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By M Ben, P de Donato, M Kongolo

The extensive literature on sulfide flotation indicates that pyrite poorly floats under alkaline condition. Xanthate concentration has a positive effect on pyrite flotation, but above a pH of 11, pyrite seems to be strongly depressed, independently of the concentration in xanthate. In this investigation, aeration and xanthate concentration effects were studied for pyrite flotation conditioned at pH 11 with lime. Results presented in this paper include surface infrared analyses and pulp chemistry measurements which have showed that aeration had a dual effect on pyrite flotation. It induced pyrite surface activation by oxygen, and oxidation of ferrous iron to ferric hydroxides or oxyhydroxides species. It also favoured dissolution of CO2, leading to calcium carbonate precipitation and adsorption onto pyrite surface. Both CO2 dissolution and ferrous oxidation generated protons and decreased pulp pH. Pyrite flotation was observed to be effective with a statistical monolayer of xanthate that could be adsorbed as mixture of dixanthogen and metal-xanthate complex. Non-floated fractions showed high amounts of carbonate, and presence of hydroxyl iron sulfate (Fen(OH)m(SO4)p, xH2O) which have inhibited the hydrophobicity effect of adsorbed xanthate. Environmental desulfurisation could be improved by aeration control causing pyrite oxidation and pH decrease to reach optimal flotation condition with a relatively low xanthate concentration.

Jan 1, 2005

By Mur D. M

Metal ferrites are formed by the high temperature reaction of various metal oxides with hematite and are commonly found in the calcines derived from the sulfation roasting of zinc, copper and nickel sulfide concentrates. The Jarosite Process is designed to treat such zinc ferrites by hot acid dissolution but little information is available on the basic reactivity of various ferrites and the effect of Eh. As part of an overall study of the reactivity of calcine products from copper and nickel sulfide concentrates it has been found that Eh plays an important role in the rate of dissolution of magnetite, hematite and nickel oxide by HC1 and H2SO4. Further studies on the reactivity of pure synthetic copper,zinc,and nickel ferrites also show a dependence on Eh. This paper discusses the relative reactivity of iron oxides and metal ferrites in 1 M HC1 and the results of electrochemical studies using cyclic voltammetry. A mechanism for the dissolution reaction is proposed as well as factors which determine their leaching. It is shown that the rate of leaching of metal ferrites with HC1 is enhanced in the presence of reducing agents such as Cu(I) and Sn(II). By contrast the leaching of NiO is enhanced by oxidising agents such as Cu(II).

Jan 1, 1987

By C Chen, W J. Bruckard, F R. A Jorge

The base metal industry mines and processes hundreds of million tonnes of ore per annum to produce saleable products and large tonnages of waste by-products such as tailings. These ores usually contain less than 1 wt per cent of toxic elements (As, Sb, Bi, Cd, Se, Te, Hg, etc), which are subsequently treated with the other components in the ore during the production of concentrate through to saleable metal products. The deportments of minor elements across the various unit operations of a process flow sheet do not normally receive the attention that the major elements receive. However, these minor elements can have a major influence on the quality of the products as well as an economic and environmental impact. Therefore, a high degree of control over their deportments is a key step in reducing their dispersion in the biosphere. Ongoing work at CSIRO has been examining minor element deportments across unit processes used for smelting and refining and the options for early removal of minor elements, as well as methods for safe disposal of some toxic elements. This paper provides an overview of the R&D activities undertaken at CSIRO to develop tools and methodologies for improved management of minor elements during the processing of sulfide ores.

Jan 1, 2006

The mineral resource that a mining company has access to, represents the majority of the embedded value that exists within the company, as well as the competitive advantage that the company has over its peers. However, the real value is only realised once effective mining plans have been put in place, which optimise the extraction of the resource, and add measurable value to the company. The concept of mineral resource management (MRM) has been developed in South Africa, to ensure this optimisation happens in an integrated and quantifiable manner, such that value is added and risk is reduced, resulting in bottom line improvement for the stakeholders of the business. This paper describes the process of mineral resource management, and draws on successes and failures of various companies, to illustrate how it should be implemented, and what measures should be put in place to ensure its success. This requires a fundamental re-appraisal of the way in which mining companies plan and execute their businesses, and focuses attention on real value adding activities and behaviour through the use of economic value added as an appropriate metric by which to measure real value and risk. Specifically, the paper focuses on these aspects as applied to planning models and processes, exploration activity and risk management, to ensure operational and project success.

