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By M D. Melville, B C. T Macdonald, J Dixon

The acidic and metal rich waters that are generated from acid sulfate soil (ASS) drainage can have damaging impacts upon ecosystems. The most obvious impact has been the discolouration of water and occasional fish kills. ASSÆs produce these acidic and metal rich waters when pyrite in soil is oxidised. Land management techniques are an essential long-term requirement to minimise the amount of pyrite oxidation. Acidic water that cannot be prevented through land management can be neutralised by other techniques. Powdered lime is the most common material in agriculture that is applied directly to soils and waters. Powdered lime can be expensive and if applied dry it may aggregate. Since the aggregated particles of lime are larger they could sink rapidly in the water column and not react. In waters with high concentrations of dissolved iron and aluminium the lime particles may become coated with a metal oxy-hydroxide precipitate, which will decrease its reactivity. A unique lime-dispensing machine, the Waterways Lime Spreader, has been developed to neutralise acidic waterways. The Waterways Lime Spreader can produce a solution rich in fine lime from larger limestone fragments. The current size of the machine means only 3.5 grams per second of limestone can be emitted. This output will neutralise low acidity waters, however, for high acidity waters the time for neutralisation can be long. More reactive chemicals such as hydrated lime or increasing the size of the machine will reduce this neutralisation time. The Waterways Lime Spreader is also capable of producing slurry mixtures if powdered materials are required. Trials with the Waterways Lime Spreader were undertaken in part of the Clothiers Creek catchment located in northeast NSW, Australia. A small drain with a water volume of 4 m3 was neutralised with crushed limestone to pH 6.9 from an initial pH of 2.6 and an acidity of 902 mg/L CaCO3 in 160 minutes. In comparison a drain with a slightly larger volume of 6 m3 that had an initial pH of 3.2 and an acidity of 753 mg/L CaCO3 was neutralised with hydrated lime to pH 11.8 in five minutes. The Waterways Lime Spreader has been used successfully to neutralise water from acid sulfate soils. It is expected that future applications of the machine may be for the neutralisation of acid rock drainage or acidified lakes.

Jan 1, 2003

By Delahey G, Dunne R

At New Celebration Gold Mine the advent of treating primary sulphide ores resulted in decreased gold recoveries of four to ten per cent. The grind coarsened due to an increase in ore hardness and gold in the residue was found to be associated with pyrite. Finer grinding improved recoveries but was impractical as production rates would have decreased to unacceptable levels. An alternative approach that has proved to be viable combines both gravity separation, to recover the coarse gold bearing sulphides, and then regrinding the concentrate in a tower mill prior to releaching in the cyanide leach circuit. The tailings treatment plant was commissioned in December 1990 and details of the first 18 months' operations are Provided.

Jan 1, 1993

By Whiten WJ, Narayanan S

Data from ball mills of a wide range of sizes are analysed using detailed mathematical models and non-linear least squares fitting techniques. This analysis reveals that the relative power inefficiency of large ball mills is due to inefficient grinding of coarse (plus 4 mm) particles in these mills. A qualitative physical hypothesis is proposed to explain this behaviour. The results of the analysis can be used to scale up ball mill behaviour, using the mathematical models and techniques developed. A simpler ball mill scale-up procedure is also proposed, and its limitations stated. Laboratory experiments are being conducted to determine the average size distributions of single particles of different ores after breaKage. These experiments can distinguish between the different ores, and it is hoped to use their results to model and predict the grinding of different ores in ball Mills.

Jan 1, 1978

INDEX OF CONTENTSBlast Furnace SlagsForehearth AccretionsConverter SlagsConclusionsIllustrationsCOMPOSITION OF SOME COPPER SLAGS FROM PORT KEMBLASamples of copper slags from the Port Kembla Smelter of the Electrolytic Refining and Smelting Co. of Australia, Pty. Ltd., have been submitted for mineragraphic examination, with reference to the mode of occurrence of copper in them. The samples included (I) blast furnace slags, (H) a forehearth accretion, and (IH) converter slags. 1. BLAST FURNACE SLAGS Four series of samples of blast furnace slag have been submitted. The. chemical compositions of the several slags are shown in Table 1. Analyses Nos. 1 and 2 are of samples of slowly or normally cooled slag, taken from the slag dump, Analyses Nos. 3 and 4 are of samples comprising slowly or normally cooled slag, together with granulated slag from the same melt.

