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By Takashi Furuyama, Sukeyuki Mori, Abel Bissombolo

"In flotation practice, a good recovery of minerals largely depends on the degree to which the valuable minerals have been liberated from the associated gangue during the grinding process. Therefore, a regular measurement of the degree of liberation can provide data for the assessment of the quality of separation and predicts the effect of changes in the grinding-classifying circuit on flotation process. Generally, the standard procedure for measuring the degree of liberation requires the preparation of polished sections - a time consuming operation that also has the disadvantage of providing an overestimated number of free particles because of the stereological nature of produced samples.The present work is an alternative approach to avoid these miscalculations and establish a system of control for fluorite flotation plants. The system deals no only with the state of liberation but also the dynamic behavior of individuals particles and mineral components within the grinding-classifying and flotation circuits. It involves methods such as sieving, x-ray diffraction analysis, study of polished sections and microscopic counting of preliminarily sieved minerals particles from a fluorite processing plant, randomly dispersed on a glass slide, but not embedded in a resin mounting medium. If a complete information on the textural properties of minerals in the ore (including its mineral components distribution) can be obtained through x-ray diffraction analysis and study of polished sections, the microscopic counting is used to determinate with enough accuracy the mineral liberation, estimate the grade of fluorite ore and products, determinate the deportment and approximate recovery of individuals particles and mineral components within the investigated circuit. For a count of 100-1000 particles in each n-size range, the counting method was found to be a particularly reliable and less time consuming operation that could substitute the chemical analysis of fluorite ore for an estimate of the grade:"

Jan 1, 2003

By Victor Avdokhin, lvan Kovlekov

"Studies of the process of concentration of gold-containing sands and technogenic resources show that the main reason of gold losses is misbalance between size of gold particles and degree of roughness of mineral bed. This results in free circulation of small gold particles in pores with following washing off the particles from the bed by turbulent flows.We elaborated design of magnetic sluice, intended for improving efficiency of recovering fine gold by optimizing magnetic field of a magnetic system on the base of forming catching coat from magnetic mineralsThe magnetic sluice includes trough-shaped body from magnetic-conducting material. On the bottom of the trough, magnets are placed, and opposite poles of the magnets are oriented outwards. Thickness of the bottom is determined to be sufficient for locking magnetic lines of force of the magnets on each other. The magnets of rectangular plate shape are placed on the rough bottom, covering the whole surface or with spare areas; the magnets are placed across the trough with alteration of rows with the same pole orientation."

Jan 1, 2003

By Carsten Gerold

The paper is giving an overview about successful operating Loesche Vertical ? Roller ? Mills (VRM) installations and summarises the main benefits of the dry compressive Loesche grinding technologies in Airflow- and Overflow-Mode. Some of these benefits are optimised energy efficiency of the grinding - classifying - circuits, increased mineral recoveries and decreased OPEX costs, at a parallel simplification of the process route. Within this paper the process values of the Loesche VRM are compared to existing or planned conventional grinding ? classifying circuits. Further advantages discovered in pilot trials and examples for new more efficient process route alternatives are given. The paper reports about production and pilot trial experiences obtained by crushing and grinding Iron Ore, Iron Ore Concentrates, Copper Shale, Copper Matte, Copper Slag, Titanium Slag, Tin Slag, Steel and Stainless Steel Slag with Loesche VRM.

Sep 1, 2012

By G. Atesok

Turkey?s EU affairs started in 1963 with the Ankara Treaty. On 31 December 1995 the Customs Union between Turkey and the European Union came into effect. In order to achieve the Copenhagen Criteria?s, Turkey, made laws parallel to the Framework Programs. On 3 October 2005, with the confirmation of ?Membership Framework Document? the negotiation process of Turkey has started. Coal had important role in the industrialization of EU and it is directly related to Energy and Environmental subjects. In this point many restriction became with the some protocols, in last decades. European Union composed Energy and Coal Policy, therefore engaged to reduce the emissions, and made new regulations. This regulations concern Turkey?s energy future, since large; but low quality of lignite reserves of Turkey, it is expected to have some difficulties with Union?s Environmental Legislation during Turkey?s congruity process. With the last natural gas import agreements of Turkey, the production and consumption of coal sunk in last seven years. However, considering environmental sustainability, the role of coal in energy production will rise up in the coming future. In this paper, in terms of Turkey Energy Sector, production and consumption problems of coal discussed and evaluated considering EU?s coal, energy and environmental rudiments.

