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By R-H Yoon

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analysed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was also found that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K232) estimated from the film thinning experiments were used to predict the disjoining pressure isotherm using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (He) of the foam films stabilised by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, He increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is at its maximum level in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.

Jan 1, 2005

By Smith C. B

Major diamond pipes discovered in Western Australia in the late-1970s exhibited a number of unique features that not only resulted in Australia becoming the largest diamond producer in the world in volume terms by 1986 but also changed geological thinking on the primary occurrence of diamond. They were: - lamproite is an alternative primary diamond host to kimberlite. - the extremely high mean grade of the Argyle lamproite pipe at 5 ct per tonne. - the tectonic setting of the lamproite pipes in mobile zones mar- ginal to the Kimberley Craton in contrast to the traditional African setting within stable cratons. Diamond was one of the earliest economic minerals discovered in Australia but 128 years elapsed between its first recognition and the first Australian economic pipe discovery (Argyle). During that period some 200,000 ct of alluvial diamonds were mined in Australia (mostly in New South Wales), but such alluvial output is insignificant on the world scene where annual production today runs at 95 million ct of natural stones some 76010 of which comes from primary pipe sources such as Argyle which alone produces 30 million ct per annum. Of particular significance therefore is the geological nature of the primary diamond source rocks in Australia. The Argyle and Ellendale Pipes are lamproites, differing from kimberlite in their mineralogy and geochemistry, and characterised by the presence of typical lamproite minerals such as leucite, priderite, potassic richterite, and the abnormally high content of chemical elements incompatible with ultramafic rocks. But not yet widely appreciated is that many other Australian olivine-rich lampro- phyres also contain diamond. Such picritic alkaline rocks can

Jan 1, 1988

By R Dwyer

Iron ore currently mined in Australia generally requires very little beneficiation. However, depleting high-grade resources means that in the future low-grade iron ore deposits will need to be mined to meet the increasing demands of the global steel industry. Along with the increased demand, the industry faces additional pressure to reduce the environmental impact of mining and mineral processing. This has stimulated research beyond incremental improvements to conventional processing into alternative low-impact processes, including biotechnological approaches to mineral processing.Bioflotation and bioflocculation have emerged as relatively recent technologies, in which bacteria and/or their extracellular material may be used as flotation reagents (collectors or modifiers), enabling improved selective separation of minerals. The primary advantage is the production of a selective, environmentally-benign alternative to conventional flotation reagents. A biotechnological approach may also be taken in the beneficiation of high-phosphorous iron ores utilising bacteria capable of iron reduction and phosphorous solubilisation.Samples from three iron ore deposits in Western Australia were examined for bacteria suitable for iron ore benefi ciation. A number of common soil microorganisms including Pseudomonas spp, Limnobacter thiooxidans, Paenibacillus spp, and Ralstonia insidiosa were identified using culture-independent molecular techniques. A number of anaerobic species belonging to the genus Clostridium were also identified in the core samples. Selected aerobic species were enriched and isolated on high nutrient media in the presence of haematite. Several of the isolated strains showed an affinity for iron ore, attaching to haematite in enrichment cultures and further demonstrated through adhesion studies. Other isolated species such as Ralstonia isidiosa and Pseudomonas stutzeri are known to solubilise rock phosphates in soils and have potential for the removal of phosphorous from Australian iron ores.

Jul 11, 2011

By M S. El Salmawy

In order to develop the HF-free flotation reagent system, the main objective of this investigation was to study the possibility of separation of quartz from feldspar using non-ionic surfactants as the collector. The non-ionic surfactants used were polyoxyethyl cethyl ether (PECE) and polyethylene glycol monocethyl ether (PGME). The flotation behaviour of quartz and microcline with PECE and PGME was investigated. Each surfactant was a good selective collector for quartz with its recovery being influenced by pH and surfactant concentration. Quartz is floated favourably by both types of polyoxyethylene non-ionic surfactant whereas microcline was not so much. The floatability of quartz increases as the oxyethylene length of surfactants increases. Zeta potential measurements in the system of PGME/mineral were also carried out. It was determined that in the absence of PGME the points of zero charge for quartz and microcline should be approximately at pH 2.5 and 1.8, respectively. The addition of PGME to the system causes both minerals to become less negatively charged. Differences in the zeta potential value between quartz and microcline, in the presence of PGME, were detected. It can be suggested that the interaction of the oxyethylene group to the microcline surface should not be as strong as that to the quartz surface. In the mixed surfactant system of PGME and dodecylamine acetate (DAA), a small addition of DAA causes drastic enhancement of quartz flotation in the wide pH range of 1 ~ 10. In the mixed surfactant system selective flotation of quartz from microcline would be anticipated at pH

