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By Potter DJ, Firkin GR

The Imperial Smelting Furnace operated by Sulphide Corporation Pty. Limited at its Cockle Creek zinc-lead smelter was recently equipped with tuyeres angled at 25 degrees instead of the usual 10 degrees. This change was prompted by the results of model studies undertaken by tha Research Department of Imperial Smelting Processes Limited, at Avonmouth in the United Kingdom, and by the favourable results of operating trials on the Cockle Creek furnace using bent-tip tuyeres to simulate 25 degree inclination. The use of 25 degree angle tuyeres has made it possible to operate with lower zinc values in discard slag and has improved hearth stability over a wider range of sinter quality and composition.

Jan 1, 1981

By Yan D. S

The removal of antimony from a refractory gold-bearing stibnite ore by roasting and selective chlorinating roasting was investigated. The influence of roasting temperature, roasting time, roasting atmosphere and type and amount of chlorinating agents on antimony removal were studied. The laboratory studies carried out included roasting tests of 4 g samples in a laboratory rotary kiln, followed by 400 g samples roasted in a fluidised bed. The test results revealed that antimony was efficiently removed by roasting at temperatures over 800¦C in a nitrogen atmosphere. The most efficient volatilisation of antimony was achieved with the addition of ferric chloride at temperatures between 350-600¦C.

Jan 1, 1995

By Phillips H. R

The action of free rolling disc cutters is well understood, relationships between disc geometry and performance having been established both in the laboratory and under field conditions. However, under severe operational conditions a malfunction of the disc bearing assembly is likely to produce a definite change of cutting action. Collapsed or siezed bearings can even prevent the disc from rolling and thereby create what is equivalent to a drag pick. This paper describes a programme of laboratory experiments using deliberately stalled discs. Their performance under such conditions is contrasted with that for a free rolling disc and also with a drag pick having a ridged front developing into a negative radiused back clearance angle. In conclusion an assessment is made of the influence stalled discs can have on the torque and thrust requirements for a tunnel boring machine.

Jan 1, 1981

By Gonzalez-Dominguez J. A, Dreisinger D. B

At Cominco's Zinc Refinery at Trail, British Columbia impurities are removed from zinc sulphate electrolyte by a two-stage purification process using zinc dust. Copper, cadmium and thallium are removed in the first stage whereas cobalt is removed in the second stage. Cobalt removal kinetics are affected by soluble antimony and copper additions to the electrolyte. This study was focused on the kinetics of cobalt removal by zinc powder cementation. Experimental variables included copper and antimony concentrations, pH and temperature. Common organic additives employed in zinc plants were studied to determine potential interactions with the cobalt removal process. Cementation products obtained from laboratory experiments and plant practice were studied using SEM. A number of significant results were obtained: 1. Copper and antimony ions were sustantially removed from solution during the early stages of the cementation reaction (within the first 15 minutes). Cobalt cementation kinetics are slow and follow a first order kinetic regime. 2. A drop in the cobalt removal rates can be correlated with a rise in the Eh of the slurry. 3. Ligninsulphonate, Percol 351 and animal glue at levels of 2 mg/L significantly impede cobalt cementation.

Jan 1, 1993

By Recepoglu O, Tolun R, Yavasoglu N, Bulutcu AN

Scheelite was floated from a low-grade (0.28 per cent W03) calcitic (96.30 per cent CaCO3) scheelite ore using oleoyl sarcosine as collector and alkylated 8-hydroxyquinoline as modifier. Compared to oleoyl sarcosine alone, the grade and the recovery of scheelite concentrate were increased from 8.07 per cent to 33.54 per cent and from 55.1 per cent to 73.4 per cent, respectively. Infrared studies with pure calcite and scheelite minerals showed that while alkyl oxine is adsorbed on the scheelite surface, it is not adsorbed on the calcite.

Jan 1, 1993

By Robbilliard K. R, Floyd J. M

The problems facing the metallurgical industry from the viewpoint of the range of unacceptable residues, flue dusts and slags currently produced from the electrolytic zinc process, electric arc furnace scrap treatment, and blast furnace operation in lead smelting and the Imperial Smelting Process (ISP) are addressed. The application of the Ausmelt technology is discussed and analysed for the pyrometallurgical treatment of zinc plant residues, steel plant flue dusts and lead blast furnace and ISP slags, as well as the more complex issue of smelter modernisation to avoid production of zinc plant residues in the future. Processes developed from pilot work are described and indications of the economics of treatment of electrolytic zinc plant neutral residue and jarosite are given.

