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By Robert Lee

"International competition is presenting the Canadian steel industry with a major challenge. While Canadian companies have invested in new technology, research and development, activity by Canadian industry, in general, lags significantly behind that of its major competitors. While OECD countries increased their research and development spending during the 1980s, Canada's R&D funding levels have changed little since the early 1970s and have actually dropped since 1986, despite greater public discussion on the issue. This fact is reflected in the relatively slower pace of innovation in the Canadian steel industry, despite the efforts of both government and industry.In addition, there are a number of factors that undermine the competitiveness of the Canadian steel industry, in particular in relation to the United States. Among these are higher interest rates, labour costs and tax rates, as well as an overvalued Canadian dollar. Canadian steel companies are thus feeling the full impact of the current economic recession. This recession, combined with recent strikes, have, for example, caused serious losses for Algoma and Stelco.In spite of these objective difficulties, the Canadian steel industry has been able to survive and continues to strive for a leadership position in the world market. Since World War II, heavy investment in new technology has allowed the industry to upgrade its facilities and increase productivity, while at the same time improving quality and reducing pollution. This last point is particularly important in view of public insistence on improvements to the quality of the environment. Over the next decade, this technological innovation must be maintained and intensified if industry is to meet the challenge of international competition and attain a leadership position."

Jan 1, 1991

By G. Shore

"The development of a DC resistivity instrumentation system for data acquisition in extreme topography yielded an unexpected bonus in the quality and information content of the type of raw data gathered. Not only were traditionally too-rough areas being investigated systematically for the first time, the unique high-density, multi-directional raw data were providing the opportunity to greatly expand the range of conductive and resistive signatures that could be accurately recognized. Using a true 3-D inversion algorithm, 3-D earth resistivity imagery began to show distinctive anomaly patterns for hydrothermal mineralization at the seldom-visited resistive end of the spectrum, successfully imaging epithermal gold systems in conditions that had defied conventional ground and airborne geophysics for years.The traditional mode of designing a resistivity survey to test a specific target concept was shown to be an unnecessary limitation on exploration thinking when a single sweep acquisition of dense, multi-directional 3-D raw data could effectively provide the all-targets “shotgun” coverage that would take 10 or 12 conventional surveys to duplicate. Exploration planning has the opportunity to move from single steps of trial and error geophysical testing to a mode of mapping everything at the outset, and then sorting out what might be of exploration interest in the results. Survey parameterization becomes the non-technical process of marking an outline on a map and declaring “survey here.” Operational and interpretational reasons for not testing where the exploration interest lies have all but disappeared. With any-terrain capabilities and unprecedented raw data density and overlap to support interpretation of complex conditions, that outline can be drawn through extreme rough terrain, including lakes, cliffs, industrial facilities, and grounded installations to test for generally unknown sub-surface features of potential interest.As more is learned about the larger-scale signatures of ore settings and the district-scale geo-electric imprint of hydrothermal processes on lithology, it appears that the only thing certain about ore signatures is their uncertainty. This is not bad news. New opportunities abound as the advanced 3-D technology allows a first effective look at the previously unexplorable rough terrain or complicated settings, and a second look at areas where older results may now be known to be non-definitive."

Jan 1, 2002

By B. F. Osborne

"A new sensor cannot be considered in isolation from the process in which it is utilized. This paper, describing an on-stream particle size analyzer, therefore gives considerable emphasis to the slurry handling techniques employed to ensure that the instrument is presented with a representative sample. A new sampler is described, which continuously abstracts a small, representative sample from a closed pipeline containing a flowing slurry. This sample is then diluted, thoroughly mixed and pumped to a head tank, from where a continuous stream is fed at a constant rate to the size analyzer. Data are presented to show that particle size segregation is minimal throughout this sampling and sample preparation. A continuous particle size analyzer based on a separation principle is described, and the basic parameters of size distributions, and how they relate to this particular instrument, are considered. Typical results are given. An electronic system is presented which accepts the basic sensor outputs, and converts these to a particle size signal suitable for process control. Finally, the use of an inplant computer to process the sensor signals to obtain a particle size signal is briefly considered."

