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Aspects of the formation, decomposition and acid solubility of zinc ferrite were examined to find potential ways of increasing the recovery of zinc from a calcination process of mineral concentrates. Ferrite can begin to form within 2 hours at 450¦C. while complete reaction can occur after 35 minutes at 700¦C. The nature of the starting materials has a pronounced effect on the rate of formation and below 700¦C. ZnSO4 and Fe2O3 proved to be the least reactive of the materials investigated. It is possible that iron in a mineral admixed h sphalerite can be converted to a relatively inactive form, however, it does not seem possible to prevent zince f formation when iron is in the sphalerite lattice. At the two temperatures examined, 650¦C. and 700¦C, the presence of SO2 in the atmosphere accelerate .e formation of ferrite. Prolonged exposure to such atmospheres, however, caused the ferrite to decompose to ZnSO4 and Fe203. The optimum temperature for decomposition was 650¦C. and it was virtually complete within 2 hours in an atmosphere of 10% SO2 in air. Zinc ferrite was also decomposed by CO at low concentrations, and by heating with limestone at 1000¦C. for at least 2 hours. The solubility of zinc ferrite in acid was influenced by the starting materials used. As both the reaction temperature and the time at temperature increased the acid solubility decreased. The acid solubility was a minimum when the ___i_.. n - I -r~...................c -..... F, fe..i+e --A frn... A01- +^ Z(lo/

Jan 1, 1970

Synthetic and commercial activated carbons are characterised for several chemical and physical properties. A range of techniques is used to establish correlations between physicochemical parameters and gold- adsorption activities. The most important parameter in the carbon activation process for a product with a high gold-adsorption activity is the activation temperature. High activation temperatures yield products with large micropore volumes which provides sites that are ideal in size for adsorption. The surface area of an activated carbon is not necessarily a good measure of its adsorption activity. Surface oxygen-containing functional groups are identified by Fourier transform infrared spectrophotometry to be comprised mainly of ethers and hydroxyls. These functional groups line the edges of the micropores imparting a polar character to the pore and aid in the solvation of the adsorbate. Oxidants such as nitric acid result in a proliferation of surface carboxyl groups. resulting in a negatively- charged surface that is not conducive to the adsorption of gold.

Jan 1, 1993

By Tran T

The kinetics of cementation of silver chloro-complexes from sodium chloride solutions onto copper and zinc was studied using rotating disc electrode system. The activation energies were found to be 10.8 and 30.5 k7/mole, in a 3M NaCl solution on copper and zinc discs, respectively. Higher dissolution factors were obtained on zinc disc, due to hydrogen evolution, whereas, copper dissolved close to the predicted values. Scanning electron microscope studies were conducted both on copper and zinc- cdiscs-to evaluate the deposit morphology and its effect on reaction kinetics. Two stage deposit growth was observed both on copper and zinc discs. Smooth, coherent initial deposit followed by tree-like secondary dendrites formed on copper, whereas, scattered bulbous initial deposit followed by porous dendrites was typical on zinc disc.

Jan 1, 1992

Timely disclosure of information germane to the taking of investment decisions makes an essential contribution to ensuring the growth, efficiency and integrity of our capital markets. It is a core contributor to the maintenance of fair, orderly and transparent markets. Australia has a strategic need to protect and enhance market integrity. Australia is ranked tenth in the Morgan Stanley Capital International (MSCI) World Index, yet represents only 1.59 per cent of that Index. In order to survive and grow in this globally competitive environment, Australian capital markets û the drivers for economic activity in Australia û need to attract foreign investment and engage retail capital. The communication of relevant and comprehensible information to the investor plays a vital part in fostering investor confidence, thereby building depth and liquidity in our market. We have had a rewarding partnership with the mining industry to develop and recognise reporting standards which could allow ready comparability and investor understanding of the mining investment vehicle. Our mining market has been successful because of the high standards of professionalism and the intellectual capital that has been built up among the participants û the mining professionals, brokers, analysts, mining investors, professional advisers and the market operator. The balance of knowledge and understanding among these participants combined with the competition for capital, contributes to the standards for our mining market in a way that the market operator simply cannot replicate by market rules alone.