Jan 1, 2005

In reviewing recent developments in the process mineralogy of gold it is convenient to distinguish between visible (>0.1 pm) and invisible gold (1 - 2 pm in size in polished section; these can scan the surface of a polished section, identifying the gold minerals, recording co-ordinates of the grains for subsequent examination, and making measurements of areas and sizes of the grains. However, problems of sample reliresentivity in polished section mean that such data may not give good quantification of gold mineral proportions and liberation/locking characteristics and other methods are required for this (amalgamation, cyanidation, ultra-fine milling and cyanidation). Characterisation of invisible gold in bulk material (eg a sulphide concentrate) can be done by mineral separation, ultra-fine milling and cyanidation or by quantitative point analyses of a large number of mineral grains. Analytical methods include electron microprobe analysis (detection limit normally -200 ppm but -10 ppm by using special techniques), ion microprobe analysis (secondary ion mass spectrometry - SIMS; detection limit -0.2 ppm) or proton microprobe analysis (PIXE; detection limit

Jan 1, 1992

THE reduction of iron from the ferric to the ferrous state prior to its titration by permanganate or dichromate may give erroneous results in the presence of other reducible metals such as titanium. Stannous chloride and metallic zinc both reduce tetravalent titanium to a lower form, and so increase the consumption of the oxidizing standard: solution. Sulphuretted hydrogen and sulphurous acid do not reduce titanium, but are slow in action and troublesome to manipulate.Sulphuretted hydrogen is considered to be the best reducing agent for iron in the presence of titanium.* In the method to be described the advantages of the H 2S reduction are retained without the disadvantages of using the gas. The reduction is carried out by the action of a metallic sulphide having a solubility product of such a value that the sulphide iom, are utilized as fast as they are formed, and but little free sulphuretted hydrogen is given off.Cadmium sulphide was the first to be tried, but its solubility product (3.6 x 10 - 2~)t was apparently too low. The reduction was satisfactory, but the excess was very difficult to remove. Zinc sulphide (S.P. = 1.2 x 10 - 23) was found to be quite satisfactoryin both respects. The zinc sulphide is preferably used in the form of an emulsion prepared from pure zinc sulphate as follows: About 100 grm. of ZnS047H20 is dissolved in 2 litres of water. H2S is passed until no further precipitate is obtained, the acid formed being barely neutralized from time to time by the addition of ammonia. The precipitation of the sulphide in a slightly acid solution gives a finer emulsion than that prepared in an alkaline solution, and any iron present remains dissolved. The precipitate is allowed to settle and the clear liquid decanted. The precipitate is then shaken up with more water, acidified with a little sulphuric acid, allowed to...

Jan 1, 1922

By J C. Small

Time-dependent deformation occurs when geo-materials are under an applied load; this may lead to additional deflection of a tunnel structure and the stress redistribution in the surrounding rock, shotcrete lining and rock bolt support system over time. A better understanding of this creep behaviour can improve the reliability of design, construction and maintenance of tunnels. Hence, the present investigation was carried out on the time-dependent properties of rock, shotcrete and the combined tunnel support system. Tunnels constructed in different ground conditions were modelled. The closure changes of the tunnel with time and the redistribution of stress in the surrounding rock, shotcrete lining and rock bolts due to the creep deformation were analysed. Results of the present analysis were compared with the results from the commercial program ABAQUS.