Jan 1, 1993

By Thornton D, Firth B, Kojovic T, Brien G, O&apos

Coal fragmentation is a function of coal type and mining process. Each unit step in the mining, handling and crushing chain of coal imparts energy to the material and impacts on size degradation and consequent mineral matter liberation and pla

Jan 1, 1998

By Orr D. B

This is a case history of prospec- ting carried out by Comstaff Pty. Ltd. over the Pinnacles Area, part 4 of Exploration Licence 5/63, 9 km north of Rosebery in Western Tasmania. Evidence is presented to show that A 0 soil samp ling is a viable prospecting method for outlining polymetallic sulphide occur- rences in areas where leached organic/ glacial soils are common. Diamond drilling of low threshold anomalies has intersected base metal mineralisation.

Jan 1, 1977

Pbo activities have been measured in conventional blast furnace and direct smelting type slags at 1200¦C. Much higher activity coefficients than previously measured have been obtained and attributed to interactions between iron and lead oxides. The behaviour of PbO in the two types of slag reflects their relative silica contents. Simple equations derived from mathematical modelling work are presented for the prediction of Pbo activities in complex industrial slags.

Jan 1, 1984

Carbonate-hosted massive sulfide ores of the American cordillera compose a distinctive genetic class. Discordant fea-tures of occurrence together with measured high-temperatures of formation indicate their essential epigenetic character and close spatial association with centers of thermal activity during evolution of the cordillera. Their metallogenic character is complex from region to region: Cu-Zn-Pb-Ag, Pb-Zn-Ag, and Cu-Zn-Ag-Au represent extremes of composition and each may be identified with specific terranes of occurrence, notwithstand-ing an inferred common process of formation. Beyond the presence of a thermal center, other controls that may be identi-fied include apparent but obscure properties of primary perme-ability or chemistry of hosting strata, and secondary controls are imposed by stratigraphic differences in which permeability is strongly contrasted. Structures that act as channelways may be identified in some instances. Notwithstanding their intrinsic value, search for these ores is difficult and requires the solution of complex geochemical and three-dimensional geometric problems.

Jan 1, 1990

By Reilly L, Worner H. K

The EnvIRONment process has been developed to treat steel works dust and organic wastes simultaneously. A pelletised feed is fed into a special DC electric furnace, the pellets becoming immersed in a molten slag above a carbon saturated bath. The iron oxide in the pellets is reduced and carburised whilst the organics are broken down to carbon monoxide, carbon dioxide, hydrogen and water vapour. Volatile metals are vapourised and collected in the baghouse. Over two years of trials in a 100 kg DC electric are furnace has brought the process to the stage where it is ready for commercialisation.

Jan 1, 1995

The most frequent initiation of coal dust explosion results from the ig- nition of high methane volumes, often at low concentration close to the minimum flammability limit, by a weak ignition source, e.g. frictional sparks. Tests performed in the 400 m underground test gallery of 7.5 m2 cross section indica- ted the following: 1. Methane at 200 m3 volume and con- centration 4.0 - 5.0 % CH4 may initiate the coal dust explosion. 2. Suppression of explosions result- ing from such initiation is very difficult, even when employing triggered, barriers.

Jan 1, 1988

By Boyd G

This paper describes the planning, analysis, design and operational experience of highwall mining based on auger drilling techniques applied to thick coal seams exposed in an opencut highwall. Being the first time such technology has been used in Australia, a large commitment to technical design and logistics planning was given by Callide Coalfields Pty Ltd. This commitment included technical and operations management and supervision, mine services, and the retention of consultants to undertake geotechnical analysis, instrument preparation and instrument installation.

Jan 1, 1991

By Bukeikhanov D. G, Syedin V. F, Sagyngaliyev K. S

The present paper describes a method of simulating deposits of com- posite structure by means of computers. The method employs mathematical tech- niques to study the openworks zone formation dynamics in open-pit mines with any mode of the works front ad- vance as well as to determine, on oriented graphs,the optimal direction of openworks expansion.

Jan 1, 1977

By Laird CH

Large quantities of brown coal are excava ted from open cut mines in the Latrobe Valley to fire the base load thermal power stations of the Victorian Electricity System. Most of the coal is removed using bucketwheel excavators which have been modified or specially designed for the conditions encountered. The actual digging efficiency of the bucketwheel excavator is strongly influenced by such factors as wheel speed, slewing speed and tooth design and arrangement. The coal deposit, although not difficult to work, is not uniform and the operation of the machine is influenced by the stability re- quirements of the excavation face.

