Search Documents

By M. F. Goudge

ROCK wool, one of the most recent additions to the list of Canadian-made, insulating materials, is a soft, light, fibrous material consisting of interlaced, flexible, glassy fibres so exceedingly fine that, individually, they are almost invisible to the naked eye and will float in air. In the process of manufacture, a suitable rock, generally a self-fluxing argillaceous dolomite consisting of nearly equal proportions of acidic and basic constituents, is melted to a completely fluid state and then converted into fibres either by a blast of steam or air, or by a mechanical device. The increase within the past five years in the number of plants in the United States making rock wool and slag wool has been remarkable, especially in view of the depressed conditions prevailing 'with most industries during this period. In 1930, there were only 8 plants reporting production of .these materials, whereas at the present time there are 44 plants in the United States listed as making these products, and there are 3 plants in Canada. In 1929, the total sales of rock-wool products in the United States amounted to-$2,377,324. In 1934, according to the National Rock and Slag Wool Association, 26 member companies reported sales of $3,695,405, and in 1935 the sale's of 30 member companies had a value of $5,571,469. The establishment of the rock-wool industry in Canada followed the publication in 1931 of a report (1) by the Mines Branch, Department of Mines, Ottawa, in which was set forth the results of field work and laboratory studies which indicated that large deposits of rock in the Niagara peninsula, hitherto regarded as valueless, were suitable for the making of rock wool. This report was supplemented in 1934 by another report (2), giving the results of further laboratory and commercial-scale tests on the rock from these particular deposits, which proved conclusively that rock wool of good quality could be made from the rock in question.

Jan 1, 1936

By Knud Sinding

Environmental reporting by mining firms takes many forms and change frequently. The objective of these reports is related to increasing the legitimacy of mining firms with their diverse stakeholders. This study, focusing on internet-based reports, shows that there are considerable variations in reporting. This phenomenon is interesting because it belies the efforts pursued by leading industry members under iniatives such as the Global Mining Initiative and the Mining, Minerals and Sustainable Development project. The observed variation, both internally among reports and between reports and other industry policy statements, suggests that the industry needs to explore the possibilities for more convergence in terms of reporting quality. Based on theoretical constructs from the management literature we present a series of arguments defining necessary and sufficient conditions for durable and well-institutionalized reporting practices and standards.

May 1, 2002

By C. G. McLachlan

Abstract This paper deals with the application of the cyanide process to recover gold from a pyrite concentrate produced by means of differential flotation. This concentrate before cyanidation contains from 0.09 oz. to 0.14 oz. gold per ton, of which only about 60 per cent is recoverable. The rest is so fine that it remains interlocked in the pyrite and therefore is not acted on by the cyanide. The concentrate also contains about 15 per cent pyrrhotite and 0.4 per cent chalcopyrite, both of which are cyanicides. The cyanicidal effect of the pyrrhotite is inhibited by preacracing the pulp with lime, and maintaining a high lime alkalinity during cyanidation. The effect of the chalcopyrice is reduced as far as possible by removing those particles which are free by means of a further flotation step immediately prior to cyanidation. This involves the flotation of some very fine material. After nullifying as far as possible these two cyanicides, the concentrate is cyanided directly, i.e., without being roasted. This leaves the pyrite available for subsequent sale as a source of sulphur dioxide and sulphuric acid, and the entire residue of the cyamde plant, amounting to about 500 tons per day, 1s now being disposed of in this way. Prior to deciding on direct cyanidation, a number of laboratory roasting tests were made. These showed chat, 1f proper control were exercised, a better recovery of gold could be effected from the roasted product than by the direct method of treatment. The tests also showed that the capital cost o the plant would be much higher than that needed for the procedure adopted. The possibility of subsequently selling the pyrite for its sulphur content would also have been eliminated. Introduction A previous paper has described in considerable detail the application of the flotation process to improve gold recovery from Noranda's milling ore, and in so doing has covered the production of an auriferous pyrite concentrate. The present paper deals with the recovery of gold by cyanidation from that concentrate. This gold, though intimately associated with the pyrite, can, for metallurgical purposes, be considered as all occuring in the native state.

