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By Edward Rybinski, Serkan Dikmen, Walter Valery, Jorge Ghersi, Roberto Valle, Alex Jankovic, Javier Linares, Frank Davila

Compañía Minera Antamina is a polymetallic mining complex that produces copper and zinc concentrates as primary products and molybdenum and lead/bismuth/silver concentrates as by-products. In 2007, Metso Process Technology and Innovation (PTI) was contracted to increase SAG mill throughput by integrating and optimising blast fragmentation, crushing and grinding for the harder M4/M4A (CuZn) ores. Following the implementation of recommendations provided by Metso PTI, the SAG mill throughput increased from 2750tph to reach an average of 3600tph for the remainder of 2007. Due to continued application of mine to mill integration and optimisation philosophy, by 2010, the concentrator consistently exceeded the target of 4400tph while processing harder CuZn ores.

Jan 1, 2012

By A. J. Antony Chettupuzha

Electronic Product and Process Management [EPPM] systems provide the capability to establish and map information flow between different parties in a construction project as well as model project processes. Much of the information relating to processes and their structure, the actors that operate them, and the data associated with each instance of a process is encapsulated within workflows. The wealth of information contained in an EPPM system can be exploited to extract knowledge that can provide significant cost benefits to construction companies. Workflows provide an ideal medium for the capture of knowledge over the course of a project lifecycle. We demonstrate how this knowledge may then be used to analyze workflows and determine metrics that establish the suitability of workflows to construction processes. We present a conceptual approach to measure the performance of a workflow, its constituent components and evolution, which may be used to lay the foundation for establishing paragon workflows suited to classes of construction activities.

Aug 1, 2013

By P. R. A. Andrews

"The sillimanite group minerals, kyanite, sillimanite and andalusite are identified as alumino-silicate minerals with the common chemical composition AIP3.Si02' so that each possesses similar physical properties. Kyanite is the most abundant mineral and mainly occurs in Quebec, Ontario and British Columbia; sillimanite occurs in Ontario and Manitoba; and andalusite in Nova Scotia. The main use for the sillimanite-group minerals is in refractory applications for the production of refractory bricks and shapes. In refractory applications, the main performance criterion is the relative percentage of mullite formed within the material during firing. This phase gives a greater degree of resistance to creep deformation and slag attack, and improves the ability of the refractory to withstand high temperatures under load. The beneficiation of refractory silicate minerals has been the subject of many investigations at CANMET, and the former Mines Branch. Eighteen kyanite, two sillimanite, and three andalusite evaluation studies were conducted between 1933 and 1987. A review of some of the more important studies is presented, which includes information concerning mineralogy, beneficiation methods and flotation data."

Jan 1, 1995

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By X. Cao, X. -G. Chen, K. Liu

As is well known, the standard Al-Cu 206 cast alloys have extremely low iron contents, usually less than 0.15 wt. %. Recently it is found that the iron contents of the 206 cast alloys can be extended up to 0.5 wt. % through the precise control of the iron-rich intermetallic phases. In the present work, the tensile fracture surfaces of the 206 cast alloys with various iron contents are systematically analyzed to understand the failure mechanisms. Results show that higher iron contents can reduce the tensile properties (especially the ductility) of the alloys mainly due to the increasing volume percent and size of the iron-rich intermetallics. Tensile failure mainly occurs at the iron-rich intermetallics/matrix interfaces for the platelet ß-Fe, but by the self-disassociation for the Chinese script a-Fe and Alm(FeMn). Cracking is easier to initiate and propagate along the longitudinal axis of the platelet intermetallics, but it can be deflected along the branches/arms of the Chinese script iron-rich phases, making the alloy more resistant to the propagation of the cracks, and thus the Chinese script iron-rich intermetallics are less harmful than platelet ß-Fe. In addition, it was also found that the Chinese script a-Fe has even a less damaging effect compared to the Chinese script Alm(FeMn) due to the relatively small size and compact morphology.

Jan 1, 2014

By M. Labrie, H. L. Gibson, G. Doiron, J. J. Watkins, D. H. Watkinson

The Corbet deposit is one of 17 proximal Cu-Zn massive sulfide deposits located. within the Noranda Cauldron which occurs within the core of the Noranda Volcanic Complex. The deposit is located at the top of the Havrian Formation, the lowermost formation of the 3000 m thick Mine Sequence; the deposit has Yielded 2.75 M tonnes of ore grading 3% Cu, 0.96% Zn, 2.06 g/t Ag and 1.0 g/t Au. The multi-lens Corbet deposit formed within a 250 m wide crater that occurs within a localized breccia pile. The Corbet breccia pile was constructed by explosive magmatic and hydrovolcanic eruptions localized along the south flank of a larger andesitic shield volcano that formed during the waning stages of Havrian volcanism. The breccia footwall of the deposit allowed unfocused and widespread hydrothermal discharge that resulted in the development of a large area of chlorite and fringing sericite alteration that exceeds, by six times, the size of the sulfide lenses and represents a significant exploration target.