Jan 1, 2002

This paper deals briefly with the geology and mineralisation of the Ediacara Mineral Field, which is located about 300 miles north of Adelaide in the Mount James Range.The field was discovered sane time prior to 1872. Total recorded production for the field amounts to a few hundred tons of lead and 36 tons of copper. Re-listing of the field during 1961-62 led to its classification as a Mississippi Valley type deposit. Diamond drilling has partly outlined the spread of mineralisation and confirmed its stratiform distribution,Sources for the metals are suggested and various possible mechanisms. of deposition are described.

Jan 1, 1963

Tokyo Metropolitan Government designs the stormwater storage plans in underground, as a measure of flood control in completed urban district and improvement of combined sewarage system. This time, introducing those plans, we report about IKEJIRI and SIN-KOMAZAWA STORAGE TRUNK LINEs design and construction. They are located in Meguro river basin of the Morigasaki drainage area. Both storage trunk lines have capacity to store 15O,000m3 of stormwater. They are in use for countermeasure of flood till Meguro river's strengthening (intensity 50 mm/h) is ended. And after the strengthening, they will be in use for improvement of river water quality, through the storage of combined sewage and first runoff, which, otherwise overflows weirs and flows to river in a rainy day. These storage trunk line's full length is about 5700m. Boring diameter 66140 mm (f = 2672m) and 47800 mm (I = 2866m) of these tunnels are constructed by Mechanical Shield tunnelling method. And boring diameter 3600 mm x 4000 mm (R = 180m) is constructed by NATM tunnelling method. We began works in 1983, and have a mind to complete in 1987.

Jan 1, 1987

By T Gibbons, M Korte, C Brent, K Runge

The Barrick Osborne concentrator has gone through a number of upgrades since commissioning and steadily increased production from the original 119 t/h design capacity to 265 t/h milling throughput in 2008. This was achieved incrementally over several years, by maximising operating efficiencies, in order to minimise capital expenditure, and take advantages of economies of scale; but more importantly it was reached with no measurable loss of recovery. Osborne currently processes a blend of under- ground with open pit material from the nearby Trekelano deposit. Following primary/secondary crushing, the material is processed through a rod/ball mill grinding circuit ahead of rougher/scavenger flotation that produces a copper concentrate.Osborne was seeking a further increase in plant throughput of the order of 15 per cent, but at more sustainable levels of secondary crusher plant utilisation. In early 2008, Osborne contracted Metso Minerals Process Technology Asia-Pacific and South America (MMPT) to review the entire process from run-of-mine feed to final copper concentrate. This review would be done concurrently, with surveys of both the crushing/ grinding and flotation circuits being performed at the same time. The outcome would be a steady-state model of the complete flow sheet allowing the crushing/grinding model to interact with the flotation circuit model such that overall process optimisation was possible. Two key outcomes for the operation are exploration of the operating limits of the currently installed plant, and projection of the logical next stage of potential capital plant expansions. This paper covers Part B or the flotation component of the project. A separate paper discussing Part A or crushing and grinding is also being presented at this conference. Surveys of the Osborne flotation circuit were performed along with a comprehensive review of the cell characteristics including measurements of the gas and froth phases of individual flotation cells. These data resulted in a size-by-size floatability component model of the complete circuit. This circuit model was then used to perform steady-state simulat- ions to evaluate options to improve both overall circuit and individual cell performance. The grinding circuit model discussed in a separate paper or Part A of this project was then used interactively with the flotation circuit model to recommend the best operating regime to maximise overall efficiency. For example, the balance between increased crushing and grinding costs versus higher copper recovery and final concentrate grade. Due to changes in market conditions in the fourth quarter of 2008, the focus was shifted to prioritising operational changes rather than capital expansion modifications, in order to improve circuit performance.

