faite grace à une analyse du déplacement dynamique suivant l'index de Newmark. Tous les calculs sont effectués par le biais d'un système de calcul appellé 3DSLOPEGIS dans lequel te GIS est utilisé pour gérer l'analyse spatiale. En plus de cela, les résultats du coefficient de sécurité en 3D, des probabilités, le terrain susceptible de glisser, et ses limites, peuvent être quantitativement évalués en trois dimensions. Die Bewertung von Erdrutsch-Instabilität und risiko sind zu einem Thema von großen Interesse für sowohl Geowissenschaftlern und Ingenieuren als auch von Gemeinden und Verwaltungen in vielen Teilen der Welt geworden. In dieser Arbeit, basierend auf einem neu entwickelten Geografische Informationssysteme (GIS) gitterbasierten 3D deterministischen Modell und mit der Böschung als Untersuchungsobjekt wird die Erdrutschgefahr durch den Index des 3D-Sicherheitsfaktors kartografiert. Unter der Annahme, dass der erste Rutsch der untere Teil eines Ellipsoiden ist, wird die 3D kritische Schlupfoberfläche in der 3D-Böschungsstabilitätsanalyse mit einer Minimierung des 3D-Sicherheitsfaktors mit der Monte Carlo Zufallssimulation erhalten. Die Fehlerwahrscheinlichkeit des Erdrutschs wird mit einer Annäherungsmethode berechnet, bei der die Verteilungen von f,c und dem 3D-Sicherheitsfaktor als innerhalb normaler Verteilungen angenommen werden. Die Beurteilung der Erdbeben-ausgelösten Erdrutschgefahr wird mit der dynamischen Verdrängungsanalyse mit dem Index der Newmark-Verdrängung gearbeitet. Alle Berechnungen werden mit einem Berechnungssystem mit der Bezeichnung 3DSLOPEGIS ausgeführt, bei dem eine GIS-Komponente zum Erfüllen der GIS räumlichen Analysefunktion verwendet wird. Neben der Ergebnissen des 3D-Sicherheitsfaktors und der Wahrscheinlichkeit kann der mögliche Erdrutschkörper und der Umfang dreidimensional quantitativ identifiziert werden.

Jan 1, 2003

By Evelynn Stirling

Agenda ? Emissions legislation ? Cummins Tier 4 Technology ? Cummins Experience with Technology ? Operation and Maintenance Impact The Emissions Challenge ? The 2014/5 emissions regulations present the most significant challenge to our customer?s diesel powered equipment design and operation in recent history? ? ?and Cummins has the solution.

Aug 1, 2013

By Daniel Hoffman, Katerina Aifantis, Ibrahim Miskioglu, Jaroslaw Drelich

"A new method to determine the elastic modulus of a material using the atomic force microscope (AFM) has been proposed by Tang et al. (Nanotechnology 2008, 19, 495713). This method models the cantilever and the sample as two springs in a series. The ratio of the cantilever spring constant (k) to diameter of the tip (2a) is treated in the model as one parameter (a=k/2a). The value of a, along with the cantilever sensitivity, are determined on two reference samples with known mechanical properties and then used to find the elastic modulus of an unknown sample. To determine the reliability and accuracy of this technique it was tested on several polymers. Traditional depth-sensing nanoindentation was preformed for comparison. Using both methods, the elastic modulus of the polymers tested was calculated. The elastic modulus values from the AFM were within ±(5-20)% of the nanoindenter results.IntroductionThe atomic force microscope (AFM) has proven to be a useful tool for characterizing materials on the micro- to nano-scale. The most common use of AFM is to image and measure the topography of the sample surface, but AFM has also been used to characterize the mechanical properties of materials [1-3]. With AFM's ability to scan the sample surface, features of interest can be found and indented. It provides an advantage over traditional nanoindenters that use optical microscopes and thus cannot resolve nano-scale features. This makes AFM a useful tool for characterizing materials on the nano-scale."

Jan 1, 2011

By Charles Zahn

Direct mass spectrometric determination of alcohols in the presence of hydrocarbons has not been possible because of the similarity of hydrocarbon and alcohol mass spectra. Experiments have demonstrated that by converting the alcohols to their trimethylsilyl derivatives, characteristic mass spectra are obtained free of interference from hydrocarbon ion fragmentation. Hexa- methyldisilazane is the reagent selected for the conversion, An improved method of preparing the reagent is given, Mass spectrometric determination of alcohols as trimethylsilyl ethers now is not only possible without prior separation from other materials, but the range of the room-temperature mass spectrometer is also extended to include the C10 alcohol region. Water does not interfere because it is converted to hexamethyldisiloxane, which has its own distinctive mass spectral peak, Experience indicates that other compounds such as glycols, amines, and phenols probably could also be determined by mass spectrometry of their trimethylsilyl ethers. Studies on the similar detemination of phenols in coal oils have been started, When mass spectrometry is not available, gas-liquid chromatography of alcohols before and after their conversion to the trimethylsilyl derivatives probably could be performed. The preparation and properties of the trimethylsilyl derivatives of 23 alcohols, 2 glycols, 3 amines, and 1 mercaptan are detailed. INRODUCTION During investigations by the Bureau of Mines at the Pittsburgh Coal Research Center relative to the development of Fischer-Tropsch processes, complications were encountered in the mass spectrometric analysis of alcohols in hydrocarbon oils. The fragmentation peaks of the alcohols and the hydrocarbons were so similar that an accurate analysis was not possible, Since involved separation techniques are necessary to isolate alcohols from hydro-carbons for separate determinations, efforts were turned to the search for a