Jan 1, 1993

By R. Bonnar, R. J. McH. Clark

"The Cheminis gold mineralization zone is approximately 6.5 km west of the Kerr Addison Mine along the Larder Lake Shear Zone, in the southern part of the Abitibi Greenstone Belt. The zone is very similar in appearance to the flow ore at the Kerr Addison Mine and occurs at the same stratigraphic position. Drilling has demonstrated that the gold mineralization at Cheminis persists to a depth of over 3000 ft .The mineralization is hosted by a pyritic, tuffaceous sediment which occurs within a sequence of volcanics and sediments which have been pervasively carbonatized. The gold is largely enclosed within pyrite grains and the amount of gold in the layers of pyrite increases in the layers closest to a graphitic f ault zone.It is suggested that the gold mineralization may be primarily related to the syngenetic sulphide concentrations formed during fumarolic activity on the seafloor along the Larder Lake Shear Zone. At a later stage a hydrothermal event associated with alkalic volcanism may have resulted in regional carbonatization and further concentration of the gold in the vicinity of fault zones."

Jan 1, 1987

By K. A. Hughes

Under the oxidizing conditions of the McClean Lake Tailings Management Facility (TMF) hydrocarbons entrained on the surface of tailings material from mill processes are gradually converted to soluble bicarbonate ion. This has been observed to be a process occurring over approximately three years likely encouraged by the presence of a microbiological community within the tailings mass and in the water column. A recent tailings sampling campaign has provided evidence that bicarbonate ion is participating in the conversion of gypsum to calcite. In older tailings, equilibrium with calcite appears to be controlling the terminal bicarbonate ion concentration.

Aug 1, 2010

By C. W. Hancher, B. D. Patton, W. W. Pitt

"There are a number of nitrate-containing wastewater sources, as concentrated as 30 wt % NO3 and as large as 2000 m3/day, in the nuclear fuel cycle. The biological reduction of nitrate in waste water to gaseous nitrogen, accompanied by the oxidation of a nutrient carbon source to gaseous carbon dioxide, is an ecologically sound and cost-effective method of nitrate waste disposal. These nitrate-containing wastewater sources can be successfully biologically denitrified to meet discharge standards in the range of 10 to 20 g N(NO3-)/m3 by the use of a fluidized bed bioreactor. The denitrification bacteria are a mixed culture derived from garden soil; the major strain is Pseudomonas. In the fluidized-bed bioreactor, the bacteria are allowed to attach to 0.25- to 0.50-mm-diam. coal fluidization particles, which are then fluidized by the upward flow of influent wastewater. Maintaining the bacteria-to-coal weight ratio at approximately 1:10 results in a bioreactor bacteria loading of greater than 20,000 g/m3,This paper describes the results of a bio denitrification R&D program based on the use of fluidized bioreactors capable of operating at nitrate levels of up to 7000 g/m3 and achieving denitrification rates as high as 80 g N(N03-) per day per litre of empty bioreactor volume. IntroductionThe discharge of wastewater containing nitrate at concentrations greater than stipulated by the Environmental Protection Agency (EPA) creates an environmental hazard and constitutes a civil and/ or criminal legal liability.(I.2) At present, we have three options: (1) recycle and reuse of nitrate streams the total economic and technical balance should be Closely examined; (2) use of an alternative acid, which may pose an entirely different set of problems ; or (3) disposal of nonreusable nitrate sources by an environmentally acceptable procedure."

Jan 1, 1980

By H. K. Olsen, B. Thomassen, H. K. Schønwandt, L. Grahl-Madsen, H. Stendal

Abstract-The central part of the early Proterozoic Ketilidian orogen in South Greenland consists of an I-type granitoid batholith transected by four regional NE-SW-trending shear zones. The batholith was probably emplaced during subduction, from the south toward the Archaean craton in the north, in a sinistral transpressional system. A regional sediment sampling program covering 5000 km2 shows a close connection between a gold-mineralized trend and one of the major shear zones within the epizonal facies of the batholith. The gold mineralization is not directly related to the major shear zones, but occurs in quartz-veined and silicified second-order structures. High-grade (up to 114 ppm Au over 6 m) low-tonnage mineralization is found within these second-order structures cutting both amphibolites and granitoids. The mineralization is characterized by negligible or small alteration halos. Gold is associated with various element combinations of enhanced As-Bi-W- Cu, which indicate that the mineralization is mesothermal in origin.