Jan 1, 1946

By M. Dupuis

Recently, a new approach to controlling alumina feeding in a H.H. cell has been proposed [1, 2 and 3]. This approach, labeled In Situ aluminium cell control, is based on a correlation between the slope of the cell voltage during a no feed observation period and the dissolved alumina concentration in the bath. Once the dissolved alumina concentration has been estimated, a primary calibration surface uniquely relating the dissolved alumina concentration and the anode-cathode-distance (ACD) to the cell voltage is used to estimate the cell ACD. Once both the alumina concentration and the ACD have been estimated at the end of the observation period, a PID controller can be used to regulate the rate of alumina feeding using only the normalized cell voltage to calculate the error between the estimated dissolved alumina concentration and a target value. The In Situ aluminium cell control algorithm has now been tested with the Dyna/Marc [4, 5 and 6] cell simulator demonstrating that it should be possible to control a H.H. cell in this manner with less variation in the dissolved alumina concentration and other process variables producing a prediction of improved cell current efficiency and power efficiency.

Jan 1, 2011

By Jesús L. Valenzuela, José R. Parga, Salvador Aguayo, Héctor Moreno

The Merrill Crowe zinc-precipitation process has been applied worldwide on a large number of operations for the recovery of gold and silver resulting in a higher consumption of zinc dust from cyanide solutions. However, in some of plants this precipitate is of low quality, because lead, cadmium and especially copper are precipitated along with gold and silver. The low quality precipitate also requires more fluxes in smelting and shortens crucible life. In this study, a process is introduced to remove copper, silver, lead and cadmium from barren solutions following the Merrill-Crowe process. Copper and silver are removed by precipitation in a serpentine reactor, using sodium sulfide as the precipitator, and sulfuric acid for pH control. The recovery of lead and cadmium ions with natural hydroxyapatite using cow bone powder (CBP) as a new adsorbent material, is introduced. CBP is capable of removing lead and cadmium ions from aqueous cyanide solutions with 99% efficiency. It has the ability to compete with other existing commercial adsorbents for the removal of lead and cadmium. Results show that pH value has a significant effect on copper cyanide removal efficiency, and it was determined the optimal pH range to be 2 - 3. At this pH value, the copper cyanide removal efficiency achieved was up to 99 %; and for the cyanide associated with copper cyanide complexes, the recovery was 90%. Finally, the precipitate quality was improved 400% .This procedure was successfully run at three mines in México.

Jan 1, 2014

By W. A. Padgham, H. Helmstaedt

Field evidence for current hypothe e about age and kinematic ignificance of gold-bearing hear zones in the Archean Yellowkni fe greenstone belt is reviewed , and it is concluded that major disagreements between previous workers are a direct result of differences in stratigraphic and tructural in terpretations of the Yellowknife Supergroup. Although goldbearing hear zone appear to be confined to the mafic volcanic pile of the Kam Group. it can be shown that shearing affected all supracru tal rocks, including the Jackson Lake Formation. now con idered to represent the youngest unit of the Yellowknife Supergroup. tructural ob ervations are incompatible with the hypothe is that the hear zones represent loci of ynvolcanic gravity sliding but are consistent with earlier conclu ions that shear zone development commenced with rotation of the volcanic pile and continued as re ult of lateral shortening broadly overlapping with the emplacement of granitoid batholiths. Shear Zones are common throughout the entire green tone belt. yet productive zone are confined to the Yellowknife Bay Formation of the Kam Group and localized where flow abut with a high angle again t the contact of the We tern Plutonic complex. However. no obvious tructural and lithological features have been recognized that are more favorable for gold deposition and distinguish the shear zones and flows of the area around the mines from those of other parts of the greenstone belt. The model that gold wa transported by metamorphic solutions and that hear zones were the firs t-order control for gold deposition provides no explanation for the trong localization of the depo it . As porphyries with elevated gold contents are present in and near ome of the mines. the possibility that gold was deposited from hydrothermal system around fel ic intrusion representing early phases of the Western Plutonic complex should be given erious consideration.

