Search Documents

By E. Milosavljevic, C. H. Bucknam, K. L. Gabby, T. C. Eisele

"Since mercury is chemically similar to silver, it tends to dissolve along with the silver and gold during cyanide leaching. Ultimately, mercury is recovered along with the silver as mercury/silver/gold amalgam, which requires retorting to remove the mercury prior to refining the silver and gold. A possible approach to separating mercury from silver and gold in cyanide leach solutions is to take advantage of the replacement reaction between [Hg(CN)4]2- and Ag2S, which results in precipitation of mercury as HgS while dissolving silver as [Ag(CN)2]-. Results are presented demonstrating that mercury can be removed from cyanide solutions with high effectiveness while, at the same time, recovering additional silver in solution. Initial experiments with static flasks in the laboratory showed a high degree of mercury removal could be achieved. Results using actual metallurgical plant products in bottle roll tests indicate the process works on a larger scale, but also results in significant gold losses if the solution being treated has high gold levels, such as carbon stripping pregnant eluent solution. IntroductionThe dissolution of mercury along with precious metals during cyanide leaching is a long-standing problem, which can result in significant mercury toxicity issues (Washburn, 2003). Mercury is first dissolved by the cyanide solution, and then, since it has a great deal of chemical similarity to silver, it follows silver throughout the concentration and recovery processes, ultimately being recovered as a silver/ mercury amalgam when the metal is precipitated by either the Merrill-Crowe process or by electrowinning.While it would be desirable to either prevent mercury dissolution entirely while still allowing silver dissolution, or to selectively capture mercury before the precious-metals recovery step, there is not yet an effective and economically practical approach to doing this (Grosse, 2003; Ravichandran, 2004; Misra, 1998; Pai, 2000). There are a few processes that have been proposed, such as differential adsorption. While activated carbon, as used in the carbon-in-pulp process, is not highly selective between mercury and silver (Washburn, 2003), it may be possible to achieve some separation by selective elution of the carbon to produce high-mercury and low-mercury eluates (Bunney et al., 2010). Certain synthetic resins were shown to be selective for gold but are more expensive than carbon, requiring special equipment, and have not yet been shown to be selective for mercury (Grosse, 2003). There may be potential for differential dissolution approaches, as thiosulfate leaching does not dissolve mercury sulfides as readily as it dissolves gold (Oraby et al., 2010), and it is possible that it may be similarly more selective for dissolving silver relative to mercury. Some work has also been done with selective precipitants, such as sodium polythiocarbonates (Bucknam, 2007), and 1,3-benzenediamidoethanethiol (Matlock, 2002). Common problems with these approaches include introduction of a solid:liquid separation step, reagent costs, the need to measure the mercury concentration for process control for minimizing silver losses, and regulatory requirements to retort otherwise stable mercury concentrates."

Jan 1, 2015

By Ryan Ward

The Missouri River Intake Screen Structure and Tunnel (MRISST) is one phase of the Red River Valley Water Supply Project (RRVWSP), a vital piece of infrastructure in the state of North Dakota to transport water to drought-laden communities in the eastern half of the state. The scope of work consists of constructing a cofferdam in the Missouri River, mining a 1,600-foot by 74-inch tunnel from a secant pile shaft near the riverbank into a cofferdam, and erecting a 40-foot Y-shaped vertical pipe structure in the cofferdam to support the intake screens. Construction personnel worked in the river through the North Dakota winter to construct the cofferdam and contended with high hydrostatic pressures and raveling sands, gravels, cobbles and boulders while mining the tunnel. Diligent planning and meticulous execution were essential to overcoming the challenges encountered below the Missouri River.