Jan 1, 1962

By Steven Norris, William Moler, Michael Cole, Patrick Doig, Debi Lewis, Craig Pyle, Matthew Crow

The recently completed Lower Northwest Interceptor Program (LNWI) in Sacramento, California comprises, ten pairs of micro tunnels totaling 4,369 m (14,417 ft),three horizontal directionally drilled bores totaling 956 m (3,154 ft), and two large diameter tunnels under the Sacramento River totaling 1,198 m (3,953 ft). This paper briefly summarizes surface and subsurface conditions, and planning and design considerations. It then goes on to describe problems encounterd with each trenchless crossing, as well as lessons learned with respect to shaft construction, ground control at shafts during tunnel break-in and break-out, frac-out and heave, settlement, obstructions, coordination with permitting agencies, and application of geotechnical baseline reports.

Jan 1, 2007

Generating short- and long-term mine production schedules in isolation and independently from each other means that only a local optimum can be achieved when each scheduling phase is carried out. The globally optimal solution however, can be achieved when integrating scheduling phases and accounting for the interaction between short-term and long-term activities simultaneously. This paper addresses the task of integrating short- and long-term production plans by combining the short-term objective of minimising deviation to targeted mill feed grade with the long-term objective of maximising net present value (NPV) into a single mathematical model. A case study is presented which compares the present values of the same stope data set scheduled via separate long and short-term models and than by the proposed integrated model which applies a predetermined penalty for each tonne of metal deviation to target for the respective ore tonnage being processed. This allows an operation to obtain a globally optimal scheduling regime when taking into consideration the cost and loss of value resulting from fluctuations in grade to the mill over the short-term.

Dec 6, 2010

By M. G. Maruma

The effect of the amount of cold reduction and annealing temperature on the evolution of the texture of AISI 441 steel is reported. The steel was cold rolled by 62%, 78%, and 82%, followed by isothermal annealing of each sample at 900°C, 950°C, and 1025°C for 3 minutes. The crystallographic texture was determined by Phillips X?Pert PROMPD texture diffractrometer. Microstructures were characterized using optical microscopy and scanning electron microscopy (SEM).The results show that sample that received 78% cold reduction and annealing at 1025°C presented the highest Rm-value and lowest ?R-value, which would enhance its deep-drawing capability. In addition, this sample showed the highest intensity of shifted ?-fibre, notably {554}<225> and {334}<483>. It can therefore be concluded that the ?-fibre, which favours deep drawing, is optimal after 78% cold reduction and annealing at 1025°C.

Jan 1, 2013

By C. -T. Mutale, A. S. Tuling

Titanium can exist in three different oxidation states. Its oxides are numerous and in presence of iron and oxygen, iron-titanium oxide compounds can also form. Some of the oxides are non-stoichiometric, making the determination of the thermodynamic properties of titanium and its oxides in molten steel and in slag difficult. Therefore, for the assessment of titanium activity in molten steel using the electrochemical measurements of oxygen partial pressure, the identification of oxides in equilibrium with titanium is important. This paper reports on an investigation of solid titanium oxide inclusions, which have been identified by combining different methods of analysis on quenched samples. These samples were taken from a Fe-Ti-melt at 1600°C, quenched in cold water then mounted and polished for optical microscopy. The oxide inclusions were analysed using transmission electron microscopy (TEM) with energy dispersive spectroscopy (EDS). Both single crystal and polycrystalline diffraction patterns were used to identify the oxides by comparing the d spacings with those in the ICDD X-Ray Diffraction (XRD) database. XRD was used to analyse the oxide particles on the top of slow cooled samples. It was found in the TEM study that the similarity of the diffraction patterns of the various phases meant that unique identification was difficult to achieve in some of the diffraction patterns. However, TiO, Ti2O3, Ti3O5, Ti4O7were identified in quenched samples, while TiO2, FeO.TiO2and iron oxides were seen in slow cooled samples. It was also confirmed that the type of oxides is related to titanium content of the samples. Keywords: Titanium, Titanium Oxides, Iron, TEM, XRD, thermodynamic.

Jan 1, 2004