Jan 1, 1949

By Rankin W. J

Increasing concern with the emission of sulphur dioxide from smelters and roasters has caused renewed interest in processes which can use waste sulphur dioxide, such as the sulphation of nickel laterite ores. The process described here proposes to by-pass the production of sulphuric acid and react laterite directly with a sulphur dioxide containing atmosphere. A thermodynamic analysis identified operating windows in which nickel sulphate forms while iron oxide (the major impurity in most laterite ores) remains stable. The initial assumptions included unit activity of all species except nickel oxide. The lowest possible nickel oxide activity (while maintaining selectivity) increased with increasing temperature, indicating that selective sulphation is favoured by low temperatures. The temperature of interest was found to be between 500 and 800¦C. Calculations show that a feed gas containing ten per cent SO2, five per cent 02, balance N2 requires a temperature greater than 650¦C for selective sulphation of nickel. Laboratory experiments showed that the assumption of unit activity of ferric sulphate was unrealistic above about 680¦C due most likely to the formation of solid solutions which decreased the ferric sulphate activity. Results are presented which illustrate the limiting equilibrium sulphur trioxide partial pressures at 700 and 730¦C below which selective sulphation occurs. Cobalt extraction was usually between 80 and 95 per cent under conditions yielding selective sulphation, whilst nickel extraction was about 50 to 75 per cent depending on temperature and choice of upper limit of iron extraction. An operating diagram is presented for a limonite ore and shows that the optimum reaction conditions are 680¦C and an input gas containing 20 per cent SO2. Under these conditions nickel, cobalt and iron extractions are 73, 95 and two per cent respectively.

Jan 1, 1996

By Marshall B, Gee R. D

Geological data processing by machine enables'an increased rate of coverage, better supervision and control of field programmes, increased effectiveness of field operators, and vastly improved access to old and new field data. Even a system of restricted felxibility enables a mapping programme to be organ- ized and conducted independent of personnel changes, whilst elimination of much compilation time increases the rate of cover- age such that it relates to mode of transport and geological complexity rather than to personality factors. A machine is useful only if applied to tasks suited to its capabilities, and must be aimed at those types of mapping in which a limited number of attributes adequately define the problem, and the data is of a form suited to coding and is normally collected in sufficient abundance to make compilation wearisome. Machine systems are therefore unsuited to most types of lithological mapping and to most types of exploration in new areas, but have proved useful in many branched of cartographic geophysics (e.g. gravity and magnetics), and in cartographic Geochemistry.

Jan 1, 1969

By Thirumalai K, Peluso R. G

The United States has more than 45 billion tons of economic coal reserves in seams above 10 feet thick and current underground production from thick seams represent less than three per cent of the total production. A tripling of underground production from thick seams is necessary within the next 10 years to meet U.S. coal production demands. An analysis of underground accident and production data is presented in the paper. A study of accident and injury distribution in different coal seam heights in the eastern and western part of the United States in seams ranging in thicknesses from 5 to 15 feet indicates that the seam thicknesses do not produce adverse impact on underground injury incidence. Accidents associated with roof falls and haulage account for about 70 per cent of underground mining injuries.