Jan 1, 2006

The accuracy with which block values are known can have a fundamental effect on the success of an operation.From a geostatistical study the variance of the error in extending sample values to block values can be determined and the engineer must ensure that this is sufficiently small by adjusting the size of blocks or moreintensive sampling. A study is given for a deposit showing a high degree of anisotropy and it is shown that the shape of the block is not important in determining the estimates.

Jan 1, 1976

ICI Australia has been developing PC-based software to assist the blast engineer to design and monitor open pit blasts. The scope of this software differs significantly from commercially available mine design packages.The software is designed for routine use in a normal production environment. The system enables the engineer to produce practical documents which include: a drilling plan, a loading sheet, a hook-up diagram, an inventory of explosives and auxiliary items, and other data on the blast such as tonnages and powder factors.

Jan 1, 1992

By P Collins, C Sheriff

The Sand Queen gold mine is a typical Archaean narrow, high-grade gold quartz lode deposit within a shear hosted system. Initial mining during 1904 - 1948 produced 181 659 ounces of gold from 248 564 tonnes of ore milled at an average production grade of 22.7 g/t Au, which equates to a minimum of 750 ounces per vertical metre. The current mining operation is using the old Sand Queen main shaft to access the Sand George deposit, which is a narrow quartz lode system discovered in the same shear structure along strike to the south of the Sand Queen mine workings. Current underground resources contain 360 200 tonnes at a grade of 11.8 g/t Au for 136 500 ounces. Mining is scheduled to produce 20 000 ounces of gold annually. Re-opening of the Sand Queen mine and underground development of the Sand George lodes has revived several grade control issues relevant to a narrow, ænuggettyÆ gold lode mining environment. These include the dependence of assay grade of individual samples upon a number of factors, including how and where a sample is collected, how and where it is analysed, and how grade data is used to estimate an æaverageÆ grade. Ideally, the only way to achieve an acceptable estimate of ætrue gradeÆ is to mine and mill a large parcel of ore (eg >100 tonnes) from each lode or ore type. In a mining operation producing relatively small tonnages from a number of separate ænuggettyÆ gold lodes, availability of resources and operational constraints may preclude intensive sampling for predictive grade control. At the Sand Queen mine, one of the key issues has been to establish a reliable system for estimation of gold grade with which to reconcile milling data. Extensive use has been made of detailed geological data to understand the grade distribution within individual lodes and between lodes, so as not to rely solely on assay results.

Jan 1, 2008

By Fountain C. R

In April 1987, Mount Isa Mines Limited (MIM) commissioned an ISASMELT reactor to smelt 15t/h of copper concentrate at the Mount Isa Copper Smelter. This unit was based on the Sirosmelt lance technology and incorporated features proven in the Lead ISASMELT plant which has been operating in the MIM Lead Smelter since 1983. From April 1987 to June 1989, the copper smelting plant treated 167000 tonnes. Concentrate, coal and fluxes are fed continuously to the furnace. Oxygen enriched air is injected through a lance which is submerged in the slag bath. Matte and slag are tapped together through a single taphole into a reverberatory furnace, and from there are treated with normal reverberatory furnace production. Advantages of the process include its ability to eliminate most lead and arsenic in feed, its flexibility with respect to feed composition, sizing and moisture, and the plant's low capital cost. Acceptable refractory life has also been demonstrated. The commissioning of a 70 t/day oxygen plant has rerated the plant from 15t/h to 18t/h while allowing a reduction in fuel usage of one third. A trial using 150 t/day oxygen was carried out in May 1989, and showed that the furnace could treat 48 t/h chalcopyrite concentrate while maintaining a very low fuel requirement. The oxygen trial results have given considerable confidence for plant scale-up. Detailed project evaluation is currently underway for the replacement of the roaster and reverberatory furnaces at Mount Isa with a single 110 t/h ISASMELT reactor.

Jan 1, 1989

Scale build-up in titanium palladium alloy spent electrolyte heat exchangers in the residue treatment plant commissioned at Risdon, Tasmania in 1971 was shown to be a mixture of manganese dioxide and anhydrite (CaSO4). The manganese dioxide was deposited as a result of thermal decomposition of permanganate ions present in the spent electrolyte. It was shown that deposition of manganese dioxide and associated anhydrite scale could be prevented by prior reduction of permanganate ions to the manganous (Mn++) state by the addition of ferrous ions. In the plant this was conveniently accomplished by injecting into the inlet line to the heat exchangers sufficient zinc plant solution containing ferrous sulfate to decolourise the spent electrolyte. This action prevented deposition of such scale for another 21 years, until the heaters were finally decommissioned in March 1992. Measurements indicated that addition of the reducing solution lowered the anodic potential of the titanium alloy by 200 - 300 mV (depending on the solution resistance), but that it was still +300 to 400 mV with respect to a standard calomel electrode. It was shown that, if necessary, a small impressed current could be applied to provide anodic protection. Before scale deposition was overcome by the addition of ferrous sulfate solution, badly scaled heat exchangers were cleaned by recirculating a solution of hydrogen peroxide in spent electrolyte or dilute aqueous sulfuric acid, after laboratory testing of a variety of possible solvents for the scale. Corrosion tests indicated that attack on the titanium alloy by the acidic peroxide cleaning solution was insignificant.