Jan 1, 1978

By Stuart M. S, Allen P. B

The Childe Harold deposit was mined by the Granny Smith Joint Venture (GSJV) from late-March through to early-December 1993. This was a fast-tracked mining project whose history began with an offer to purchase agreement being signed at the end of October 1992. A feasibility study was completed by the end of December 1992 after completion of a reverse circulation (RC) and diamond drilling program. Subsequent additional definition drilling culminated in a remodelling of the reserve by March 1993, by which time all necessary governmental and company approvals had been granted. The crucial aspect of mining Childe Harold quickly was to maintain oxide ore supply to the Granny Smith mill at the maximum possible rate for blending with existing fresh ore stocks. As a result, high production rates had to be balanced with

Jan 1, 1994

The Mount Isa mine in North West Queens- land produces a total of nearly 10 million t/yr from separate copper and silver lead zinc orebodies. Sampling information is mainly obtained from diamond drilling on 30 to 40 metre centers in both types of orebodies. For the copper orebodies the majority of the core is analysed for copper content using a non-destructive bulk analyser developed by the Australian Atomic Energy Commission. The diamond drill core in the silver lead zinc orebodies is usually sam- pled as sawn half core and assayed in the com- pany laboratory using a variety of methods dependent upon the level of metal content and/or the elements required. Underground development is sampled where additional information is required to improve the ore reserve estimate. The copper areas are sampled using a standard 2.0 m by 2.0 m chip sample of the wall. The chips are taken on a 250 mm spacing. Lead areas are sampled using a 100 mm wide by 4 mm deep channel over intervals determined by the area geologists. The massive, irregularly shaped copper ore bodies are mined as large sublevel open stopes and pillars. Ore reserve estimation on both a production unit and global scale is routinely carried out using a geostatistical system developed in-house and running on a Sperry 1100 mainframe computer. Copper grade, tonnes and the Kriging var- iance are estimated at points on a user defined grid. The Kriging program uses 10 m assay composites from diamond drill core and underground chip samples. One average (rela- tive) variogram is used throughout the main copper orebodies. The validity of using an average variogram was verified by the original geostatistical study undertaken in the late 1970's.

Jan 1, 1987

By G M. Tranell, M Tangstad

The CO2 footprints in the production of Mn-ferroalloys and silicon/ferrosilicon are correlated with the fossil carbon consumption. The CO2 emissions may be reduced in the Mn-ferroalloy process by increasing the degree of prereduction and reduction of carbonate materials, while the silicon/ferrosilicon process is optimised based on silicon yield. By changing the fossil reductant into biogenic reductants, the global warming potential will be decreased even more. Even if the reductants are biogenic reductants, there will still be a global warming potential (GWP) in eg the electrode consumption and the CH4 emissions in the charcoal production. To reduce the use of fossil reductants there are also more disruptive technologies like the use of H2 that at least for the silicon production is on a very low technology readiness level (TRL). Using metallothermic processes will reduce the use of carbon but requires carbon neutral metal reductants. Electrowinning can have low CO2 emissions, and the electrowinning of pure Mn is a technology of high TRL. Salt and oxide electrolysis is under investigation for both Mn and Si production however the research is still on a low TRL. The use of CCS/CCU (carbon capture storage/utilisation) is a part of obtaining carbon neutral processes. Last, the energy mix used for these energy demanding processes is discussed.

Aug 21, 2024

By Nairin J. D, Hayes P. C

Detailed studies of the microstructures and compositions of zinc and lead blast furnace sinters have been undertaken. An analysis of the results obtained has indicated that in many cases the microstructures of these complex materials can be explained by the solidification of melts from pseudo-ternary phase systems. Further laboratory studies have been carried out to more accurately determine the extent of primary phase fields and the liquidus temperatures in the appropriate binary and ternary systems. This approach shows considerable promise in simplifying the descriptions of slag systems used in oxidising and reduction smelting processes for lead and zinc recovery.

Jan 1, 1992

By K Verbeken, D Seveno, A Maslov, I Bellemans

Recycling and decarbonisation current metallurgical processes is key for our planet’s future and in both cases, digital twinning will play an important role. However, the various modelling techniques being used for digital twinning require a lot of input values on variables such as viscosities, diffusion coefficients and surface energies that need to be known as a function of temperature, atmosphere and composition, but which are not widely available, such as in databases, for molten slag phases. The need for more accurate data on physical slag properties is clear and will be extremely relevant for making more realistic and quantitative simulations. Some of these properties are difficult to determine, which is inherent to the very high pyrometallurgical temperatures. Therefore, this work focuses on some aspects related to determining electrical conductivities, viscosities and surface tensions of slags via a combined experimental-modelling method. Besides experimental work, molecular dynamics (MD) simulations can be used to investigate oxidic slag physical properties. With MD simulations, one can follow the time evolution of a system (consisting of atoms or molecules) by integrating Newton’s equation of motion. The input for an MD simulation mainly consists of a force field as well as initial positions, velocities and mass of each atom. The determination of the transport properties in existing literature of MD simulations in oxidic systems, is typically based on incorrect assumptions. For example, to determine the ionic conductivity, the frequently-used Einstein-Stokes equation fails to take into account all ionic types and neglects correlated motion. Furthermore, the viscosity determination via the Einstein-Stokes formula also assumes independent motion of the different ions. This paper gives a brief overview of the opportunities and challenges related to the use of MD simulations for oxidic slag systems.

Jun 19, 2024