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By Valery V. Kostjuk, Victor. N. Bredikhin, Alexander I. Shevelev, Evgeny A. Kazban

"The investigations to improve the process data have been done in order to stabilize the functioning of drying units. The scheme of turnings preparation with centrifuging and subsequent thermal degreasing (tandem) is proposed. To improve the efficiency of the process the scheme of reclamation of the centrifuge fugate is developed with production of oil and service circulating water. Empirical dependences of the turnings temperature influence on the lubricant-coolants content in centrifuging are gained. When the turnings temperature is increased to 80 C the residual content of LC is decreased by 1.5%. The investigations aimed to improve the preparation of non-ferrous turnings have allowed to decrease the melting loss by 15-20%; to stabilize the process of thermal drying of turnings; to decrease sharply (by 60- 70%) the volume of LC combustion products; to reclaim the centrifuge fugate and produce oil and servicecirculating water.Non-ferrous turning and primarily aluminum and copper alloys turning is a stable source of secondary raw materials for metallurgical works.Direct by lubricant-coolants (LC) of various types: synthetic, semi synthetic, oily and emulsions.On the base of investigations concerning various methods of the non-ferrous turning processing the favorable one has been selected taking in to consideration the economy, ecology and quality of the finished product (alloy). Two-stage process is developed. The main idea of the process is the elimination of the lubricant-coolants (LC) to the limit specified in advance. The applied method is centrifuging with subsequent final elimination of LC by thermal method.Constant value of LC content at the inlet of the thermal unit excludes practically the oxidation of metal and as a consequence increases the output by 10 –15 % in metallurgical processing."

Jan 1, 2003

By Francis Pitard

"The optimization of metallurgical processes requires an in-depth understanding of the heterogeneity carried by any constituent of interest. It emphasizes that knowledge of the Theory of Sampling (TOS) is the necessary step to ensure that valuable and valid research programs, pilot plants, feasibility studies, plant design and plant operations have been set on solid foundations. Too many publications today are solely based on the properties of the sample, with no mention of how this sample relates to anything in the environment where it was collected. Unfortunately sampling is an error-generating process that leaves no apparent tracks of its shortcomings. Indeed, it is easier to track down analytical errors than sampling errors. Consequently, bad sampling practices plague the scientific community and the industry and are responsible for severe money losses, unsatisfactory science and processing, and sometimes litigation. A point-by-point strategy is presented addressing sampling problems in early stages of a project. Sampling system requirements for metallurgical accounting and process control are listed. The use of Chronostatistics is suggested to determine if sampling systems are performing satisfactorily and to identify the various types of process variability that may not be easily detected by a conventional inspection of available chronological data. This strategy will help engineering firms, manufacturers, managers and supervisors to provide, install, use and maintain key sampling systems located at very important points in a process. Equipped with the appropriate sampling and statistical tools it becomes easier to minimize reconciliation problems with the mine, with suppliers and with clients. Contrary to the beliefs of many people, good sampling systems are not expensive because in the long run they help to reduce hidden cost and better regulate plant productivity; they most certainly minimize the number of unnecessary meetings looking for solutions where there are none. The suggested strategy will help specialists to extract maximum information from the available data, as large investments and crucial decisions depend on it."

Jan 1, 2014

By Yi-jun Cao, Jin-cai Ran, Guo-sheng Li, Jiong-tian Liu, Li-jun Deng, Shu-lei Li

A fly ash sample from a power station in Guangdong province has been characterized by size separation, X-ray diffraction, contact angle measurements and X-ray Fluorescence. The ash sample had a loss-on-ignition (LOI) (%) of 15.54% and a large proportion of the unburned carbon was distributed in the +74 µm and -20 µm fractions. Contact angle measurements suggested that the removal of unburned carbon from the fly ash using flotation would present some challenges. The effects of various operating variables on the removal rate of unburned carbon (RUC) (%) and (LOI) (%) were determined using a cyclonic-static micro bubble flotation column (FCSMC). Within the range studied, the optimum diesel oil dosage was 1200 g/t, abies oil (frother) dosage was 600 g/t, pulp density was 20%, superficial gas velocity was 1.4 cm/s and circulating pressure was 0.20Mpa. Column flotation tests indicated that the FCSMC method a viable and effective separation process for removing the unburned carbon from the fly ash. Under the optimized conditions, a clean ash with 2.13% LOI and 94.21% RUC was obtained.