Jan 1, 1972

By E. Asselin, G. K. Yue

"In the present study, electrochemical measurements, especially cathodic potentiodynamic polarization (CPC) and cyclic potentiodynamic polarization (CPP), have been employed to study the kinetics of ferric reduction on chalcopyrite in aqueous Fe(II)Fe( III)H2SO4 solution at 90 °C and 110 °C. Results from the calculation of speciation in the above solution reveal that, at both 90 °C and 110 °C, the real Fe3+/Fe2+ ratio is much lower than the nominal ratio, which leads to smaller VALUES (for the reversible potential of the ferric/ferrous couple. Exchange current densities of the ferric/ferrous couple were obtained and are on the order of 106 10 5 A/cm2 a t 9 0 °C and 1 07 10 6 A/cm2 at 110 °C, respectively. The Tafel slopes from the CPP method are higher than those from the CPC method at both 90 °C and 110 °C. The transfer coefficients were about 0.360.59 at 90 °C and 0.370.65 at 110 °C. Based on the exchange current densities obtained, the rate constant kc was calculated. It was found that kc at 90 °C was slightly larger than at 110 °C, especially for the results obtained by the CPC method. The average rate constants are 862.17 cm/s for CPC and 65.30 cm/s for CPP at 90 °C, and 477.69 cm/s for CPC and 63.53 cm/s for CPP at 110 °C for nominal Fe3+/Fe2+ ratios ranging from 1:1 to 1000:1. INTRODUCTIONChalcopyrite is one of the most abundant copper-bearing minerals, accounting for approximately 70% of the world’s known copper reserves (Wang, 2005). Most of the currently proposed leaching processes are based on sulfuric acid with ferric ions and/or dissolved oxygen as oxidants. Some of these processes have been piloted in attempts to implement these technologies on an industrial scale, such as Activox (U.S. 5,232,491, 1993), Nenatech (U.S. 5,993,635, 1999), Dynatec (U.S. 5,730,776, 1998), AAC/UBC (U.S. 6,503,293, 2003), Total Pressure Oxidation (U.S. 5,698,170, 1997), CESL (U.S. 5,874,055, 1999) and Galvanox (U.S. 7,846,233, 2010).To date, much effort has been devoted to understanding the kinetics and mechanisms of the oxidative processes (Biegler & Horne, 1985; Córdoba, Muñoz, Blázquez, González, & Ballester, 2008, 2009; Ghahremaninezhad, Asselin, & Dixon, 2010; Hirato, Majima, & Awakura, 1987; Hiroyoshi, Kuroiwa, Miki, Tsunekawa, & Hirajima, 2004; Warren, Wadsworth, & El-raghy, 1982) or the cathode reduction reactions of chalcopyrite itself (Arce & González, 2002; Biegler & Swift, 1976; Biegler, 1977; Nava, González, Leinen, & Ramos-Barrado, 2008), by chemical or electrochemical methods. However, as the most important cathodic processes in chalcopyrite leaching systems, the cathodic reductions of ferric ions or dissolved oxygen are worth measuring due to their effects on the overall leaching rate, as predicted by mixed potential theory."

Jan 1, 2012

By M. E. D. Raymont

"During the history of the sulphur industry there have been three distinct phases of production. Factors controlling supplies during these periods have shifted from demand for sulphur to demand for energy and a cleaner environment. The pattern of brimstone production is t raced through these phases and includes estimates of future supply; these indicate an involuntary excess production of some 20 million plus tons per year by 1980 unless some large-scale new uses are found. Traditional uses for sulphur, including fertilizer, chemicals, fibers, etc., are generally expanding slowly; how• ever, supply in ""by-product"" form alone will soon outstrip demand. The predicted oversupply situation can be corrected by the development of novel potential markets. Promising areas include construction materials, insulation and plastics, among others."

Jan 1, 1972

By A. M. Salomon de Friedberg

"With respect to impurities, HBM&S' copper smelter, located in Flin Ron, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Ron is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&S' metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.IntroductionHudson Bay Mining & Smelting Co. Ltd. (HBM&s), has been operating its metallurgical complex located in Flin Flon, Manitoba, since 1930. The smelter and zinc plant were originally separate entities with respect to production. The smelting operation consisted of traditional multiple-hearth roasters, a reverberatory furnace and Peirce-Smith converters. The zinc plant also utilized multiple hearth roasters and then followed with sulphuric acid leaching, purification and electrowinning. The zinc plant also recovered cadmium from a separate purification/electrowinning circuit.The two plants operated essentially independently of each other until rising zinc levels in the copper concentrate and large stockpiles of zinc-rich leach residues prompted the construction of the fuming plant in 1949. The smelter used pulverized coal to reduce zinc oxide present in the reverb slag and then captured the resulting zinc bearing fume in the fuming plant baghouse. The fume was sent to a separate ""oxide roaster"" in the zinc plant where it was first roasted to remove halogens and then leached to recover the contained zinc. This oxide fume became a major source of feed to the zinc plant accounting for roughly one quarter of the total zinc production. Furthermore, through the smelter's treatment of sulphide leach residue, both copper and zinc recoveries were improved for the over-all complex."

