Search Documents

By Maria Margarida Lima, Maria Lucelinda Cunha, Dora Algarvio

"The main goal of the present work is the quality improvement of the recycled aggregates produced by a construction and demolition waste (C&DW) recycling facility located in Montemor-o-Novo, Portugal. The recycling process was developed on a pilot plant scale with 50 t/h of capacity. Process operations are the hammer mill comminution, magnetic separation and screening.In order to improve the knowledge on the C&DW, a characterization procedure was implemented by hand-sorting, magnetic and density separation on representative samples. On the other hand, to improve the quality of the produced aggregates, the bar screen size fractions were analysed, according to the Portuguese Standard (NP EN 933-1 2000).Wood was identified as the critical contaminant, representing 17% by weight of the total contaminants. Sieving results showed that about 97%, 76%, 56%, 98% and 57% were on the correct size range, which lower results are probably due to the type of screens and/or the material characteristics of the recycled aggregates.IntroductionThe construction and demolition waste problemConstruction and demolition waste (C&DW) is generated by the construction activity, resulting from both, buildings or other structures construction and old structures demolition. As a reference, it can be told that C&DW comprises about 40 to 50% of rubbish (concrete, asphalt, bricks, blocks and dirt), 20 to 30% of wood and related products and 20 to 30% of miscellaneous wastes [1]. In Portugal, C&DW is classified in the LER (Portuguese nick name for the European Waste List), Chapter 17, and includes a diversity of wastes, like concrete, bricks, ceramics, bricks, wood, glass, plaster, copper, zinc, lead, iron, steel, as well as insulation and roofing materials. C&DW stream has several characteristics which make it particularly difficult to deal with and are summarized in the following five items.(1) Lack of information on quantities generated: In Portugal, the C&DW sector has been neglected over the past years, which meant that there are not consistent information concerning the quantities and composition of these wastes yet. Several estimates, based in different assumptions, indicate different results, which may vary from 219 Mt to 10 931 Mt [2]."

Jan 1, 2008

By Kenji Monden

"In order to obtain basic data for the development of highly thermally conductive composite materials, the thermal conductivity of a resin composite material with an Aluminum Nitride filler was assessed. Several different measurement techniques such as the xenon flash and the temperature wave thermometric analysis method were employed to gather data on these composites. An excellent match between theoretical and experimental data was achieved by employing a predictive expression that takes into account the effect of percolation on thermal conductivity.IntroductionA thermal solution composite is made by incorporating dense inorganic fillers with high thermal conductivity into a resin. Because the composite materials have high thermal conductivities, they have been used in electrical products that generate excessive thermal energy during operation, such as inverters, amplifiers and motor drivers. They function as electrically insulating and thermally conducting parts of the electric modules. As the uses of thermal solutions are expanded, composites of higher thermal conductivities will be required. The aim of this work was to investigate, evaluate, and try to predict the influence of key parameters on thermal conductivity and diffusivity. This was achieved by analyzing the effect of both volume fraction and shape of Aluminum Nitride ceramic fillers and measuring the thermal conductivity. In addition, the influence of percolation on thermal conductivity is considered. The thermal conductivity of the composites is discussed by employing a predictive equation using literature data of thermal conductivities for both the filler and resin. As well as thermal conductivity measurements the effect of volume fraction of the filler was also explored.ExperimentalSpecimen PreparationThe composite samples were prepared from silicone resin and Aluminum Nitride (AlN) fillers. The AlN fillers with an average particle size of 20 µm are shown in Figure 1. The mean diameters of the AlN particles used are given in Table I. For comparison the AlN fillers with an average particle size of 5 µm are shown in Figure 2. A planetary centrifugal mixer was used for simultaneously dispersing the components uniformly and de-aerating the mixture. After mixing, these materials were placed in a silicone rubber case and cured at 150 °C for 1 hour."