Jan 1, 2014

By Fang Liu, Xin Tan, Zhong-ming Wang, Yan-bo Shang, Jie Zhao

"The flotation separation of sulphides bulk concentrate containing Cu, Zn, Mo and Bi, which was obtained by both table-flotation of gross sand of gravity separation of wolframite and bulk flotation of wolframite slimes using butyl xanthate and oil No. 2, etc., has been conducted by using the cyanide process in the tungsten concentrator. The process has problems of high reagents consumption (25 tonne of cyanide dosage per year) and mineral processing cost (800~1000 RMB reagents cost per tonne of by-product concentrates), high mutual containing loss in the by-product concentrates and serious environmental pollution caused by lots of cyanide-containing wastewater. In order to solve this problem, a new cyanide-free separation technology is studied, which is used to process this sulphides bulk concentrate with 8.68% Cu, 8.98% Zn, 0.26% Mo, 1.58% Bi and 40.12% S. The results of the closed circuit test show that Cu, Zn, Mo and Bi can effectively be separated from this sulphide minerals concentrate by using the reasonable flotation-gravity flowsheet, high-efficiency collectors and regulators simultaneously. The metallurgical recovery and concentrate grade are as follows: molybdenum recovery is 94.63% with 50.62% Mo content; copper recovery is 85.18% with 29.29% Cu content; zinc recovery is 75.92% with 46.49% Zn content; total Bi recovery is 65.08% with 16.86% Bi content. The new technology is an alternative to the cyanide process due to its low cost for reagents, satisfying separation results and economic profits, and solves the problem of environmental pollution caused by the use of large quantities of cyanide. Some important parameters in separating the Cu-Zn-Mo-Bi sulphides concentrate are also introduced in this paper. This study provides pretty good technical support for separating the polymetallic sulphide ores containing Cu, Zn, Mo and Bi by cyanide-free technique."

Jan 1, 2014

By S. Q. Zhu

A newly developed coal flotation collector ZFC and its flotation characteristics for five different coals were introduced in this paper. ZFC is an emulsion composed of 27% diesel oil, 70% water and 3% surfactants. The main surfactant is synthesized with oil which is environmental favorable and reproducible. Compared flotation experiments show that, at the same dosage, ZFC give 2%~5% recovery promotion than typical collector with only a slightly ash content increment, but saving 70% diesel oil. Zeta-potential and Wetting heat measurement indicate that the surfactant helps the interactions between oil and coal particles, the industrial application tests in several coal preparation plants demonstrate that ZFC is suitable both in technical and economical aspects.

Jan 1, 2014

By David Verrelli, Melissa Kistner, Leanne Smith, Chris Aldrich, Lidia Auret, Warren Bruckard

In this investigation, different mixtures of realgar and orpiment particles were floated in a laboratory batch flotation cell and multivariate image analysis was used to estimate the arsenic content in the froths. The analysis was based on the froth colour, as well as extraction of three groups of textural features, namely those based on grey level co-occurrence matrices (GLCMs), wavelets and local binary patterns (LBPs). Collectively, these features provided better information on the arsenic content of the froths than any one of the individual groups of features. Partial least squares models could explain approximately 78% of the variance in the arsenic by using all the features combined. The colour content, particularly the green component in the red-green-blue (RGB) features, provided almost as much information as each of the three sets of texture-base features individually.

Jan 1, 2014

By Robert van Hille, Alison Lewis

The precipitation of a selection of metals from both a synthetic and an actual metal-rich effluent was investigated. The experimental aspects of this study were carried out in a two-stage process consisting of a pre-treatment clarifier and a fluidised bed (pellet) reactor. Each unit operation in the two-stage process was investigated separately. The pre-treatment clarification stage at pH ˜ 5 resulted in a 99.9% removal of iron and 97.3% removal of aluminium. The pellet reactor was used to precipitate nickel as nickel carbonate from a pure stream and a removal efficiency of 99.6% was achieved. The high local supersaturation at the reagent inlet points caused the formation of a large amount of fines, but these agglomerated onto the pellets up the length of the bed. For copper precipitated as copper sulphide from a pure stream, a maximum removal efficiency of 92% was achieved. The high local supersaturation at the reagent inlets also caused the formation of a large amount of fines, but the extremely sparingly soluble nature of copper sulphide meant that the fines were not agglomerated up the length of the bed. For removal of cobalt as cobalt carbonate from an actual stream, a stable cobalt removal of only 60% was achieved. This was found to be due to the presence of magnesium, which reduced the cobalt precipitation efficiency through the formation of the magnesium bicarbonate ion.