Jan 1, 1976

Black coals occur in most of the major sedimentary basins in Australia. In addition to the better known Permian coal occurrences of the Sydney, Bowen, Oaklands and Galilee Basins, coals of Permian age occur in the Arckaringa Basin in South Australia, the Bonaparte Basin in Northern Territory and the Collie, Perth and Canning Basins in Western Australia and the Tasmania Basin in Tasmania. Coals of Triassic age occur in the Ipswich Callide and Tarong Basins in Queensland, the Tasmania Basin in Tasmania and the Leigh Creek area in South Aus- tralia. Coal bearing rocks of Jurassic age occur in the Mulgildie Basin and Maryborough Basins in Queensland and in both the Queensland and New South Wales portions of the Clarence Moreton Basin and Surat Basins. They also occur in the Perth Basin in Western Australia. Rocks of Cretaceous age known to contain coal occur in the Styx, Maryborough and Laura Basins in Queensland, the Gippsland Basin in Victoria and both the Queensland and New South Wales portions of the Surat Basin. The coal measures have been deposited in a variety of sedimentary environments and the coals vary widely with regard to thickness, extent, banding characteristics, maceral and ash content. However, they are generally of low rank and most are suitable only for steaming.

Jan 1, 1975

The need to schedule ore production to make maximum use of the strength gained by cem- ented fill during curing is discussed, to show how cement content and hence fill cost can be kept down for any particular operation. Results from laboratory testwork on Isa Mine fill conducted by the author while employed by Mount Isa Mines Limited form the basis of the Discussion

Jan 1, 1973

By Porter I, Singh RN

An advanced elasto-plastic finite element model adopting a modified Von Mises yielding criterion was used to simulate progressive failure of the rock strata surrounding a room and pillar mine structure. The model conformed to the strain-softening behaviour of rock and accounted for post-failure residual strength. The simulation was achieved in such a way that material values were updated after each FE run, according to the stress criterion until the solution reached the final equilibrium steady state of the mine structure. The suggested structural stability analysis approach accounted for the main features of the structure degradations produced during loading through changes in rock material stiffness and subsequent evolution of stresses. Comprehensive parametric analysis was performed and the inevitable effect of interaction of the roof, pillar and floor on the overall mine stability limit was investigated. The numerical results clearly showed that linear models could not realistically represent the true behaviour of the mine structure. The results obtained are in good agreement with that predicted in the field.

Jan 1, 1992

Cyanide-extractable gold is far more meaningful in the definition of ore, and control of extraction, than fire- assayable or aqua regia digestible gold. The use of cyanide- extractable gold addresses the significant problems of over- as well as under-assaying by fire and aqua regia digests. The problems of conventional control or diagnostic cyanidation extractions: lengthy extraction, and masking by pregrobbing in cyanidation extractions for assay purposes; are surmounted with a novel activator - Leach WELL. Full extraction of liberated gold, insignificantly affected by preg-robbers, can now be achieved within 30 minutes. This can assist in reducing common gold losses presently often hidden by inappropriate mine call factors, and/or high grade cut values. This paper includes a discussion of fundamental mechanisms of cyanidation, preg- and assay-robbing, which underlie the phenomena Involved.

Jan 1, 1992

By McKenzie C. K, Stewart R. S, Simpson J

Blast control in small scale underground mining leads to improved fragmentation control, improved control over overbreak and dilution, and the optimisation of drilling and charging operations. Greatly improved control can be achieved through blast monitoring, to confirm proper implementation of blast designs and blasthole charging. Further improvements can be achieved through simple modelling, enabling blastholes to be placed in the correct locations and charged with the correct weight and strength of explosive. Improved design can be shown to significantly reduce overbreak and dilution, and even ground support costs. In one mine in Quebec, open stopes of widths varying from 2.5 metres to four metres and dipping at 36¦ to 38¦ were designed to achieve zero dilution using open sloping blasting practices. The first stope designed in this manner was monitored in detail and achieved its objective.A method for contouring damage around blastholes is presented as a basis for selection of drilling patterns, with particular application to the control of overbreak and dilution. Contouring can be used to provide reliable estimates of either overbreak or damage (where rock is broken het reynainc in nlarr)

Jan 1, 1993

Sublevel open stoping (S.L.O.S.) was introduced at Rosebery in 1972 in the wider ore blocks below 14 level, largely replacing cut and fill methods which had been in use up till that time. During 1973/74 the method produced 10% of primary stoping tonnes, and by 1981/82 it increased to 65%. Because of the increasing reliance placed on sublevel open stoping for primary stoping production, every effort was made in both planning and operating to: - maximise ore recovery and reduce dilution - increase productivity - reduce costs.