Jan 1, 2014

By Sudhir Srivastava

India hosts a wide range of globally significant mineral resources, including four fuel minerals; 11 metallic minerals; 22 minor minerals and 52 non-metallic minerals. The country ranks among world?s top five nations for its commodity reserves of coal and iron ore. Interestingly, only small part of country's landmass has been explored that provides opportunity for future substantial mineral discoveries. India plans to double infrastructure investments to US$ 1trillion. Despite the challenges in infrastructure project implementation, mining sector remains a key driver of demand growth for commodities in the years to come with a good prospect to grow in future.

Sep 1, 2012

By Adam Jordens, Olga Kuzmina, Christopher Marion, Kristian Waters

"In order to meet the growing demand for non-Chinese rare earth suppliers many new rare earth (RE) mineral deposits are currently under development, however these deposits typically include many minerals for which there is little processing information available. One of these deposits is the Nechalacho deposit located in the North West Territories of Canada. This deposit contains multiple RE minerals including bastnäsite, zircon, fergusonite, allanite and monazite. The work presented here investigates the use of different classes of flotation collectors (carboxylic acids, hydroxamic acids, phosphoric acids) typically used in RE mineral flotation to float the Nechalacho ore directly. Flotation tests are also conducted as the final step in a beneficiation process incorporating centrifugal gravity concentration and magnetic separation. This combination of centrifugal gravity concentration and magnetic separation rejects low specific gravity gangue minerals such as K-feldspar and plagioclase and concentrates high specific gravity minerals such as magnetite and hematite. The removal of low specific gravity gangue helps to improve flotation and the removal of ferromagnetic iron oxides is important prior to flotation using certain chelating collectors."

Jan 1, 2014

By Jan Cilliers

The demand for minerals has never been higher. Moreover, the rate at which this demand is growing is unprecedented, and expansions and new mines will be required to fulfill these growing needs. This, in turn requires a skilled engineering workforce that can develop and operate minerals extraction processes to utilise effectively more complex ores. The International Mineral Processing Council (IMPC) has established a Commission on Mineral Processing Education to consider the global challenge of ensuring an adequate supply of well-trained mineral processing engineers. The Commission has, for the past four years, been collecting international information of the recent mineral process engineering supply position and with a view into the near future. The data collected by the international Commission members are as follows: ? Undergraduate student numbers in minerals engineering ? A breakdown of their male/female ratio ? The fraction of the students from each course that enter the minerals industry ? Teaching staff numbers and age profile This data has been collated and analysed, and the findings are presented. It is clear from the analysis that the supply situation is very different in different regions of the world, and that great opportunities exist for targeted recruitment into the industry to meet the future talent demand. Further, an attempt at correlate the supply of minerals engineers based on the local mineral production rate is shown, which shows that there are clear outliers.

Sep 1, 2012

By Graeme J. Jameson

In conventional flotation machines, the recovery is strongly related to particle size. As particle size increases, the recovery also increases, reaching a maximum in the range 20 to 120µm. Beyond this range however, the recovery declines quite quickly. The reason for the decline in recovery observed with coarse particles can be traced to the effect of turbulence. Bubbles trapped in turbulent eddies rotate rapidly, and when the centrifugal force on a particle exceeds the retaining forces due to surface tension, the particle detaches. Since the centrifugal force varies as the cube of the diameter of the particle, and the attachment force varies simply as the diameter, being proportional to the length of the contact line, it is clear that detachment forces will predominate as the particle size increases. The corollary is that the recovery of coarse particles can be improved if the level of the turbulence in the cell can be reduced to a minimum. In this paper, a new type of flotation machine will be described, in which the particles to be floated are suspended in a fluidized bed. An up flow of fluidizing water is provided, by recycling liquid from the top of the cell. The recycle stream is aerated in a high-energy device that disperses the air into fine bubbles that capture the fines and ultrafines. Results are presented for several minerals and coarse coal. Keyword: fluidized bed flotation