Jan 1, 2008

By D J. Clark, R F. Wright, M D. Goodz

The A1 Gold Mine is a Devonian-age narrow vein high-grade gold deposit located 115 km east of Melbourne. The mine operated almost continuously from 1861 to 1992 producing 442 334 ounces of gold (13.8 t) from 530 436 tonnes from primary gold ore tonnes processed at an average recovered grade of 25.9 g/t Au. The A1 dyke was attributed with a yield exceeding 620 000 ounces (19.3 t) of gold (including gold in alluvial and tailings deposits), and was renowned as one of VictoriaÆs premier mines paying considerable dividends. The orebody was principally in a diorite dyke bulge 150 m long, 45 m wide and 700 m deep and was mined via two vertical shafts. The mine site was closed in 1992 and the site was rehabilitated in 1999. In 2008 - 2009, a diamond drilling program identified various extensions to the host dyke lithology and to gold-bearing quartz vein filled fault zones over a 700 m strike length. The outcome of this study was the establishment of a mine geology corridor four times longer in strike length than the original 1970s model. This opens A1 dyke hosted deposit style to exploration outside the historical dyke bulge and provides exploration opportunity for all similar deposits. Construction of the first 3D geological model has developed new insights on the host rock diorite dyke system and identified various extensions to both host stratigraphy and to gold-bearing mineralised structures. Coarse visible gold in quartz vein mineralisation (>30 g/t Au) and medium-grade stockwork mineralisation (8 - 15 g/t Au) has been intersected within 100 m of the surface and up to 300 m along strike of the nearest historical underground workings. At depth it appears that the mineralisation is continuous with the main dyke body with consideration of minor rotation in the strike orientation and limited reverse thrust faulting showing maximum displacement of 10 - 20 m. Along the A1 mine corridor, between two and five parallel dykes are observed at different drill sections. The gold mineralisation is hosted mainly within the dyke rocks, but where the sedimentary rocks are intensely silicified or are xenolith rafts, the gold mineralisation continues across these sedimentary rock blocks. There has been inference to the role of silicified sedimentary rocks as a second ore host and a bounding material for inflections in fault and vein orientations. In the central 150 m long A1 mine dyke bulge, the extremities are demarcated by four to five parallel dyke fingers (referred to as apophyses) going both north and south. These apophyses are clearly observed both vertically and horizontally between levels No 4 and No 9. The dyke fingers entrap sedimentary rock xenoliths and collectively form the A1 dyke æcorridorÆ, which is quite uniform in overall width from the easternmost contact (footwall) to the westernmost contact (hanging wall). Dyke fingers were assumed to coalesce at depth into a single dyke, but recent drilling shows this feature to repeat in several positions with depth and along strike. Key observations are the relationship between gold grade and fracture density, alteration, sulfidation, host rock morphology û relation of contact shape and fault zones. These relationships allow for the classification of prospectivity indicators and geology as a guide to potential extensions of mineralised zones. Mining geology is contributing to the whole-of-mine life planning and development where decline path, stockpile and infrastructure positions are controlled by geology.

Jan 1, 2009

By X Ling, M Barati, E Moosavi-Khoonsari

In the pyrometallurgical process of secondary lead recycling, a desulfurising agent, such as Na2CO3 is added to minimise the emissions of sulfur into the atmosphere, while silica is introduced into the smelter as a fluxing material. Subsequently, a significant amount of Na2O and SiO2 remains in the downstream reverberatory furnace and blast furnace slags. However, there is limited understanding of the thermodynamic behaviour of silicate-based lead slags rich in Na2O, posing challenges in accurately determining the optimal condition for targeted metal recovery and final slag composition. In this work, the equilibrium phase relations of the PbO-Na2O-SiO2 system in the primary phase field of Na2SiO3 are studied from 800 to 1000°C via equilibration-quenching method. Samples with different compositions were prepared and held in platinum capsules in air at these temperatures to reach equilibrium. The equilibrated samples were subsequently quenched and the phase compositions were measured by electron probe microanalysis (EPMA). The results were then compared to those of previous studies and any discrepancies were resolved.

Jun 19, 2024

The title of my address today 'An Environment for Mineral Development' is a play on words, but I wish to use the meaning of the word environment in the broadest possible context to comment on those factors that control mineral development in New Zealand today. Of prime importance, let us consider the current economic environment in which New Zealanders live and work, as individuals and communities, and as a trading nation. It is the expanding growth requirements of the emerging nations and the interactive economic forces of our international trading partners and competitors, that dictates New Zealand's economic environment and thus the priority to develop its natural resources. As an itinerant New Zealander who has kept a watching brief over the economic environment in New Zealand over the last 30 years, I say, without prejudice, that I am concerned to have seen New Zealand's external and internal trading position deteriorate so rapidly in the last decade. I am concerned that a significant proportion of the population has been extremely slow to realize that with the creation of the European Economic Community, in the late 1950s, and following the first OPEC oil crisis in 1973, New Zealand in a corporate sense came close to technical bankruptcy.

