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By Raymond B. Ladoo

"The name bentonite has been applied to a group or series of clay-like materials characterized by an alkaline oxide and alkaline earth content of 5 to 10 per cent, fine grain Giza, high absorptive powers, and usually very strong colloidal properties.Bentonite probably represents no mineral of fixed composition, and its physical properties vary considerably. The type material from Wyoming is light yellow or greenish yellow in color, but from other localities it may be cream colored, white, gray, pink, dark brown or even black. It is exceedingly fine grained, very plastic and highly absorbent. The appearance may be dull or powdeay, but a freshly cut surface usually has a waxy luster. Some varieties have the appearance of wax and may be cut into very thin, translucent shavings. The fracture of the type material is roughly conchoidal, that of other varieties is platey and shale-like, while still others have no typical fracture. Bentonite is highly absorbent; .hen wetted it will absorb more than three times its weight or seven times its volume of water. Some varieties when wetted with water expand to more than six times (some experimenters report eight times) their original volume. The wetted material is exceedingly smooth and soft and feels like soft soap. Unlike most clays, bentonite is easily fusible at a comparatively low temperature.Under a high-power microscope bentonite seems to consist of extremely small, more or less rounded, grains of uniform size, but the texture of most varieties is so fine that individual grains can not be distinguished.Some varieties when finely ground and thoroughly agitated with water will stay in suspension indefinitely, forming a translucent gelatinous mass. The addition of small amounts of acids or sodium chloride seems to have little or no tendency to raid coagulation or settling. Other varieties of similar analysis and appearance go into suspension more easily, but settle out again in a comparatively short time. It has been suggested that the material which stays in suspension indefinitely is a true colloid of the emulsion or lyophilic type."

Oct 1, 1921

By Jodi Roberts, Curtis Deredin, Jean-Guy Paulin

"Since the establishment of the Six Sigma quality improvement program in 2001, several projects have been successfully carried out in the copper-lead, zinc, copper separation, lead upgrading and bulk flotation circuits in the Brunswick Concentrator.This paper provides an update on the process improvement initiatives that have taken place since 2004 using the Six Sigma methodology:•,The recirculation of warm water to the flotation circuit (to save on energy costs)•,Installation of a heat recovery tower to recuperate the heat lost from the zinc dryers•,Installation of an extra row of cleaner-scavenger cells for the copper-lead circuit for extra capacity, and a new reagent scheme for the copper separation circuit that have increased copper and lead recoveries.INTRODUCTIONThe Brunswick Mine Concentrator (Xstrata Zinc Canada) is located near Bathurst, New Brunswick and is one of the world’s largest lead/zinc mines. Milling of ore commenced in 1964 from the No. 12 orebody, with an expansion in 1966 to accommodate ore from the No. 6 open pit mine. The concentrator utilizes selective flotation to produce zinc, lead, copper, and bulk lead/zinc concentrates. The ore is a complex massive sulphide, consisting of approximately 20% valuable minerals, 60% pyrite and 20% silicates.Figures 1, 2, and 3 illustrate the historical annual average metallurgical performance and process improvements achieved at Brunswick Mine for the zinc, lead and copper concentrate products. The objective is to continuously direct metallurgical performance towards increasing grades and recoveries while minimizing operating costs."

Jan 1, 2008

By W Donovan

Concern exists about the potential release of metals from the proposed mining operation at Martha Hill to the Ohinemuri River. Speculation on possible impacts is fuelled by the dearth of published data on existing metal levels not only for this river system but for streams throughout the Coromandel. At first sight this lack of data is surprising given the apparent interest in this subject and the fact that future mining activity in this region has been a possibility since at least 1979. That such a situation has arisen is not altogether unexpected given the difficulties faced by various organisations, including the mining industry, in determining metal levels which are generally acknowledged to be low. This paper presents data for a number of stations in the vicinity of the proposed operation; it explains the analytical procedures which were adopted and the rationale for them and relates the information which has been obtained to water quality criteria.