Jan 1, 2009

The ore mined from the Lead Lode of The Zinc Corporation leases consists of a fairly granular mixture of galena, marmatite, chalcopyrite, tetrahedrite, pyrrhotite, pyrite, and lollingite with a gangue association of calcite, quartz, bustamite, rhodonite, mangan-hedenbergite, garnet, fluorite, mangano-calcite and apatite. The silver content of the ore occurs in three minerals tetrahedrite, dyscrasite, and pyrargyrite, the last two mentioned occurring in microscopic association only. Other metallic and gangue minerals are also present in this complex mineralogical association, but do not influence the milling operations.Fortunately, the silver minerals favour the galena and chalcopyrite as their host minerals, thus facilitating the recovery of both copper and silver in the lead concentrate. The ore from the Lead Lode assays from 14 - 18 per cent lead; 3.0 - 4.5 oz silver per tonne, and 9.5 - 12.0 per cent zinc.A parallel lode, known as the Zinc Lode, is well developed in The Zinc Corporation leases. This lode assays from six to eight per cent lead, 1.5 oz silver per ton, 18 - 25 per cent zinc with a siliceous gangue. The common Lead Lode gangue minerals, calcite, rhodonite, bustamite - are very rare in present underground exposures. No metallurgical work was done on this ore during the pilot plant operations.The aim in the milling process is to produce:1. A lead concentrate with the maximum economic recovery of lead, silver, gold, copper and antimony, and minimum zinc content.2. A zinc concentrate with the maximum economic recovery of zinc, cadmium, and cobalt, and minimum iron, arsenic and fluorine content.3. A waste residue containing sufftcient granular material to be utilised as underground fill.In considering the economics of the milling practice the above three requirements plus consideration of the tariffs submitted by the purchasers of concentrates were the deciding factors in the evolution of the present milling practice.Towards the end of 1924 The Zinc Corporation Limited added to and adapted the old zinc tailings plant for the treatment of 5000 tons of crude ore per week. This plant, which operated until January 1936, was in general principles similar to the standard Broken Hill methods of ore concentration, whereby the galena was recovered by the gravity concentration methods of jigging and tabling with selective flotation concentration of the residual galena and marmatite. One important difference from other Broken Hill plants was that the primary grinding of the jig tailing was performed with flint-loaded mills operating in closed circuit with revolving screens. Two primary grinding sections were installed, each consisting of two 5 ft diameter by 10ft long tube mills loaded with flint pebbles working in closed circuit with four 3 ft diameter by 3 ft wide revolving screens covered with 22mesh Toncap woven wire screen with 0.57 mm opening. Each section carried a circulating load of 28.3 tons per hour for a jig.

Jan 1, 1994

By Liu Y

Ventilation, air leakage, and various cutting, loading and support movement operations all have a role in dust distribution on longwall faces as shown by the results of a large number of dust measurements on different longwall operations in the Bulli seam on the South Coast. It is concluded that leakage of air on the face has demonstrable mfluence on the exposure of the shearer operator to dust level. It is possible to calculate dust generated by various elements of a rrurung operation on the face from a single point measurement. In the examination of dust deposition from the source of generation as a function of particle size, it is found that respirable dust can remain airborne over long distances without any significant drop in concentration, if unobstructed.

Jan 1, 1995

Gold mineralisation at the Macraes Gold Project is hosted in the Hyde-Macraes shear zone and can be traced for ~30km along strike, although economic resources are confined to a 7 km section in the vicinity of the Macraes township. The shear zone, which typically dips at a low angle (~20 o ) to the NE, is bounded by an upper hanging wall shear and a lower footwall fault. Mineralisation occurs along the hangingwall of the shear zone as well as in low angle concordant shears and stockworks. Ore types include graphitic cataclasites with variable amounts of quartz veining, ælode schistsÆ and quartz-vein stockworks. Rehabilitation at the mine has focused on creating an environmentally benign site dominated by pasture to allow continuation of the traditional pre-mine farming economy. Changing regional economics, continued urbanisation and a reduction in traditional employment opportunities has seen a rethink in the long-term rehabilitation outcomes. The community has recognised that the rehabilitated site will provide the basis of a viable tourism venture and the creation of a Heritage and Art Park (working title æGolden Point ParkÆ) is the culmination of that process.

