Search Documents

By Michel Brissette, Shaheer Sanuri, Veroljub Mihajlovic

"The main purpose of geometallurgy is to improve the mine planning by mapping hardness and throughput into the mine block model using geostatistics to eliminate the large production fluctuations caused by the ore hardness variability coming from different parts of the pit. However, not all grinding testwork available commercially can be applied to geometallurgy because of large amount of sample required and the associated cost per test. Geometallurgy is now being used in designing grinding mill but as the mining project progress, the accuracy of engineering must improve from 30-35% during the scoping study to 10-15% at the bankable feasibility stage and less than 5% for Engineering Procurement and Construction Management. For SAG milling, the SAG Variability Test (SVT) is an abbreviated version of the standard SAGDesign test developed for this geometallurgical need. The same amount of ore than the original test is ground for three cycles into an open batch SAG test and then the SAG pinion energy is predicted to the standard end point of 80% passing 1.7 mm. For ball milling, a Bond Variability Test (BVT) was also developed using the SAG ground ore from the SVT. The Bond ball mill grindability (Gpb), corresponding to the average of the net grams per revolution from the last three cycles of the Bond test, is also predicted from the third cycle. The relative error for both the predicted SAG ore hardness (WSVT) and Bond Work Index on SAG Variability ground ore (Sv-BVI), in kWh/t, averaged 5.5% and 3.8% respectively compared to the SAGDesign testwork values and are within 7% and 10% respectively from plant benchmark and within 7% from the samples sent to all partner laboratories. Both tests can be continued to measure the true hardness necessary for mill sizing. This article discusses the development of these two new tests, SVT and BVT, their potential use and accuracies in any geometallurgical program."

Jan 1, 2014

By T. Suzuki

Acid leach liquors from spent lithium-ion batteries employing lithium cobalt dioxide (LiCoO2) as a cathode active material contain valuable metals such as cobalt and lithium, as well as common metals such as aluminum and copper. The objective of this study was to develop a hydrometallurgical process providing a high selectively between aluminum, cobalt, copper, and lithium from hydrochloric acid solutions. Batch experiment results showed that selective hydroxide precipitation approach was not suitable because a significant amount of cobalt and lithium was co-precipitated with aluminum and copper hydroxides. In contrast, batch experiments and the subsequent data analysis indicated that the sequence of solvent extraction circuits using PC-88A, Acorga M5640, and tri-n-octylamine (TOA) extractants effectively separates four metals of interest. In the first circuit of the proposed process, copper was selectively extracted by Acorga M5640 at the pH 1.0-2.0. Aluminum, cobalt, and lithium remain in the aqueous phase. In the second circuit, aluminium is selectively extracted by PC-88A at pH 2.0-2.5. For the separation of remaining cobalt and lithium, Acorga M5640 provided higher separation efficiency compared to PC-88A single extractant and PC-88A/TOA mixed extractant. However, the stripping efficiency of cobalt from the Acorga M5640 organic phase was found to be low (less than 10 %). Therefore, PC-88A/TOA mixed extractant rather than Acorga M5640 is an advisable choice for the separation of cobalt and lithium. Keywords: spent lithium-ion secondary batteries, solvent extraction, lithium, cobalt

Sep 1, 2012

By C. L. Lin

Previous research on particle damage during high pressure grinding roll (HPGR) crushing was limited by the resolution of point-projection micro CT systems and the extent of damage was described by the percent of particles cracked for different crushing methods as determined at a voxel resolution of 40 microns. With recent advances in X-ray optics, the resolution afforded with point-projection micro CT systems has been improved by at least an order of magnitude using a lens-based X-ray micro CT system. With the use of X-ray lens imaging the resolution is determined by the lens rather than by the spot size of the micro-focus X-ray source. The high resolution X-ray micro CT (HRXMT) system made by Xradia with a voxel resolution of less than 1 micron is now being used for the characterization of particle damage during HPGR crushing. In this way, the direct 3-D determination of the internal damage of crushed ore particles which vary from 40 mm down to 100 microns in size is being studied at a voxel resolution of a few microns. The number, size, and shape of cracks can now be measured at this improved resolution and for the first time the specific crack surface area distributions of the crushed product can be calculated from HRXMT images using specially designed software tools for 3D analysis. Results from selected crushing operations are presented. Copper ore particles from HPGR crushing at high pressure (6 N/mm2) are severely damaged having crack specific surface areas as great as 10 mm2/mm3. Keywords: HPGR, particle damage, X-ray micro tomography, crack surface area