Sep 1, 2012

By Peter Rubie, John Russell

"For many years, optimizing the relining of hard rock grinding mills has been complicated by the large number of variables, the low frequency of relines (resulting in a slow relining experience assessment and review cycle), and the potential economic risk associated with some changes to relining equipment or work practices. A technology that has its roots in the automotive manufacturing industry is being utilized to construct a statistically accurate, configurable, and dynamic simulation of the mill relining process. The detailed effects of various mechanization and process changes can be rapidly modeled and compared. Application of this discrete event analysis technology in the mineral processing industry delivers a range of benefits to many industry stakeholders. For example, mill maintenance managers and contract relining companies can embrace the opportunity to benchmark current performance against world’s best practice. Concentrator plant designers and mill manufacturers, informed by this technology’s scientifically defensible data set, can accurately plan for maximum plant efficiency when designing an infrastructure and equipment combination that truly maximizes annual plant availability. Time-motion studies of grinding mill reline data at mills of varying dimensions, liner configurations, mill relining equipment, operator and tool variables, have been integral to the development of this dynamic simulation tool and its associated data set. Access to mill relining simulation technology will enable mineral processing industry professionals to take advantage of an increased capacity to develop mineral concentrator performance optimisation initiatives within the given financial, physical and technological constraints of the individual concentrator plant."

Jan 1, 2014

By K. Sasaki, H. Miki, Y. Muta, T. Hirajima, G. P. W. Suyantara

"Selective flotation of chalcopyrite and molybdenite is continuing problem since its selectivity is not perfect and current NaHS process needs closed system flotation plant because of hydrogen sulfide emission on acidic condition. Some alternative additives investigated as chalcopyrite became hydrophilic and molybdenite kept hydrophobic. XPS analysis indicated chalcopyrite became hydrophilic since iron and copper sulphate, hydroxide was covered on the surface whereas molybdenite kept hydrophobic since only molybdenite can be seen. Flotation experiments of chalcopyrite and molybdenite mixture sample indicated excellent separation that 95% of molybdenite can be recovered as froth and 93% of chalcopyrite can be recovered as sink. Flotation experiments with real bulk flotation concentration indicated similar separation result compared with current NaHS additive system. Possible mechanisms and detailed phenomenon were investigated based on the surface analysis and thermodynamic calculation etc. this alternative additive is easy to handle compared with NaHS since it does not emit effluent gas and commercially preferable.INTRODUCTIONMany copper mine often associates molybdenite (MoS2) as trace mineral. It is important to separate molybdenite and copper mineral efficiently since molybdenite is valuable mineral and also contamination of molybdenite into copper concentrate decrease concentrate value. Conventional separation of copper sulfide and molybdenite has been achieved with sulfide bulk flotation followed by selective molybdenite flotation with NaHS addition since NaHS works as a depressant for copper sulfide (Bulatovic, 2010; Ansari and Pawlik, 2007b). However, this current process shows imperfect molybdenite recovery (Liu et al., 2012, Zanin et al., 2009) and depressant such as NaHS needs to be used under specific flotation plant since it might be environmental contaminant (Ansari and Pawlik, 2007a). there are still unknown on the effect of depressant NaHS, but one of the theory is NaHS reductant effect. It is worth to investigate the effect of other reductant as depressant on chalcopyrite. On this research, typical reductant, Na2SO3 are added to utilize for selective flotation of chalcopyrite and molybdenite."

