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By P. Taskinen, D. Lindberg, H. Viitala

The formation of copper chlorides in flue dust or deposits in heat recovery boiler of copper smelters or waste-fired boilers may lead to formation of corrosive partially molten deposits on walls and heat exchangers of the boilers. These deposits can contain various other metals, such as alkalis, Fe, Zn, Pb together with oxides and sulfates. In the present study, a thermodynamic model for copper-containing binary and ternary metal chloride systems within multicomponent CuCl-CuCl2-FeCl2-FeCl3- PbCl2-ZnCl2 system has been assessed and optimized based on own experimental phase equilibrium data, as well as literature data. The thermodynamic properties of the liquid phase was modelled using the quasichemical quadruplet model and a thermodynamic database was optimized to predict all available experimental data within the experimental error limits. The thermodynamic database allows for more accurate predictions of potential corrosion-related issues in various heat recovery boilers and waste-fired boilers due to formation of copper chlorides. INTRODUCTION In the copper flash smelting, flue dust can cause severe problems in the gas train, used for separating dust from the SO2-rich off gas, by forming corroding accretions on the walls of the heat recovery boiler. Formation of dust build-ups in the boiler need to be cleaned regularly and potential corrosion damage checked, requiring costly and unscheduled shutdowns of the flash smelting process. Compounds of copper and zinc among other elements having high vapour pressures may volatilize during the smelting of the copper concentrate, forming dust when the process gas cools down. Also, particles of solid or liquid iron oxides originating from the ore get transported with process gas to the heat recovery boiler as a result of entrainment in the flue gas (Miettinen, 2008) The dust deposit build-ups on the boiler walls are formed partly by direct impact of particles and partly by vapour condensation on the boiler walls. The initial deposition takes place by the condensation of vapours that contain zinc, lead, arsenic and other metals having high vapour pressures. Also, low melting point eutectic components of alkali salts such as chlorides and sulphates can act as sticky cohesive particles attaching to the boiler walls. The fine particles landing on the surface of the porous dust deposit layer react in the SO2-rich atmosphere of the boiler to sulphates. The process gas within the boiler contains SO2, O2, SO3, H2O and N2 that diffuse into the porous accretions to form a stagnant gas layer within the dust deposit structure. The composition of this gas layer may differ greatly from the composition of the process gas that is flowing on the surface of the accretion layer. Locally HCl and H2SO4 are formed and even a reducing atmosphere may exist within the dust deposit layer, allowing new reactions to take place. The local micro-atmosphere may enable metal sulphates to be reduced to secondary sulphides and even metallic components. Within the accretion layer, components may be formed that would not be stable in the gas atmosphere inside the boiler (Miettinen, 2008). This may be the mechanism by which for instance chlorides of Cu, Fe and Zn are formed within the deposit layer.

Jan 1, 2019

By J. R. Lucas, R. L. Frantz

Mine sealing programs for the alleviation of acid mine drainage were begun by the Federal Government in the '30's. As part of an acid mine research project to The Ohio State University, a field test was undertaken to determine the effectiveness of mine seals for reducing mine acid. Details of the tests made at the McDaniels mine show the feasibility of air-sealing and flooding an acid-producing drift coal mine. Work by the University continues. The Federal Government undertook in the early thirties an extensive mine sealing program for the alleviation of acid mine drainage. In the states of West Virginia, Ohio, and Pennsylvania many general summaries have been made on this program but no critical evaluation with supporting data has been found on the effectiveness of mine seals for reducing mine acid. Because of this it was decided to undertake a field testing program as part of an acid mine research project of the Engineering Experiment Station, The Ohio State University. The objective of this phase of the project was to develop and install a field research laboratory for acid mine drainage studies. Specifications for such a mine laboratory were developed and resulted from the following considerations: 1) Size and preservation—the test mine shou1d be of limited size to permit frequent and detailed examinations; it should be in a reasonably sound condition to permit safe entry. 2) Isolation—the mine should be physically separated from all other mines. 3) Openings—a minimum number would be desirable to reduce the sealing problem. 4) Structure—the mine especially near the openings should be structurally sound. 5) Acid production—the mine should be producing significant quantities of acid. After considerable searching, the McDaniels mine was selected in the Hocking coal field in Vinton County just above Lake Hope State Park in southeastern Ohio. The small drift mine in the middle Kittaning coal consisted of two small rooms with one mine opening about 6 ft above a seasonal stream bed. Before it was finally decided to seal the mine, a short study was made of the acid drainage over several months. Fig. 1 shows a plot of acidity (milligrams per liter), flow (gallons per minute), and acid production (pounds per day) vs time over the sampling period. Because the coal was overlain with a porous sandstone, the mine drainage was consistent the year around even though the mine was