Jan 1, 1993

By J. A. Finch

"Gas dispersion in flotation defines the efficiency of the process once the chemistry has been established. There are three measurements, superficial gas velocity, gas holdup, and bubble size, which along with the derived quantity bubble surface area flux, are used to define “gas dispersion.” Sensors for measuring gas dispersion in industrial machines have been developed. This communication describes the working principle of the techniques and illustrates their potential to detect problems and to improve the operation of individual cells, banks and circuits. IntroductionFlotation is the most widely used process to separate minerals and is finding increasing application in other chemical and environmental fields. The process exploits natural and induced hydrophobicity to collect selected particles on the surface of a bubble. Once the process chemistry to control hydrophobicity has been established, the efficiency depends on dispersion of air to generate the necessary bubble surface area. Bubble surface area flux, Sb, the interfacial area generated per unit time and unit area of the machine, is emerging as one of the most useful variables to quantify gas dispersion (Gorain et al., 1997, 1998) although not without its critics (Heiskenan et al., 2001).For a bubble population of mean size db at a superficial gas velocity (or rate) Jg, the bubble surface area flux can be derived from geometric considerations (Finch et al., 1999):"

Jan 1, 2002

By C. M. Anson

Introduction The prosperity of any country today is dependent upon the efficiency and growth of its primary steel industry. The ?march of the United States of America to its present commanding position in world affairs parallels the growth of its steel industry. The remarkable growth of that industry was possible only because bountiful providence endowed that country with adequate supplies of the raw materials necessary for steel making -coal and iron ore. If we accept this hypothesis, and surely we must, then to what extent can we envisage the future of our own country? This symposium deals with the most important of the raw materials required for steel making -iron ore. If we are blessed with a bountiful supply of iron ore, then surely a glorious future awaits only our taking advantage of that blessing. It is becoming increasingly evident that Canada has immense iron ore deposits. It is my privilege to make you acquainted with one of these, one that can only be classified as among the more important ore reserves in the world. I refer to the Wabana ore deposits in Newfoundland. Location These deposits lie under the floor? of Conception bay, off the east coast of Newfoundland. They consist of a series of beds which outcropped for a distance of about three miles on the northeastern shore of Bell Island, dipping at approximately 8° toward the northwest. This three-mile outcrop is the only key to the occurrence.

Jan 1, 1951

By Abu Syed H. Kabir, Mehdi Sanjari, Steve Yue, Jing Su, In-ho Jung

AZ31 magnesium alloy sheets were produced by high speed rolling (HSR) at 1000 m/min at a low temperature of 100 ?. A high reduction of 72% can be achieved in single pass. At the reduction of 30%, the microstructure was covered by shear bands and twins. When the reduction was increased to 49%, dynamic recrystallization (DRX) was clearly observed in the vicinity of shear bands and twins and the full recrystallization was seen at a reduction of 72%. In order to study the static recrystallization (SRX) behavior on the heavily twinned structure, annealing was then carried out at 200 ? on the as-rolled specimens at the reduction of 30% for different times. Static recrystallized grains were also firstly observed on shear bands and twins after 45 s and the microstructure was mostly fully recrystallized after 1 h annealing with a few retained large elongated un-recrystallized grains. Texture weakening was found during annealing on the heavily twinned specimens by SRX, but not during high speed rolling by DRX. In the present study, effect of DRX and SRX on microstructure and texture evolutions during rolling and annealing were compared.