Jan 1, 2003

By Jury P. Nazarov

"At present the traditional study of crystal lattices of nmerials in a topic “flota tion mineralogy ” is used up. The present investigation is development of the a sclsical approaches to t he analy sis of ideal crystal lattices and f ormation on the basic obtained results of consultation, having practical chara cter.The strategy of develop ment floatation reagents i s offered, which basic pr inciple – complementary assembling m olecules forming surface co mpounds so thatth e steric charact eristic of the “visitor "" (of a polar gro up of molecule SAS) corresponded to the st er ic requirements of the ""o wner"" (elementary cell of a mineral), or coincided inter molecular cavities). In itsh case process of for mation of surface com pounds ca n be considered(a first approximation) as a realization of a principle of the design er "" LEGO "".The approach, which basic idea consi deration actioonf reactant ions and ions of ele mentary cell as three-di mensional objects is developed. And at suchp paroach the laws of a ster eometry - laws describin g spatial effect s are applicable. Thus it is possible toconsider a miner al surface as a mat r ix - basis for formation of the requirem ents to polar group of a molleec cuollector, and or (it is possible) depressant. As a whole approach represents a generalized principle double com plementation, enveloping both power, and geometric asp ects (concept ""lock "" and “key "" - spatial conform ity. Figure 7 (left). Fragment of a crystal lat tice of ap atite. Oleic acid ions interact on ly with th e calcium cations locate d on a long axi s of an elementary c ell. Magenta colour represe nts the calciu m cations, which are n ot particip atin g in interactio n, as th e degree of screening by ions neighbours exceeds 1.Figure 2. (right)The illustration of space complementary. “Afterbuilding” an elementary cell of apatite (radical PO4) related molecules of the visitor – alkyl phosphate (polar group PO4). Cations of calcium are not shown."

Jan 1, 2003

By S. Banisi, A. Ghasemi, S. Zare, F. Ghorbani, E. Nematollahi

"Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Working at the maximum operating capacity of comminution equipment plays a significant role in the efficiency of the circuit. Appropriate design of cone crusher feed box could result in the choked crushing which is known as a vital factor in achieving target performance. In this research, the non-uniform cone crusher feeding at the Sarcheshmeh copper complex was studied and appropriate measures were taken to solve the problem. The problem resulted in non-uniform and high wear rate of crusher liners and high fluctuations of power draw. In recent decades, the discrete element method (DEM) has been applied successfully to study the effect of different factors on the behavior of particles flow. In this work, various designs for feed box were tested using an in-house developed DEM software called KMPCDEM©. The best feed box design obtained from the simulations was selected, constructed and installed in of the cone crushers. The new feed box design resulted in more uniform feed distribution on the distributor plate of crusher indicated by a reduction of the standard deviation of power draw measurements from 13 to 3 kWh. The better control of the crusher, 49% increase in the crusher throughput and finer and narrower product size distribution were the main outcomes of the installation of the new feed box. Furthermore, the wear rate on mantle and liners of crusher not only decreased but it also became uniform.INTRODUCTION Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Reaching the maximum operating capacity in comminution equipment is a key sign of approaching the nominal productivity of the process. Due to the effect of crusher efficiency on the downstream circuit performance, optimization of the crushing circuits has received considerable attention (Herbst, & Potapov, 2004; Quist, & Evertsson, 2010; Li, Huiqi, McDowell, Glenn R, Lowndes and Ian, 2014; Cleary, Sinnott, Morrison, Cummins, & Delaney, 2017). Improving the performance of crushing circuits not only decreases the capital and operating costs but also increases the efficiency of downstream grinding circuits (Jacobson, Janssen, & Urbinatti, 2010). In cone crushers particles can be subjected to two different modes of compressive breakage; single particle breakage (free feeding) and inter-particle breakage (choked feeding). The maximum efficiency of the cone crusher directly depends on the type of feeding arrangement (Operation Manual, 1977). An appropriate feeding must lead to choked feeding the cone crusher. If the rate and method of feeding the crushers are correctly be executed, the maximum efficiency of the crushers could be available (Jacobson et al., 2010)."