Jan 1, 1961

By Stephen H. Chung

The blasting performances identified above are considered to be the most practical ones for judging the effectiveness of a design combining explosives / rock / drill pattern. In a total blast design process, productivity relates closely to both fragmentation and heave / displacement of muck. In cast blasting, the more overburden displaced by explosives, the less blasted material there is left to be removed with mechanical equipment such as draglines or trucks. For wall protection and dilution control, estimates of the maximum extent of cracks / damage generated in situ due to blasting will help determine the location for drilling and loading perimeter blastholes.

Jan 1, 1994

By William A. Hustrulid

A technical and economic evaluation of the potential for improving mining productivity through the use of underreamers in blastholes, specifically in relation to Minnesota taconite, Arizona surface copper and in situ mining operations is presented. Included are (1) a review of the drilling and blasting practices presently being used, (2) a discussion of current underreamer technology. (3) the presentation of a general economic cost model for underreaming, (4) the application of the model to surface taconite, surface copper and in situ mining, and (5) a summary discussion including required performance specifications, potential overall benefits, and recommendations for further development.

Jan 1, 1977

By S. V. Ulianov, A. Y. Senchenko, E. M. Kurchevskaya

"A process sample of old copper-containing tailings (-2.0+0 mm) from an iron-ore plant was tested in TOMS institute in order to develop a process for copper concentrate production. The study of tailings material composition indicated that -0.2+0 mm fraction was efficient and contained 97.26% of copper. Copper is predominantly concentrated in chalcopyrite which is present both in free form and in intergrowth with ore and rock-forming minerals. Study of chalcopyrite using an optical microscope and Qemscan SEM determined that the most grains surface was covered with oxide films. Additionally, a lot of grains had micropores on their surfaces that indicated a partial mineral leaching. The oxide films did not make it possible to float copper minerals from head material. It was recommended to apply an attrition operation to restore chalcopyrite floatability. In order to increase selectivity a regrinding stage for a primary copper concentrate was introduced to obtain P80 26 um. Taking these recommendations into account a flotation flowsheet was developed to process the old Cu-containing tailings. The flowsheet allowed us to obtain a concentrate with 23.5% Cu content at 71.5% recovery.INTRODUCTIONStudy of material composition is an important prerequisite for development of a minerals processing technology. Mineralogical study contributes to search for an efficient technology to recover valuables and for prospective methods of minerals processing.The use of such up-to-date analysis methods and equipment as Qemscan and Mineral-C7 allows one to determine minerals size, liberation degree, and mineral associations. Mineralogical data can reveal reasons for hard processing of minerals prior to development of the process.The advanced process mineralogical methods used to study Cu-bearing pond tailings indicated several factors that influenced development of the process. The first one is a barren size fraction which is to be removed from the process in order to considerably reduce the costs connected with grinding. The second is the presence of films on chalcopyrite surface; in this context, a preliminary attrition of the material was recommended. The third factor is finely disseminated Cu minerals in sulphide and in the rock, which predetermined selection of particle size for flotation. All these data led to significant decrease in time required to develop the process technology. The developed process flowsheet based on the obtained mineralogical data is present in Figure 1."

Jan 1, 2016

By M. J. Gilbey

Cross passageways between adjacent tunnels in passenger rail or transit systems may be used during train fire emergencies to evacuate passengers to points of safety in the non-incident tunnel. Rescue trains can be brought into the non-incident tunnel to remove passengers to expedite evacuation times as compared to walking along bench walls to the nearest egress stairs. In cases of multiple train emergencies, the required ventilation capacities can result in high pressure differences between the incident and non-incident tunnels. These pressure differences can make it difficult or impossible for a normal person to open doors of a cross passageway between adjacent tunnels. If opened, the velocity of the airflow through an open cross passageway can reach levels high enough to impede passenger evacuation. This paper describes the analysis of this problem for a sample rail tunnel. A ventilation concept that mitigates the problems of high cross passageway door opening forces and high velocities through open cross passageways is presented.