Jan 1, 1986

By H S. Ellis

Flow studies have been conducted on nickel-water suspensions in a 1in.-diam., 42-ft.-long transparent lab-oratory pipeline at concentrations of up to 25 per cent, by volume, and slurry velocities of up to 15 ft/sec. The average size of the nickel powder was approximately 150 mesh (106J.L). Three flow regime were noted. At the highest velocities, i.e., above 10 ft/;sec., where the concentration distribution through the vertical diameter was most uniform, pressure gradients could be correlated with the Durand-Condolios equation (7,8). An intermediate region, i.e., from 7 ft/sec. to10 ft/sec., could be distinguished, the lower velocity limit being that at which nickel particles began to deposit. This region was also marked by decreasing pressure gradients, for a given concentration, as the velocity was reduced. The upper velocity limit in this region was also uniquely defined in that the friction factor for any nickel concentration was the same as that for water. In the third regime, below about 7 ft/sec

Jan 1, 1963

By Tom Cooney

A small number of mining contractors worldwide have evolved their businesses to be able to provide a ?total service solution? to their clients. Thiess, an Australian-based international mining service provider, works with numerous clients to tailor delivery methods and commercial arrangements to suit individual projects. The benefits of Thiess? extensive experience is brought to each client and project, whilst business improvement within projects, to the mutual benefit of both the client and Thiess, is a key part of all long term contract relationships. Historically, optimal business outcomes were closely related to the achievement of production and cost performance measures. Whilst these remain fundamental to successful mining businesses, other elements of sustainability are assuming increasing importance. As a large energy user, greenhouse and energy management is becoming an important part of Thiess? business. Thiess is a signatory to Australian government initiatives such as Greenhouse Challenge Plus, and is integrating energy management into its operations and business improvement programs, in many cases to the benefit also of the client. This paper will highlight the benefits that an organisation such as Thiess can bring to a mine owner. Thiess? approach to business improvement and cost reduction, sustainability and energy management, as well as the relationship between these will also be considered. Increasingly, overall mining performance is dependent on the alignment of formally disparate elements.

May 1, 2007

By G. M. Dunn

Pressure leach autoclave circuits are employed in the leaching of ores, concentrates, mattes, alloys and intermediates for the recovery of metals into solution. Once the metals are extracted into solution the value metals can be recovered by hydrometallurgical means such as by purification followed by electrowinning, hydrogen reduction, pyrohydrolysis, crystallisation and other unit operations. In many of these integrated flowsheets the pressure leach step is pivotal to the recovery of the value metals from the host material. In an expansion or a new project, a large component of the capital cost can be associated with the pressure leach step and process engineers frequently look for opportunities to mitigate costs. This paper examines a new route for increasing the capacity of an exothermic pressure oxidation leach for sulphide concentrates, sulphide and phosphide mattes and alloys.

Jan 1, 2004

By M. J. Michaud, M. J. Lavigne

"A cornerstone of any successful mining project is an understanding of the mineral assemblage and metal distribution comprising the deposit. Knowledge of the precise mineral/ metal zoning enables an operation to utilize different mining and processing methods optimized for different parts of the deposit. The Lac des Iles mine, located in northwestern Ontario, is one operation that depends on a good understanding of these issues. Current resources for the Roby Zone total 94.1 Mt grading 1.66 g/t Pd, 0.18 g/t Pt, 0.14 g/t Au, 0.062% Cu, and 0.053% Ni.The Roby Zone occurs within the gabbroic portion of the Lac des Iles intrusive complex and consists of three compositionally and texturally different ore types with variable PGE, base and precious metal contents. PGE occur as sulphides and bismuthotellurides in net-textured sulphides, coarse sulphide blebs and as finegrained inclusions within secondary silicates.Knowledge of the precise mineral/metal zoning has directly and indirectly improved several operational aspects, including resource modelling, mining, and processing. For example, metallurgical recoveries have been increased by up to 3% to 5% and concentrate grades have increased by up to 100%. IntroductionLac des Iles Mines Ltd., a wholly owned subsidiary of North American Palladium Ltd., owns and operates a 3000 t/d open pit mine and concentrate facility, located 100 km north of Thunder Bay in northwestern Ontario. The Lac des Iles PGE-gold-copper-nickel mine has been in commercial production since 1993 and in 1997, produced 1.8 million grams of palladium, 127 000 g of platinum, 114 000 g of gold, 438 000 kg of copper and 354 000 kg of nickel (North American Palladium Ltd., 1998).Under the Industrial Research Assistance Program (IRAP), a two-year study of the mineralogy of the Roby Zone was undertaken with a goal of improving the profitability of the mine. Geological mapping, petrography and geochemistry of the Roby Zone were completed during this study. Utilization of the detailed mineral/metal zoning identified as part of this study was implemented at the mine and shown to positively impact many operational aspects including mining and processing."