Sep 1, 2012

By W. P. Roux

With depletion of higher grade iron ore reserves, and the need to process finer, lower grade material; there is a need to better understand the recovery efficiency of jigging process. The use of Positron Emission Particle Tracking (PEPT) was examined as a technique, to study the motion of particles inside a laboratory batch jig. PEPT is a noninvasive method that can provide three dimensional kinetic data of a particle during jigging. Particles with different densities and sizes were traced under the same jigging parameters, to obtain a data set that can be used for the development and verification of jigging models. From the results, detailed information on the stratification rate of a particle was obtained, with adequate resolution to see particle movement through an individual pulse. Detailed data of this nature is critical for the validation of CFD and DEM models. Keywords: positron emission particle tracking, jigging, jig models

Sep 1, 2012

By Jens Markowski

The EU Directive 2000/53/EC on end-of life vehicles (ELVs) states that in 2015 at least 85 wt.-% of a vehicle has to be reused or recycled. This result in the obligatory need to separate additionally metallic and other components of the automotive shredder residues (ASR), so that they can be professionally prepared for recycling and reuse further. Currently the iron-containing fines of ASR are deposited as it is not possible to process in blast furnaces due to its particle size (< 4 mm), composition and material properties. Additionally problems are also caused in handling and transportation (dust) of the material. This work focuses mainly on the ASR materials utilization in blast furnaces. Material was further separated into two consecutive fractions by carrying out repeated crushing and magnetic separation twice. The two fractions have significantly higher iron content (up to 75 wt.-%) compared to the initial material mixture. The materials were assessed for their usage in blast furnaces based on the possible pelletisation with and without binders, stability of pellets, shape and size of pellets, etc. Pelletisation of the material was carried out with a single mould pellet press. Further lignite coal was added to the mixture as additive which improved the pelletisation behavior and the mechanical stability of pellets. Lignite coal was chosen as a reducing agent in the blast furnace process contributing towards additional savings in energy supplied. The experiments reveal that the production of pellets from iron-containing fines is possible with a lignite coal admixture of about 15 wt.-%. These pellets displayed good mechanical stability and can be used in blast furnace processes in recovery of the recyclable metals which are currently not recycled. The recycling of not yet recyclable metals would reduce the deposition and can be easily adopted into the economic cycle by their utilization. Keywords: Automotive shredder residue (ASR), FE-fines, pelletisation

Sep 1, 2012

By Barbara Peszko, Tadeusz Tumidajski

"Various methods are used to identify the grain composition of fine-grained materials because so far the best notion of the grain size has not found and there is no single method to define grain size. In practice the most important are the following grain sizes: sieve diameter dt, effective diameter de, substitute diameter d2 and statistical diameter dst. The mentioned sizes are connected with the methods of analyses. Methods are correct but measure of different diameters of grain and their results are different.The most important methods of granulometric composition analyses are the following: the sieve analysis, the sedimentation method and the conductometric (Coulter-Counter) methods. In each of these methods various physical features connected with the grain size are measured.Sizes of grains defined by different formulas or measurement methods are associated mutually by dependencies, which are results of differences in their determination or calculation ways.In order to determine principles of results comparison the classification analysis results on linearly or non-linearly connected was made. Analyses which results demonstrate the same type of grain size distribution are treated as linearly connected. It is based on the general formulae which determines the probability density function of random variable which is the function of another random variable having the known density function.In order to show the difference in the grain composition of the same material qualified by different methods, three methods of investigations were distinguished. They are: the sieve analysis performed on precise sieves, the sedimentation analysis performed by means of a sedimentation balance “Sartorius” and the microscopic analysis performed after preparing a microscopic slide where the grain size was measured by the Martin’s method.The materials selected for the analysis were quartzite and glass, which are the material of high purity.The obtained results of mentioned above three types of analyses were approximated by distribution function of four distributions: Weibull, log-normal, cut Weibull and Gaudin-Schuhman."