Jan 1, 2002

The mineralogy, maero- and micro-textures of Thackaringa ore are simple and have many counterparts among base metal-quartz-siderite vein type deposits elsewhere.The ore consists predominantly of galena, sphalerlte, chalcopyrite, tetrahedrite, and arsenopyrite in a quartz and siderite gangue. Silver minerals, as such, appear to be lacking and silver values are no higher than in other sulphide ores of this type. These features contrast very markedly with those of the A.B.H. Consols Lode which appears to have emanated from the north end of the Broken Hill Main Lode Horizon during high grade regional metamorphism. The Consols Lode has been regarded as of Thackaringa type, and both are regarded as possibly arising from the remobilization of Main Lode Horizon ore. Whilst this may yet prove to be so it appears that the marked differences in mineral composition between the Consols and the Thackaringa types, would require somewhat different modes of regeneration.Thackaringa ore, as well as A.B.H. Consols ore, on this basis, would necessitate the development of a metahydrothermal ore fluid to account for their present apparently hydrothermal (or pseudo-hydrothermal) constitution...

Jan 1, 1967

By T Hodgkin

The WA Goldfields is a highly productive gold and nickel mining area, but is arid with highly saline groundwater. Groundwater is widely used to supply process water to mines in the region but high groundwater salinity, commonly exceeding 50 000 mg/L TDS, tends to increase processing costs, limit end uses for the water, cause problems with disposal and potentially increase impacts on a sensitive arid environment. The area has low rainfall (200 - 270 mm/year) but run-off, particularly during cyclonic events, is high. Our experience suggests that stream flow from catchments in the area can produce a divertible yield of 8 - 17 ML/km2/year. An evaluation of stream flow harvesting using AnglogoldÆs Jubilee Pit predicted that 1000 ML/year of good quality water could reliably be supplied to the Sunrise Dam Gold Mine. Because of high rainfall variability, it is likely that an alternate source of water supply will be necessary when operating a surface-water harvesting scheme in the WA Goldfields. However, a combination surface/groundwater supply could have substantial cost, operational and environmental benefits compared to traditional supply systems that utilise groundwater only.

Jan 1, 2003

IT is most remarkable and valuable property of mediurn and high carbon steels that they should be so susceptible to heat treatment, the wide range of variability in tenacity, ductility, etc, due to the normal influence of the carbon in the untreated material being enormously inereased thereby.The physical properties of steel and other metals are much more closely related to their structure than to their ultimate analysis.For instance, we may by chemical analysis determine the carbon content of a steel to be 0.5% ; but this information alone is insufficient to enable us to say what are the physical properties of the metal.Such a steel may possess 11 tensile strength of anything from 35 tons per sq. in., with much ductility, up to 80 tons per sq. in., with practically no ductility, according to its heat treatment. A microscopie examination, on the other hand, would show the structural composition of the steel, from which its physical properties could be approximately deduced. From this it will readily be understood that the microscope has played an important part in the development of modern rnetallurgy, and to-day it is in daily use for the examination of metals and alloys in the laboratories of most works dealing with the rnanufaeture and working of metals.THE IRON-IRON CARBIDE EQUILIBRIUMTo understand fully the mode of occurrcnce of the different constituents of a knowledge of the Iron-Iron Carbide equilibrium diagram (Fig. I) is essential to heat-treat steel successfully and to interpret microstructures correctly such a knowledge isabsolutely indispensable.A portion of the Iron-Iron Carbide Diagram, dealing with steels below 1000 and containing up to 1 carbon is given below.It should be noted that the diagram deals entirely with pure carbon steels, and does not indicate the influence of the usual so-ealled "impurities" present in all commereial carbon steels...