Jan 1, 2003

By J. Walker, G. E. Kim

Since May of 2000, Mogas Industries, in partnership with F.W. Gartner Thermal Spraying Co. and using the services of Perpetual Technologies, has invested time, energy, and resources towards developing novel ball valves for high-pressure acid-leach (HPAL) service. In addition to developing new valve designs, an aggressive coatings development effort has been undertaken to improve the protective quality of the coatings so as to enhance the performance and extend the life of valves in severe HPAL conditions. In 2001, Mogas Industries qualified and applied a nanostructured titanium oxide (n-TiO2) coating for gold and nickel/cobalt HPAL services. The n-TiO2 coating provided dramatically superior protection against abrasive and erosive wear, fared very well against high-pressure autoclave corrosion testing, and has performed well in HPAL service.

Jan 1, 2004

By A. Holland, T. Krumins, E. Olin, J. F. M. Castilleja, J. Geldart, C. Fleming, I. Jackman

A flowsheet has been developed to treat the flotation tailings from a copper mine in Mexico to recover gold and silver by cyanidation and carbon-in-pulp (CIP). The plant will treat ~15,000 t/day of a 60:40 blend of current flotation tailings and the mine’s historic tailings. The tailings also contain a significant amount of cyanide-soluble copper, and the economic viability of the project is strengthened by recovering most of the copper and cyanide associated with this process. The solution and solid phases in the CIP tailings will be separated in a counter current decantation (CCD) circuit and the CCD solution overflow will be treated by a SART Process. Copper precipitates as a salable copper sulphide product in the SART Process and the cyanide that is associated with the copper complex is regenerated as free cyanide. After SART, a portion of the SART product solution will be recycled to leach to reuse the free cyanide, while the remaining solution will be used as wash water in the CCD circuit. Incorporation of the SART Process in the flowsheet allows the CIP circuit to be operated aggressively as a gold plant, which means most of the silver in solution passes through CIP to SART. Silver co-precipitates with copper in SART and is recovered very efficiently with the copper sulphide by-product. Incorporation of SART also allows the leach and CIP circuits to be operated with relatively high levels of free cyanide, which enhances silver leach kinetics and helps keep copper from loading onto the carbon in CIP. The flowsheet was developed in the laboratory and successfully demonstrated in a fully-integrated pilot plant in 2018.

Jan 1, 2019

By K. Liu

"In the present work, two-step heat treatments with preheating treatments at different temperatures (175, 250 and 330°C) as the first step followed by the peak precipitation treatment (375°C/48h) as the second step have been performed in Al-Mn-Mg 3004 alloys to study their effects on the formation of dispersoids and evolution of elevated-temperature strength and creep resistance. During the two-step heat treatments, the microhardness is gradually increasing with increasing time until to a plateau after 24 hours when first-treated at 250°C and 330°C while there is a minor decrease with time at 175°C. Results show that both the yield strength and creep resistance at 300°C reach the peak values after the two-step treatment of 250°C/24h+375°C/48h. The formation of dispersoids is greatly related to the type and size of pre-existing Mg2Si precipitated during the preheating treatments, in which that coarsened rod-like ß’-Mg2Si strongly promotes the nucleation of dispersoids while finer needle-like ß’’-Mg2Si has less influence. Under optimized two-step heat treatments and modified alloying elements, the yield strength at 300°C can reach as high as 97 MPa with the minimum creep rate of 2.2×10-9 s-1 at 300°C in Al-Mn-Mg 3004 alloys, enabling them as one promising candidate in lightweight aluminum alloys for elevated-temperature applications.INTRODUCTION Due to the rapid demand from weight-sensitive automotive and aerospace industrials for the light alloys, such as aluminum alloy on the elevated-temperature applications, Al-Mn 3xxx alloys has been developed to obtain the good properties at both room temperature (RT) and elevated temperature, in which the dispersoid-strengthening mechanism plays a significant role (Li & Arnberg, 2003; Li, Muggerud, Olsen & Furu, 2012; Liu & Chen, 2015, 2015). In our previous works (Liu & Chen, 2015, 2015; Liu, Ma & Chen, 2017), the yield strength and creep resistance at 300°C of Al-Mn-Mg 3004 alloy were further improved by modifying the alloying elements, such as Fe and Mo, to optimize the characters of dispersoids, including the size, distribution and the dispersoids free zone (DFZ). For instance, Mo was introduced in aluminum alloy to further improve the volume fraction of dispersoids and reduce the area of DFZ, leading to increasing on both the strength and creep resistance at 300°C (Liu, Ma & Chen, 2017). On the other hand, the mechanical properties became worse at higher Fe content due to its consumption more Mn to form Al6(MnFe) intermetallics, resulting in less available soluted Mn for the precipitation of dispersoids (Liu & Chen, 2015). Therefore, optimizing the characters of dispersoids is always the key to improve the elevated-temperature properties of dispersoid-strengthened aluminum alloys for elevated-temperature applications."