Jan 1, 2013

By M. Fafard, R. Ahmed, O. Dion-Martin

"The optimization of aluminum sheet and tube forming needs the use of large strain finite elements software. The precision of the predicted results from those simulations depends mainly on the quality of constitutive law of the material used. In order to improve quality of these simulations, Barlat has suggested a new yield function named YLD2000-2d. This criterion describes the anisotropic behavior of the rolled aluminum plates. This work consists of characterizing the AA5754 alloy and estimating the material parameters needed for the YLD2000-2d criterion in LS-DYNA. In order to get these parameters, various mechanical testing were performed such as bulge and tensile tests. Moreover, the bulge test was also used to obtain an estimation of work hardening curve in large strain condition, up to 50%. The objective of this paper is to share the experimental results of the characterization of AA5754 aluminum alloy.IntroductionResearchers from National Research Council Canada's Aluminium Technology Center (NRCATC) and Aluminium Research Centre - REGAL, are working on aluminium tube hydroforming processes of AA-5754-0 alloy, used in automotive industries. Hydroforming process presents several difficulties such as wall thinning and section changes. In order to control them, some parameters can be set during the process like pressure rate and end feed level [1]. Given the complexity of the parts and the variability of the control parameters, the use of finite element method (FEA), like LS-DYNA, based on large strain theory is thus necessary. The accuracy of predicted results depends mainly on the quality of the constitutive law used to model the behavior of material. FEA results seem to be valid with the von Mises yield criterion used in some cases. But, given the anisotropic properties of the AA-5754 alloy, a more appropriate criterion could be used. The *MAT_ BARLAT YLD2000 shell material criterion, developed by Barlat [2], who's taking into account the anisotropic behaviour, was chosen due to its large flexibility and its good adaptation to particular elastoplastic behavior of aluminum. However, the use of this criterion needs to determine some material parameters by experimental way."

Jan 1, 2013

By Jean Igor Margem, Lucas Barbosa de Souza Martins, Frederico Muylaert Margem, Noan Tonini SImonassi, Sérgio Neves Monteiro, Rômulo Leite Loiola

"Fibers of giant bamboo (Dendrocalmus Giganteus) are amongst the strongest lignocellulosic fibers. Although studies have been already performed, limited information exists on the mechanical properties of polymeric composites reinforced with continuous and aligned giant bamboo fibers. This work evaluates the tensile strength of this type of composite. Standard tensile specimens were fabricated with up to 30% of fibers aligned along the specimen's length. The fibers were press molded with a commercial epoxy resin mixed with a hardener and cured for 24 hours at room temperature. The specimens were tested in an Instron machine and the fracture surface analyzed by scanning electron microscopy. The tensile strength increased significantly with the amount of giant bamboo fiber reinforcing the composite. This performance can be associated with the difficult of rupture imposed by the fibers as well as with the type of cracks resulting from the bamboo fiber/epoxy matrix interaction, which prevents rupture to occur.IntroductionDue to growing concern about the ambient impacts from industrial activities, our society is ever more using environmentally friendly materials. In this regard, cellulose-based natural fibers, known as lignocellulosic fibers, become a promising solution. Nowadays, they are being considered as a substitute for synthetic fibers, such as glass fiber, used by the industry on a large scale [1-5]. The application of these natural fibers is also motivated by many advantages like good toughness and less wear of equipment used in the processing of composites. In addition, such composites are environmentally friendly because they are renewable, biodegradable and neutral with respect to C02 emissions, the main responsible for global warming and climate changes. [3,5,6].Lignocellulosic fibers also have some disadvantages in relation to synthetic fibers such as the difficulty of coupling with polymer matrices, due to the hydrophilic character of fiber and the hydrophobic nature of the matrix, as well as dimensional heterogeneity [ 4,5]. This last one is characteristic of the nature of this material and constitutes an obstacle to the use of these fibers in certain projects, especially those that aim high performance. The above mentioned disadvantages are worrisome reasons for the occurrence of reduction in the strengthening capacity, as indicated by the rule of mixtures for composites [7]."