Jan 1, 2003

By T. Fujita

A high-grade fluorite ore is converted into hydrogen fluoride to produce many kinds of materials containing fluorine. Recently, it is becoming necessary to use low-grade fluorite ore due to the depletion of high grade ore. The low-grade fluorites usually have impurities such as SiO2, P, CaCO3 and arsenic. The most impurities such as SiO2, CaCO3 and P can be removed by using flotation method. However, the removal of arsenic is difficult, and the arsenic contamination decreases the hydrogen fluoride production percentage. The novel technologies for processing low-grade fluorite ore are urgently needed, in order to lower the arsenic concentration to less than 100 mg/kg. In this study, the removal of arsenic from low-grade fluorite ore has been investigated by means of an autogenous grinding using tower mill in sulfuric acid aqueous solution and 0.3 mm zirconia balls in water. The nano grinding in water can prevent the dissolution of 0.3 mm size zirconia balls as grinding media by sulfuric acid solution. Experimental results showed that the arsenic concentration was reduced from 260 mg/kg to 90 mg/kg and CaF2 recovery reached 90% by this process.

Sep 1, 2012

By Gábor Mucsi, József Faitli, Imre Gombköto, Sanjay Kumar, Zoltán Molnár, Balázs Ráczkevi, Ádám Rácz

"Generally, fly ash particles are very fine (< 100 ?m), mainly spherical and glassy materials form an outer shell on it. This paper deals with the laboratory investigation of ground fly ash based geopolymer. This material can be applied in many fields, mainly in the construction industry, e.g. non-structural elements, concrete, pavements and products, containment and immobilization of toxic, hazardous and radioactive wastes, advanced structural tooling and refractory ceramics, and fire resistant composites used in buildings, etc. The preparation of fly ash using high energy density milling is presented. Systematic experimental series were carried out in order to optimize the preparation process. The particle size distribution (LPSA) and structure of fly ash (FTIR) and the uniaxial compressive strength ,the permeability and structure of geopolymer product, furthermore the rheology of geopolymer paste were investigated. The product properties were studied as a function of the fly ash fineness. As a result of the investigation the relationship between the grinding circumstances, the ground material properties and the geopolymer characteristics was identified. It was found that the above mentioned physical properties of the geopolymer strongly depend on the grinding process."

Jan 1, 2014

By Y. Y. Zhou

This paper introduces the application of CRIMM high-gradient magnetic separator in refinement of feldspar powders as well as the supporting technical outfits needed by the refining process with the high-gradient magnetic separator as main equipment. It could reduce the content of Fe2O3 to 0.03% with a deferrization rate of 85.88% from the feldspar raw ore containing 0.17% Fe2O3by using the above refining technology, producing an ultrapure feldspar product.

Jan 1, 2014

The multiphase reactive flow in process equipments, e.g., fluidized beds, involves complex coupling among flow, heat/mass transfer and reaction kinetics over scales ranging from molecules, sub-particle eddies up to equipments. Conventional two-fluid model (TFM) ignores the effects of meso-scale structures, and hence is not suitable for describing the intrinsically multi-scale heterogeneity within multiphase systems. To be consistent with the meso-scale structures, we proposed a structure-dependent multi-fluid model (SFM), and closed its drag force by invoking the stability condition defined in the energy-minimization multi-scale (EMMS) model. The SFM reduces to the conventional TFM if homogeneous distribution is assumed within each grid, and reverts to the original EMMS model if it is used to describe steady state, global behavior of a fluidized bed. The multi-scale computational fluid dynamics (CFD), which is characterized by coupling of TFM and EMMS drag coefficient, can then be viewed as a simplified solution of the SFM. We demonstrate that the SFM significantly improves the accuracy and at the same time enables higher efficiency by allowing for much coarser grid used than in TFM. Recent application of it in 3D, full-loop, transient simulation of industrial processes, e.g., fluid catalytic cracking, coal combustion, gasification, kaolinite clay calcinations, shows its advantages in helping design and troubleshoot multiphase process equipments. Keywords: meso-scale, SFM, multiscale, CFD, simulation, structure, EMMS, multiphase