Jan 1, 2017

By André van Wageningen

Since the beginning of this century Boliden Mineral and Atlas Copco have worked together in stages on improving the accuracy and quality of drilling. Navigation of the drill rigs with IREDES has been in use in the Boliden mines for several years. Recently the capability of the system has extended with map navigation to more accurately follow the ore in cut&fill mines. The system allows for changes on the individual round level to follow the ore without changing the whole design for the heading. Those changes are done in a CAD-system and remove the need for face markings and will allow for even better accuracy in both height and wall position. All the information between the CAD-system and the drill rigs is exchanged using the IREDES standard. This paper describes the workflow and the use of the IREDES standard.

Oct 1, 2009

By F. R. Archibald

SINCE the opening of the Beattie mine, in 1933, the concentrate produced by flotation has been considered refractory. As the gold extraction by cyanidation was poor, the concentrate, during the first four and a half years of operation, was shipped to a smelter for further treatment. After the installation of the cyanide plant, in 1934, seventy per cent of the gold in the concentrate was recovered before shipment to the smelter. In 1937, a roasting plant was built so that treatment might be complete at the mine. Much experimental work had been done by a number of investigators prior to the installation of the roasters, but none of them had seriously attempted to identify the causes of, or the elements responsible for, the refractory behaviour of the concentrate. Intensive investigation in this direction commenced in the Beattie lab-oratory in July, 1938, has led not only to the identification of several causes contributory to the refractory behaviour, but also to revisions in procedure and principles with respect to roasting Beattie concentrate in particular and arsenical concentrates in general. The accuracy of the identification of these causes and the soundness of the principles is borne out by interpretation of roasting plant records, by improvements and simplification since applied. to plant operation, and also by laboratory and test-plant results on arsenical concentrate produced by another mine. It is the purpose here to present an account and interpretation of the laboratory investigation, together with a correlation of laboratory and plant results. Incomplete extraction of the gold by cyanidation after roasting is due primarily to the nature of the material roasted, and secondarily to the manner in which it has been roasted. There is a possibility that better extraction may be obtained by improvements in both particulars.

Jan 1, 1939

By X. -G. Chen, K. Liu

Nowadays, great interests are rising on aluminum alloys for the applications at elevated temperature, driven by the automotive and aerospace industries requiring high strength, light weight and low cost engineering materials. As one of the most promising candidates, Al-Mn-Mg 3004 alloys is found to possess considerably high mechanical properties and creep resistance at elevated temperature resulted from the precipitation of a large number of thermally stable dispersoids during heat treatment. In present work, the effect of Fe contents on the evolution of microstructure as well as high temperature properties of Al-Mn-Mg 3004 alloys has been investigated. Results show that the dominant intermetallic changes from a-Al(MnFe)Si at 0.1 wt.% Fe to Al6(MnFe) at both 0.3 wt. % and 0.6 wt. % Fe. In the Fe range of 0.1 to 0.6 wt.% studied, a significant improvement on mechanical properties at elevated temperature has been observed due to the precipitation of dispersoids, and the best combination of compression strength and creep resistance at 300°C is obtained in the alloy with an intermediate Fe content (0.3 wt.%) with finest size and highest volume fraction of a-Al(MnFe)Si dispersoids. The superior properties obtained at 300°C makes 3004 alloys more promising for high temperature applications. The relationship between the Fe content and the precipitation of stable dispersoids as well as the materials properties has been discussed.