Jan 1, 1986

By M. Hesham El Naggar, Osama F. E. Drbe

"Abstract: The use of micropiles has greatly increased the last twenty years, including applications involving low capacity micropile networks, seismic retrofitting, underpinning of existing foundations and high capacity foundations for new structures. This paper presents a field study of the behaviour of single hollow core micropiles in firm to stiff lean clay. Eight micropiles were installed using hollow bars (76 mm OD and 48 mm ID) with air/water flushing technique and advanced to a depth of 5.75m: six micropiles were installed using 228 mm (9 in) drill bit and two micropiles were installed using 178 mm (7 in) drill bit. All micropiles were instrumented with linear potentiometers to measure the vertical displacement of the micropile head and vibrating wire strain gauges to measure the axial strain at three points along the micropile length. Twelve full scale tests were conducted on the eight micropiles, four monotonic compression, four cyclic compression and four tension tests. Only the results of micropiles tested under monotonic compression is presented in this paper. The full scale load tests and a comparison of the performance of the micropiles with 228 mm and 178 mm drill bit are presented and discussed in terms of load-displacement curves, bond strength and tip resistance. The results showed that the proposed values of bond strength in FHWA give a conservative design of the hollow core micropiles. The micropiles constructed with 228 mm drill bit performed marginallybetter than the micropile with 178 mm drill bit in terms of the ultimate capacity.IntroductionMicropiles have been defined in a variety of ways, but can universally be classified as small diameter (less than 300mm), bored, and grouted in place piles (FHWA, 2005; Bruce et al., 1999; and Scherer et al., 1996). They can sustain axial (compression and tension) and/or lateral loads. Dr. Fernando Lizzi used micropiles in 1952 for underpinning of historic buildings damaged during World War II (Bruce D. A., 1988). Since then, micropile applications have expanded rapidly to include underpinning for existing foundations, in situ reinforcement, and seismic retrofitting and foundations for new construction. In particular, micropiles have graduated from use in low-capacity micropile networks toapplications as single high-capacity foundation.Micropiles capacity is affected by the construction technique, which involves drilling, placing reinforcement, and placing or pressurizing the grout. For example, the drilling method influences the degree of bonding between the grout and the ground, and the placement of reinforcement and the choice of grouting method have an impact on the development of the bonding. Bruce et al. (1997) showed that grout/ground bond is most affected by the grouting method. Based on the type of pressure applied during the grouting process, micropiles are classified as follows (FHWA, 2005): Type A: grout is placed under gravity pressure only using either sand-cement mortars or neat cement grout. Type B: pressures typically in the range of 0.5 MPa to 1 MPa are applied in order to inject the neat cement grout into the drilled hole while the temporary drill casing is withdrawn. Type C: involves two-step process; neat cement grout is first placed in the hole under gravity pressure head only as in type A, and prior to the hardening of this primary grout, a similar grout is then injected via a preplaced sleeved grout pipe at a pressure of at least 1 MPa. Type D: like type C, this type is a twostep process: neat cement grout is placed in the hole under gravity pressure head only (but pressure could be applied in some cases), additional grout is injected via a sleeved grout pipe at a pressure of 2 MPa to 8 MPa once the primary grout has hardened. In some cases, a packer is used inside the sleeved pipe, enabling specific horizons to be treated. Recently, Type E micropile is proposed, which involves"

Jan 1, 2014

By Eric Dussell

Commercial or industrial explosives are mechanically-mixed, fuel-oxidizer composites which exhibit varying degrees of non-ideal behavior. Non-ideality results from a relatively slow and state-insensitive reaction rate (Lee, 1990) and is characterized by C-J pressures, velocities or expansion isentropes significantly lower than those expected from equilibrium, steady-state calculations such as Tiger or BKW (Mader, 1979). This departure results from significant amounts of explosive material which remain unreacted at the sonic point. Energy released by continued combustion within the emergent supersonic region downstream of the sonic point, constrained by local sound speed, cannot flow to the shock front and do work on it. The significant amount of this ‘late energy” and its slow time rate of release must be considered in any blast performance model.