Jan 1, 1985

By Mitchell G. W, Purvis A. H

The Lady Loretta silver-lead-zinc deposit lies north of Mount Isa in folded and faulted Proterozoic carbonate sediments. The deposit was discovered in the late 1960's as a result of a soil geochemical survey. Subsequent surface drilling outlined mineralisation folded into a synclinal structure extending to a depth of 460 m and containing exceptionally high grades within the keel of the syncline. Pancontinental Mining Limited and Outokumpu Oy of Finland acquired the property in 1985.

Jan 1, 1988

One of the biggest drawbacks of deciding upon a heap leach method of treating gold ore is the risk associated with the full-scale production heaps not performing as predicted by the testwork. This paper examines the key decisions that are taken in the design of a heap leach project, and suggests ways in which exposure to these risks can be minimised. It also looks at monitoring techniques to give early warning of problems and possible remedial actions.

Jan 1, 1994

By B Beamish

"All underground coal mines in Australia are required to develop a Spontaneous CombustionManagement Plan (SCMP). The New South Wales Government has developed a guideline (MDG1006) to assist operations to comply with this requirement. A reference document is alsosupplied with the guideline that describes the type of information that is needed for input to theplan, including identifying possible tests that can be used for propensity assessment. However,there is no clear indication of what program of sampling and testing is suffi cient to provide adefi nitive assessment of spontaneous combustion propensity prior to and during mining. This paper reviews the existing methods available for quantifying spontaneous combustion propensity and discusses the sampling requirements that are needed from exploration to mining. A new, more defi nitive method of spontaneous combustion testing is also presented that benchmarks coal self-heating performance from mine ambient temperature to thermal runaway. Examples of the eff ectiveness of this new test method for identifying and quantifying reactive pyrite in coal as well as quantifying the diff erence between dry and wet season conditions are provided in the paper."

Jun 1, 2012

By Neill B. K, Fander H. W, Wong K, Dunlop G, O&apos

Commercial interest in refractory gold is increasing rapidly. This trend is supported by the work patterns of Amdel, where, apartfrom routine process- ing of free-milling and refractory ores, the majority of testing now includes biological and pressure oxidation studies to enhance gold recoveries. Central Mineralogical Services have examined, among other ores, an apparently unique type of refractory coating. A summary is given of experience at Optimet Laboratories, Pty., Limited. Research into nitric acid pre-oxidation, underway at the South Australian Institute of Technology since 1987, has shown significant improvements in gold recoveries, and in some cases, large reductions in reagent consump- tions. Three final-year student research projects were undertaken in 1990, jointly between the University of Adelaide and the S.A. Institute of Tech- nology. These projects involved biological pre-oxidation, pressure leaching, and Scanning Electron Microscope examination of refractory ores, and the resultant pre-oxidation and cyanidation products.

Jan 1, 1991

By K Esmaeili, S Aziznejad

Impact-induced rock fragmentation is a mechanism that is commonly used for rock breakage in drilling and crushing. Additionally, rock fragmentation by blasting is frequently used in rock excavation operations. Experience shows that the presence of discontinuities can significantly influence the impact-induced damage and fragmentation of rock. Quantification of the response of jointed rock masses to impact loads is complicated by the fact that the available laboratory tests are mainly designed for aggregates or intact rocks. It can be argued that neither of these tests adequately represent a jointed rock mass. This paper presents the results of a series of numerical simulations used to investigate the influence of pre-existing discontinuities on the impact-induced fragmentation of rock masses. The methodology includes determination of the static and dynamic mechanical properties of a rock unit by conducting a series of laboratory tests on intact rock samples collected from a quarry in Canada. A 2D distinct element code, Particle Flow Code, was used to generate a bonded particle model in order to simulate both static mechanical properties (uniaxial compressive strength, elastic modulus, Poisson’s ratio and indirect tensile strength) and dynamic mechanical property (drop weight tensile strength) of the intact rock. The calibrated numerical model was then used to construct large-scale synthetic rock mass samples by incorporating discontinuity networks of different intensity into the bonded particle model. Finally, the impact-induced fragmentation inflicted by a rigid projectile particle on the jointed rock mass samples, simulated by a synthetic rock mass model, was determined. More fragmentation was observed for the rock mass samples with higher joint intensity.CITATION:Aziznejad, S and Esmaeili, K, 2015. Effects of joint intensity on rock fragmentation by impact, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 377–384 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Isaac AK