Jan 1, 2015

By A. M. Salomon de Friedberg

With respect to impurities, HBM&S' copper smelter, located in Flin Flon, Manitoba, is in an unusual position. In addition to the usual concerns, the fact that copper and zinc production at Flin Flon is closely integrated results in the unique situation where feed to the copper smelter typically contains 7% to 8% zinc. This paper discusses the ramifications to copper smelter operations resulting from the marriage of HBM&S' metallurgical plants. Distributions of impurities (specifically Zn, Pb, Ni, As, Bi, Sb, and Cd) are presented and operating practices designed to reduce the impact of impurities on anode copper quality are detailed.

Jun 1, 1993

By Peter R. Drummond

THE paper consists of four sections: (1) a discussion of early work; (2) presentation of the results of a chemical investigation of Falcon-bridge nickel-copper blast-furnace matte; (3) application of the results of this investigation to mattes in general; and ( 4) a summary of conclusions. All general discussion will be confined to the fundamental system of ferrous-cuprous sulphides (FeS-Cu2S). Nickel-, lead-, and zinc-bearing mattes will be treated as minor varieties of the parent system. DISCUSSION OF EARLY INVESTIGATIONS Matte investigations may be divided into three classes: first, those treating the sulphides as alloys-theoretical studies of the system FeS-Cu2S, such as those of Hofman (ll)t or Carpenter and Hayward (2); second, chemical research on mattes made under smelter conditions, such as that carried out by Hawley (3) or Avetision ( 4); third, combinations of the . above, such as the investigations of Gibb and Philp (5) or Fulton and Goodner (6). Much research in the first of these classes, including determinations of . freezing points and of data for structure-composition diagrams of the system FeS-Cu2S, was carried out in the period 1890-1910. LeChatelier and Ziegler (1, 13) proved that FeS, when heated alone above its melting point, dissociated in part, and Friedrich ( quoted by Fulton, 6) showed the same for Cu2S. The reactions may be expressed by the following equations: [xFeS yFe + yS (volatilized)+ (x -y)FeS xCu2S )'Cu+ yS ( vohtilized) + (x -)')Cu,S ] Sulphur is lost by volatilization, leaving a melt of metallic iron plus ferrous sulphide in the one case, and of metallic copper plus cuprous sulphide in the other. If the mixed sulphides are heated far above their melting points, there results either an iron-rich matte containing Fe-FeS-Cu2S or a copper-rich matte containing FeS-Cu2S3-Cu, depending on the relative amounts of each sulphide in the mixture.

Jan 1, 1940

By Duanyou Li, Qing Xiao, Zhiwang Wang, Xiaoqing Gan

"Seepage is a major cause of earth-rockfill dam failure. Numerical simulation of infiltration process, distribution of drift, flow velocity and direction after the impoundment can guide seepage control and evaluate its effects. A double field coupling model is established based on soil consolidation theory and the interaction between the seepage field and the temperature field. The simulation is implemented under the situation of core wall setted, core wall not setted, and core wall setted with concentrated leakage. The results indicated that the saturation line height was significantly reduced due to impervious core wall, and the temperature distribution is uniform above the saturation line. If concentrated leakage occurs, temperature distribution of dam was significantly changed, which is consistent with theoretical inference.INTRODUCTIONEngineering seepage field distribution must be calculated in seepage control design, optimization, and correction of new engineering construction of earth dams, as well as in seepage monitoring and evaluation of existing earth-rockfill dams. The aim of calculation is to identify the important parameters in seepage field, such as the coefficient of permeability, seepage flow, pressure, head, and allowable seepage slope, for effectively implementing seepage control design, correction, safety assessment, and anti-seepage reinforcement. These seepage parameters usually can be obtained by in-situ test and back-analysis based on reliable monitoring data.In order to obtain reliable monitoring data and reflect the earth-rockfill dam seepage state and change process, appropriate monitoring technology and monitoring method is necessary. The traditional seepage monitoring method is through site inspection and sensors (e.g., osmometer, piezometric tube and measuring weir) that buried in the structure and its foundation. However, there are still some disadvantages:"

Jan 1, 2015

By L. H. Bergmann

THE blasting practices described are fairly representative of those employed in the coal mines of Eastern Canada. As such, they may be of interest to Western Canadian coal mine operators. The treatment of the subject is general, no attempt being made to discuss blasting operations at any particular coal mine in detail. All the mines dealt with are mining bituminous coal and are classified under the Coal Mines Regulation Act of the Province of Nova Scotia as 'closed light' mines. As such, they are required to use only 'permitted' explosives and to apply them in a 'permitted' manner, except where authority is given by the Mines Department to do otherwise.