Sep 1, 2012

By Kazimierz Trybalski

"Simulation methods have a big potential in the studies and analyses of complex technological processes and schemes. The simulation method used jointly with flow diagrams and related transmittance models allows describing and analysing dynamic characteristics.The paper presents results of simulation analysis of dynamic characteristics of ore dressing system, called closed circuit mill-classifier-mill. Such systems are widely used in ore processing plants. The system was analysed as a typical system with material feedback, to establish its dynamic characteristics.Flow diagram conforming to the technological scheme is presented in a figure. Transmittances shown in the scheme are defined as follows:GMP - transmittance of rod mill,GP, KZ, GW, KZ - transmittances of overflow and underflow streams of spiral classifier, respectively,GMK - transmittance of ball mill,GT - transmittance of underflow stream from classifier to ball mill,GU, MP, GU, MK - fraction transmittance of outflow streams of rod and ball mill, respectively, summed up at classifier input.Taking into account, in base of carried out analysis the transmittance forms of individual system elements. The calculations are based on numeral forms of transmittances of individual blocks, defined through industrial experimentation.Step input function to rod mill was assumed to be a step of mass ore flow rate to the mill. Responses are defined as product densities.This figure demonstrates the way of input signal transmission by consecutive elements of the system and shape of these elements' responses. It can be noticed that step signal undergoes gradual change from the stream of the first order to those of higher and higher orders as a distance from process leading edge increases. Simultaneously, the impulse signal is subject to systematic smoothing and decay. From the technological point of view, the most important is response stream in point 5 (on the above figure) that characterises classifier overflow, which is a final product of this system."

Jan 1, 2003

By Z. Chen

This study is concerned with the behavior of bubble clusters in a well-controlled turbulent flow. We used a specially designed cell where the bubble aggregates could be formed and exposed to breakage by a rotating impeller. The effects of impeller speed and the concentration of collector on cluster behavior were studied. It was found that the size of the clusters increases with the concentration of collector used. We also found that although the clusters could easily be destroyed under the action of impeller, they could reform, especially at lower impeller speeds. It was observed that the size of the bubbles arriving into the impeller region in the absence of particles before breakage was considerably higher than the size of the clusters formed at the same impeller speed. It appears that both cluster breakage and re-formation take place simultaneously, and the extent of formation and regrowth is mainly determined by the hydrophobicity of the particles and the impeller speed.

Sep 1, 2012

By I. Zh. Bunin, G. K. Khachatryan, N. E. Anashkina

For optimization of diamond processing technology the influence of nanosecond high voltage pulses on mechanical and technological properties of diamond crystals and kimberlite rock-forming minerals (calcite, olivine, serpentine) was investigated. Using methods of Fourier Transform Infrared Spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), microscopy and mikrohardness measurement the changes of structural, physic-chemical surface properties, and microhardness of minerals as the result of impacts, was studied. Non-thermal impacts caused a decrease of kimberlite rock-forming minerals microhardness in general to 40-66% as the result of surface microstructure destruction which is caused by formation of micro cracks, traces of surface breakdown and other defects. At the same time, the pulse energy impact on natural diamonds led to formation of B2 type crystal lattice microsift defects, elevated concentration of which increases the hardness properties of crystals. The obtained result indicates possibility of applying pulsed energy effects to improve the softening efficiency of diamond-bearing kimberlites rock-forming minerals without damaging the diamond crystals and ensuring their preservation by the subsequent grinding of ores. By IR and X-ray photoelectron spectroscopy revealed that processing by hight voltage pulses causes a change of natural and synthetic diamonds surface functional cover composition. Short-term exposure (~ 10 - 30) leads to detachment and partial destruction of secondary phases mineral films on the surface of natural technical diamonds, increasing floatability and hydrophobicity of crystals. However, with increasing duration of treatment (~ 30 - 150) occurs surface hydroxylation (found by XPS for synthetic diamonds), as a result of diamond surface layer oxidation. The effect of increasing the natural diamonds flotation activity by 14% (from 47% to 61%) was experimentally established as a result of processing diamond crystals with nanosecond pulses (~ 10-50 sec), which indicates the principal possibility of using pulsed energy impacts to intensify the diamond flotation during processing diamond-bearing kimberlites.