The combination of shot-firing and stage loader, and a prop and bar support system is an accepted drivage method. The support configuration is based on the final prop density, and assumes relitively uniform load sharing between the props. During the development of a longwall faceline at a medium depth (approximately 600m) British coal mine using such a drivage method, a fall occured overnight, effectively closing approximately 40m of the drivage. The severity and speed of the fall prompted an investigation into the performance of the temporary support system installed prior to chock installation. This paper deals with the investigation which disclosed some major contributory factors towards loss of strata control.

Jan 1, 1986

By Taylor R. N

Flow simulations have been performed on the flash-smelting burners currently used at KNS. This paper presents studies of the heat transfer between gas and particles at the burner exit. Gas and particle temperatures, velocity and concentration profiles of the two-phase flow are calculated by the mathematical model. The predicted gas temperatures have been favourably compared against values measured by thermocouples placed near the burners in the flash furnace. The predicted particle temperatures are also reasonable when compared with the measured temperatures.

Jan 1, 1992

The Late Permian intermediate to silicic talc-alkaline Drake Volcanics of New England, N.S.W., consist largely of shallow marine, redeposited volcaniclastic rocks which host epithermal Ag-Au deposits. Pervasive hydro- thermal alteration is widespread. The 200-300 m Cataract River Member includes several sedimen- tation cycles composed of massive pumice brec- cias, overlain by laminated sandstones and siltstones, interbedded with marine, fossil- iferous mudstones. Two distinct groups of cla- sts exist within the volcaniclastic beds: 1. Lithics of predominantly intermediate compos- ition lavas that have undergone subaerial epi- clastic erosion and transportation; 2.Pumice, quartz and plagioclase crystals which have not been reworked by epiclastic processes. The lithic clasts were derived locally in a sub- aerial environment within the Drake Volcanics, and pumice and crystal fragments from contem- poraneous centres of silicic volcanism else- where in New England, N.S.W. The latter group of clasts was transported to Drake by Plinian airfall or rafting, and fell and was washed on- to emergent portions of the Drake Volcanics, where reworked locally derived fragments occ- urred. Cold state subaqueous mass-flows, prod- uced by slumping, resedimented the mixed vol- caniclastic detritus into the marine basin in a series of cyclic units with massive lower parts, and laminated upper zones. Modern ana- logs of the palaeogeographic setting in New England, N.S.W., in the Late Permian are pro- vided by the Taupo Zone, New Zealand, and sou- thern Kyushu, Japan.

Jan 1, 1987

By Coombes J, Richards W. L

The objective of this paper is to illustrate, in a practical way, how both geologists and mining engineers can use conditional simulation to add value to their decisions. Inherent assumptions, requirements and essential components of condition

Jan 1, 1998

By S R. Grano

The selection of the proper frother, specifically for a given ore, is essential in flotation. Traditionally, strong and stable froths are required in the scavengers, where metal recovery needs to be maximised, while selectivity must be achieved in the roughers and cleaners, where grade of concentrates is the main issue. The physical properties of a froth are determined both by frother type, by process water composition and by the amount and nature of the suspended particles. The evaluation of different frothers, in terms of metallurgical performance, is complicated at plant scale, since it may lead to periods of malfunctioning of the process and unacceptable decreases in recovery. On the other hand, evaluation based on frother chemistry only, is often unsatisfactory, because the frothing response is strongly ore dependent. A procedure, and proper tools, was developed at the Wark in order to perform the screening of candidate frothers at batch scale on real pulp samples. The main parameters related to froth stability (half-life time, froth height) are measured after introducing the pulp samples into a foaming column, where different conditions in terms of frother addition, agitation and aeration can be maintained. The approach has been applied to the selection of frothers for the flotation of an Australian sulfide ore. Procedure and results are discussed.

Jan 1, 2006