Jun 13, 2023

By M. Hakan Morcali, Onuralp Yücel, Haldun Gürcan, Serdar Aktas, Semih Özbey, Alper Keskin

"This work presents a method for the precipitation of cobalt sulfate by alcohols, specifically ethanol and methanol. The effect of the initial concentration of cobalt, the volumetric ratio of alcohol to cobalt sulfate solution, the addition of sulfuric acid and ammonia, and the effects of common ions on the precipitation percentage were investigated. The performances of ethanol and methanol were compared in terms of the precipitation percentage of cobalt sulfate, and explanations for different performances are offered. In the sulfate-based solution, the alcohol was shown to displace water ligands from the first coordination sphere of the cobalt(II) cations, which led to the precipitation of the cobalt ions as cobalt sulfate heptahydrate. SEM analysis revealed that the particle sizes of the powders produced by this method are smaller than those of commercially available cobalt sulfate. The scientific literature contains no data on the solubility of cobalt sulfate in ethanol. In this study, the solubility product constant (Ksp) for cobalt sulfate was experimentally calculated to be approximately 1.15 x 10-5.IntroductionCobalt sulfate, which is one of the most important compounds of cobalt, is used in the electroplating and electrochemical industries. The addition of cobalt sulfate to nickel-plating baths makes the treated metals brighter, harder, smoother and more ductile (Armstrong et al., 1988). It is also used as a desiccant for lithographic inks, varnishes, paints and linoleum, as well as in storage batteries, e.g., nickel-cadmium (Ni-Cd) and lithium-ion (Li-ion) rechargeable batteries (Kang et al., 2010). Cobalt sulfate is employed as a coloring agent in ceramics, enamels and glazes to prevent discoloration and as a copigment for the decoration of porcelain. In addition, cobalt sulfate has been used in animal feeds as a mineral supplement (Budavari et al., 1996; Kirk and Othmer, 1999).In the past, brewers used cobalt sulfate to prolong the life of beer foam (Kesteloot et al., 1968). Ranchers have dosed livestock with cobalt sulfate or used fertilizer enriched with this mineral to ensure that their animals obtained sufficient amounts of the trace mineral, which is essential to the production of vitamin B12. Cobalt sulfate has also been used in veterinary medication to prevent and treat cobalt deficiency in ruminants, which causes a reduction in feed intake and body weight, accompanied by emaciation, anemia and debility.Cobalt sulfate is a water-soluble bivalent cobalt salt. Cobalt sulfate heptahydrate dehydrates entirely at 420° C, and the dehydrated salt forms red monoclinic crystals."

Jan 1, 2015

By Valérie J. Bertrand, Richard W. Lawrence, Marcos G. Monroy

Two cemented paste backfill (CPB) formulations containing pyritic tailings were leached in deionized water in flooded and alternating air-flooded environments and in a simulated acid rock drainage-type (ARD) solution. Scanning Electron Microscopy (SEM), solid phase chemistry and acid-base accounting measurements documented the weathering characteristics of the CPB samples. Short-term exposures of the portland-CPB samples preferentially dissolved the cement binder to a greater extent than slag-Portland CPB mistures. In all cases, the added neutralizing potential provided to backfill by cement was short-lived and insufficient to neutralize the acid generating potential of the mixture.

Jan 1, 2000

By M. L. Free, N. Dhawan, M. S. Safarzadeh, J. D. Miller, M. S. Moats

"The drum agglomeration of nickel laterite and gold ores has been optimized through the design of experiments (DOE) using a Taguchi L16 (45) orthogonal array to determine the optimum conditions for maximizing average agglomerate size and minimizing the amount of fines. The effects of controllable operating factors including moisture content (nickel laterite ore: 34-37%; gold ore: 7-10%), retention time (2-3.5 min), drum speed (15-45% critical speed), drum load (nickel laterite ore: 8-32 %; gold ore: 6-22%) and acid concentration (150-600 g/L) on the performance of the agglomeration process were studied.For nickel laterite ore, maximum average agglomerate size and minimum percent fines (-1 mm) occurred under the following conditions: drum load (23.7%), moisture (36.5%), time (3 min), drum speed (30% critical speed) and acid concentration (150 g/L). Under the studied nickel laterite ore conditions, the most effective parameters for maximizing average agglomerate size and minimizing the amount of fines were found to be drum load and acid concentration, respectively. Drum speed had a statistically significant effect on minimizing the amount of fines. Maximum average agglomerate size and minimum percent fines (-1 mm) for gold ore occurred under the following conditions: drum load (19.3%), moisture (8.5%), time (2 min 15 s) and drum speed (40% critical). The most significant factors for maximizing average agglomerate size and minimizing the amount of fines for gold ore were found to be drum load, time and moisture.IntroductionSeveral heap leach operations have experienced problems in terms of poor recovery due to percolation issues caused by low-grade complex ores, tailings and clayey deposits. Poor percolation can lead to low metal extraction due to solution channeling or the development of impermeable/dead zones within the heap (Dhawan et al., 2012; Kappes, 2005). Improper heap building practices such as the use of loose agglomerates and inadequate attention toward the presence of clay minerals have been among the main reasons for percolation issues. During the transport of ore material, severe segregation of the material can occur. To overcome percolation problems, a major improvement was made through the introduction of agglomeration prior to ore placement. If the ore particles and agglomerates are of similar size, segregation can be avoided to a great extent (Dhawan et al., 2013; Kinard and Schweizer, 1987; McClelland and van Zyl, 1988). Agglomeration improves the uniform percolation of solution through ore heaps and is applicable to many ores, wastes and milled tailings (Bouffard, 2005; Dhawan et al., 2013). Manning and Kappes (2005) reported agglomeration/ stacking accounts for ~14% of the total heap leaching operating cost. The cost of binder is a primary contributor toward the total cost. Also, the lack of consistent quality control tests for agglomerate often leads to operational problems. The details are mentioned elsewhere (Dhawan et al., 2013). Considering the significant contribution of the agglomeration/stacking step toward the total heap leach operating cost, it is appropriate to study the agglomeration behavior and its optimization for two different ores. The reason to study the same parameters for different ores is the fact that significant variability in the agglomeration behavior of different ores has been reported to exist in industrial operations."