Jan 1, 2005

Chile, which hosts around 30 per cent of the worldÆs copper resources, is now the largest producer and exporter of copper. Chilean copper output accounts for more than one-quarter of total worldwide production. An increase to around 40 per cent is forecast by the end of the century. In addition, Chile ranks eighth in silver production and 11th in gold output. In Chile, mining generates more than eight per cent of the countryÆs GDP and the total value of mineral exports is more than US $7.85 billion corresponding to more than 25 per cent of South AmericaÆs mineral production. The rate of growth of Chilean mineral production is indeed impressive. Table 1 shows that in the period 1969 - 1998, copper annual production increased 564 per cent from 667 000 t to 3 764 000 t. Gold production went up 27 times from 1827 to 49 770 kg. Silver output grew 1219 per cent from 95 650 kg produced in 1969 to 1 166 380 kg in 1998. Several facts explain this dramatic increase of production, but the most important was the success of exploration sustained over the same period. This resulted in the discovery of several world-class deposits which when developed into mines, account for much of the production increases. Therefore, this summary review shows the success of basic exploration carried out during the last 30 years in the Chilean territory. The review is based on data already published in different specialised mining books or magazines. It only includes those world-class discoveries not the lesser discoveries important at local scale. All figures were calculated using 1998 $US dollar and average estimated metal prices valid for 1999: copper $US 1653 per t ($US 0.75 per pound), gold $US 9452 per kg ($US 294 per ounce) and silver $US 177 per kg ($US 5.5 per ounce).

Jan 1, 1999

By T C. McCuaig, D B. Mapleson

The Wannaway Deposit is a structurally modified komatiite-hosted nickel-sulfide deposit. Until recently, nickel sulfide accumulations surrounding the Widgiemooltha Dome had been studied with a focus on understanding volcanological aspects of komatiite flow regimes and nickel-sulfide accumulation. Although volcanological features can be observed at Wannaway they are overprinted by several generations of structures associated with multi-phase deformation of the Dome. On the mine scale, two significant deformational events can be distinguished that control ore distribution. The first deformational event is represented by the formation of a layer parallel foliation within the footwall metabasalt and boudinaging of the ore into two distinct orebodies (mega boudins) during a north-south compressional event. Evidence of a second compressional event (east-northeast-south-southwest) is defined by reverse > dextral thrust-folding of the ore zone. The latter deformational event focussed the sulfide ore into thrust front positions where folded ore sequences are mined with stope widths up to nine metres wide. Later stage compressional and extensional deformation phases are observed but have minor, localised effects on the geometry of the ore zone. Four orders of control on the geometry and distribution of ore are interpreted through a combination of primary and secondary features observed at Wannaway. Extending the structural aspects of the secondary overprint features into areas of potential mineralisation has not only defined targets for extensions to the Wannaway Deposit, but has also aided to delineate high grade mineralisation and aid mining decisions. Obtaining an understanding of the volcanological conditions of formation, and more importantly, the structural evolution of the Wannaway region has been an integral part in optimising production.

Jan 1, 2003

In the early ages man contented himself with the use of such tools and appliances as would assist him in the enlightenment of his labours. With the advancement of science, numerous motives, with modifications and adaptations, have been introduced to enlighten labours, and in many cases have taken the place of man, but it can hardly be said that this applies to shovels, although one of the oldest implements of labour; certainly, with the introduction of the steam shovel the labours of man have been considerably reduced, but the hand shovel of today is used similarly to that of years ago.If the principle of the hand shovel has not been improved upon, it must not be suggested that the manufacturers of this article are not endeavouring to improve its quality, and the main point with which the manufacturers have to contend is the production of an article which will give a maximum of durability combined with a minimum of lightness. In order to accomplish this they must select suitable material, and subject it to such heat treatment process that will produce a shovel having a maximum of hardness and toughness without being unduly brittle, and which will withstand the excessive wear to which it is subjected.In this article an endeavour will be made to explain (a) the manufacture of shovels; (b) the defects commonly met with-the cause of same and measures which are necessary to remedy them.Before doing so a brief description will be given of the class of steel used for shovels; this is an important factor, and a steel which is admirably suitable is a plain carbon one containing approximately 55 - 70% C., and closely resembles that used for the manufacture of railway rails. This plain carbon steel is very extensively used, although at present alloy steels are being utilised to a certain extent for shovel manufacture, and with suitable heat-treatment.

