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By Chih-Huey Lin

The Au/?-Al2O3 catalyst prepared by AuCl3 impregnation is subjected to the influence of residual chlorine after an oven drying. A post-impregnation NH4OH treatment was able to eliminate chlorine, and to reduce the cluster size of Au moiety. However, the CO oxidation activity was not increased by this post-impregnation NH4OH treatment. This suggests that certain metal-support interaction (MSI) is the determining factor for the activity of Au catalysts. Thermal treatment under H2, O2 or He was attempted to increase MSI of the prepared catalyst with or without the post-impregnation NH4OH treatment. No significant activity enhancement was found but the TPD analysis suggests that a H2 treatment has a higher chance to induce MSI.

Oct 1, 2003

By M. S. Moats

As smelter feeds become more complex, the impurities that ultimately report to electrorefineries are changing. Many of these impurities collect in the electrolyte and must be controlled. As commercial copper electrorefineries look to expand their capacities by increasing their operating current density, the interaction between electrolyte composition and anode passivation can cause operational difficulties. To improve the industry's understanding of the passivation phenomena, the role of electrolyte composition was evaluated using commercial electrorefining anode samples. The electrolyte composition variables examined were copper, acid, nickel, arsenic, chloride, thiourea and glue. Finally, the role of non-commercially utilized additives, such as bromide and polyethylene glycol were studied. From this investigation, electrolyte parameters that inhibit copper dissolution through copper sulfate precipitation, copper oxide stabilization and/or absorbed species lead to accelerated passivation. Species that prevent passivation have the ability to complex cuprous ions. Possible mechanisms for the role of each.

Jan 1, 2007

By William Petruk

Mineralogical investigations in connection with gold metallurgy are usually performed to find the reason for poor recoveries by cyanidation or by other leaching techniques. Poor recoveries most commonly are obtained when (I) native gold is encapsulated in an insoluble mineral as "invisible gold"; (2) native gold is coated with a precipitate; (3) gold-bearing products are insoluble in cyanide solutions; (4) carbonaceous material in the ore adsorbs gold; and (5) associated minerals decompose and consume cyanide. Samples of refractory material quite often have low gold tenors. It is difficult to find the gold-bearing minerals in such samples with an optical microscope because the probability of finding trace minerals in samples is small. The probability decreases with decreasing grain size of the gold-bearing mineral and with decreas¬ing gold tenor of the sample. Techniques have been developed to increase the success rate of finding gold grains; some are (1) concentrating heavy minerals; (2) preparing special polished sections; (3) searching with an image analyzer; and (4) dissolving associate silicate and sulphide minerals.

Jan 1, 1989

By F. Moraw

The use of redox fuel cells in which oxygen is replaced by other oxidants such as ferric ions can have significant advantages [1-3]. For example, the cathodic reaction rate (e.g., exchange current density) can be increased by several orders of magnitude compared to the oxygen reduction reaction, and platinum group metal (PGM) catalysts are not required. As a result of the higher aqueous solubility of the oxidant in a redox fuel cell compared to that of oxygen the rate of mass transfer (e.g., limiting current density) is greater by several orders of magnitude. The redox fuel cell can achieve high efficiencies and has other fuel cell advantages. The main issue with the redox fuel cell cathode is the regeneration of the oxidant where low conversion efficiencies are achieved even with platinum group metal (PGM) catalysts. In the work discussed here the Fe3+/Fe2+ redox fuel cell cathode is characterized over a range of electrolyte concentrations and operating conditions, and electrode materials. Cyclic voltammetry and electrochemical impedance spectroscopy are mainly used for electrochemical characterization and mechanistic determination of the cathode redox couple. Further characterization with selected compositions and materials is done in a redox fuel cell (hydrogen - Fe3+/Fe2+). The mechanism and the advantages and disadvantages of the fuel cell redox cathode are discussed with respect to other approaches and other redox couples.