Jan 1, 2018

By Ronald Díaz

"Cerro Corona is a porphyry ore with different geometallurgical units and alterations produced by an extensive family of geological failures that have determined a special type of mineralization. With the increasing depth of the mine, it is estimated that the host rock will be less altered. Consequently, the ore will have a higher resistance to breakage accompanied by associated problems such as lower throughput. In light of this reality, various projects have been carried out with the objective to optimize mineral processing of ore with low clay content and high hardness, including reducing the blasting grid, increasing the load factor, using adequate mixtures of hard ore, reducing crusher settings, installing air guns in the transfer chutes, increasing ball charge, and changes in the lifter design, wear control in the hydrocyclones, syntonization of control logics, supervisor control of the SAG mil, characterization of feed ore, etc. However the most important factor was the teamwork between mine and plant personnel, aiming at common objectives for the company. These projects started in 2011, including characterization of mineralogical domains, breakage and blasting characteristics, and also a revision of the actual operating conditions in the crushing and grinding circuit. The development of different designs of the SAG mill lifters and the unloading grates, a 16% ball charge increase, improvements in the blasting process, reduction of the primary crusher setting, weight reduction on the feed lid, and variation of operational parameters, all allowed the company to achieve its objectives of maintaining impact control and steel recharge within the expected operational parameters. The achieved throughput is above design capacity, sustainable, and not without new challenges for maintaining and optimizing this production level."

Jan 1, 2014

By D. Saramak

Investigations over the application of hybrid comminution circuits with the High-Pressure Grinding Rolls (HPGR), on the main comminution stage on the basis of the lime and cement industry, were presented in the paper. Two crushing circuits were investigated, the first HPGR-based and the other one, with conventional jaw crusher. The results presented in the article confirm that hybrid comminution circuits with the application of HPGR are innovative ones, and they assure achieving the technological and economic competitiveness in the mineral raw materials processing industry. They are much more favorable in terms of the final product fineness and capacity but insignificantly less effective about the unit energy consumption. Technological performance of conventional crushing circuit and HPGR-based one were also compared in lab scale. The circuit with HPGR application gives finer products both on crushing and grinding stages. The average particle size reduction obtained in HPGR-based circuit is as much as twice greater, comparing to the conventional crushing devices. Keywords: comminution, HPGR technology

Sep 1, 2012

By Paulo Sérgio de Oliveira, Joaquim D. Donda, Andreia C. Rosa

"The search for energy efficient technologies for comminution processes is constant in mineral processing studies, since those processes represent a major percentage of operational costs. In this context the use of stirred mills is increasing, especially for ultrafine grinding. Although many authors claim that these new equipment are more efficient than the conventional ball mills, there were very little chances to prove that in a practical way, since there are few industrial circuits where those technologies perform the same duty. Therefore, the regrinding circuit of Germano second concentrator offers an interesting opportunity: a vertical mill operating in parallel with two ball mills. During almost two years of operation, several sampling campaigns were conducted to evaluate the vertical mill performance and to compare the operational data of the three mills. The industrial data was also compared to jar mill tests results, which are monthly conducted in Samarco labs in order to predict the specific energy consumption required by the ore fed to these circuits. The vertical mill demonstrated the same ability to achieve the product specifications of the ball mills while proved to be able to reduce the medium specific energy consumption in about 40%."