Jan 1, 2015

By M. H. Morcali

Pistachio nut shells, an agricultural waste biomass, and Lewatit TP 214, a commercial sorbent, were investigated as adsorbents for the adsorption of platinum from dilute hexachloroplatinic acid solutions. Before the pistachio nut shells were carbonized, adsorption percentage was 65%, whereas Lewatit TP 214 ensured almost 100% adsorption. However, after the pistachio nut shell was carbonized at 1,000° C under an argon atmosphere, the platinum adsorption (%) increased two-fold. The effects of such parameters as sorbent dosage, contact time, temperature and solution pH on adsorption were studied in detail in batch mode. The adsorption equilibrium data were best fitted with the Langmuir isotherm model. The maximum adsorption capacities, Qmax, at 25° C were found to be 38.31 and 33.22 mg/g for the carbonized pistachio nut shell and Lewatit TP 214, respectively. The adsorption of platinum on both sorbents was found to be described by the pseudo-second-order kinetic model. The results indicated that the activated carbon prepared from pistachio nut shells can be effectively used for the removal of platinum from acidic solutions.

By P. T. Bissert, L. Yan, J. R. Srednicki, J. A. Yonkey

"Refuge alternatives (RAs) are required in underground coal mines to support life post-disaster. RAs are mandated by MSHA to maintain an apparent temperature (AT) at or below 95°F (35°C) while providing a safe and livable shelter for a minimum of 96 hours. Because strata composition and mine temperatures will affect the final AT within an occupied RA, NIOSH researchers have collaborated with five underground coal mines across the US to characterize the effects of geographic location and seasonal temperature fluctuations on mine air temperature, relative humidity, and mine strata temperatures. The data collected indicates that some mines will experience greater temperature fluctuations than others, based on geographic location. The mine which demonstrated the greatest temperature differential over the course of the year resulted in a mine air temperature that ranged from 53.4°F (11.9°C) to 84.2°F (29.0°C) and a rib surface temperature that ranged from 55.4°F (13.0°C) to 82.8°F (28.2°C). This data suggests that the location and seasonal peak temperature can significantly affect the mine strata temperature, which could lead to a fully occupied RA exceeding the 95°F (35°C) AT limit over the course of 96 hours. The data reported in this paper could be used to examine the heat buildup inside an RA for actual mine conditions. Thermal simulations could be implemented to evaluate maximum occupancy ratings based on actual mine temperatures and strata compositions. INTRODUCTION In the event of a mine disaster, miners’ primary focus is to escape. Should their attempt be futile, they can enter a refuge alternative (RA) to await rescue. In 2008, the Mine Safety and Health Administration (MSHA) mandated that underground coal mines implement RAs within 1,000 ft (304.8 m) of the working face and spaced within one-hour travel distances in outby areas where persons work such that persons in outby areas are never more than than a 30-minute travel distance from an RA or safe exit. These RAs are required to provide a safe and habitable shelter for a minimum of 96 hours and to prevent the apparent temperature (AT) from exceeding 95°F (35°C) [1]. There is concern throughout the industry that in some cases the internal ambient of occupied RAs may exceed the 95°F (35°C) AT limit due to the potentially hot mine atmosphere as well as the metabolic heat generated by RA occupants and the carbon dioxide scrubbing system. The National Institute for Occupational Safety and Health (NIOSH) has conducted tests in its Safety Research Coal Mine (SRCM) and its Experimental Mine (EM) to investigate heat buildup in RAs. It was found that the number of occupants in an RA may need to be reduced based on the ambient mine temperature, which varies from mine to mine [2]. Further testing and analyses were completed to evaluate the mechanisms (conduction, convection, radiation) by which heat is transferred from an RA to the mine surroundings. Additionally, the effects of varying mine strata compositions on the heat buildup inside an RA were studied [3]. The mine strata temperatures will increase due to heat transfer from within an RA. Depending on the mine strata composition, some mines may be more thermally conductive than others. For example, sandstone is much more conductive than shale or coal (i.e. it disippates heat at a quicker rate). All things being equal, the air temperature inside of an RA after 96 hours will be higher for a mine with strata that has low thermal conductivity compared to a mine with high thermal conductivity."