Jan 1, 2005

By I. M. Santos Moraes

The control of minor impurities (mainly As, Sb and Bi) in copper refineries has been a great challenge. Caraiba Metais' copper refinery produces a very high quality copper, registered in LME as grade A, and recognized as amongst the top ten in the copper world. At Caraiba's Tankhouse Bi and Sb are controlled by means of electrolyte bleed-stream removal after partial decopperizing in a set of electro-winning cells (liberators). Another way of reducing the Sb and Bi content in the electrolyte is by means of the arsenate precipitation chemistry. It is well known that the use of high arsenic concentrations in copper refinery electrolyte has the advantage of causing most of the bismuth and antimony to report in the anode slimes. However, the use of such mechanism of control may contribute to other undesired problems such as antimony and bismuth precipitation in the bulk of the electrolyte, what may cause severe contamination problems. This paper describes a period when some cathode contamination with Sb occurred at Caraiba Metais' Copper Refinery. It also presents an analysis of several process parameters related to the problem, the possible causes for the contaminations as well as the actions taken to correct the problem.

Jan 1, 2007

By J. Robitaille, P. Cousin

"Agnico-Eagle Mines Ltd, Laronde Division, is a gold operation processing ore containing copper and zinc. Copper is recovered as a concentrate prior to gold cyanidation.Copper concentrate grade was improved with the implementation of an on-stream analyzer. Further improvements to the copper concentrate grade could be achieved throughefficient zinc depression.High cyanide cost linked to the copper content in the flotation circuit tails, prompted some modifications to the flotation circuit. Economics and environmental issues were considered. A Maxwell cell was retrofitted with an Outokumpu HG cell mechanism stabilizing it's operation. Secondly a flotation column was added to increase circuit capacity.This paper will address flotation circuit operation difficulties, successes and results achieved before and after modifications.RESUMELes Mines Agnico-Eagle division Laronde sont considéré comme étant un producteur d'or. Le minerai révèle toutefois des teneurs appréciables en cuivre et zinc. Un circuit de traitement combinant des étapes de flottation du cuivre et de cyanuration de l'or a été adopte. Le rejet de la flottation est lixivie pour son contenu en or.La teneur moyenne en cuivre du concentre final fut augmentée suite a l'implantation d'un système d'analyse en continu. Une séparation plus efficace de la sphalérite se devra d'être obtenue afin d'améliorer davantage la qualité du concentre produit.Le contenu en cuivre au rejet du circuit de flottation influence directement la consommation en cyanure. Pour cette raison, certaines modifications à la flottation sont devenues nécessaires. Des facteurs d'ordre économique et environnemental ont été considérées. Une cellule existante fut transformée en cellule HG d'Outokumpu, stabilisant son opération, et une colonne de flottation fut ajoutée au circuit afin d'accroitre sa capacité.Le présent document se veut une rétrospective des problèmes d'opération vécus, des solutions apportées ainsi que des résultats obtenus et de leurs implications suite aux améliorationseffectuees."

Jan 1, 1995

By A. R. Guest, R. Clayton, J. Jakubec

"The potential for mudrushes is a potential hazard that should be evaluated during cave mining studies. Mudrushes are a phenomenon that can have very different origins, but produce the same results: injury, loss of life, damage to property, excess dilution, production delays, or mine closure. Although mudrushes are more common in cave mines than other mines, any mining activity that enables the accumulation of fine particles and water is susceptible to mudflow. This paper describes the process developed by the authors during the past decade to evaluate the risk of mudrushes, specifically in caving and sublevel caving mines.RÉSUMÉ Un danger potentiel qui devrait être évalué durant les études d’exploitation par blocs foudroyés est la possibilité d’afflux de boue. Le phénomène des afflux de boue peut avoir des origines très diverses; les résultats sont cependant les mêmes : des blessures, des pertes de vie, des dommages à la propriété, une dilution excessive, des délais de production ou des fermetures de mines. Bien que les afflux de boue soient plus fréquents dans les mines exploitées par blocs foudroyés, toute activité minière qui permet l’accumulation de particules fines et d’eau est sujette à des coulées de boue. Le présent article décrit le processus développé par les auteurs au cours de la dernière décennie pour évaluer le risque d’afflux de boue, surtout dans les mines exploitées par blocs foudroyés et par sousniveaux foudroyés."