Jan 1, 1997

By William H. Pomroy

Spontaneous combustion fires involving high-sulfide-content ores are a relatively infrequent yet serious safety hazard in mining. They are also the cause of lengthy mine shutdowns because they typically occur in areas of a mine where abundant fuel material is present but which are inaccessible for fire fighting. This Bureau of Mines report describes research to design, fabricate, and test in the laboratory and field a system that warns of spontaneous combustion fires in metal mines. Overall performance of the detection system was found to be satisfactory, in that the system was capable of reliably detecting low levels of combustion products believed to indicate the preflaming stage of spontaneous combustion in metal mines. Installation of similar systems in mines with a high risk of spontaneous combustion is recommended. Principal operating problems and recommended corrective actions are also discussed.

Jan 1, 1987

By C. C. Hamilton, G. R. Lane

Traditionally, mineral sands are evaluated by preparing several mineral products using a combination of heavy liquid-, magnetic-, and electrostatic methods. Whole-rock assays (WRA) are then conducted on ilmenite, rutile and zircon products in order to determine trace element contents, which may affect project feasibility. Combined methods can be time consuming, expensive and even outdated due to the use of banned and toxic chemicals such as clerici solution. Coupled with large field-sample quantities, these procedures can potentially introduce unacceptable sampling and related errors. Modern mineralogical analysis techniques can provide complete mineralogical inventories on a single THM product, reducing the amount of processing involved in satisfactory characterization of early exploration samples. A small exploration sample can be processed to produce a small THM concentrate using readily available gravity/density methods. In turn, the THM product is submitted for Whole Rock Analysis (WRA) and mineralogical inspection by X-ray diffraction (XRD), and microscopic evaluation. Modal mineralogy and textural data can be determined using optical methods, automated image analysis, and scanning electron microscope (SEM) based systems. Benefits of automation are reproducibility and the capability of rapidly analysing thousands of particles as opposed to manual optical methods. Automated systems include the use of Automated Digital Image Analysis (ADIS), and SEM-based systems such as the Mineral Liberation Analyser (MLA) and QemSCAN. For detailed mineral chemistry, microanalysis techniques ranging from electron microprobe (EMPA) to Secondary Ion Mass Spectrometry and Laser Ablation Mass-Induced Coupled Plasma-Mass Spectrometry (LAM-ICP-MS) are used. Examples of these automated and analytical methods are presented. ADIS at SGS-Lakefield Research uses optical characteristics to identify and measure mineral species in THM samples; rutile, pseudorutile, ilmenite and leucoxene can be distinguished. Analysis of a single THM product provides bulk modal mineralogy and grain size distribution of particles and the individual mineral grains. Textural information is also obtained detailing mineral associations as well as degree of alteration. Where textural and chemical resolution renders mineral identification ambiguous, SEM-based methods offer better resolution. Examples of this ambiguity are shown in this paper, which leads to QemSCAN as the preferred method where within-grain variability is concerned. Sampling and measurement strategies are followed to meet study objectives, providing a value-added framework for a sequential, cost-effective strategy, which will meet due diligence and bankable accreditation criteria. Studying a THM product by electron microprobe and LAMICP-MS may reveal potential fatal flaws related to mineral chemistry. Low detection limits in the range of 200 to 500ppm are possible using electron microprobe analysis for suitable matrixes (U, Th in zircon). For the detection of ultra low level elemental contaminants, LAM ICPMS is the most accurate method of evaluation. Elements including U, Th, La, Ce, Nb, and V in Ti-minerals can be determined down to 50 ppm.

Jan 1, 2005

By Liping Yu Che, Xiaotie Wang, Mingli Cao, Jizu Yongfu Yuan

"It is difficult separating fluorite from Ca, Ba, Si intergrowth minerals than simple from Si, using common reagents such as combination of oleic acid or paraffin soap and water glass, but the finest quality fluorite concentrate whose grade is over 96%F must be required in chemical plant.This paper studies the flotation process of native fluorite from calcite, barite and silicate minerals whose flotation properties is similar to fluorite, using new effective collector H602 and new depressor S602 that is cheaper in cost, and describes the flotation properties. In order to determine optimum flotation separation condition, the effect of pulp pH, pulp temperature, pulp density and the effect of dosage of reagents on flotation were investigated and the flotation result was provided by oleic acid collector and the results of collector H602 were compared with those of collector oleic acid in the test. The test result of ore samples shows that at moderate pulp pH values (10.5-11.5) and other moderate technical conditions, the fluorite mineral can be obtained by new reagents and the rational reagents combination. The conclusion is 98%F of fluorite concentrate can be obtained, using the combination of H602 and S602 and only 5 steps in techniques. The paper discusses the mechanism of the flotation separation of fluorite mineral from intergrowth minerals."