Jan 1, 2018

By Wei Sun, Ruolin Wang, Jianjun Wang, Xiaodong Li, Honghu Tang, Yuehua Hu, Anh V. Nguyen, Haisheng Han, Kefeng Chen, Zhao Wei

It is difficult to separate scheelite especially from fluorite with fatty acid collectors because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface. A simplified flotation process using Pb-BHA complexes was developed to replace the energy-inefficient Petrov’s process of using a fatty acid, increasing the recovery of scheelite and reducing the cost. The relationship between surface chemical properties (crystal chemistry, solubility, and Zeta potential) of minerals and flotation by using a fatty acid or Pb-BHA complexes was studied in detail to provide new insights into the selective separation mechanism. The results indicate that the scheelite surface exposes more O atoms than Ca and that they are negatively charged due to the anisometric dissolution of Ca and WO4, which provides the possibility for separation using selective interfacial reaction. The FTIR and Zeta potential results indicate that both chemical and electrostatic adsorption play an important role in the adsorption of Pb-BHA complexes on the scheelite surface. The XPS results of the atomic composition and binding energies confirmed the presence of the adsorbed Pb-BHA complexes and that O and Ca may be the active adsorption sites. Therefore, scheelite was able to be collected by forming either a Ca-O-Pbcollector or W-O-Pb-collector (BHA). However, fluorite was only able to be collected by a fatty acid collector and colloidal [H2SiO3]n -, and a high temperature was needed improve the selective desorption of the adsorbed fatty acid collector by forming Ca-[H2SiO3]n - on the fluorite surface, resulting in serious problems in industry. However, the Pb-BHA complexes significantly contribute to improving the recovery of scheelite minerals, simplifying the flotation process, and circulation of the residual reagents and water. The new process has been applied in Shizhuyuan Mine, and improved the recovery by almost 10%.

Jan 1, 2018

By S. P. Nagaeva, O. U. Poperechnikova, A. V. Kuptcova

"In case of free gold presence in ore, there is always problem of a choice between the gravity-flotation and gravity separation flowsheets. Study of morphology of gold being extracted by different methods allows to find the most efficient solution. One of the latest methods of gold concentration for wide range of grain size (-0.8+0 mm) is a flash flotation. The paper presents comparative testing results of flash and centrifugal separation.The goal of the studies was to determine process and flotation parameters of flash flotation. In case valued minerals are soft if compared to host rock, such minerals tend to concentrate into circulating load of grinding circuit. Thus, valued minerals can be overground, and in turn, will result in low extraction in flotation circuit. Integration of flash flotation operation into process flowsheet has been evaluated. Flash flotation operation can be successfully used not only for gold but also copper, lead, nickel and silver minerals.With low-sulphide ores being a case study under laboratory conditions, various flotation (impeller rotational speed, air flowrate) and process (pulp density, collector consumption, frother consumption, time of flotation) parameters were studied in view of its impact on gold flash flotation. Experiments were carried out under laboratory conditions using special pneumatic mechanical flotation machines.INTRODUCTIONGravity separation is used for extraction of coarse gold before cyanidation and before flotation of polymetallic ores to increase gold total recovery into gravity copper and lead concentrates.Benefit of the flash flotation is efficient recovery of coarse gold carrier particles (sulphides) thus preventing its regrinding and, as a result, low recovery. Furthermore, combination of flash and conventional flotation results in final tailings that do not require further cyanidation.Combined gravity-flotation flowsheets are designed for concentration of ores containing gold within thewide range of grain sizes (see Table 1)."

Jan 1, 2018

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"For about 20 years, the use of bacteria to control the flotation process for the production of raw material concentrates has been the subject of worldwide scientific and engineering efforts. The objective is to reduce the consumption of biologically non-degradable toxic reagents. The principle idea is to use the activity of bacteria in natural leaching processes – known since the middle of the last century – for controlling flotation processes.It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS), excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 21 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction. Pure mineral phases and mineral mixtures were used for the flotation tests. The outcome was reproducible results with technical flotation machines. The research results known so far are mainly based on investigations with micro flotation devices, which are usually used for the characterization of reagents and which do not allow a direct translation to the technical scale."