Jan 1, 2016

By Chan-ho Park

As the building has recently become bigger, higher, and freeform, a technology called BIM(Building Information Modeling), which is a key technology that integrates construction and IT(Information Technology), has been rapidly introduced and expanded. Because BIM technology offers various benefits, countries that introduced BIM early has been actively promoted. However, misperceptions of BIM are prevalent in countries such as South Korea that have adopted it relatively late, with lack of awareness of its fundamental purposes. Under these circumstances, transparent and quantitative performance assessment needs to be executed in order to eliminate the misperceptions, and to explain and revitalize the BIM introduction. These quantitative performance measure KPI (Key Performance Indicators) to be measured should be prioritized. As derive performance indicators in terms of the four types (financial, customer, internal processes, learning and growth), and performance management systems, Uses the BSC to seek a balance between short-term financial goals, values and the value of long-term goals. Uses the BSC(Balanced Scorecards) to derive performance indicators in terms of the four types (financial, customer, internal processes, learning and growth), and performance management systems, seeking a balance between the value of short-term financial objectives and the value of long-term objectives. Through this, the KPI (Key Performance Indicators) which is used for measuring the effect of the BIM will be generated and also the method that can determine whether the generated KPI figures are objectively inter-connected will be suggested as well.

Aug 1, 2013

By C. Allen, M. Gangal, J. Stachulak

"Most underground diesel equipment is equipped with diesel oxidization catalysts (DOCs) to reduce carbon monoxide and hydrocarbon emissions. DOCs do not alter nitrogen oxides concentrations but can promote the oxidization of nitric oxide (NO) to the more toxic nitrogen dioxide (NO2). Vale and CanmetMINING have been researching how to reduce worker exposure to diesel emissions by testing mining equipment DOCs. Results indicate a > 77% decrease in carbon monoxide concentration but a 46–315% increase in NO2 concentration for 8-mode test cycles. It is recommended that DOCs that increase NO2 emissions be evaluated regarding their continued use in underground operations.RÉSUMÉ La plupart des équipements miniers souterrains sont équipés de catalyseurs d’oxydation diesel (DOC) afin de réduire les émissions de monoxyde de carbone et d’hydrocarbures. Les DOC ne modifient pas les concentrations des oxydes d’azote mais ils peuvent faciliter l’oxydation du monoxide d’azote (NO) en dioxyde d’azote (NO2), plus toxique. Vale et CanmetMINING effectuent des recherches pour réduire l’exposition des travailleurs aux émissions de diesel en analysant les DOC des équipements miniers. Selon les résultats, une diminution > 77 % dans la concentration de monoxyde de carbone est atteinte mais elle est accompagnée d’une augmentation de 46 à 315 % de la concentration en NO2 pour des cycles d’essais à 8 modes. Il est recommandé d’évaluer les DOC qui augmentent les émissions de NO2 pour décider de la poursuite de leur utilisation dans les opérations souterraines."

Jan 1, 2016

By P. Lauzon, C. Oprea, S. Zhou, G. Oprea, J. Rigby, T. Troczynski

Hydration of basic refractories could occur during storage, drying after installation or in use. In order to assess the hydration resistance of various commercially available magnesia-chrome bricks, hydration tests were performed in steam at 110, 120, 130 and 150°C. The changes of the modulus of elasticity by the impulse excitation method, apparent porosity, air permeability, average pore size and pore size distribution were correlated with the hydration data. Mineralogical and microstructural changes were also studied on selected specimens by XRD and SEM/EDS. The hydration mechanisms were discussed in correlation with the chemical and mineralogical compositions of the experimental bricks, in particular with the nature of the mineralogical phases at the grain boundaries.