Jan 1, 2014

By Y. H. Tang, H. Y. Zhang

"Tailings from lead-zinc mine contain plenty of dolomite and low-grade fine-grained barite, which is difficult to enrich by mineral processing. Since the density of barite and dolomite has some differences due to the fine dissemination size in a complex sedimentary, the gravity separation tests were conducted with no results obtained. The magnetic separation was conducted to remove the magnetic gangues, and the results were not satisfactory because of the gangue minerals such as limonite and others were low in content. The results of floatation tests showed that the mineral separation of barite and dolomite is quite difficult because that they have similar mineral floatability. Experimental research shows that the good results can be obtained by “desulfurizationbarite floatation” processing with the new depressant TS. The barite concentrate containing BaSO4 91.27%, BaSO4recovery is 70.25% when sodium dodecyl sulfonate serves as a collector and TS as the depressant.INTRODUCTIONBarite is an important mineral material. Often associated with other minerals, it usually needs to be separated by mineral processing in order to meet the application requirements. The main barite beneficiation methods include hand sorting, gravity separation, floatation, magnetic separation, acid leaching, etc. Usually barite associated with oxide ore such as fluorite dolomite, quartz ore etc. are also associated with sulfide ore such as pyrite, sphalerite and galena. The separation between barite and sulfide ore (such as pyrite) is easy. On the other hand, the separation between barite and oxide ore (such as dolomite and fluorite) is very difficult. There are quite a lot of reports on the separation between barite with fluorite dolomite however the separation between barite and dolomite is seldom discussed.The ore properties are quite complex attributable to mineral assemblage containing a large amounts of dolomite. As the density of barite and dolomite has some differences, gravity separation between them is usually easy. The gravity separation tests were conducted with no results obtained due to the fine dissemination size in a complex sedimentary. The magnetic separation was conducted to remove the magnetic gangues, and the results are not satisfactory as the gangue minerals such as limonite and others were low in content. Due to the fine dissemination and intimate association of minerals, and barite and dolomite contain the same group ions of Ba2+, Ca2+ and Mg2+, the results of flotation tests showed that the mineral separation between barite and dolomite by flotation means problematic. Previous studies have been conducted by several institutions but none to date has come up with a satisfactory process in dealing with the deposit. This may be attributable to: high cost of reagents; unsatisfactory performance. Therefore, the key to the flotation separation of barite and dolomite is the application of selective inhibitors. Based on previous test observations and years of extensive research experience in barite processing technology, with the new depressant TS has selectivity inhibition on dolomite developed and used, good results can be obtained by “desulfurization-barite flotation”, which allows barite in the lead-zinc tailings to a comprehensive recovery."

Jan 1, 2018

By S. Banisi, E. Arghavani, Gh. Parsapour, S. Mousavi

Maximization of water recovery in thickeners is an essential step in the mineral processing industries. The Gol-E-Gohar iorn ore processing plant uses a center pier thickener with a diameter of 38 m and depth of 4 m. The feed rate is 50 t/h solids with a concentration of 5% (w/w), and it has been designed to provide an underflow containing 50% solids. The performance of the thickener was not as expected judged by the overflow stream containing 0.6% solids and water loss of 52 m3/h in the underflow. A criterion called the index of flocculation incorporating the perimeter-based fractal dimension of flocs, floc size, and settling velocities was proposed and used to determine the optimum flocculant dosage which was found to be 20 g/t. The fractal dimension of flocs in a pulp containing 5% solids was found to be between 1.16 (no flocculant) and 1.56 (40 g/t flocculant) which indicated highly branched and loosely bound structures for the flocs as flocculant dosage increased. At these conditions, the size of the flocs which was recorded by a digital microscope increased from 93 µm to 403 µm. A new feedwell with a special design with the aim of preventing flocs breakage and maximizing energy dissipation of pulp was constructed and installed. These modifications led to an increase in the thickener drivehead torque from 5% to 18% of the rated torque, indicating a higher bed depth. Finally, installation of a PID controller reduced the drivehead torque relative oscillation from 52.0% to 12.7%. These changes increased the solids concentration of the underflow from 49.0% to 56.9%, decreased the overflow solids concentration from 0.6 % to values smaller than 0.01% and resulted in a reduction of 27% in water loss in the thickener underflow.