Jan 1, 2013

By Djalma Souza, Rubén Sánchez, Regina Maria Pinheiro, Carlos Maurício Fontes Vieira, Sergio Neves Monteiro

"This work has for objectives to characterize a waste generated in the form of sludge during the treatment of the effluent of a paper making industry and to evaluate the effect of its incorporation up to 10 wt.% on the properties of a clayey body used for brick production. For the characterization of the waste the following techniques were used: X-ray diffraction, X-ray fluorescence, differential thermal analysis and termogravimetric analysis with mass spectrometry. Specimens were prepared by uniaxial pressing at 20 MPa before firing at 750 °C. The physical and mechanical properties evaluated were: linear shrinkage, water absorption and flexural rupture strength. The results showed that, in agreement with the characteristics of the waste, its recycling into red ceramic can contribute to decrease the consumption of fuel during the firing stage. However, the waste changes the physical and mechanical properties, generating a deleterious effect on the water absorption and flexural rupture strength of the ceramic.IntroductionAccording to the Brazilian Association of Pulp and Paper, in the last 10 years, the global production of paper grew 35%. Brazil produced 8,2 million tons of paper in 2004 and held the position of the seventh largest world manufacturer of pulp, with about 9,4 million tons per year [1]. The pulp and paper industry generates effluents that present problems related to their disposal, even after the treatment. Among the solid wastes generated by this industry, the main waste is the primary sludge from the effluent treatment plant (ETP).After the initial treatment the decanted solids go through a dewatering stage, generating the solid form denominated primary sludge. This sludge resembles a paper paste of dark gray color when humid, and clear gray color when dry. This primary waste is composed basically of kaolin, pulp, traces of chemical substances and water. This waste generated in the pulp and paper industry depends on the characteristics of the process and of the employed techniques. It can vary significantly from one industrial unit to another, even in the case that the final products are similar. Its composition is approximately 60% of kaolin and 40% of pulp, and these percentages can vary in some moments as a function of the process [2,3]."

Jan 1, 2008

By llya Perederiy, Vladimiros G. Papangelakis, Indje Mihaylov

"Nickel slags obtained from various smelting furnaces and converters differ in terms of their chemical composition and microstructure. The microstructure of the slag is largely affected by how fast the slag is cooled after being discharged from the furnace. Slow cooling is known to promote crystallization and growth of phases such as crystalline fayalite (Fe2Si04), magnetite (Fe3Ü4) and vitreous silica (S1O2). Slag granulation causes rapid solidification of the melt in the form of either an amorphous solid or highly intergrown crystalline silicate and oxide phases. Smelter slags contain entrapped Ni, Co and Cu in the form of dissolved oxides and matte inclusions. Extraction of the entrapped metals by high pressure oxidative acid leaching (250°C, 70 g/L initial H2SO4, up to 90 psi O2, 45 min) relies on the dissolution of the metal bearing minerals. The impact of the slag microstructure on the accessibility of these minerals to leaching, as well as the morphology of the produced residues is discussed in this paper.IntroductionIt was shown previously that entrapped base metals can be efficiently extracted from naturally cooled (as opposed to granulated) crystalline nickel smelter and converter slags using high pressure oxidative acid leaching operating at 250°C, ~40 g/L terminal acid and 60 to 90 psig oxygen overpressure [1, 2,3,4, 5, 6].Mineral characterization work performed on a naturally cooled crystalline nickel furnace slag from Vale's operations in Sudbury (ON, Canada) was previously reported [4]. Fayalite (Fe2Si04) and magnetite (Fe3U4) were detected using powder X-ray diffraction. These two minerals as well as silica (S1O2) and matte ([Fe,Ni,Cu]Sx) were also identified with the help of energy dispersive X-ray spectroscopy (EDX) on cross-sectional images obtained with a scanning electron microscope (SEM) operating in the backscattered mode. Nickel converter slags obtained from Vale's operations in Sudbury were found to be mineralogically similar to the furnace slag, but with higher contents of matte entrainment and magnetite based on the SEM-EDX observations [6]."