Jan 1, 1926

By Richmond GD

The Hellyer concentrator of Aberfoyle Limited commenced production in 1989 processing a fine grained, massive sulphide ore containing Zn, Pb, Ag, Cu and Au as values. Four concentrates are produced - copper/silver, lead, zinc and bulk (Pb/Zn) - with overall payable recoveries (1991) of 80 per cent Zn, 55 per cent Pb, 50 per cent Ag, 30 per cent Cu and ten per cent Au. Metallurgical development work commenced immediately after plant commissioning, and continues. The flotation response and liberation analysis on a size basis highlighted reagent balance problems associated with tower mill regrinding of sphalerite, poor conditioning of flotation pulps, poor selectivity for fine galena, and insufficient liberation. These were the main causes of values lost to tailings, values reporting to the 'wrong' concentrates and of impurities in the concentrates. Modifications to tower mill regrind circuit operation, and the use of improved conditioning techniques have greatly improved concentrator performance, particularly in the finer (-5 micron) size fractions. Studies of concentrator and laboratory flotation by size and liberation analysis are the basis of diagnostic metallurgy. The techniques used to evaluate the improved concentrator performance are discussed.

Jan 1, 1993

The value derived by good mine planning is often underestimated as many mines steer their attention to the more immediate and more easily recognised successes made by the day-to-day operational æbush fireÆ fighting. Similar to machine maintenance, the efforts made to quickly rectify short-term breakdowns are well recognised; whereas the value derived from the work in planning, scheduling and undertaking preventative maintenance is not so obvious or readily quantified. Too often the focus of the business shifts to building and supporting an efficient operations team at the expense of developing a highly experienced team of mine planning practitioners that are well trained with procedures and purpose-built tools to develop optimum mining strategies. A resource has an inherent value based on its quality parameters and its likely mining conditions. How well that value can be unlocked is governed, to a large degree, by the proficiency of the mine planning practitioners, as they, essentially, set the foundation of the mine business and the path along which the mine will operate. The importance of having a well documented and procedural mine planning methodology that integrates both a thorough technical and economic understanding of the resource cannot be over emphasised. The aim of the mine planning process is to develop a robust mine design and production capability which can best cater for future uncertainty whilst providing the best opportunity to maximise cash flow into the business. The planning process must be transparent and auditable, clearly summarising the process steps and assumptions made to arrive at a justifiable and defendable outcome. To provide maximum value to the business, the planning process must be repeatable and scalable to enable easy replication throughout the different mines and projects within an organisation. The diminishing numbers of highly experienced personnel within our industry, coupled with the growing pressure to clearly demonstrate that appropriate due diligence has been exercised, means that well documented and monitored mine planning processes using purposed built and innovative tools need to be developed to ensure optimum outcomes.

Jan 1, 2009

The paper sets out the context for water and the challenges that have to be faced in the battle to alleviate global poverty. It acknowledges that the world has been blessed with abundant water but because of population and development pressures, and the projected changes in climate, avoiding serious water shortages in some places will be difficult. MiningÆs use of water is placed in context and the paper then considers the specific threats to the industry in terms of availability and price and the need to find mechanisms to deal with the issue of resource degradation caused by abandoned mines. Rio TintoÆs use of water is then set out and three examples are given of how different water challenges have been addressed. The paper goes on to consider each element of a water strategy designed to move Rio TintoÆs performance towards excellence. This strategy incorporates improved management procedures (policy, principles, standards and targets), performance enhancement (through use of the Rio Tinto Water diagnostic and technology changes) and working with others in the academic and NGO community who seek to address the same global issue.

Jan 1, 2003

By K Schiefelbein, P OÆGrady, R Balusu, T Ren, T Harvey

"An extensive research program has been undertaken over recent years to reduce the risk of fires and explosions in underground coal mines. The research projects have integrated extensive field studies and computational fluid dynamics (CFD) models of goaf gas flow behaviour to develop optimum proactive strategies to prevent and control spontaneous combustion and fires ingoaf areas. The research has developed a fundamental understanding of the air and gas flowbehaviour in goaf areas and provided a detailed understanding of the eff ects of various geological,ventilation, operational and inertisation design parameters on goaf gas distribution. The researchinvestigations have also provided a better understanding of the flow behaviour of gases from the heating in the goaf areas and the effect of various gas and spontaneous combustion controltechnologies and strategies. Field studies conducted at a number of underground coal mines have shown that the proactive strategies were successful in reducing oxygen ingress into the goaf areas and in reducing the risk of fires and explosions in the underground coal mines. The results of various research investigations and guidelines for reducing the risk of fires and explosions in underground coal mines are presented in this paper."