Jan 1, 2014

By Rodney J. Hundermark, Sharif Jahanshahi, Shouyi Sun

"The major platinum producers in South Africa make use of electric furnaces for the melting of platinum group metal (PGM) bearing nickel – copper concentrates. To gain better understanding of the furnace operation, research was conducted at CSIRO Minerals in Melbourne, Australia. One aspect of the research project was the investigation of the factors affecting the electrical conductivity of melter type slags.Electrical conduction in slags can occur through two mechanisms: ionic and electronic. There is good understanding of the ionic mechanism. In slags containing high levels of iron, the dominant mechanism is electronic as a result of charge hopping (electrons or holes) between ferric and ferrous ions. There is limited understanding of the electronic mechanism and one of the aims of the research was to investigate this mechanism further.Experimental work was carried out at 1450 °C on Al2O3–CaO–FeOx–MgO–SiO2 slags similar in composition to the melter slags (typical composition range (wt%): Al2O3: 5, CaO: 5-15, FeOx: 10-30, MgO: 15-25, SiO2: 40-60). The approach was to vary the oxidation state of three different basicity slags and measure the conductivity response. The slags had molar (CaO+MgO)/(Al2O3+SiO2) ratios of 0.43, 0.64 and 0.94 and FeOx contents of up to 40wt%. A twoelectrode technique was employed with a shallow layer of slag contained in a magnesia crucible. The small amount of slag facilitated relatively quick equilibration (up to one hour) with the gas atmosphere. Experiments were typically started in air and sequentially reduced using different ratios of CO and CO2 gases.Conductivity increased with increasing basicity and increased significantly with iron oxide content. Above 20wt% FeOx, electronic conduction was significant and the conductivity varied with the oxidation state of the slag. The typical response of the conductivity to the change in oxidation state was the following: starting in air, as the slags became more reduced, the electrical conductivity increased to a maximum at around pO2 = 10-7 to 10-4 atm and then decreased with further reduction. The value of the pO2 at which the maximum occurred was dependent on the total iron oxide content and basicity of the slag. The magnitude of the conductivity of the slags increased with increasing FeOx content in a range of 20 to 170 S/m for 20 to 40wt% FeOx. For a given FeOx content in the slags, the oxidation state dependence of the conductivity varied with slag basicity. The trend observed was that the maximum in the conductivity occurred at higher oxygen partial pressures for the lower basicity slags."

Jan 1, 2003

By Edson Charikinya, Pierre-Henri Koch

"The extraction of mineral values from ore requires liberation followed by separation steps. Liberation is achieved by size reduction operations which are energy inefficient processes typically dominating the energy consumption in a mineral concentrator. As the grade of ore reserves declines, future viability of mineral operations will be determined by energy costs of comminution. The application of high power microwave energy to secondary crusher products has been suggested as a possible commercially viable thermal treatment method for reducing comminution energy and improving value mineral liberation. Recent studies have shown that microwave pre-treatment of coarse sphalerite ore particles (> 5mm) at specific microwave heating energies (1-3 kWh/t), induces microfractures and creates new crack surfaces. This suggests that subsequent crushing of these microwave treated particles could yield enhanced liberation. However, limited studies have been carried out investigating the mode of breakage and the extent of enhanced liberation in that case. The objective of this study is to develop numerical methods for quantifying the extent of enhanced liberation and mode of breakage in crushed microwave treated and untreated particles. Sphalerite ore particles representing small (-5+4.75) mm, medium (-16+9.5) mm, and large (-25+19) mm HPGR and cone crushed particles were microwave treated at specific energies between 1-3 kWh/t. Cracks in the ore particles before and after microwave treatment were analysed with QEMSCAN and numerical models of the measured particles (before and after microwave treatment) were developed in MATLAB. The propagation of random and non-random cracks was investigated by simulating comminution of the modelled treated and untreated particles. Results of this study demonstrate that the breakage mechanism and the liberation of valuable minerals from gangue in microwave treated and untreated particles is significantly different. This study contributes to the development of numerical tools to quantify crack propagation in heterogeneous ore particles."

Jan 1, 2018