Jan 1, 2017

By Roy A. Grancher

HAPPY BIRTHDAY Not only is 1971 the Centennial Year of the AIME, but it also marks the One Hundredth Anniversary of the United States Portland Cement Industry. On September 26th in 1871 David O. Saylor of Allentown, Pennsylvania, received his patent Numbered 119,413 for the manufacture of portland cement. "Cement" had been used in the United States before that. This was, however, natural cement - a direct product of rocks as found in nature, usually burned at low temperatures in open kilns. During the early 1800s this natural cement played an important role in such projects as the building of the Erie Canal. It was only after the Civil War that small amounts of high priced portland cement was imported from Europe. The successful use of this material in construction led to Saylor's experiments and subsequent patent for the manufacture of a scientifically controlled product in this country. These one hundred years have witnessed four major "ages" of cement . . . three of them occurring in the last quarter century since World War Two. The first age was the "Age of Development", a seventy-year period which saw the growth of cement and its concrete end uses as major construction materials. Next followed a period called the "Age of Demand" when, after the war, cement became in short supply relative to large building requirements. In effect a cement shortage existed. The decade of the Sixties proved to be the "Age of Reaction", with its courses of action coming in response to the problems that arose when the industry's expansion programs provided too much capacity. Today cement, and the concrete industries, find themselves entering the "Age of Reason". Overcapacity, low price, rising costs, and poor returns are several of the reasons behind that name, As these industries face the construction challenge of the Seventies, and beyond, the application of basic management principles (otherwise known

Jan 1, 1971

By A. Noble

"In coal and mineral processing, several numeric parameters are used to quantify the separation performance of unit operations. For density-based separations, the partition curve is used as the starting point for many stages of diagnostic analyses. The curve is often quantified by its midpoint slope sharpness, and this single value is subsequently used for technical evaluation, benchmarking, and comparison. While this analytical approach does depict misplacement by relative density class, it inherently prioritizes middling separation and does not consider process economics or the micro-price value of individual classes. An alternative parameter, the organic efficiency, does indirectly consider process economics, but it does not reveal information on the root cause of lost revenue or misplacement. In this paper, a new analytical approach, the partition moment of inertia, is introduced. This parameter reconciles the technical misplacement data derived from the partition curve with the economic data derived from micro-pricing. The result is a new analytical procedure that promises better use of performance data. IntroductionPartition curves are commonly used in the characterization, evaluation and simulation of various physical separators. In mineral processing, partition curve analysis is routinely applied to hydrocyclones, screens, density separators and other beneficiation technologies that are based on intensive physical properties. Graphically, the partition curve depicts the recovery of particles as a function of the physical property on which the separation is based, such as particle density, size or magnetic susceptibility. Given the probabilistic nature of many real separators, the partition curve often exhibits a characteristic S shape (Fig. 1), similar to a cumulative normal distribution. Other geometric features of the curve are also depicted in Fig. 1, including the high and low closeout, or bypass, values; the midpoint slope; and the separation cut point, defined as the property value with 50 percent recovery.Partition curve analysis was originally proposed to evaluate coal washability (Tromp, 1937). Given the limited computational resources at the time, the analytical methods relied heavily on graphical construction and interpretation of the curve. Owing to the simplicity of calculation and interpretation, many of these graphical approaches are still widely used for performance analysis today. The most common calculations are based on the slope of the partition curve at the midpoint. Increased slopes correspond to enhanced separation performance, as a perfect separation exhibits a stepwise transition from 0 to 1 at the desired cut point, that is, an infinitely large slope. One common formulation of this slope, the Ecart Probable, Ep, is derived by evaluating the slope between the 25 and 75 percent recovery points:"