Jan 1, 2009

By Rozbeh Moghaddam, William D. Lawson, Priyantha W. Jayawickrama, Hoyoung Seo, James G. Surles

"This study provides calibration of resistance factors (?) for design of driven piles to implement Load and Resistance Factor Design (LRFD) for bridge foundations using Texas Cone Penetration (TCP) Test data. The basic research approach was to compile a database of published full-scale load tests including projects from the Texas Department of Transportation’s (TxDOT) historical archive and projects from neighboring state DOTs. Load test results from neighboring states were leveraged by performing new geotechnical borings with TCP tests at the project sites. The final dataset consisted of 30 load tests performed on precast square concrete piles, with pile widths ranging from 356 to 508 mm and penetration depths ranging from 5.2 to 25.5 m, driven in soils. Ultimate capacities for each load test were interpreted based on Davisson, 5%, and 10% settlement criteria. These measured ultimate capacities were compared against predicted capacities estimated from TCP blow count values (NTCP) and design charts following the procedures outlined in TxDOT’s Geotechnical Manual. From the comparisons, statistical parameters of the biases (??= measured capacity/predicted capacity) such as mean and coefficient of variation were obtained. Resistance factors (?) for LRFD were then determined using Monte-Carlo simulations for each ultimate capacity criteria with the target reliability indices of 2.33 and 3.00.INTRODUCTIONThe Texas Department of Transportation (TxDOT) has used the Texas Cone Penetration (TCP) test since its development in the 1940s. The TCP test is an in-situ penetration test to characterize the materials encountered during geotechnical exploration. Texas currently maintains over 53,000 bridges in the National Bridge Inventory (FHWA 2016), and most of these bridges plus other transportation infrastructure in Texas are supported by foundations designed using the TCP test and its associated foundation design method. The Oklahoma DOT adopted the TCP test and foundation design approach in the 1970s, so the foundations for most of the 23,000 bridges in Oklahoma’s inventory were also designed using the TCP method. With this significant body of experience, the TCP method has been viewed as a straightforward, relatively easy-touse foundation design method that consistently yields safe, serviceable, economical, and maintainable foundations. TxDOT’s deep foundation design method is documented in the TxDOT Geotechnical Manual (TxDOT 2012) and currently employs the allowable stress design (ASD) approach. However, the Federal Highway Administration (FHWA) has mandated that the states begin to implement the LRFD method in place of the older ASD approach (Densmore 2000). This paper presents resistance factors at ultimate limit state (ULS) for design of driven piles using the TCP test, resulting from efforts to be in compliance with the FHWA policy."

Jan 1, 2017

Although the mining of metals was well established by the time of the Roman Empire mining skills did not really advance greatly for many centuries. Miners did not have the scientific knowledge to distinguish minerals, to process them, and to obtain the best recovery. Each mine essentially developed its own methods in isolation, most of them dangerous. However, with the beginning of the industrial revolution in the early 18th century there was a rapid increase in mining activity in Central and Western Europe and an accompanying need to educate professionals in the developing fields of science and technology. There was also a need for specialised schools (for example, Schools of Mines) to accomplish this since the universities of the time, formed as early as the first half of the 12th century, were cloistered institutions, focused on the study of classics, theology and law. The earliest attempts at organised technical education were made in 1702 with the establishment of a School of Mines in Frieberg, Germany (Table 1) to service rich copper mines, and in 1747 with the establishment of a School of Mines in Paris. By this time, the industrial revolution was well under way and other Schools rapidly followed, at Clausthal in the Ruhr region of Germany in 1775; in 1777 at Almanden to service the mercury mines of Spain (later transferred to Madrid); in 1780 at St Petersburg, Russia and at Falun, Sweden in 1819. The academic staff for these new institutions were often trained in the original School at Frieberg.

Jan 1, 2002

By E. C. Westman

Three-dimensional velocity tomograms were generated on a daily basis to image mining-induced changes to the overburden above a longwall mine. The hypothesis was that a coherent redistribution of seismic velocity, due to the development of high-stress zones, could be imaged at the mine scale. Seam depth was 360 m and source location depth varied from 100 to 1000 m. Sixteen geophones were distributed over a 600 by 600 m square area on the surface above the mine. More than 12,500 events were recorded over an 18 day period. The recorded seismicity provided input for the local-earthquake tomography code, SIMULPS. Eighteen tomograms were generated and high-velocity regions correlated well with high abutment stresses. Additionally, the high-velocity regions were observed to redistribute as the longwall face retreated. These results indicate that velocity tomography can be used to provide a better understanding of temporal changes within a rock mass, and can potentially be used to produce a better understanding of the mechanisms that lead to unanticipated ground failures.