Jan 1, 2003

By Mario E. Rossi

The full economic evaluation of a mining project requires a block model that provides an estimate of the tons and grades of available resources. The model must be representative of the mineralization to be found at the time of mining for specified extraction periods and within acceptable error margins. In an operating mine, there may be a reasonable understanding and estimates of actual dilution and ore loss. This paper discusses the issue from the perspective of a project at a feasibility or preproduction level of development. Three types of dilution are discussed. Internal dilution (or change of support) is function of the spatial distribution of the mineralization and its relation to the operation?s selectivity. Geologic contact dilution is the unavoidable mixture at contacts or boundaries of material with different geologic characteristics, grades, or metallurgical performance. Operational planned and unplanned dilution should also be considered, sometimes incorporated by factoring the resource model, but more accurately by mimicking the grade control process. The resource estimation process always carries uncertainty, which is sometimes significant, and usually caused by several factors. These include quantity and quality of drill hole information; quantity and quality of geologic data; grade estimation methodology; dilution and mining recovery factors applied; etc. A key decision is to whether estimate as accurately as possible the in-situ geologic resource or to estimate the tons and grade of the material to be fed to the processing plant. The geologic modeling and grade estimation methods used are conditioned by this decision.

May 1, 2009

By R. Karl Zipf, Francois E. Heuze

Stress analysis programs such as MULSIM/NL, LAMODEL, MinSim 2000, and EXAMINETAB are used in the mining industry to analyze stresses and displacements in coal mines, platinum mines, gold reefs, and tabular-type deposits. These relatively simple numerical models can efficiently simulate yielding and failure of a rock mass near a mine opening and subsequent stress transfer. The main input parameters for these models are a family of nonlinear stress-strain curves for the in-seam material. For many applications of these models, such as in coal mining, extensive field measurements and observations exist from which to estimate these stress-strain curves and calibrate the numerical models; however, such measurements are lacking for other types of mines. A three-step method is presented to determine nonlinear stress-strain curves for boundary-element (BE) programs used in many mining applications. The method requires a suite of laboratory-scale strength tests at various confining pressures. Note that this analysis uses laboratory-measured strength and modulus properties of alluvium. The dependency of the mechanical properties of alluvium on scale has not been established, although more tests are being planned. However, it is believed that the relative comparisons performed are valuable regardless of scale effects. First, the FLAC2D computer program is used to model the laboratory tests and determine cohesion (c) and friction angle () for a Mohr-Coulomb material model. Second, another FLAC2D model uses the c and values to calculate vertical stress and strain around a single opening in the rock mass. This model calculates the stress-strain path of points at various distances from the opening boundary. Finally, based on these stress-strain paths, the stress-strain curves needed for a BE analysis are derived. This three-step method was demonstrated in a large, flat-lying underground test facility in very weak rock. The BE analyses agreed well with observations of failure at the test facility and provided a basis for evaluating the behavior of alternative layouts.

By W. L. Acherman

The Bureau of Mines found the chemical and galvanic corrosion behavior of the TZM and molybdenum-30 tungsten alloys to be generally equal or superior to that of unalloyed molybdenum in many aqueous solutions of acids, bases, and salts. Notable exceptions occurred in 1 [N] nitric acid, where both alloys corroded appreciably faster than molybdenum. In mercuric chloride solutions, the TZM alloy was susceptible to a type of crevice corrosion which was not due to differential aeration. The alloys were usually not adversely affected by con-tact with dissimilar metals in galvanic couple experiments, but the dissimilar metals sometimes corroded galvanically. Both alloys were resistant to substitute ocean water spray at 60° C.

Jan 1, 1968

AQUILA Mining Systems Ltd., designs, develops and delivers systems for measurement, analysis, simulation, control and automation to the mining, construction and petroleum industries. The objective of current efforts by AQUILA is the continued development and refinement of computerbased systems and techniques to automatically process monitored performance data from surface blasthole drills and mining shovels, and the management and coordination of these pieces of equipment by GPS (Global Positioning Systems).