Jan 1, 2012

By Dmitri Goljandin, Jaan Kers, Xiangjun Zuo, Lifeng Zhang, Priidu Peetsalu

"In this paper, the mechanical milling of the electronic wastes was carried out. The metal parts and plastic parts were roughly separated. The final plastic powder size could be as small as ~100 µm. Then the pyrometallurgical recycling Printed Circuit Boards (PCB) was executed. The mechanisms of thermal degradation and combustion are investigated using TG/DTA and MS. Some chemical powders, such as Na2CO3, NaHCO3, NaOH and CaCO3 are used to control the exhausted toxic gas such as Br2. Introduction Waste electric and electronic equipment (WEEE), or electronic wastes (E-wastes), has been taken into consideration not only by the government but also by the public due to their hazardous material components [1-3]. From the point of material composition, electronic wastes can be defined as a mixture of various metals, particularly copper, aluminum, and steel, attached to, covered with, or mixed with various types of plastics and ceramics [4]. Precious metals have a wide application in the manufacture of electronic appliances, serving as contact materials due to their high chemical stability and their good conducting properties. Platinum group metals are used among other things in switching contacts (relays, switches) or as sensors to ascertain the electrical measurand as a function of the temperature [5]. Table 1 [6] gives examples of the metal composition of different electronic scraps from literatures. Additionally, non-ferrous metals and precious metals content have gradually decreased in concentration in scraps. The value distributions for different electronic scrap samples are shown in Table 2 [6], where the metal price data are from London Metal Exchange (LME) (Octoebr 2007). It can be seen that for cell phones, calculators, and printed circuit board scraps, the precious metals make up more than 70% of the value, for TV boards and the DVD player they still contribute to about 40%. This indicates that the major economic driver for recycling of electronic waste in industry is from the recovery of precious metals. Behind the precious metals come copper and zinc, while Al, Pb, and Fe are less value. Recycling of electronic waste is an important subject not only from the point of waste treatment but also from the recovery aspect of valuable materials."

Jan 1, 2008

By Zhangm Mingming

Three samples received from the EAF shop were characterized by chemical, X-ray diffraction (XRD), optical microscopy (OM) and scanning electron microscopy (SEM) methods. The objective of this characterization work was to investigate the occurrence of nickel, copper, zinc, sulfur and phosphorus and to identify their origin and associations with iron minerals in the concentrate samples from the mines. The samples were identified as MINERAL, PELLET, and HRD. The latter is the DRI product. All three samples were received as fine powders. The results indicate that, in the mineral sample, magnetite is the major iron oxide mineral with hematite as a second phase based on the OM and XRD studies. Pyrite [FeS2], chalcopyrite [CuFeS2] and bravoite [(Fe,Ni)S2] are the major sulfide minerals. Trace amounts of apatite [Ca5(PO4)3(F,Cl,OH)], wardite [Na4CaAli2(PO4)8(OH)8 6H2O], giniite [Fe;(PO4)4(OH)3 2H2O] and vivianite [Fe3(PO4)2 8H2O] were identified by SEM and XRD. Microscopic studies also indicated that most of the sulfide grains in the mineral sample are present either as liberated fine particles (about 10 microns) or as inclusions within the magnetite and hematite grains. XRD studies revealed magnetite as the major mineral with subordinate amounts of hematite and pyrite confirming the microscopic findings. Copper, nickel, and zinc are mainly present as chalcopyrite, bravoite, and franklinite [(Zn,Mn,Fe)(Fe,Mn)2O4] in trace amounts in the mineral samples, respectively. Impurities carry over to the pellet and HRD samples. Chemical analyses of the three iron-bearing samples indicate that sulfur and phosphorus in the pellet sample exceeded the specification. Since liberated pyrite and chalcopyrite particles were observed in both the mineral and pellet samples, magnetic and flotation processing routes should be effective for sulfide removal but at the cost of iron losses. The high phosphorus content of all three samples indicates that there are phosphates which are difficult to remove by the current concentrating processes (magnetic separation and flotation).