Jan 1, 2004

By Y. Turen, Y. Karakas, E. Candan, C. Sahinturk

In this study, wettability between sprayable tundish lining (MgO) and molten steel was investigated by using sessile drop method. Content of glass fiber (SiO2) in the MgO varied between 0 to 8 wt% whereas mean particle sizes of the MgO were 25, 75, 150 and 300µm. Experimental results revealed that contact angle (0) of sessile drop on the MgO was not altered by the addition of glass fiber up to 1 wt.% whereas above 2 wt.% addition decreased the 0 considerably. Contact angle, 0, increased considerably with increasing MgO particle size. SEM analysis showed deposition of glass phase was present at the interface as the finer MgO particles were used.

Jan 1, 2004

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

Cambior has been involved in the Guiana Shield since 1990, first in Guyana and then in Suriname starting in 1994. This paper presents the history of Omai Gold Mines Limited in Guyana, where commercial production started in 1993 after an investment of US $150 million. In 1995, the mine was expanded in order to increase the milling capacity to 21,000 tonnes per day. After ten years of production, approximately 3 million ounces of gold have been produced. Building on this experience, Cambior became involved in Suriname with the Rosebel Project. A US $95 million pre-production program started in the fourth quarter of 2002, and the mine should be in commercial production early in 2004.

May 1, 2003

By R. H. McCorkell

Radon emanation rates. J. and compositions of materials from the Canadian Certified Reference Materials Project (CCRMP) indicate that the fraction of the Rn produced that escapes, E, is usually 1% to 8% and the 238U decay chain is nearly in secular equilibrium. For some Chinese ore standards, E values are higher than f or the CCRMP materials. Standard ore tailings have 2/oPb concentrations higher than expected from their 226Ra concentrations and Rn escape rates (12 - 34%) . Biological materials have E ˜100%, their ash E ˜0%. Pelletizing ore powders at 20 000 lb/in2 reduces J by only 20 - 40% but only 2% of Rn escapes from pressed Li2B4O7 pellets and 0.01 - 0.04% from fused Na2B4O7 or Li2B4O7 discs. Large, difficult-to-explain random variations in J are observed in some situations but several highly reproducible ways of measuring emanation rates have been found.

Jan 1, 1986

Orebody classification systems ? Modern classification systems ? Genesis and environment of deposition (Important in economic geology) ? Shape and structure / Form, texture and mineral content ? Mining and geomechanics ? Size ? Massive versus tabular Requirements for mining method selection ? Classification of ore deposit ? Shape, size, attitude, continuity ? Grade and distribution, strength and large scale structures present, mineralogy and small scale structure, host rocks ? Classification of mining method ? Method of support (Stress ? strength ratio) ? The method selection ? Geographical and economic factors of the location

Feb 1, 2008

By Selvia Tourn, Liliana Castro

"Abstract - Argentina, a large country with an important agriculture industry, needs an ever-increasing amount of phosphorus and potassium, as essential elements for plant growth. Current requirements are met from imports, but potential resources exist in Argentina. For example, several phosphatic occurrences are known in paleo-marine basins, the most significant of which are in Tertiary units in Patagonia. In addition, two types of potassium deposits are also known in Argentina: evaporite deposits in the Neuquén Basin at depths of 750 m to 1500 m contain 22 to 25 wt% K2O equivalent; and glauconitic sandstone containing about 6 wt% K2O has been identified in Patagonia.Several experiments were undertaken to test unprocessed phosphate rocks as slow-release, direct-application fertilizers, with good results. In addition, it is proposed that direct application of glauconitic sands would provide an efficient and economic alternative source of potassium. Tests with glauconite samples are still in progress. The existence of both phosphate and glauconitic rocks in Patagonia suggests that development of an extractive industry for these materials would not only help Argentina approach self-sufficiency in fertilizer usage, but also assist in the socio-economic development of this region."