Jan 1, 2015

By K. Purazrang, P. Musavi Garavi, P. Sh. Naseri, P. Abachi

The fracture behavior of high strength Al7050 alloy was investigated at room and elevated temperatures using small size, V-notched tear (called Kahn specimen) and compact tension, CT, specimens, respectively.To study the elastic-plastic behavior of the alloy, the tensile test was also performed on the sub-sized cylindrical tension test specimen. The microstructure of the alloy was examined using optical- and scanning electron- microscopy. The rupture mechanisms and crack path were also studied by examination of specimens' fracture surfaces using SEM. The microstructure examination revealed equiaxed grains and some elongated grains in rolling direction, with the areas of partial re-crystallized grains where coarse intermetallic particles are mostly found.In general, fracture surfaces were indicative of dimpled ductile type. Considering the fractographs of tensile specimens, the void growth mechanism is also dominant in fracture of these specimens. Nevertheless, in some regions, smooth areas can be observed due to the friction during rupture process. The results of mechanical tests at RT made the evaluation of tear strength to 0.2 % tensile yield strength ratio, as a measure of notch toughness, available. According to elevated temperature, 150°C, test results and plots of log da/dt vs. log KI , the crack propagation behavior over discrete ranges of crack growth rates could be assumed linear and then be obeyed as a power law equation in the form of da/dt = A (KI)n .

Jan 1, 2015

By J. O. Marsden

Over the past decade, the copper industry has been through an extended downturn followed by several years of sustained high copper price. A number of new technologies have been developed over the past 10 years aimed at reducing costs by decreasing energy, labor, and materials requirements, or by increasing metal recovery. The energy intensity of different copper extraction routes and different technologies varies considerably and this has a significant impact on the economics of extraction. Based on average ore grade materials, the total energy for the extraction of copper typically varies from about 24-26 MJ/lb (6.7-7.2 kWh/lb) for the mining, crushing, milling, flotation, smelting and refining route to about 14¬16 MJ/lb (3.9-4.5 kWh/lb) for the mining, crushing, heap leaching, solution extraction and electrowinning route. New technology developments are providing opportunities for significant reductions in energy consumption for copper extraction, representing energy savings up to 20-25% in some cases. In addition, in many cases, these new technologies have introduced environmental, safety and health benefits over the incumbent technology. Some of these technology developments have been more successful than others, and many hold great promise for application in the coming decade. This paper provides an overview of the technology developments that have occurred, and explores the underlying reasons behind successful implementation.

Jan 1, 2007

By G. Guzman

In the framework of the optimization of Teniente Converter operation the new system of automatic flux feeding through gar-gun was implemented in the Potrerillos Smelter, Codelco Chile, Salvador Division. The control algoritm based on simple iron and silica balance adjusted by empirical coefficients was incorporated in the logical programmer. The programmer works in real time gathering information from the plant instrumentation events and introduced chemical assays of concentrate, slag and flux. Through the auto-tuning of the automatic operation the criterions of optimal flux dosage were determined. Four month of operation of the automatic flux feeding system demonstrated the stabilization of magnetite content in the slag in the narrow range from 18 to 20% and the decrease of flux consumption, corresponding to annual savings US$ 340,000. Additionally, the automatic system helps operators in the control room in fast determination of optimal fluxing and avoid the errors in flux dosage affecting the slag quality and its impact on refractory wear.

Jan 1, 2007

By K. Janghorban

Multilayered ceramic-metal composites were produced by solid state diffusion bonding of polycrystalline alumina and three Al alloys containing 1 to 2%Sr, 2% Mg and Mg + Si (5057 Al alloy), The multilayered structures were fabricated at 610°C under a compressive stress of 3 MPa for 2 hours in He-5%H atmosphere, The ceramic-metal interfaces were studied by SEM and TEM equipped with energy dispersive spectrometer (EDS). Addition of 1 wt % Sr to Al promoted good adhesion, without producing any interfacial products, while the Al-2%Sr was poor in this regard due to the presence of dispersed A14Sr which is an intrinsic phase in the Al-Sr phase system, The Al-2%Mg alloy produced a continuous film at the interface, which was characterized to be MgAl2O4. Al alloys containing Mg and Si (5057 commercial alloy) produced not only the spinel structure (MgAl2O4), but another phase rich in Mg and Si (close to Mg2Si), These latter interfacial reaction products were not the intrinsic phases in Al-Mg alloys, and were reaction products at the Al2O3 ?Al alloy interfaces.

Jan 1, 2005