Jan 1, 2018

By P. M. Solozhenkin

"Galvanochemical process (GChP)) cleaning of sewages is realized in the field of shortcirquited galvanic elements from the mixture current the materials place in purification’s solution and form multitude galvanopairs without external electric field in presence oxygen of the air. The galvanochemical process is electrochemical process utilizing galvanic pairs: coke - iron, iron - copper and others and process does not require chemical reagents.The effect of basic parameters of the cleaning effectiveness have been studied depending on oxidizing of galvanopairs. Adjusting nature, type of galvanic pairs and forming three component system possible to enlarge emf circuits to 2.378 V.The role of ?2, as basic agent, for generation of hydrogen peroxide and hydroxyl ions.It was stated, that removing of metal ions from solutions occur mainly on account of sorption and hydrolytic sedimentation of iron oxihydrates.Determined separate stages of the process: coagulation, sorptions of admixtures on freshly formed ferric oxides and oxidizing destruction of organic components of effluents in presence of ?2 ? ?2?2. Shown efficiency of the method for removing of Cu, Cr, Ni, Zn, As ions, as well as fluoride, phosphate and cyanide anions and oil products, surface-active and flotation reagents. Cleaned water can be recycled for some processes non-critical toward residual concentration of admixtures, as total salt contents is lowered on 60-75 % and reaching limits of concentration for toxic components.The concept of high power unit creation was developed, and galvanochemical pulsator is presented. The pulsator is not expensive, and exploitation expences are low, as well as servise is simple with high effectiveness, and capacity. The galvanoflotation process is developing, combining galvanochemistry and flotation of hydrofobic admixtures (oil, surface-active agents).The galvanochemical flotators are presented."

Jan 1, 2003

By David I. Verrelli, Boris Albijanic

"Froth flotation is an exceedingly complex physicochemical process. The convenience of distilling much of the complexity of the bubble-particle interactions into a single parameter has led to the continuing popularity of the classical ‘induction time’ to quantify the threshold for bubble-particle attachment to occur. Despite this popularity and the simplicity of the concept, there is no single universal method of evaluating the induction period. In this paper, we begin with a critical review of the available techniques for estimating the induction period. These are: back-calculation from experimental (micro) flotation tests; pushing a particle toward a stationary bubble (or vice versa) using an atomic force microscope (AFM); pushing a bubble toward a stationary bed of particles in the ‘Induction Timer’; pushing a bubble toward a stationary solid surface using the ‘integrated thin film drainage apparatus’ (ITFDA); and dropping particles onto a submerged stationary bubble using the ‘Milli-Timer’ device. Each one of these methods has advantages and disadvantages, and the best choice depends on the application. In the experimental section, we present quantitative comparison of the induction periods estimated using two different techniques, namely the Induction Timer and the Milli-Timer. The same particles were tested in each device, under the same conditions. It was found that by tuning the operation of the particle pick-up device, similar estimates of induction period could be obtained to the estimates made by direct observation with the Milli-Timer. In the former device a bubble is driven toward a particle bed at a controlled rate, whereas in the latter a particle’s motion is governed by the hydrodynamics. The potential to match these presents an intriguing prospect for better understanding the bubble-particle interaction, and the possibility to ‘calibrate’ the simpler Induction Timer against direct observations."

Jan 1, 2014

By Slobodan B. Vujic

"Some twenty years ago, during construction of flotation in the “Veliki Krivelj” copper and non-metallic mine Bor, a computer supported system for remote controle of technological process was installed. Nowadays, the major part of equipment of this system is worn-out and technically old-fashioned. Having this in mind a decision was made to design a new computer supported information-management system for Flotation. The paper presents a concept and features of project solutions.For the requirements of remote monitoring and management of technological process in Flotation of “Veliki Krivelj”, Copper and non-metallic minerals mine in Bor, Yugoslavia (hereinafter: CNM Bor), a measuring-regulation equipment was implemented and a computer control system, adjusted for that time, built some twenty years ago. The major part of this equipment is today worn out and technically out of date.Having estimated that production and business activities could hardly be more efficient, operative and successful on one hand, and available mineral and other resources rationally exploited, the CNM Bor made a decision in 1999 to improve information-management function of Flotation. The idea was that the set task be realized through development and introduction into practice up-to-date integrated and computer-supported production-business information-management system. The first logic step in completion of this task refers to engineering-creative determination of information management system (hereinafter: IMS), namely to project elaboration.When considering the real system from technical, technological, organization, monitoring-management, logistic and business aspects, the Project on IMS of Flotation, should provide a rational, modern and, for the real system conditions, complete solution. The Project solutions should be based on the most recent knowledge from computer and measuring-regulation technics as well as from CIM concept (Computer Integrated Manufacturing)."