Jan 1, 2003

By M. Honarmand, Z. Moezifar, H. Ranjbar

Abstract - The Sar Cheshmeh area covers an area of 640 km2, and is located in the southern part of the Iranian Volcanic-Sedimentary Belt. ETM+ images have been used for alteration mapping. The Crosta method was found useful for enhancing exposed areas containing hydroxyl and iron oxide minerals. However, field checking has shown that this method is not able to identify all the known areas of hydrothermal alteration. Many of these altered areas are also not clearly resolved in the geophysical data. In order to improve resolution of such areas, integration of remote sensing and geophysical data may be helpful. The Darrehzar Cu deposit was chosen as a control area. The data have been divided into two sets: explanatory and target variables. The explanatory data are Landsat hydroxyl and iron oxide images and airborne geophysical data (K, U, and Th total counts, and total magnetics). The target variables are rock geochemistry and ground geophysics. Data analysis and integration of geophysical and remote sensing data were performed using directed principal components. This technique is found to be useful for the delineation of hydrothermally altered areas with more confidence.

Jan 1, 2002

By P. E. Weidmark

Allard, M., Hucka, V.J., Das, B., and Borchtch-Komponietz, V.I., "Investigation of seismic vibration due to large blasts in Gaspe Copper Mines"; (in Russ); The Industry of Chemical Raw Materials; Referativnyi sbornik; 5:18-20: 1978. Askew, J., McCarthy, P.L. , and Fitzgerald, D.J ., "Backfill research for pillar extraction at ZC/NBHC"; Mining with Backfill; Proc 12th Cdn Rock Mech Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:100-lJO; 1978. Barrett, J.R., Coulthard, M.A., and Dight, P.M., "Determination of fill stability" ; Mining with Backfill; Proc 12th Cdn Rock Symp; May 23-25, 1978; Sudbury; CIM Spec Vol 19:85-91; 1978.

Jan 1, 1979

By J. C. Botham, T. D. Brown

"Coke is the most costly item in steelmaking via blast furnaces . Recent innovations in cokemaking have been directed toward reducing this cost while simultaneously improving coke quality and expanding the range of coals used in the process. It is also important to meet increasingly stringent environmental legislation.Improvements in coke quality have been achieved by novel blend selection procedures, by charge density control using both selective pulverization and partial briquetting, and by the use of modifying additives.The Canadian Carbonization Research Association provides a focus for Canadian cokemakin g research which has demonstrated these technologies in a series of pilot-scale experiments."

Jan 1, 1980

By M. Lytle

"The Corbin area of southeastern British Columbia has been a coal mining area since 1908. Byron Creek Collieries Ltd. Has operated its Coal Mountain Mine in this area from 1974 until the present. In February 1981, this company was purchased by Esso Resources Canada Ltd.Coal Mountain is structurally complex and standard computer algorithms are not applicable to model the overturned synclinal structures and faulted bedding surfaces. This paper discusses two approaches used by Esso Resources staff to model the geology of Coal Mountain.The first approach projects digitized cross-section data along trend to develop a large data base which correctly approximates the shape of the structure. The spatial orientation of the structure is corrected by merging the generated data set with drill-hole data. The second approach uses digitized cross-section and bench-plan geology to generate a block model of the coal reserve.HistoryThe Coal Mountain Mine, also known as the Corbin Mine of Byron Creek Collieries Ltd. is located 24 kilometres south of Highway 3 in southeastern B.C.In 1905, two American businessmen recognized the coal potential of the area during a horseback tour. The two businessmen, D.C. Corbin and E.J. Roberts, formed the Corbin Coal and Coke Co. to mine and market coal from their newly acquired 6075 hectares of coal licenses. By 1908, the town of Corbin was under construction, a 22.4-km rail spur was constructed from the mine to the main CPR line and the first underground mine began to produce coal. An open-pit operation was also developed at the 1828-metre elevation using a steam shovel loading into rail cars. The company operated continuously until 1935, when a lengthy strike forced suspension of operations.In 1943, the Consolidated Mining and Smelting Company Ltd. (now known as Cominco Ltd.) operated two surface mines to produce coal for its smelters at Kimberley and Trail, B.C. This operation ceased in 1948."

Jan 1, 1982