Jan 1, 2016

Satisfactory means of managing growth in boom towns is a concern in mineral, energy and other large industrial developments. This session will include examinations of socioeconomic impacts, major issues such as social disruption, case studies, methods of managing growth, and concerns involving Indian lands. Innovative methods will be offered to assist the public, government, and industry in finding solutions to managing growth in rapidly growing communities.

Jan 1, 1979

By Chaoxun Zhao, TAIYOU LI, JIAQI JIN, Jan D. Miller, Chen‑Luh Lin

A large portion of the energy consumed in copper concentrators is used to reduce the particle size of the feed by crushing and grinding. The cost of metal production could be reduced if low-grade particles of cm size were removed prior to further processing. Two copper sulfide ore samples (3 × 1 cm) from Arizona were analyzed by micro X-ray computed tomography (Micro-XCT) to determine the grade of copper sulfide in each particle. For copper ore sample A, a significant number of particles contained very low amounts of copper, while some particles had copper sulfide grains of mm size. Based on Micro-XCT, it was expected that 85% of the copper for sample A could be recovered at 65% of mass rejection during preconcentration by sorting. However, in sample B (a different copper ore), distribution of copper sulfide was dispersed primarily in each ore particle, so for the particle size class of 3 × 1 cm, liberation of copper sulfide and gangue minerals was not significant. In view of the XCT results, dual energy (DE) X-ray radiography was used as a basis for sorting. Previous DE X-ray radiography of a drill core sample demonstrated that this rapid detection method can be used to identify rich or poor Cu-bearing coarse particles. Pilot scale X-ray sorting of sample A (10 × 1 cm) showed 31% rejection of a 0.08% Cu gangue product with a corresponding recovery of 90% copper.

Nov 30, 2021

By V. K. Reddy Kallam, NEHA PANDEY, Sunil Kumar Tripathy, ARIJIT BISWAS

The study investigates SO2 leaching of low-grade ferruginous manganese ores to selectively recover manganese as MnSO4 and produce battery-grade electrolytic manganese dioxide (EMD). The effects of leaching parameters (duration, temperature, SO2 flow rate) on Mn recovery were studied. Under optimum conditions, 97.9% Mn recovery was achieved. The MnSO4 leach liquor was purified and used for electrowinning EMD with 88.01% purity and battery-active γ structure.

Apr 20, 2022

By W. Petruk

An investigation was conducted to determine the minimum number of samples that must be studied by image analysis of polished sections in order to characterize a mill product and to determine the apparent mineral liberation. It was found that a representive polished section cannot be prepared from an unscreened sample that has a wide size range of particles. Similarly individual screened' fractions are not representative of the sample because minerals are partitioned during screening. Consequently the quantities of soft brittle minerals are increased in fine grained fractions and quantities of hard minerals are increased in coarse grained fractions. It is assumed that results obtained by combining data for a series of narrow size range screened fractions (1 Tyler size range) are representative of the sample, and relatively accurate apparent mineral liberation data can be obtained for a mill product by analysing each fraction and combining the data. Somewhat less accurate data would be obtained by analysing a series of screened, fractions that have a wider size range of particles (5 Tyler size ranges). Mineral liberation analyses show that the most reliable apparent mineral liberation in each screened fraction is a value taken from a smooth curve drawn through the lowest points on a graph of % free vs size. A correlation between the apparent mineral liberation in screened fractions and calculated mineral liberations using Kings liberation model is good for sphalerite but not for chalcopyrite and galena.