Jan 1, 2003

By C. Raghu Kumar

Hydraulic or teetered bed separators (TBS) are finding new avenues for application in the field of mineral processing. Floatex Density Separator (FDS) is a hydraulic/teetered bed separator capable of operating at high tonnage due to its advanced instrumentation. FDS/TBS is being used in Indian mineral sand industry for classification and segregation of different minerals. The purpose of this paper is to provide details on the performance of the plant scale FDS in recovering the chromite from feed (below 1mm size). Historically this feed has been processed using hydrocyclones and spiral classifiers; however, there is a strong trend now to employ teetered bed separators, thus allowing significant changes to be made in the plant for improving process efficiency. In the present work, the performance of the plant scale FDS is described in terms of partition curve (yield, cut size, classification efficiency/Ep) for different combination of process variables and also in terms of metallurgical grade and recovery. It is found that, efficient classification can be achieved at a maximum cut size of 380 µm with and the imperfection is also reported as low as 0.16. The grade of the underflow product is enriched as maximum as 52.2% Cr2O3 from a feed assaying 40.4% Cr2O3.

Sep 1, 2012

By Milind Chikhale, Yogesh Reja, Keshav Tyagi

"Using computer models for process design is a well-established practice in the mineral industry. In recent years, there has been emphasis on modeling of processing plant as a whole. This paper covers development of a model for iron ore processing plant. Basic purpose of this model is to use simulation for efficient plant design and help in minimizing risk at the very initial stage of project. Feed to the plant is Hematite iron ore from a deposit located in Eastern India. Major processes in plant include multi-stage crushing, screening, grinding, classification, gravity and magnetic separation. Models for different process equipment were developed using METSIM and Bruno simulation software. Customized black box models and known mathematical models were used for predicting behaviour of processes. Data needed was identified based on the model type. The required data was arranged as per project requirement and processed for development and validation of model. Equipment models were developed and validated on the basis of process design basis, theoretical and empirical data from technical references, and bench scale and pilot scale testwork results. Validated process circuits were assembled to simulate and represent the entire plant process. The result shows expected variation in plant output as a result of variation in the feed. Study concludes by discussing potential applications of the model in plant design."

Jan 1, 2014

By Grigori I. Voiloshnikov

"The long-term studies on development of the technology for precious metals recovery using activated carbons executed by Irkutsk Research Institute of Precious and Rare Metals and Diamonds (IRGIREDMET) were finished by successful introduction of ""Carbon-In-Pulp"" process in Russia (1984).The review of some studies, accompanied by development, testing, introduction and subsequent improvement of considered technology, carried out by IRGIREDMET is submitted in this paper.The basic regularities of gold and silver adsorption onto activated carbons from cyanide, thiourea, chloride and other solutions are investigated using various phisical-and-chemical methods ( X-ray photoelectron spectroscopy, Voltammetry, X-ray microanalysis etc.). Using voltammetry it was found that gold cyanide is adsorbed onto activated carbon without chemical changes and partial reduction of gold is possible only during drying of carbon samples before analysis. Metallic gold and silver may be dissolved in boiling cyanide solution at argon atmosphere when they are in contact with activated carbon surface. Gold adsorption mechanism for activated carbons has great differences from that for the ion exchange resins. So the most probable mechanism for gold adsorption from cyanide solution is adsorption of neutral molecules Me n+[Au(CN)2-]n.X-ray quantitative microanalysis technique was developed to investigate gold adsorption kinetics onto spherical activated carbon. Gold profiles in granules of activated carbon for various adsorption conditions were tested (carbon particle size, mixing efficiency, adsorption time etc.). Mathematical methods were used to determine gold diffusion coefficient within activated carbon granule.The properties of various types domestic and foreign activated carbons were tested and the demands to activated carbons suitable for gold extraction were determined. As a result foreign and Russian activated carbons AG-90, AG-95 were recommended for use at Russian gold plants. Domestic adsorbents are cheaper in comparison with foreign activated carbons. The methods to restore carbon adsorption activity including acid treatment and thermal reactivation were tested and implemented."