Jan 1, 1995

By H. K. Olsen, B. Thomassen, H. K. Schønwandt, L. Grahl-Madsen, H. Stendal

The central part of the early Proterozoic Ketilidian orogen in South Greenland consists of an I-type granitoid batholith transected by four regional NE-SW-trending shear zones. Thebatholith was probably emplaced during subduction, from the south toward the Archaean craton in the north, in a sinistral transpressional system. A regional sediment sampling program covering5000km2shows a close connection between a gold-mineralized trend and one of the major shearzones within the epizonal facies of the batholith. The gold mineralization is not directly related to the major shear zones, but occurs in quartz-veined and silicified second-order structures. High-grade(up to 114 ppm Au over 6 m) low-tonnage mineralization is found within these second-order structures cutting both amphibolites and granitoids. The mineralization is characterized by negligible or small alteration halos. Gold is associated with various element combinations of enhanced As-Bi-W-Cu, which indicate that the mineralization is mesothermal in origin.

Jan 1, 1995

By Ken Wood, Luc Duval

"The development and operation of the milling circuits treating the different Selbaie orebodies are discussed in this paper. The project is reviewed from metallurgical evaluation through construction to present operating status. The current flowsheets are described, with discussion of some unusual features.IntroductionThe Selbaie concentrator commenced initial production in August 1981, treating underground B zone copper ore in a single 1500 t/d circuit. Throughput was increased to 1650 t/d in 1985. The mill was expanded in 1986 to treat ore from the A-I zone open pit; an independent circuit was added to selectively treat 5000 t/d of copper-zinc ore. Current total mill throughput through both circuits averages 7200 t/d with the production of approximately 270 t/d of copper concentrate and 230 t/d of zinc concentrate.This paper describes the stages involved in bringing the project from initial laboratory testing to its current status as one of the most important producers of silver, copper and zinc in Quebec and a major employer in the region."

Jan 1, 1990

By J. Béland, C. Giguère

"The auriferous mineralization at the Sigma-2 gold mine occurs in quartz-carbonate-tourmaline veins emplaced in a fractured granaphyre layer in the upper part of a differentiated gabbro-diorite sill. Kinematic indicators show that fracture planes were active as strike slip, dip-slip (reverse) and tensional faults.Measurements of attitudes of fractures and movement vectors indicate eight different sets that can be grouped into three systems: (I) an east-west oriented system includes a subvertical set and two other sets dipping north and south respectively; (2) a subhorizontal system of two conjugate sets bisected by a third tensional set; and (3)a system of sub vertical conjugate northeast and north-northwest trending sets.Kinematic analysis indicates that the subvertical set of the east west system was subjected to dextral strike-slip movement activated by a northwest-southeast compressive stress whereas the bulk deformation resulting from the remaining and subsequent seven sets can be explained by a protracted subhorizontal north-south compressive stress.The valuable gold mineralization is found principally in the fracture-filling veins of the subhorizontal system and subordinately in the other sets; among these other sets, the NE trending subvertical one is slightly more favourable.The over-all tectonic picture is that of an early mild dextral strike slip faulting in a ductile-brittle medium followed by a general flattening involving, first, a vertical and, later, a lateral extension by fracturing in a medium that had become brittle.The structural features are such that the differentiated sill could not be the source of the auriferous hydrothermal solutions."

Jan 1, 1990

By R. H. Duval

"In May 1936, Pamour started producing gold by cyanidation of flotation concentrates, and in 1939 was milling about 1, 600 tons per day.Refining records dating from 1939 show two oil-fired furnaces in use, (Rockwell type 46 11 x 29 11 inside oval shell).Refining time averaged 7. 83 hours during the year 1939, indicating a complete refining shift of about 9. 33 hours. That year appears to be characteristic of the period with regard to time required and results obtained.For that year total fineness (gold + silver) of the bars averaged 940 (approx.), but it frequently dropped below this figure, sometimes far below.Furnace lining life varied widely from three to seven or more months. Sillimanite was the standard lining but Mullfrax 41 was frequently used.For many years refining practice remained practically unchanged, and in 1960 procedure still consisted essentially of mixing a flux(% Composition Borax 41, Silica 11, Soda-Ash 11, Nitre 15, Mn02 22) with cyanidation precipitate in the ratio of l. 2 to l and heating to a medium heat (yellowishred, 2000° F) with a low flame for a long time. Time required was about 10. 5 hours per refining. Results were still much as detailed above.At this time it was decided to revise refining procedure, in an effort to shorten refining time and obtain consistently good bullion fineness."