Jan 1, 2012

By Ali Kucuk, Bekir Karasu, Keriman Karaveli Pekkan

"Zircon (zirconium silicate) is the main opacifier of glossy, opaque, white colored, frit-based wall tile glazes. However, zirconia containing frits employed in the preparation of these glazes increase the production cost and therefore, limit zircon usage as a raw material at industrial scale. With the present study, it was searched whether borax solid wastes could be evaluated as a component in the starting relevant frit recipes. The wastes were obtained from Eti Maden Kirka Boron Company of Turkiye. Frit production, glaze preparation, application, and fast single-firing of glazed wall tiles were conducted under laboratory working conditions in Anadolu University, Department of Materials Science and Engineering laboratories. Beside standard tests applied to the final glazed wall tiles, color and gloss analyses of the fired glazes were conducted with a spectrophoto-meter and a gloss-meter. Characterization of these newly produced glass-ceramic glazes was made by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) techniques. IntroductionFrits are the indispensable constituents of most industrial glazes which mature at temperatures below 1150 °C [1]. In the traditional opaque glazes used in wall tile industry, opacity usually originates through hardening of glass matrix by adding high amounts of zirconia containing frits into the glaze batch [2]. Nowadays, researches point out that certain type of glass-ceramic layers can be alternatively employed as tile coatings lowering the use of zirconia containing expensive opaque frits. A rather high crystallization capacity of glass- ceramic glazes due to zirconia presence in glass network makes them suitable candidate as a glaze coating with a desirable micro-structure. One of the best methods to obtain an opaque glaze surface is to induce a crystal phase in the coating, whose refractive index differs significantly from that of the glassy matrix. The opacity of such coating is determined by the diffusion, refraction and reflection of light through the layer containing emerging crystals, and the degree of opacity mainly depends on the size and quantity of crystals. The development of glazes not consisting of expensive or toxic components is of special interest [3]."

Jan 1, 2008

By P. Chris Pistorius

"Use of coke in blast furnace ironmaking is the main origin of carbon dioxide emissions from integrated steelmaking. Use of pre-reduced iron feedstocks would reduce the coke rate and, if pre-reduction were carried out with natural gas, would decrease the overall carbon intensity of ironmaking. Blast furnace productivity would also increase, because the blast volume per unit of hot metal would decrease. This paper shows that these trends can be predicted quantitatively, by using a conceptually simple Rist-style blast furnace mass and energy balance, assuming furnace productivity to be limited by the tuyere gas flow rate. Such predictions would assist in optimizing the choice of the degree of reduction and relative amount of pre-reduced blast furnace feed.IntroductionSteelmaking is responsible for some 5% of world CO2 emissions, at a rate of approximately 1.9 tonnes of CO2 per tonne of cast steel [1]. In integrated steelmaking, the ultimate source of most of the CO2 emissions is coke, the indispensible (and expensive) fuel and reductant for blast furnaces. There are several research programs underway worldwide which seek to lower the carbon intensity of ironmaking; one of the largest is the European ULCOS program [2], in which the main proposed change to blast furnace ironmaking is to scrub CO2 from the furnace off-gas (for possible sequestration), recycling the remaining gas to the furnace. To limit the recycling nitrogen load, oxygen rather than air is used to combust coke.A conceptually simpler approach is to charge prereduced feed (direct-reduced iron) to the blast furnace. This approach has been used for some two decades at the AK Steel Middletown plant, where some 200 kg of direct-reduced iron (DRI) is charged per tonne of hot metal [3]. The Middletown blast furnace has exceptionally high productivity (rate of iron production relative to the furnace hearth area), simply because less coke is required per ton of hot metal if part of the feed is already metallic. Midrex [4] has provided some quantitative predictions of the implications of DRI use in the blast furnace, stating that for every 10% of Fe in the feedstock that is in metallic form, the fuel requirement decreases by 7% and the productivity increases by 8%."