Jan 1, 1982

By S-C Shim, H-R Lee, Y Kang, H Shin

Since iron oxide and silicon oxide are major gangue components in various types of ore, FeO-SiO2 base slag, ie fayalite slag, has been often encountered in pyrometallurgical processes of non-ferrous metals. During most matte production processes such as the smelting of Cu, Pb, and Ni, the FeOSiO2 based slag is inevitably formed and plays an important role in refining crude metal as well as engineering aspects. Recently, similar pyrometallurgical approaches have been attempted in the recovery of valuable metals (Ni, Co, Cr) from wasted secondary batteries. Thus, the viscosity of the FeO-SiO2 based slag has great significance in properly controlling smelting processes. However, when molten metal or matte does not coexist with the slag during the measurement, there has been a serious difficulty in maintaining Fe valance and consequently, the slag composition. In the present research, the viscosity of molten FeO-SiO2 slag was measured in 1573~1673 K using a rotational viscometer. In order to keep the state of iron oxides, the oxygen partial pressure was controlled using CO/CO2 gas mixture. The optimised ratio of CO/CO2 could be calculated using Fe/Fe2+ and Fe2+/Fe3+ equilibria at each temperature. The composition of the slag, particularly Fe valance, after the measurement was analysed with the aid of an inductively coupled plasma – optical emission spectroscopy (ICP-OES) and an automatic potentiometric titrator. The measurement showed that the FeO-SiO2 slag has considerably low viscosity values in the molten state, and it sharply increases as the temperature decreases. In spite of the careful oxygen partial pressure control, a part of Fe2+ was found to be oxidised to Fe3+, with a maximal case reaching about 20 per cent. The increase in viscosity of FeO-SiO2 at low temperatures can be attributed to the composition change due to an unavoidable Fe2+ oxidation. In addition, the relationship between the change in the viscosity and the liquidus temperature of FeO-SiO2 based slag was discussed to understand the composition dependence of viscosity.

Jun 19, 2024

An exploration and preliminary mine design contract was undertaken in Thailand to establish whether adequate lignite resources existed for the addition of future power generation plant through to the year 2000. The lignite ranges in heat value from 14 to 24 MJ/Kg (air dry basis) and occurs in 2 major seams consistituting measured reserves of 536 Mt (with an ash cut-off level of 45 % on an air dry basis) and a strip ratio of 4.1 bank cm/t. The paper describes the pre-planning, programming, equipment used, project management, logistics and exploration methods adopted to undertake the contract in a monsoonal area using Australian drilling and geophysical contractors.

Jan 1, 1983

By J E. Powalisz

Obtaining a representative sample of bulk materials in process industries is critical to providing valid data for process control and custody transfer (valuation). The accuracy of a sample, that is to say how well the sample represents the material in the process, is directly related to how well the process can be controlled and to how much a product may be worth. Sampling accuracy then is in fact related to bottom line profitability.Sampling theory offers information and equations on how to take a representative sample from a process, however, the actual practice of extracting a sample from the process can be more of an art.Key sampling variables include product specifications such as bulk density, particle distribution, material conveyance, practical sampler location, sampler type and sample frequency and volume/mass.This paper discusses basic sampling theory, sampling methods, types of samplers, how to develop a ‘real world’ sampling system and current manual and automated samplers.Key points include ‘practical precision and variance’, material properties, flow properties, direct sampling versus indirect sampling, sampler types and applications.CITATION:Powalisz, J E, 2014. Bulk solids sampling, in Proceedings Sampling 2014 , pp 179–188 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