Jan 1, 1945

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter has been developed to predict the molten temperature. The primary assumption of the model was that all matte, slag and gaseous phases in the converter were in thermal and chemical equilibrium. In this model, the matte components were considered only as copper, iron and sulfur elements. In the slag making stage, all the reacted iron was converted to fayalite. The reaction rate of iron and oxygen in this stage was considered to be constant. The converter temperature was calculated by heat balance over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depends on process parameters such as oxygen efficiency and molten emissivity.

Jan 1, 2007

By C. W. K

This little sketch of the late Willet G. Miller, Provincial Geologist of Ontario, is intended to be neither a biography of his career nor a eulogy of his life. His biography has already been written in an incomparable manner by Mr. T. A. Rickard, his eulogy by Canon Cody. What more can be said of Dr. Miller than is summed up in the words of that great Canadian divine, Canon Cody, that he was "Big in body, big in heart, and, as we learned, big in brain." This article, then, will merely record a few personal reminiscences of the man himself, and while they are necessarily disjointed, they may at least serve to illustrate certain traits in his character which are not generally known or appreciated outside of the circle of his intimate friends. In the latter part of May in the year 1904, Willet G. Miller, with two? assistants, set out for the small village of Haileybury to begin his geological work in the area a few miles to the south which he was soon to name Cobalt. At that time the Timiskaming and Northern Ontario railway was not finished, although the right-of-way was cleared and partly graded. The nearest railway station was on the Canadian Pacific at the south end of lake Timiskaming, from which point the old steamer Meteor carried passengers and freight up the long, narrow and deep waters of lake Timiskaming, a very pleasant trip of some sixty miles. On this particular trip there was a fairly large crowd on board consisting of settlers going into the clay belt north of lake Timiskaming, of lumbermen, and of a few merchants and commercial travellers who were interested in the small business centres of Haileybury, New Liskeard and Ville Marie. Scarcely any attention was paid to the reports of the newly found silver deposits, although the daily papers had announced discoveries in the district six months before. As a matter of fact, the chief excitement on board was afforded by a moose, which, in swimming from the Ontario to the Quebec shore of the lake, crossed the bow of the boat, the captain steering to within a few yards of the terrified animal.

Jan 1, 1925

By I. Cotman

Dimensional stone processing has become an important part of the world extractive industry, and today?s total stone block yearly production is estimated to be around 134.000.000 tons and is still growing by an average yearly rate of approximately 20%. In future, the same production will become an important part of the mining industry and presently, in some countries it represents even the main mining output. New environmental regulations, together with landscape and nature conservation requirements, create a number of difficulties in setting up new open pit dimensional stone quarries. As a result, many dimensional stone producers have recently started to apply underground techniques in order to produce the ornamental stone blocks intended for further processing. Underground production of stone blocks requires special mining methods and so far it has not been a cost-effective excavation method for all types of rocks. Presently, this type of stone excavation is generally applied in sedimentary and marble deposits because the rock has small to no mineral quartz content. When starting a new underground dimensional stone mine, it is necessary to analyse the impact of all primary factors which are crucial to set up a technically and cost effective advanced underground dimensional stone mine. The role of physical and mechanical properties of the rock, geological conditions, mineralogical composition, micro-tectonic state of the site, rock mechanic conditions on the site, durability and saw ability of the stone are decisive factors in foreseeing the future methods of extraction. The laboratory research work as well as the field work, is very important in decision-making aimed to choose the future excavation method. Also of equal importance is the serious market research, because it renders the indication of selling price potential. Having obtained the results from both types of research, mining engineers can design the mining methods which optimize financial return to the mine. The practice approved by 15 years of testing in the underground limestone quarry of Kanfanar gives future producers very useful advice and general data to facilitate the process of exploration intended to establish new similar underground quarries.