Jan 1, 2003

By Anuttam Patra, Romain Bordes, Andreas Fredriksson, Tommy Karlkvist, Krister Holmberg, Kota Hanumantha Rao

Almost all of the flotation reagents used today were discovered by continued application of empirical methods and/or trial and error experimentation. Moreover, with the metal-ion specific approach used so far, it is difficult to separate the minerals containing the same constituent metal ion. A critical assessment of molecular recognition processes involved in biomineralization suggested the possibility of using reagents which are surface specific. The concept that the molecules consisting of two or more functional groups having appropriate spacing between those so as to achieve structural/stereochemical compatibility during interaction with the mineral surface exhibit structure-specificity is thought to be extended to the design of specific collectors in flotation processes. In the present study, for the first time, a rational design of surface active molecules, and thereby the recognition of crystal faces (of minerals) by these molecules through structural and stereochemical matching is being utilized successfully to selectively float various minerals. For this purpose, carboxylate-based collectors (for mineral specific flotation of calcium minerals) as well as xanthate-based collectors (for mineral specific flotation of sulphide minerals) with a fixed alkyl chain length but having two functional groups with varying geometrical distances (separated by a spacer of one, two and three carbon atoms) between them have been synthesized. In this article, we have discussed the design, synthesis, purification of these novel mineral specific collectors as well as their important solution parameters in relation to flotation processes.

Jan 1, 2014

By Aziza A. Yousef, Suzan S. Ibrahim, Mahmoud A. Arafa, Mohamed A. Abdel Khalek

Due to the shortage of fresh water in the Middle East, seawater has been used as an alternative in flotation beneficiation. The flotation process requires about 7 m3 of water/mt ore. This article aims to study the effect of seawater cations and anions on the flotation. Natural pure francolite, calcite, dolomite and quartz were characterized by chemical, thermal and x-ray diffraction analyses, surface area, solubility and zeta potential. Synthetic seawater was prepared with the major chemical composition similar to natural seawater as follow; 2.45% NaCl, 0.52% MgCl2, 0.41% Na2SO4, 0.116% CaCl2 and 0.07% KCl. Also, natural seawater was used in application. The point zero of charge was estimated at pH 6.5, 7.8, 9.2 and 2.2 for francolite, calcite, dolomite and quartz, respectively. Calcium ions were released from the three minerals with Mg2+ and P2O5 3– released from dolomite and phosphate, respectively. The adsorption of collector, zeta-potential and floatability of pure minerals were studied. The effect of individual cations and anions predominant in seawater are studied on individual mineral or group. The troublesome Ca2+ and Mg2+ ions should be controlled by soda ash addition. Sodium silicate improved the selectivity of mineral mixtures and natural ore. At optimum conditions the calcareous phosphate ore yielded a concentrate of 34% P2O5, at 83% recovery with 0.61% MgO, from an ore assaying 25.3% P2O5 and 9.4% MgO. To minimize the Clcontent, fresh water of about 0.5 m3 /t was used and the Cl- decreased to about 0.09 %

Jan 1, 2003

"The thiosulfate leaching process developed by Barrick to treat sulfidic high preg-robbing gold ores uses calcium thiosulfate as the leaching reagent for ores pre-treated by pressure oxidation, resin for gold recovery with sulfite/trithionate elution and reverse osmosis as a means of reagent recovery. A large portion of the research that led to the development of the technology was based on previous studies completed by different groups over the years, mainly focused on the ammonium thiosulfate system. Operational limitations in the use of the ammonia-containing recycled water in the pressure oxidation circuit were some of the main drivers for the change from ammonium to calcium thiosulfate for the development of the industrial scale process. One of the main aspects for successful gold extraction and recovery in the thiosulfate system is the pseudo-equilibrium reactions that drive distribution of the different gold species (in solids, solution and on resin) in the system. Previous studies have been focused on the thiosulfate reactions and equilibrium constants for the oxysulfur ions (thiosulfate, trithionate, tetrathionate). However, the literature around the effects of the different metal-oxysulfur complexes (Cu and Hg complexes) that form when the ore is in contact with the leaching reagents, and the related effects on stability of the gold complex is limited. The main changes in the gold complex chemistry and stability in the calcium thiosulfate system as compared to the ammonium and sodium equivalents, as well as related effects on gold recoveries, were investigated in the presence of different types of double refractory ores. INTRODUCTION Barrick has developed a thiosulfate leaching process to treat double refractory gold ores, by combining the use of acidic and alkaline autoclave pre-treatment with thiosulfate resin-in-leach (RIL). The process currently in operation at the Goldstrike mine (the TCM process), uses calcium thiosulfate as the leaching reagent, resin for gold recovery with sulfite/trithionate elution and reverse osmosis as a mean of reagent recycle. The main feed to the process plant is highly preg-robbing sulfidic ore from Goldstrike’s open pit. Prior to feeding the pressure oxidation circuit, the ore is processed through the crushing and grinding circuits and treated in preparation for acid or alkaline autoclave processing (POX)."