The purpose of this study was to investigate the effectiveness of froth fl otation for the recovery of gold from the gravity tailing stream of the former Lihir Gold Limited (LGL) operation in Ballarat. The P80 of the tailings was determined by screen analysis as 1 mm, with test work conducted on as received material along with samples ground to P80 sizes of 47, 78 and 134 microns. Laboratory scale batch flotation tests were conducted at both natural and elevated pH to investigate the impact of pyrite depression on gold recovery. Results indicated that although an increase in grade from approximately 0.7 g/t to 3 g/t was achievable at a natural pH and a P80 of 134 micron, gold recovery was low at just 35 per cent. Finer grind sizes were found to have an adverse effect on both grade and recovery. Future efforts will be focused on the sub 310 micron size fraction of the tailings, which was revealed to contain approximately 85 per cent of the available gold and may be amenable to cyanidation or ultra-fine gravity treatment.

Aug 1, 2010

By J Ledgerwood

Namakwa Sands is a mineral processing company based on the West Coast of South Africa and is solely owned by Exxaro Resources Limited. Mineral ore is mined and processed, concentrated and both chemical and mechanically upgraded before being sent for electrostatic and magnetic separation units. The final high value mineral products report as Zircon, Rutile and Ilmenite.The recovery of non-magnetic material is largely dependent upon a number of factors, including but not limited to dew point, ambient temperature, feed rate, mineral size distribution, specific gravity and mineral content in head feed. One important limiting factor to recovery in typical dry mill operations is the particle size distribution of the feed. Variance in the particle size has catastrophic consequences for recovery. This is the reason for this study. Until recently large variances in non-magnetic production were viewed to be a function of machine operation. This view was later rejected with the feed size distribution determined as the major driver of low recoveries, for Namakwa Sands orebody 50 per cent variance in particle size distribution can be noticed within one day. This is because of the successive mining blending techniques employed.The predicament is that the two modes were so closely placed together that recovery of a single mode is almost impossible without the consequence of greatly reducing recovery. The second mode was found at 125 µm while the first was at 90 µm. Interestingly, for the mentioned feed type a cumulative size distribution of a unimodal feed type is almost exactly the same as for a bimodal size distribution. Thus a plot of cumulative size distribution will show no difference due to the modes being so close together. This is the reason why this phenomenon was not noticed before.The study also found that, using an high tension roll (HTR) or rare earth roll, a fine stream with a single mode at 90 µm versus a coarse stream with a single mode at 150 µm would yield completely different results interms of yields. Larger conductive particles are thrown from the roll while small particles loose charge faster (entrainment). Results in terms of the bimodal size distribution show that even though 25 per cent of the feed type is greater than 150 µm the yields followed a similar pattern to that of the coarse particles rather than that of the majority (75 per cent) fine particles. This confirms what was published by M Ziemski and P N Holtham in 2005 on charge decay rates; they mentioned that particle bed effects played a major role in recovery.

Oct 5, 2011

Most types of nuclear power reactors use uranium dioxide fuel. Power reactors using natural uranium dioxide'fuel are of special interest to countries such as Australia that have their own uranium supplies. A wide range of uranium dioxide powders can be fabricated and the ideal one flows readily, presses without the need for binders or lubricants, sinters to the required density and gives low reject rates at all fabrication stages. Sinterable uranium dioxide is usually produced via the ammonium diuranate route. The A.A.E.C. is aiming to demonstrate production of nuclear grade uranium dioxide from Australian concentrates, improving technology where possible. Details are given of the dissolution, solvent extraction, precipitation, filtration, drying, and calcination-reduction steps. Solvent extraction from sulphate media is also under study with a view to developing a process to produce a nuclear grade product at the mine treatment plant site,

Jan 1, 1969

There are many compelling reasons why correct sampling schemes should be standard practice in the mining industry, yet there are numerous examples where poor sampling practices are known to exist in the business yet permitted to continue. It is not just technical issues that can be ascribed to the reasons for the continued use of incorrect methods. This paper proposes non-technical reasons why incorrect sampling practices continue, and identifies potential ways to overcome them.

Mar 1, 2010