Jan 1, 1926

Don Hausen was a pioneer in the field of quantitative mineralogy. Methodology that he developed at Newmont almost 40 years ago is still employed today, only the technology has advanced. Petrographic methods were stressed with an emphasis on alteration, mineralisation and paragenesis. Methodologies employed by Don on the Carlin deposit were applied to developing the Carlin Trend by helping to work out lithology and structure, which ultimately led to the discovery of deep high-grade deposits. Quantitative methods used by Don on San Manuel, Copper Creek and Superior, Arizona were applied to the development of the Batu Hijau Deposit in Indonesia. Advancements in technology since DonÆs time have made the mineralogist much more efficient. Manual measurement of peak heights off of strip charts for semiquantitative XRD has been replaced by software that does Rietveld refinement and whole pattern fitting. Hand contouring of XRD data has been replaced by digitised data incorporated into geologic models. Optical point counting, which would take a dayÆs work to process 1000 points, has been replaced by automated SEM methods where 20 000 points are possible in an hour. The use of the optical microscope remains relatively unchanged, and still remains as Don emphasised the æeyesÆ of mineral exploration. However, the information can be relayed much more quickly with digital image capture and electronic data transfer. Don insisted on becoming involved in projects at the grassroots level and supporting the project through mine closure. This made the mineralogist a liaison between exploration geologists, mine geologists, metallurgists and mine engineers. The methodology that Don helped develop continues to provide invaluable support to Newmont geologists and metallurgists worldwide today.

Jan 1, 2008

By Y Peng, D J. Bradshaw, X Chen

At NewcrestÆs Telfer gold mine, a strategy of regrinding pyrite rougher flotation concentrates has been proposed to increase gold recovery and reduce cyanide consumption in the CIL circuit. The regrinding will be followed by an additional copper/gold flotation stage, where copper minerals need to be separated from pyrite. However, although the minerals are well liberated, the separation of chalcopyrite from pyrite in the cleaner stage is not always straightforward. The surfaces of the fine particles, produced during regrinding, are more easily oxidised and contaminated than coarse particles, directly influencing the particle floatability. The depression of pyrite is difficult in the cleaner stage as well due to copper activation, a process which is also highly dependent on the grinding environment. In this study, different grinding media, including mild steel and stainless steel, was used in the regrinding to produce different regrinding chemistry, such as, pH, Eh, and iron hydroxide contamination. The effects of regrinding conditions on chalcopyrite flotation and its separation from pyrite were studied. It was found that the stainless steel grinding media, which produced an oxidising environment, was more beneficial for the separation of chalcopyrite from pyrite after regrinding. The mild steel grinding media had a detrimental effect on both chalcopyrite and pyrite flotation. This study addresses the importance of choosing suitable regrinding conditions in the pyrite and copper flotation circuit.CITATION:Chen, X, Peng, Y and Bradshaw, D J, 2012. Effect of regrinding conditions on the flotation of chalcopyrite and its separation from pyrite in the cleaner stage, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 279-286 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

The efficient development and exploitation of an orebody relies on an understanding of the mineral characteristics of the deposit. This information is valuable throughout the mining cycle - during exploration, assessment, testing, design, operation and rehabilitation. Problems can arise at each stage if there is an inadequate appreciation of the mineralogy involved and its effects on the treatment process. Modern image analysis systems now permit a more quantitative understanding of the mineralogy of an ore to be gathered. Where previously the metallurgist had to rely on qualitative information to guide technical decisions, it is now possible to give numerical estimates to the compositional and textural properties which govern the mineral concentration processes. Ore samples can be characterised according to modal abundances, mineral grain size parameters and mineral associations, all of which affect the liberation and concentration of the values. The paper will discuss the application of quantitative process mineralogy by considering a number of case studies. These include: ore characterisation to assist in exploration, assessment and mine planning; modal analysis of complex mineral suites to assist in the evaluation of ores, the deportment of values between products and the recovery or loss of these values; liberation analysis for ore testing, plant optimisation and performance monitoring; and characterisation of tailing to guide estimates of leachability, stability and rehabilitation options.