Jan 1, 1994

By W. G. K. Fleming

The general history of piling is traced up to the present time with regard to the evolution of methods and materials. The processes have been strongly influenced by developments in basic equipment and industrial change. It is noticeable that in the twentieth century more progress has taken place than in the many previous centuries. It has been strongly influenced by the general development of Soil Mechanics. Test loading is probably the most effective way to assess the success of designs and many empirical relationships have been challenged through it. As we approach a new century it appears that it will be an age of rapid equipment development, with much enhancement of understanding of what has been done. Processes of automatic construction and testing will becoming commonplace. These changes will narrow the limits of conventional scatter that have come to be accepted and to a large extent will be driven by political efforts to curtail energy consumption, to raise standards of quality and reliability, and to conserve the environment. 1. Ancient history. Piling is an ancient art. Its first mention in history is from Herodotus, the first person to commit an account of his times to the written word in the years 557 to 479 BC. He evidently had a strong interest in engineering matters because he wrote of building, brick making, reinforced brickwork, river training, canal building, bridge construction, tunnelling and its acoustic detection and piling. The piling reference comes from Book 5 at paragraph 16.

Jan 1, 1999

By W. M. Middleton

The exploiting of geothermal steam is a new endeavor in this country and is for that matter a very new science in the world. With the majority of steam wells in the world having been drilled during the last twelve years relatively little experience and knowledge has been gained that can guide us as compared to the techniques the oil and gas producers have developed for their use. We few technical personnel associated with the field find it a continuous challenge to understand and explain what effects or causes the various unusual phenomenon experienced. We have had unending discussions attempting to formulate pet theories which we can use as guides. We know, so the geologists tell us, that the source of the heat is from the hot magmatic core of the earth. Theory has it that the magma is cooling off and that hot gases are given off as this magma cools and shrinks. In volcanic' areas along fault lines where the magma reaches closer to the surface than in other areas, there is a higher concentration of gas evolution; consequently, geyser or geothermal areas are developed. As these hot gases rise toward the surface they encounter various minerals, including overlying bodies of water. It is into these underground lakes that our wells are penetrating. As the heat enters these lakes it spreads out by conduction, convection and water migration. We can strike this hot water over quite large areas in many of the geothermal fields. At present there is one anomaly to this in the United States as there is in Italy where our wells do not penetrate a hot water lake. This is at The Big Geysers in California. Here superheated steam is produced with a heat content, so high that it could not have been boiled off of a fresh water pool. This puzzled us until last year when a well was completed into a large body of brine in the Imperial Valley. This brine exists at close to 500°F and at a hydrostatic pressure sufficient to preclude any boiling. It is now believed by some of us that a similar pool of brine must exist below The Big Geysers area, from which the steam is emanating. If there is such a brine pool, it offers a plausible explanation of the high-heat content, for brine boils at a higher temperature than fresh water. I am now beginning to think that a similar brine pool may exist under all the geothermal basins for if it is under two of them, it is highly probable that it is under the others. The partial understanding of what we are drilling toward, and formulating a theory to explain its behavior helps guide us in our steam well drilling.

Jan 1, 1963

By Eugene Nel, Johan Theron, Chris Martin, Hans Raabe

"Impala Platinum Limited is the world’s second largest platinum producer, producing more than 1.7 million ounces of the precious metal last year, much of this from the UG-2 reef located in the Bushveld Complex, South Africa. As part of Impala’s ongoing expansion programme, tonnage through their principal UG-2 processing facility, near Rustenburg, was increased 40% in 2001.To accommodate the increased throughput, the role of the existing primary mills was converted from conventional semi-autogenous grinding units, to attrition and selective grinding units, operating in fully autogenous mode. The finer chromite and coarser silicate components in the mill discharge are then separated by screening and processed in dedicated circuits downstream. This way, the need to spend considerable capital to increase primary grinding capacity was averted.In the last year, considerable work has been conducted to evaluate and optimise the two downstream circuits. This has involved an optimisation programme of sampling and diagnostic flotation testing, supported with QemSCAN analysis. This paper will describe the operation of the new circuit. It will also describe some of the more novel aspects and interesting findings from the optimisation programme.INTRODUCTIONThe South African platinum industry is the world’s largest producer of platinum and the world’s second largest producer of palladium. Located in a wide area north of Johannesburg, the industry mines ores from the Bushveld Complex, one of the world’s great mineral treasure chests, containing over 70 percent of the world’s platinum, as well as extensive reserves of the other PGE (platinum group elements), chrome, manganese and vanadium. The industry employs about 180,000 people in, predominantly, underground mines, which together form an almost unbroken circle of mining operations 200 km in diameter."