Jan 1, 1965

By Neri Roux, Ross Gilders, Yemi Oyediran, Leo Cheung

Quest Rare Minerals Ltd. is developing their Strange Lake B Zone REE deposit located in Northern Quebec. An extensive batch bench scale testing program was launched to investigate open circuit rougher flotation performance under different conditions. The objective of the flotation study was to demonstrate the effectiveness of rejecting gangue minerals to flotation tailings while concentrating rare earth elements as well as yttrium, zirconium, and niobium into a concentrate suitable for further hydrometallurgical processing. Mineralization of interest at Strange Lake occurs within peralkaline granite-hosted pegmatites and minor aplite. The REE and high field strength element (HFSE)-bearing phases are hosted primarily in pegmatites as relatively fine-grained phases or pseudomorphs. The gangue phases comprise of quartz, feldspar, amphibole, and pyroxene. Potential ore minerals comprise predominantly of kainosite, gerenite, gadolinite, zircon, pyrochlore, and gittinsite. These complex mineralogical characteristics increase the difficulty for processing and provide a challenge for choosing the correct reagent scheme in rougher flotation. Process options including reverse flotation to reject the gangue minerals and de-sliming prior to the direct rougher flotation were investigated. Optimization trials were conducted using various reagent regimes and under different flotation conditions. Encouraging results were found using a combination of collector reagents supplied by Cytec Canada Inc.

Jan 1, 2014

By Curtis Rempel, John Bartlett, Alex Holtzapple

METSIM is a powerful program capable of modelling and simulating every known metallurgical and inorganic chemical process. METSIM is used by companies throughout the world to design, simulate and control operations from mine to tailings and everything in between. At its absolute simplest, METSIM can be used to create a process flowsheet. METSIM modules and built-in unit operations cover mass and energy balances for either steady-state or dynamic simulations of mine, stockpile, heap leach, material handling, comminution, beneficiation, hydrometallurgy, pyrometallurgy, gas and steam handling, and tailings management processes. Data for the material being processed can include mineralogy, particle size analysis, grade by size or multicomponent size analysis, washability data, mechanical, physical and thermodynamic properties. METSIM is written in APL (A Programming Language). Unlike C++, APL is simple and easy to learn, allowing the user to program whatever they can imagine, without first obtaining a degree in computer science. METSIM can also interface with EXCEL and other software through dynamic data exchange (DDE), allowing data to be imported and exported for viewing, analyzing and controlling. METSIM can answer simple or complex metallurgical and process questions allowing the user to predict and engineer without the issues of clumsy and tortuous spreadsheets.

Jan 1, 2014

By M. Rigaud, K. Sankaranarayanane, X. Zhou

The effect of varying fine alumina/ultra-fine alumina ratio on the Bingham to dilatancy transition in alumina based, self-flowing refractory castables has been studied in detail employing rheological tests and particle size distribution measurements. Analysis of flow resistance and torque viscosity values has shown that Bingham to dilatancy transition is strongly influenced by fine alumina/ultra-fine alumina ratio in the castable, as well as by the nature of ultra-fine alumina. The calculated values of rheological constants and the viscosity coefficient were found to increase at higher fine alumina/ultra-fine alumina ratios.

Jan 1, 2004

By R. J. Bowell

Mineralogical controls exert significant control over the extraction of uranium from its ores. Uranium speciation, associated mineralogy, deportment and uranium mineral availability are all factors of consideration when assessing leachibility. This study presents data from laboratory uranium extractions undertaken on several contrasting uranium ores from a wide range of orebodies. The results provide insight into the mineralogical factors of importance when considering uranium extraction. These results are presented within the wider context of geometallurgy and demonstrate how geometallurgical assessment, even at an early stage of mine development, can greatly assist in the design of a suitable extraction scheme.

Aug 1, 2010

By George P. Demopoulos, Amani Al-Othman, Terry C. Cheng

One critical issue in chloride hydrometallurgy is the regeneration of the lixiviant HCl that is currently achieved by pyrohydrolysis. In this paper, a low temperature HCl regeneration process was investigated which regenerates HCl and produces saleable gypsum. This process promises to reduce the generation of wastes by the reaction of spent calcium chloride leach liquors with sulfuric acid solution at low temperature. Experiments were performed to determine the optimum conditions of the reaction in terms of temperature, reagent concentrations, rate of reagent addition, mixing and seeding/recycling to produce marketable gypsum and HCl with practical strength.

Jan 1, 2004

World copper electrowinning tankhouse plant practices have been surveyed. This survey is a supplement to previous surveys that have been carried out in 1995, 1999, 2001, 2002 and 2003. On a world basis, process technology trends include the further installation of automated electrode handling systems including permanent cathode systems, automated cathode handling machines, fully automatic cranes and polymer concrete cells. Designs also have included larger electrode sizes and higher electrolyte flows and current densities. Overall these trends have further resulted in optimized tank house productivities and improved electrowon cathode purity. Most greenfield copper electrowinning projects are occurring in South America and Central Africa.

Jan 1, 2007