Jan 1, 1998

By D J. Williams, G W. Wilson, S, A B. Tran

A comprehensive field program was implemented to evaluate the internal structure and hydrology of two full-scale waste rock piles. The excavation of waste rock dumps for in-pit disposal at the two mine sites provided an opportunity to characterise the in situ properties of the dumps given contrasting geologic and climatic settings. The internal structure and materials within the dumps were observed and sampled as the waste rock piles were being excavated and placed in the open pits for permanent closure. The field program was designed to fully characterise the structure and material properties of the waste rock. The alteration of the material by physical and chemical weathering was also observed. Samples were analysed for paste pH, water content, grain size distribution and geochemistry. In situ density and matric suction were also measured. Soil water characteristic curves and saturated hydraulic conductivity were measured for representative materials. These properties were used to predict seepage pathways through the waste rock and the resulting outflow geochemistry using the finite element model SEEP/W. The materials in the dump at Site 1 were predominantly fine-grained in texture and highly weathered. The presence of dipping beds with alternating coarse and fine materials was evident throughout the profile of the dump. The structure of the waste rock appears to have an impact on the hydrologic pathways within the waste rock pile. The material in the dump at Site 2 was found to be competent and resistant to particle size breakdown. The particles range in size from clay size to large boulders with the median particle size being approximately 125 mm in diameter. The coarse-grained texture of the waste rock resulted in a loosely packed arrangement of coarse particles with little matrix material infilling the pore spaces between the coarse-grained particles. Seepage modelling for Site 1 was completed to predict seepage paths based on observed structure and hydraulic properties measured in the laboratory. The modelling showed that materials with a fine grain size distribution become the dominant pathways for flow through the waste rock pile. The modelling also showed that layers with high silt and sand contents are subject to the highest flow rates. Finer grained clay rich layers have a low hydraulic conductivity and do not convey large volumes of water. Alternately, coarse gravel and cobble materials are unsaturated under values of matric suction that approach the residual water content of the material and do not transmit liquid water. The seepage modelling together with the results of the geochemical analysis show that the dominant particle size that receives the most fluid flow and flushing ranges from fine sand to silt, corresponding to materials with air entry values ranging between 5 kPa to 50 kPa.

Jan 1, 2003

At 11 p.m. on Tuesday, 24th July 1979, an explosion of methane gas in a three heading development panel at Appin Colliery resulted in the deaths of fourteen men. The explosion followed after or was asso- ciated with a changeover of the ventilation to achieve a central intake between two returns. Investigation by Inspectors was followed by separate Judicial and Coronial Inquiries. Investigational information aimed at understanding the circumstances of the ex- plosion was prepared for the Inquiries. Recommendations following the Judicial Inquiry have been adopted by the Department of Mineral Resources.

Jan 1, 1981

Low-grade, porphyry copper type mineralization at the Moonmera prospect is related to the intrusion of a granodiorite porphyry mass into the Upper Permian "Gracemere granodiorite". Significant copper mineraliza- tion appears to be associated with the alteration assemblage quartz-sericite- kaolinite. The ore shell is surrounded by a zone where montmorillonite and kaolinite are in greater abundance and this assemblage is over- lapped, mainly at depth, by potassium feldspar alteration. Secondary biotite is abundant throughout the mineralized zone. Preliminary sulphur isotope results on the sulphide mineralization are compatible with a magmatic origin for the sulphur.

Jan 1, 1974

By Y Li, L Zhang, G Li, S C. Dominy

Qiagong skarn iron (copper) deposit is located in Xietongmen County of Tibet, China (N 29¦52Æ14.9ö, E 88¦24Æ10.3ö). It is situated at the middle-western Gangdese porphyry copper-belt. Mineralisation is related to a Himalayan porphyry intrusion, with the mineralised body occurring at the contact zone between the Tertiary Takena Formation carbonate rocks and Himalayan monzonitic granite porphyry. The melt, melt-fluid and fluid inclusions were observed in early quartz, with most abundant fluid inclusions in quartz, calcite and garnet from the skarn. The geology and inclusion assemblage show a close relationship between iron (copper) mineralisation and a Himalayan porphyry intrusion. Based on preliminary inclusion studies, this paper discussed the characteristics, evolution of ore-forming fluid and affiliation to the Himalayan porphyry intrusion. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By testing rotary-drag bits in granodiorite it was found that an increase in bit clearance angle from 241 0 to 33° decreased insert wear. Severe wear has precluded economic application of rotary-drag drilling in abrasive rock even though fast penetration rates have been achieved.From a limited number of tests and from theoretical considerations, the insert wear was inversely proportional to the thrust on the bit This effect follows the marked reduction in the linear distance traversed by the inserts, for a given depth of penetration, as thrust increases...

Jan 1, 1969