Jan 1, 2008

By Malte J. M. Gurgel, Axel Preusse

The planning, construction, and monitoring of underground storage facilities is a key factor in meeting upcoming challenges as part of the energy transition from fossil fuels to renewables. Therefore, the many years of knowledge and expertise in ground control gained from coal mining are highly valuable for new mining and storage operations. For such applications, our previous work examined cavity registration, combining structure from motion and LiDAR through a case study in a former lead ore mine. Building on this, the results of this recent case study are discussed regarding the possible application in sites for nuclear waste disposal in Germany including a view on the situation in the United States. Photogrammetric methods are particularly suitable as part of long-term monitoring, which relies on both precise survey results and a large variety of detailed visualization. In order to gain a better understanding of the resulting application potential for holistic monitoring, both existing repositories sites in Germany and ones yet to be found are examined. This search and selection process for high-level nuclear waste disposal is studied in detail together with rules resulting from the (German) mining law, regulations, and other guidelines. Hereby, key requirements of photogrammetric products like oriented images, point clouds, and three-dimensional (3- D) models are identified for different case studies. The findings on accuracy and integrity of the generated models are not only of interest for future repository sites or underground pumped storage power plants, but also offers various possibilities for underground mining of coal and other commodities.

Jul 1, 2023

By D. M. Doyle

"The Strathcona Concentrator operations, the application of control systems in the crushing, flotation and tailing fill sections, and current and future computer control concepts are described in this paper.The computer has been used for reporting and monitoring roles and operating the on-stream analyzer since start up of the mill in 1968, while over the past twenty months, it has been used for process control. The systems which have been developed include:1. The blending of pentlandite concentrate with pyrrhotite concentrate to produce a special product of constant nickel analysis.2. The blending of cement with tailing fill to produce backfill of consistent cement content.3. The supervisory control of xanthate, frother and pH to the flotation circuits to maintain the nickel copper concentrate grade within narrow limits.IntroductionThe Strathcona Concentrator is currently treating 7,200 tons per day of an ore which contains nickel associated with the minerals pentlandite (28 -32% Ni) and pyrrhotite (0.3 -1.0% Ni). The ratio of the nickel minerals varies from 4 to 15 parts of pyrrhotite to 1 part of pentlandite over the orebody. The production of a high grade concentrate re4uires the separation of this small quantity of .oentlandite from the much greater proportion of pyrrhotite and gangue and is complicated by the presence of two pyrrhotite minerals differing in nickel content, floatability and magnetic susceptibility."

Jan 1, 1974

By David D. Rabb

A report on location, sampling, assays, mineral examination, amenability leach tests, and evaluation of certain mine dumps in Mohave County, Arizona. Extractions of greater than 30 percent of the gold and silver were achieved during simulated heap leaching of selected mine dump material. Consumption of reagents was relatively low and results suggest leaching of prepared heaps is technically viable and could be economically attractive.

Jan 1, 1980

In conjunction with steady increases in production levels, longwall operators have applied greater quantities of ventilating air and spray water in an effort to control respirable dust and/or methane. Air velocities greater than 7.6 m/s (1500 fpm) have been measured on longwall faces. Operators have expressed concern over the potential entrainment of respirable dust at these high velocities. The greatest likelihood for entraining dust into the high velocity airstream may occur as shields are advanced allowing relatively dry particles to fall from the shield canopy directly into the airstream. Laboratory tests to simulate dust liberation during shield movement were conducted at the Pittsburgh Research Laboratory of NIOSH at velocities ranging from 2.0 to 8.2 m/s (400 to1600 fpm). Airborne dust samples were obtained with personal impactors to quantify the size distribution and concentration of the dust entrained at the various air velocities. Statistically significant increases in both total and respirable dust concentrations were measured as test air velocities were increased.