Jan 1, 2018

By Y. E. Brylyakov, M. A. Kostrova

"The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. In this connection, the magnitude of cation exchange, along with the content of P2O5 and CO2, is an important property of apatite staffelite ore, which largely determines the performance of concentration processes. In the examined ASO samples, the magnitude of cation exchange measured in terms of Ca2+ is 2546-4790 g/ton. The conducted laboratory studies of apatite staffelite ores with various mineral composition showed that adding calcined soda improves the recovery of P2O5 into the flotation concentrate. Full-scale tests were conducted at the apatite staffelite ore processing plant at Kovdor Mining and Concentration Operation and demonstrated the high performance of the proposed agent treatment. The test results showed that in the flotation of apatite staffelite ores, the optimum calcined soda feed rates range from 3,500 to 5,000 g/ton of the flotation feed. With close flotation feed and concentrate grade parameters, the P2O5 recovery gain is 17%. The effect of adding soda is associated with the desorption of the hardness cations from the minerals, precipitation in the pulp and, accordingly, improvement in the ionic composition of the liquid phase of the flotation feed due to a reduced content of calcium ions. Based on the test results, the proposed agent treatment with an elevated feed rate of calcined soda was implemented at Kovdor Mining and Concentration Operation in the flotation of apatite staffelite ore. The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. These minerals have certain properties requiring a more detailed examination for a better understanding of the flotation properties of apatite staffelite ores."

Jan 1, 2018

By Vladimir E. Vigdergauz

"Bubble-mineral complexes could be formatted by an attaching of hydrophobic particles to the surface of air bubbles or by an evolution of bubbles from solution onto hydrophobic surfaces. Measurements of contact angles, detachment forces (DF), induction times (IT), evolution pressures (EP) and flotation recoveries (FR) for the studying of minerals wettability at various pH and electrochemical potentials were used. An analysis of the obtained IT results show that a process of bubble attachment to a mineral surface is a rather slow one and it will scarcely be enough for bubble-mineral complex formation under the conditions of real flotation.The ranges of adhesion potentials obtained by DF measurements, Figure 1, correlate with the data of floatability-potential for pyrite. The ranges of adhesion potentials obtained by DF measurements for galena (-1 ÷0.2V) and chalcocite (-0.5÷1.2V) correlate with the potential ranges of floatability for galena (<0.2V) and chalcocite (>-0.4V). An increase of the DF and the cathodic limit of the adhesion potential with increasing length of the hydrocarbon chain were observed. EP-pH curves for sulfides are a mirror-like to the DF-pH curves, Figure 2. Structure of solid-liquid and liquid-gas borders has a determinative importance for formation of bubble-mineral complexes and subsequently flotation results. Under vacuum on the mineral surface there are produced micro bubbles and preferably they will be appeared on the hydrophobic sites. Water structure breaks near a hydrophobic surface facilitate water mass destruction and formation of gaseous phase embryos under decompression in the impeller zone. It simultaneously reduces a probability of produced micro bubbles dissolution as a result of pressure increasing owing to constant fluctuation of liquid densities into impeller zone. Comparison of Taggart’s evaluation of the suction behind blades of the impeller of an agitation-froth machine and ABEP data on galena, Figure, shows that gas evolution will be observed in the range of 1300-2700 revolutions of impeller per minute for hydrophobic and hydrophilic surfaces successively."

Jan 1, 2003