Jan 1, 2004

Commercially interesting deposits of zeolite rich tuffs and amorphous silica have been discovered recently in the Taupo Volcanic Zone (TVZ), North Island, New Zealand. This paper reviews them and comments on the potential for further discoveries. Potential markets for these unusual industrial minerals are discussed.

Jan 1, 1997

By Dale S. Preece, Stephen H. Chung

Electronic detonators and the attendant precise detonation timing that they facilitate are having a measurable effect on rock blasting in terms of improved fragmentation and vibration control. These improvements are increasingly well documented which is driving the expanding use of electronic detonators. In spite of the growing body of positive evidence concerning the benefits of precise delay timing, very little work has been done to document the impact of electronic detonators on the movement of rock. In this study 3-D computer programs, used to predict blasting induced rock heave, including the effects of detonation timing, are used to simulate the effect of precise timing on rock movement. Implementation includes quick, precise timing between blastholes going down a row and then much longer delays between rows of blastholes. For example an effective blast design might call for precise 3 ms delays between blastholes along a row and then 60 or 72 ms between rows. Several options are studied in this paper using computer simulations to draw some conclusions about the underlying physics affecting the process and how precise timing might have a positive impact on blasting induced rock motion.

Jan 1, 2005

By L. J. Leach

Quench and tempered Cr-Mo plate steel was found not to contain a fully martensitic structure as a result of either slow slack quenching or insufficient hardenability at the cooling rates used. The resulting microstructure contains bainite in combination with martensite. It is necessary to examine the implications of bainite for the toughness of the final product. Loss of toughness arises primarily from the inter-lath carbides that typically form in upper bainite. An investigation into the effect of upper bainite in a martensitic matrix of a steel grade containing 0.17% C, 0.1% Cr, 0.54% Mo, and 20 ppm Bindicated lower toughness than in a fully martensitic structure.

Jan 1, 2013

By James H. Owen

Because of price structure, ANFO is normally considered to be the most cost effective explosive used in quarry blasting. Results indicate that bulk smulsion can be more cost effective in applications where hole sizes range up to 6.5 inches in diameter while providing the simplicity of single product loading and storage. This can be accomplished without any fragmentation and/or movement loss usually in patterns which are about twice the size of ANFO patterns, allowing the combined drilling and blasting cost to be less when using bulk emulsions. Examples are presented supporting this concept using actual field results along with some simple calculations which take into account differences in the products such as density, matrix and detonation velocity.

Jan 1, 1998

By Gerald Greene

Tan various lead producers have given the subject of lead drosses much attention in recent years but the problem of their economical treatment is yet to be solved. Formerly the copper in the furnace feed was removed from the furnace in the form of matte. The speiss at that time consisted principally of the iron arsenide. The practice today is to roast off most of the sulfur and the copper in the feed forms a dross in the furnace, which is removed from the furnace with the lead. This material is poured into the drossing kettles and allowed to cool down to but slightly above the freezing point of lead. The copper dross, containing almost all of the arsenic and part of the antimony, is skimmed off and treated in a small reverberatory furnace at most plants. This is essentially a liquation process. The skimmed dross contains from 70 to 80 per cent lead, and much of this lead is liquated out. The products from this treatment are: (1) impure lead, (2) speiss and (3) matte. The speiss from the reverberatory furnace was studied in this research. The literature on the subject is of very little assistance, as almost no work has been done on the problem of establishing the exact identity of the various phases present. One author(1) states that speiss consists of a series of isomorphous compounds of the general formula FexAsy in which the Fe may be replaced by Ni, Co, Cu, Pb, Ag, Au, Pt, Zn, Cd and the As replaced by Sb, S and Bi. Hofman(2) states that the iron arsenide present is Fe5As.

Jan 1, 1935