Jan 1, 2001

By H. M. Chance

STRETCHING from New York southwestwardly to Georgia is a great range of hills and mountains consisting of pre-Palaeozic schists, slates, and gneissic and granitoid rocks, known locally by many different names; in Pennsylvaniaa as the South mountains, the Berkshire or Durham and Reading hills, and in Virginia and farther south as the Blue ridge. To the northwest of this range lies the " Great Valley," underlain by Lower Silurian limestones, and known as the Lehigh valley, Cumberland valley, Shenandoah valley, valley of Eastern Tennessee and Georgia and by other local names, but all these are parts of one valley, geologically and geographically continuous from New Jersey to Georgia. Lying upon and along the northern flank of this range of mountains, and dipping northwestwardly under the limestone of the valley, is the Potsdam formation (Primal or No. 1 of the Pennsylvania Geological Survey), which consists of sandstone or conglomerate overlain by slates. The latter are sometimes arenaceous and occasionally are replaced in part by sandstone. This formation varies from a few feet to several hundred feet in thickness. At the outcrop the slates are completely decomposed, oxidized or disintegrated, forming a belt of clay several hundred feet wide occupying the interval between the outcroppings of the sandstone and limestone. This clay-belt includes a more or less continuous series of iron-ore (brown hematite) deposits, which have been, and still are, extensively worked. The belt is more or less continuously mineralized with iron throughout its length, and hundreds of large deposits of ore have been developed and worked, producing many millions of tons of ore.

Sep 1, 1908

By E. Farrokh

Estimation of the cutter life and cost is a part of evaluating performance for a hard rock TBM in any project. Various approaches has been proposed for calculation of disc cutter life in various rock types based on machine specifications and rock strength and abrasivity. Cutter change time is a parameter that is used in some of the estimates and is defined as the average time required for changing a cutter on the cutter head and cutter life is the number of cubic meters of excavated rock per each disc cutter. Analysis of cutter life information of several tunnel projects from around the world has revealed that the published models for estimation of cutter consumption require some revisions to offer a more accurate prediction. The preliminary analysis of data shows that the average cutter change time is approximately 66 minutes for different cutter sizes and there is a minimal difference between corresponding cutter change times of the large (e.g. 19 or 20 in) versus smaller cutters (e.g. 15.5 to 17 in). This paper reviews the available and published cutter life data from various projects. It also introduces new models for estimation of cutter life and cutter change time as part of TBM down time and utilization analysis.

Feb 27, 2013

By Max J. Spendlove

This Bureau of Mines publication reviews current recycling trends in the United States. Although near-term prospects are poor for recycling most present wastes, urban refuse is an important exception. Such wastes comprise a mine above ground, and much less processing energy is normally required to recycle the constituents of urban ore than to obtain them in equal amounts from natural raw materials.

Jan 1, 1976

Study on Pure Mineral Flotation Tests of Low-Grade Phosphate Ore in Zhijin, Guizhou Province, China

Sep 13, 2010

The concentration of Mt. Morgan sulphide ore has always been attended by serious loss of gold. Until recently, with a simple selective flotation flowsheet, even the lowest grade of ore milled-about 2 dwt. per long ton-thislloss was 0·9 dwt., whilst for average to high-grade ore, 3·5 to 5 dwt., the figure was 1·5 to 2·0 dwt. Early in 1937 it was decided to equip the research laboratory for an investigation into the condition and location of the escaping gold and the physical and mineralogical barriers preventing its recovery.With the completion of: this equipment in July 1937, trial and error testing, which had been explored to exhaustion, was abandoned and a five months' research programme mapped out and commenced. Based on the knowledge so gained, a flowsheet combining primary desliming, bulk flotation of the natural slime, selective flotation of the deslimed fraction, and cyanidation of the selective flotation tailing was drafted and tried with encouraging results in a 70-lb. per hour pilot plant. This flowsheet, modified to meet current circumstances, is being dove-tailed into the existing 1,500-ton sulphide ore concentrator, though the cyanidation treatment is actually carried out in the oxidized ore mill, to which the flotation tails are pumped.RESEARCH EQUIPMENT(1) Five tube elutriator (Fig. 1) t built in the company's workshop.

Jan 1, 1939

By L. M. Irwin

This Bureau of Mines investigation relates the physical properties of copper reverberatory furnace slags to changes in composition, The smelting of upper Michigan copper ore presents some problems that probably differ from those of other copper smelting areas. The study of these problems has, however, provided important data regarding slags in general and therefore will be of value to other operations as well. Conclusions reached from this study were: (1) Slag fluidity and refractive indices varied directly with the iron content and inversely with silica, lime, and alumina, and (2) there was no apparent correlation between slag fluidity and its copper content.

Jan 1, 1962

By Robert P. Vinson

This Bureau of Mines report presents the results of tracer gas studies conducted at three facilities where bagger hoods had been installed several years ago to remove airborne silica dust from the vicinity of the bagging operator. The studies indicated that for optimum benefits makeup air must be evenly dispersed, the hood enclosures and duct systems must be as airtight as possible, the average intake air velocity of each hood should be at least 200 fpm, and the hoods and duct systems must be properly maintained.

Jan 1, 1981