Aug 1, 2013

By C. E. Baltzer, W. H. Harper

"This study has been developed to illustrate the trend and pattern of distribution applying to the quantities and costs of the fossil fuels used, and the related amounts of electricity generated, in the thermal segment of the Canadian electric utility industry.Traditionally, Canada's requirements for electric energy have been preponderantly met by hydraulic power. The need for augmented supplies of thermally generated power has mainly developed since the close of World War Il-in an era that has seen drastic decline in the production of indigenous coal and buoyant expansion in the supply of oil and natural gas. Although coal currently is faced with serious competition from the fluid fuels, the utility industry in particular promises an advancing market for coal, because of its abundant resource, at prices less likely to show sharp increase. For Canada as a whole, this trend has been progressive since 1959, and, unbelievable as it may now seem, the extent of the advance by 1975, particularly in Ontario and the Prairie Provinces, may well be as much, or even more, than the present rate of consumption for all purposes.The text and the tables and charts are arranged to focus attention on: the growth of thermal genera ting capability; the historical trend in consumption of fuel and the related production of electricity; patterns of distribution by types of fuel and thermal capacity; the relationship of steam to other sources of thermal capacity; and the quantities, costs and related percentages of electricity generated by types and kinds of fuel used, both regionally and provincially."

Jan 1, 1966

By A. G. Mattes

This paper presents an overview of passive, engineered, biologically-based anaerobic bioreactor (ABR) treatment systems of the sort that can be used to remove dissolved copper from mine wastewaters. The paper begins with a brief history of the origins of this treatment technology and continues with a discussion of principles of engineered wetlands (EWs, advanced kinds of constructed wetlands, CWs) and the use of vertical sub-surface flow (VSSF) varieties that contain pulp & paper biosolids as the reactive medium for EW cells. A brief outline of a procedural methodology used in evaluating the potential for biological treatment on a site-specific basis is also included. An introduction to the microbiology of passive biologically-based treatment systems is followed by some recent research results in the general area of wetlands and ABR research. The paper concludes with a brief discussion of several sites known by the authors to have successfully (or not) demonstrated the potential of this treatment option.

Jan 1, 2007

By W. H. Patterson

The history and experience of early companies in the Islands is illustrated by the typical transactions of Trans-Western from 1959 to date. Trans-Western had entered into farmout agreements with companies strong enough to carry out at least the required minimum exploratory work and then such development as might be warranted. The farmee companies were required to make deposits to guarantee work performance during the first period of validity, i.e. the first 3 years of the 12-year life of the permits, and at the rate of 5 cents per acre. At that time, a good deal of geology was available, as a result of extensive exploration that had been carried on by the Geological Survey of Canada and other geological enterprises, with field parties travelling over and camping on all of those Islands. Trans-Western's farmees then selected, from Trans-Western's priority on 13.5 million acres, what they believed were the lands most prospective of producing large oil and gas discoveries, and, having the right to trim off acreage which they considered less prospective, thereby reducing the acreage of Trans-Western and its farmees to in excess of 5.5 million acres. The farmees then commenced a 3-year program carrying out geological exploration to the required minimum of 5 cents per acre, and with some permanent and many mobile camps.

Jan 1, 1969

By R. B. Ellestad

Introduction Lithium has been known since 1817, when it was discovered by the Swedish chemist, Arfvedson, while working in the laboratory of Berzelius on the chemical analysis of the mineral petalite, LiAl(Si205)2. Development of the chemistry of lithium proceeded slowly, following the early work of Davy, Gmelin, Bunsen, and Matthiessen. Approximately seventy years elapsed before lithium products assumed any commercial importance, and for a considerable period it was a' very minor industry. Their chief early use seems to have been in medicine, and in the production of lithiated water. Other more important uses were gradually discovered, and the industry has had a slow but steady growth. Chemistry Lithium is classified as an alkali metal, along with sodium, potassium, rubidium, and cæsium. Like these, it is a silvery-white metal, which can be cut with a knife; it is harder than sodium, but softer than lead" It is remarkable in having a density of only 0.53 gram per cubic centimeter, which makes it the lightest metal. On ignition in air, it burns intensely to form chiefly lithium monoxide, Li2O. Like the other alkali metals, lithium reacts vigorously with water to form hydrogen and lithium hydroxide. The later is a strong base, and reacts with acids to form salts. The salts of lithium are in general analogous to those of the -other alkalies, but many of them have unique properties. For example, lithium chloride and bromide are extremely hygroscopic, and have a very high water solubility. Lithium fluoride, phosphate, and carbonate, on the other hand, are all relatively insoluble, unlike the corresponding sodium and potassium compounds. In this instance, lithium exhibits its frequent tendency to resemble the alkaline-earth group of elements (calcium, strontium, and barium). Many of the special and valuable properties of lithium are related to the extremely small size of the lithium ion.

Jan 1, 1948