Jan 1, 2012

By Ross McClelland

This paper provides a technical overview on the installation and commissioning of the Ausmelt lead smelting, slag reduction and slag cleaning operations at the HZL Chanderiya site in India. It also discusses theoretical concepts behind the process practices currently in place at HZL.

Jan 1, 2006

By Sergey Komarov, Manuela Diaz, Sano. Masamichi

"Mixing time, bubble behavior and absorption rate of gas injected into a liquid bath through rotary L-shaped lances have been studied by cold models with an effort to improve refining characteristics of metallurgical processes. Two kinds of the rotary lances were tested, namely the single-hole lance and the multi-hole lance. The effects of gas flow rate, bath depth and rotation speed were examined.It is found that when gas is injected through the rotary lances, the mixing intensity and the gas absorption rate are larger than that for the gas injection through stationary lances. The effect of rotation speed decreases as the bath depth and the gas flow rate increase.The multi-hole lance produces much smaller bubbles, which lead to an increase in the volumetric mass transfer coefficient by 3-4 times as compared with the single-hole lance. However, the effect of rotation speed is smaller for the multi-hole lance. The obtained results are explained in terms of the bubble coalescence and fragmentation, the rate of which depends on the departure bubble size and the power supplied to the liquid bath.IntroductionIn recent years, there has been a growing interest in the development of gas injector for metallurgical processes. The majority of the previous work was focused on modification to the injector design to improve mixing and to increase the of chemical reaction rate. These two goals can not be necessarily achieved by the same way. Bottom nozzles and stationary immersed top lances, which have been widely applied to steelmaking processes, are effective for the bath mixing, but have a limit to decrease in the bubble size. This results from a vigorous coalescence occurring between the bubbles when they rise in the molten bath as a bubble swarm.One of the ways to ensure the small bubble size and the effective bath stirring is the gas purging through rotary injectors. A number of studies have been undertaken to improve the refining characteristics by using rotary injectors. All of them are related to aluminum refining. The SNIF equipment (The Spinning Nozzle Inert Flotation) has significantly improved the quality of aluminum products at National Luxemburg Aluminum [1]. Rotary injectors made in the form of a disc have been applied to the Alcoa 622 [2] and the GBF processes [3]. A study of the gas injection by a rotary impeller has been carried out by C. Leroy and G. Pignacelt [4]. All researchers note the significant improvement in removal of sodium, calcium, hydrogen and non-metallic inclusion."

Jan 1, 1996

By Yinlun Huang, Cristina Piluso

"Industrial sustainability looks to improve material and energy efficiencies, product quality and variety, and productivity within an industrial zone, thus pursuing the long-term sustainable development of the region. This paper introduces a systems-based modeling methodology, which provides industrial leaders with the ability to evaluate future production options to determine the path with the highest positive impact on both their own sustainability and the sustainability of the overall industrial zone. A comprehensive study on sustainable development of an auto-manufacturing focused industrial zone under uncertainty is illustrated. Introduction Sustainable development refers to a continuous process of improvements that must be followed in order to achieve a state of sustainability. In its most general form, a widely accepted definition of sustainable development was identified in the Brundtland Report as “development that meets the needs of the present without compromising the ability of future generations to meet their own needs” [1]. Sustainability will occur when the material and social conditions can be maintained or improved for human health and the environment over time without exceeding the ecological capabilities that support them [2]. An industrial zone is defined as a geographic area comprised of a network of industrial sectors, each composed of a number of entities. Such a zone is highly integrated and complex, and contains numerous uncertainties due to each industry’s extreme dependencies on its suppliers and customers throughout the product supply chain. In the context of an industrial zone, sustainable development refers to the continuous process of advancements in the zone, and the entities that comprise it, creating more value, wealth, and profits (economically viable dimension), providing environmentally benign products with less raw material consumption and waste generation (environmentally compatible dimension), and collaboration and a direct relationship among all involved in the supply chain, i.e. the corporations, employees, suppliers, investors, communities, customers, etc. (socially responsible dimension). These are the triple bottom lines of industrial sustainability. In order for economic, environmental, and social sustainability improvements to be successfully implemented within an industrial zone, the industrial decision makers must possess system-wide analysis abilities. The analysis of the sustainable development of an industrial zone involves decisions at the local, regional, or national levels, which are complex and involves handling of ill-defined parameters with a high degree of uncertainty due to the imperfect understanding of the underlying issues [3]. This work focuses strictly on the uncertainties in future zone planning and a method and a scenario based approach that can be used to evaluate the sustainable development of an industrial zone among these uncertainties."