Jun 1, 2012

By V S. T Ciminelli

This work aimed at evaluating the acid rock drainage (ARD) potential of five samples of a Brazilian gold sulfide mine in a decommissioning process. Three of the most traditional ARD prediction techniques, Standard Acid Base Accounting (Std ABA), Modified Acid Base Accounting (Modified ABA), as static methods, and humidity cells as a kinetic method were tested. Both the Std ABA and the Modified ABA results indicated an acid generation potential for some of the studied samples. In the other cases the results were inconclusive. The five samples were then submitted to humidity cell tests during 27 to 30 weeks. At the end of the period, the leachate pH was stabilised in a range from 3.4 - 4.1 (four samples) to 5 (one sample). The presence of relatively high levels of sulfate and dissolved metals was detected throughout the operation, specifically, Ni and Zn, and less frequently, As. These findings are discussed with the help of the samples mineralogy and Eh-pH diagrams. The results obtained in this investigation indicated potential environmental risks of this mining area. In this particular case, the kinetic tests were shown to be essential to the identification of the samples ARD potential.

Jan 1, 2003

By Trutwin W, Tracz J

The outbreak of open fires underground cause disturbances to the conditions of the mine ventilation process. Thermal and chemical effects due to fire create unsteady, transient states in airflow and the spread of combustion products in the mine ventilation network. Changes in airflow have an influence on the fire, constituting a sort of feed-back between the fire and the ventilation process. This paper deals with a numerical simulation method, which enables the determination of transients caused by fires. The mathematical model, of the simulation method considered, has been based upon a: simple model of combustion of fuel in the airway, unsteady exchange of heat between the fire, airflow and surrounding rocks, airflow in mine ventilation networks and the theory of heatflow in the rocks. Initial and boundary conditions allow the determination of a set of parameters describing the airflow, the propagation of combustion products, the tempera- ture of the fire and flow etc. due to the fire. The simulation method, facilitates a graphical presentation of the spread of combustion products throughout the network. The simulation method has been prepared for an IBM PC/AT Computer.

Jan 1, 1988

A novel solvent extraction process, called the SOHNEX process, has been developed at the University of Utah. In this process, the organic and the aqueous phases flow countercurrently in a horizontal vessel, and the emulsion between the two liquid phases is generated by high-velocity gas jets injected at the bottom. The gas jets are located at certain intervals along the bottom of the vessel with phase disengagement zones on either side of the plume zone created by the gas jet. The system is simple, having no mechanical moving parts or complex internal structures, and yet provides good contact between the phases with minimal backmixing. Tests have shown that emulsions with a wide range of specific interfacial area, including that typically encountered in mixer-settlers, can be generated in this process. It has significant built-in flexibility of operation including the control of the flowrate and hold-up of each liquid phase. The SOHNEX process overcomes the difficulties in the operation of conventional solvent extraction equipment such as mixer-settlers and column extractors. A major advantage of the SOHNEX process is that the energy of mixing can be closely controlled by adjusting the strength of the gas jet. This allows an optimal control of the drop-size distribution of the dispersed phase and thus the specific interfacial area. The process is continuous, and any number of extraction and separation stages may be built into a single vessel. The gas can be recirculated in a closed loop, thus eliminating solvent loss and mist problems, especially for high-temperature operations. The SOHNEX problem can handle solutions that contain suspended solids and that form third phases. The simplicity of the equipment and operation with low maintenance will mean much reduced capital and operating costs as well as low environmental risks and improved safety. The SOHNEX process has been tested for continuous copper extraction from a dilute solution. Calculations also showed that uranium and other radioactive elements can readily be extracted in a small unit of the SOHNEX extractor while satisfying the nuclear criticality condition.

Jan 1, 2000