Jan 1, 2003

Certainly, one of the core processes for the recovery of fine magnetic susceptible iron ore particles, mainly hematite iron ores, is the wet high intensity magnetic separation or WHIMS. This paper outlines a variety of recent developments and innovative process designs in the JONES® type WHIMS. It highlights the latest examples of flow sheets in terms of the diversity of combined rougher, scavenger, cleaner stages and adds to this the new more advanced JONES® type WHIMS equipment technologies like the HIGH FLOW ? HF, the QUATTRO ? Q and the SPLITT OPERATION ? SP. As a result of the increase of the capacity and magnetic intensity, the specific production cost could be decreased. The high worldwide acceptance for this continuous development testifies for the success and state of the art technology.

Sep 1, 2012

By E. Isokangas

The production of minerals for economic use is a two-stage process, involving mining to extract the mineral from the ground, and processing to convert the mineral into a marketable product. Generally, mining and processing have been viewed as self-contained entities. Both have separate objectives, separate cost centres and key performance indicators (KPIs) that do not reflect the customer/supplier relationships that inherently exist. However, mining and processing operations are inter-connected and therefore intimately inter-related with the performance of one operation affecting the performance of another. Optimizing each stage separately without considering the whole system often misses potential economic benefits and energy savings. During the past fifteen years, the authors have been involved in implementing a holistic methodology ?Mine to Mill Process Integration and Optimisation (Mine to Mill PIO)? to maximize the overall profitability of the operation rather than just optimizing any individual process in a mining operation. Metso Process Technology and Innovation (PTI), along with their project partners, have conducted several projects to significantly increase their production- generating typically 5% to 20% higher throughput and improve the overall mine and concentrator performance through PIO methodology. This proven methodology has applications ranging from greenfield projects to long-standing operations with AG/SAG, HPGR or conventional grinding circuits. This paper explains the Mine to Mill PIO methodology and discusses the benefits of such an approach on the energy consumption, the overall costs and benefits of mining operations. The paper also summarizes several case studies illustrating the use of PTI methodology in a variety of applications. Keywords: integration, optimization, simulation, modeling, mine-to-mill, comminution, blast, drill, crushing, grinding

Sep 1, 2012

By V. Panayotov, M. Panayotova

"The combined use of semiconductor properties and specific flotation characteristics of minerals under different conditions with external influences ensures a possibility for process control and management. This work presents the relations between the volumetric and surface characteristics of minerals and the minerals' flotation ability (flotability), as well as the possibility for the flotability purposeful change. Results from proprietary laboratory and industrial research are presented showing how controlled impacts on minerals and flotation pulp improve flotation technology. Such an approach reveals prospects for the creation of new technologies for the minerals' beneficiation.INTRODUCTIONThe decrease of the useful components content in the ores, the increasingly complex nature of the raw materials, the increasing energy consumption per the unit of production, and the need to solve the problems related to the environment pollution require solutions different than the existing classical ones. One of the ways to find such solutions is the detailed consideration of the fundamental properties of minerals and, in particular, of minerals having semiconductor properties. The studies of Plaksin et al. (1968), Chanturia and Shafeev (1977), Chanturia and Vigdergauz (2008), Carta et al. (1973), Hoberg and Shneider (1975), Rao et al. (1992) have given an idea of the energy state of the minerals, their flotation ability, and the ways in which this ability can be changed in one or the other direction. The main line in these works is the study and use of the relationship between bulk and flotation properties of minerals. To improve the efficiency of the process, it is also necessary to consider the relationship between the surface properties of the minerals, especially minerals-semiconductors, and their flotation ability.THEORETICAL BACKGROUND IN BRIEFA quantitative estimation of energy changes in a solid phase in the process of flotation may be made by taking in account the changes in the Fermi level. Its position in the forbidden band is an indicator about the direction and the intensity of electron exchange between solid and liquid phases. The Fermi level energy EF enables the estimation of flotability, intensity of needed external impact before flotation, as well as efficiency of the process going on. Quantitative estimation of these processes can be made by means of the flotability coefficient Kf."