Jan 1, 1985

By John E. Caffrey

Mr. William. J. Montgomery in his book "Theory and Practice on Mine Ventilation stated "Ventilation is vitally important to underground mining for three reasons: First, it sweeps all workings with a plentiful supply of air and drives to the outside the smoke, gases, and contaminated air which would be injurious to the miners; second, it dilutes and renders harmless the explosive gases emitted from the strata, thus eliminating the dangerous conditions caused by the accumulation of these gases; third, it keeps the mine air as nearly as possible of the same composition as the outside air, thus giving to the miner the healthiest possible condition in which to work...." Specific methods to achieve the above basic reasons for mine ventilation were established in the Federal Coal Mine Health and Safety Act of 1969. Sections 303(y)(1); (y)(2), and Section 317(f)(4) of the Act, which can be broadly described as entrapment features, are controversial and debatable in the minds of many mining engineers in their intent and method for affecting, 303(y)(1) in certain cases prohibits the use of belt haulage entries as an intake for face ventilation, This is to say that air traveling in a belt entry will be placed into the returns and not used for face ventilation, 303(y)(2) limits the velocity of the air on trolley haulage entries. The regulations, as published in the Federal Register, have set this limit at 250 feet per minute unless a higher velocity is approved by the District Manager.

Jan 1, 1972

By Christopher R. Winter

Mining companies have sharpened their refocus on their tailings management strategies in recent years. Mining companies with tailings storage facilities that use the upstream construction method have been challenged to track the evolution of industry standards, assess risks, revise design, and communicate design revisions with regulators. While many aspects of best practices and industry standards have evolved in recent years as an attribute of continual improvement, the controlling standard in the design of many upstream dams is understanding the foundational strengths of hydraulically deposited tailings. Following best practices and industry standards, Hibbing Taconite Company managed by Cleveland-Cliffs, began the re-evaluation of foundation strengths underlying a system of upstream dams at the company’s iron ore mine tailings storage facility in northern Minnesota. Initial steps in the re-evaluation require reanalysis of design parameters and recommendations by the Engineer of Record to the Owner, which was followed by a series of meetings with the Technical Review Board to determine an initial path forward. Once a path forward and preliminary design parameters were determined, the Owner engaged with the State Dam Safety Engineer to discuss and seek approval of the plan. With continuous regulatory engagement throughout the process, further refinement of the design parameters for the hydraulically-placed tailings foundations underlying upstream dams began with field and lab geotechnical investigations. Following a review of risk assessments and trigger actions response plans, Hibbing Taconite revised its tailings storage facility operating plans and budget for the coming years. Based on the findings of the re-evaluation, reanalysis, and refinement of parameters, a paradigm shift was realized with the hydraulically placed tailings foundation strengths underlying the upstream system of dams. This paper explores the path that the Hibbing Taconite Company followed to understand the paradigm shift and construct downstream improvements. The plan involved tailings re-characterization, dam design revisions, operating plan reconciliation, budget revisions, wetland permitting, dam safety permit amendments, storm water prevention plans, borrow materials studies, new concrete decant structures and the pursuit to recognize and be consistent with industry standards.

Feb 1, 2024

By A. H. Kaksonen

Numerous reactor designs for biological sulfate reduction have been reported. Fluidized-bed bioreactors (FBR) can efficiently retain biomass and allow high mass transfer and reaction rates. This work reviews the development of various sulfate-reducing FBR processes for treating acidic metal- and sulfate-containing waters and recovering metals from bioleaching liquors. The FBR process performance was evaluated with continuous flow experiments under various operational conditions: fluidization rates, influent pH values, metal, sulfate and salt concentrations, hydraulic retention times, electron and carbon sources, and temperatures. Substrate utilization and sulfide inhibition kinetics were determined with batch FBR-kinetic experiments. An artificial neural network (ANN) model was used to predict the performance of the FBR. Sulfate-reducing bacteria (SRB) were characterized in FBRs with molecular and culture-based approaches with the aim to gain a better understating of the bioprocesses. Based on the studies, FBRs are well suited for the combined removal of metals, acidity and sulfate from water.