Jan 1, 2018

By D. R. Nagaraj

The traditional (popular) approach to reagent development and optimization, which has become entrenched in both research and practice for many decades, is highly reductionistic, incremental and costly, does not produce robust chemical solutions, and is not sustainable. There are also several other key drivers and changes in the mineral industry that clearly warrant a new approach. In response to these, an intense effort was made at Cytec over the past fifteen years to develop a meaningful, efficient, and sustainable approach to develop new reagents and robust chemical solutions in mineral separations. This effort culminated in three important outcomes: a) development of the holistic approach, called FLOTATION MATRIX 100? process, b) novel reagents, and c) enhanced application knowledge for reagents. In this paper, the efficiency, utility and power of the holistic approach will be demonstrated with examples using both existing and new reagents in the processing of Cu-Au, Au and Cu-Mo ores.

Jan 1, 2014

By O. Güven

In recent years, there is an increasing demand on manganese consumption which stems from the important role of manganese in carbon steel production. And the growing need for manganese ores makes the beneficiation of low-grade manganese ores more economical. In this study, the characterization and beneficiation studies were carried out to propose a flow sheet for typical low-grade Turkish manganese ores. For this aim, different gravity separation methods were applied. According to the mineralogical analysis, the major mineral phases are pyrolusite (MnO2) and psilomelane (MnO2) while the major gangue mineral is radiolarite. Gravity separation tests were accomplished by using jigs, shaking table, MGS (Multi Gravity Separator) and in order to obtain products with high Mn ratio, high intensity magnetic separation was also performed. As a result, different combinations of flow sheets were utilized and a concentrate assaying 56.5% Mn with 85 % recovery was obtained.

Sep 1, 2012

By S. Saha

Minerals in coals cause operational problems in various coal utilization technology as well as act as diluents towards its heat value. Indian coals contain higher percentage of mineral matter compared to foreign coals due to its formation through drift origin. Efficient utilization of high ash coal in environment friendly manner is the driving force for the development of clean coal technology. Coal gasification offers practical means meeting stringent environment controlled parameters for producing power, chemicals, liquid fuels and clean energy on a single platform. It is well accepted that gasification technology has sufficient potential for sustainable development of clean coal technology. Gasification reactivity depends on the coal properties and operational parameters as well as minerals present in coal. Minerals not only create operational problems but on the other side also catalyze the gasification and combustion reaction. Therefore to understand the effect of minerals on the gasification reactivity, present paper proposes to study the variation of gasification reactivity with various gravity cuts such as, 1.4-1.5; 1.6-1.7; and 1.8-1.9 of a selected coal. Gasification reactivity has been studied by thermo gravimetric analyzer (TGA) using CO2 as gasifying agent. Surface properties such as, true density, apparent density, porosity, surface area of different gravity cut samples have also been measured to find out the effect of gravity separation on gasification reactivity. Keywords: gasification, reactivity, mineral matter, gravity separation

Sep 1, 2012

By Chris Plackowski, Bruckard. Warren J., Anh V. Nguyen

"Enargite is a significant penalty mineral in the copper industry and its separation from many copper sulfides by flotation is difficult. The separation may be crudely achieved using selective oxidation techniques or through the use of pulp potential control. This paper summarizes our latest contributions to a better understanding of enargite surface electrochemistry and hydrophobicity. Oxidation, roughness, hydrophobicity and species formation on the surface of natural enargite were examined by a novel experimental approach that combines electrochemical techniques, atomic force microscopy, X-ray photoelectron spectroscopy and droplet evaporation tensiometry. It allows for synchronized electrochemical control and examination of the oxidative surface morphology, speciation and hydrophobicity of enargite at pH 4 and pH 10. At low pH, surface layer formations consisting of metal deficient sulfide and elemental sulfur were identified associated with a limited increase in roughness and heterogeneous distribution of surface species produced by initial rapid dissolution of Cu, followed by diffusion limited surface layer deposition. At high pH, a similar diffusive mechanism associated with oxidation products consisting of copper sulfate and hydroxide and a significant increase in surface roughness were established. Receding contact angle measurements showed no significant difference in the contact angle on a surface oxidized at pH 10 and the freshly polished surface. Contact angle increased from 46° on the polished surface to 59° after oxidation at pH 4. Competing effects of hydrophilic copper oxides and hydroxides, and hydrophobic species of elemental sulfur on the mineral surfaces under oxidizing conditions at pH 4, and the change in surface roughness at pH 10, contribute to the changes in enargite hydrophobicity under electrochemically-controlled oxidation conditions. Most likely, both surface species and surface roughness produced by oxidation are critical to the changes in the wettability of enargite and other sulfide minerals."

Jan 1, 2014