Jan 1, 2010

By J. B. Griffiths

Clearly there is a tremendous need for assistance in Eastern Europe since most industries must undergo major restructuring. The new governments face many dilemmas, the first task being to establish an order of priorities to deal with the numerous problems at hand. Issues such as the standard of living take low priority compared with market economy and ecological problems. The concept of a Comecon market is now virtually non-existent and trade in roubles ceased from 1991. From this time onwards countries were obliged to trade using free market prices. Governments must also avoid the economic mistakes of countries such as Poland with its high devaluation and lack of economic control and, if possible, contain inflation and unemployment. The privatization of Eastern European enterprises raises considerable difficulties, particularly for large corporations, employing anywhere from 50-100,000 people, which played a major role in the national economy. Whichever method is selected, however, still has to overcome the problem of lack of capital and evaluating the national property. For example, earnings represent only a small percentage of the value of these national industries and thus cannot convert to private ownership without foreign capital investment, either direct or as joint venture capital.

Jan 1, 1992

By A. W. Khair

Surface subsidence is a phenomenon mainly associated with longwall mining, although it can also occur if the coal pillar left to protect the surface deteriorates with time and results in the collapse of the room and pillar system. A method has been developed that utilizes physical mine models and laser holographic interferometry. This method is capable of measuring displacements as small as 5 micro- inches by means of generating displacement contours on a surface, even that of granular materials. Analysis of subsidence in room and pillar mining using models of various extraction ratios ad overburden depths along with two different types of overburden model material (sand and gelatin) has been made. The sand represented the extreme brittle conditions of geologic material while the gelatin represented visco-elastic behavior of geologic material. This paper deals with the analysis of data which has been gathered up to date, and mainly associated with the use of sand as an overburden model material. The analysis included the effect of variation of geometric parameters on surface subsidence. Among these parameters are: variation in seam depth and thickness, surface and seam inclination, and extraction ratio.

Jan 1, 1984

By Duane A. Smith

Introduction From the days of the Spanish in the eighteenth century, Colorado's San Juan mining district has attracted miners and public interest. The Spanish left behind names - San Juans, La Plata, Animas, legends of lost mines, and the remains of a few scattered mining operations. They came, but did not stay. Again in 1860-61, as a spinoff of the Pike's Peak gold rush, prospectors climbed the mountains and descended into the canyons searching for gold. They found some, not enough to convince them to remain and confront the isolation, often hostile environment and the Utes, who rightfully felt this to be their home. Not until the 1870s did miners come to stay. In their wake little camps grew in the high valleys and squeezed into narrow canyons. Nowhere else in Colorado were there more rugged mountains, a higher average elevation, nor a climate that one old Swede said was "three months of mighty late fall and nine months of winter." The San Juans proved eventually to be a mineral treasure chest. At the moment, however, the prospectors sought gold. Then they discovered silver deposits and the first rush was on. It got started just in time to be completely overcome by the Leadville excitement. At Leadville, investors almost fell over themselves to buy claims and stock in the hopes of becoming another millionaire like Leadville's own Horace Tabor. The San Juaners could only look from the sidelines and speculate how it might have been had fate been kinder. Fate was seldom kind, as these pioneers quickly discovered. From the mid-1870s on, the San Juaners wrestled with some major problems. And the fate of their district rode in the balance. The problems they faced were similar to those of other Colorado districts, compounded by their geographic isolation. Every mining district needed the best transportation system available, experienced investors combined with sound investment, and mineral reserves to develop. The San Juans offered the last in abundance. It was hoped the first two would appear. Railroads - much needed transportation link Nothing was more desired than railroad connections, the penultimate nineteenth century form of transportation. Colorado's own, the Denver & Rio Grande, resolved the issue with its mountain-hugging narrow gauge. As early as the mid-1870s, the D&RG dreamed of tapping this potentially lucrative market in southwestern Colorado. A national economic depression and then the Leadville silver excitement prevented immediate construction. Not until 1879-80 did survey crews start work.

Jan 2, 1988

By S. K. Kawatra

In most operating coal-cleaning plants, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. Reducing the pyrite recovery first requires that the primary recovery mechanism should be Identified, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not an important mechanism for recovery of liberated pyrite from freshly-ground coal when the collector is a neutral oil, and that the bulk of the floated pyrite occurs either as a result of simple entrainment or by mechanical locking with floatable coal particles. Column flotation results are also presented which show that significant sulfur reductions can be achieved by reducing levels of entrainment.

Jan 1, 1992