Jan 1, 2008

By Julie M. Melluish

The metallurgical response of the Point Leamington deposit has been studied. Two series of bench tests were conducted and various ore samples and flotation products were examined using image analysis techniques. The majority of sphalerite and chalcopyrite grains in this texturally complex ore were found to be smaller than 10 micrometres. Copper recoveries were low with losses mainly as fine inclusions in pyrite. Sphalerite recoveries were somewhat better due to a generally coarser habit. Gold and silver recoveries were also low and only solid solution silver was identified in the ore. The deposit shows poor economic prospects unless additional tonnage of high grade zinc ore can be delineated.

Jan 1, 1989

By S. C. Dhara

The recovery of Platinum Group Elements from various industrial scraps and spent materials in the form of high and low grade, such as, impure metals, matte, catalysts and other ceramic substrates, etc., has .been described by using high pressure reaction method. Nickel, Stainless Steel, Titanium and glass lined reaction vessels? are used in the reaction process. Primarily, the method involves either direct leaching of the substrates from the metal value or dissolving the precious metal from the substrate. Both acids and alkalies are used along with other reagents in the reaction process. The temperature and pressure of the leaching process are the main criteria for the reaction kinetics.

Jan 1, 1989

By Vladimir Mindin

Simulation of complex equilibria is usually done in the P-T-X coordinates, where "Xu is the amount of individual chemical components in the system. This approach is not productive in some very important cases: (i) investigation of "open" systems, (ii) determination of coordinates (trajectories) of mono-variant points, among others. To solve these and some other problems, we use the idea of chemical potentials of elements (CPE) of the system. A system of different coordinates axes (CPE-axes ) leads to a new strategy of simulation, observing the results of the simulation, and to efficient technology of compressing and storage the data of the simulation.

Jan 1, 1994

By Dongping Duan, Hongliang Han, Li Zhong, Siming Chen, E Zhou

In this study, physical, chemical and microscopic characteristics of Celestine were investigated firstly. Based on which, the thermodynamic analysis of Celestine reduction was discussed. And the experiments of Celestine carbon-containing pellets used in rotary hearth furnace process were studied. The results showed that it is feasible to deal with Celestine by rotary hearth furnace direct reduction process. When the temperature is 1200°C, C/O ratio is 0.8 and holding times is 20min, the conversion rate of SrSO4 in Celestine is above 95%, the utilization rate of Celestine is nearly 100%. This study can provide theoretical and technical basis on economical and rational use of Celestine.

Jan 1, 2016

By A. E. Clark

Rare earth compounds are widely known as possessing many extraordinary magnetic properties. In this paper, we focus on the huge magnetically induced displacements (magnetostrictions) which characterize the compounds of terbium with iron (Terfenol). Materials prepared commercially by both free-standing-zone (FSZ) and modified Bridgman (MB) techniques have now become available in large sizes and shapes. Prior to the development of the Terfenol alloys, it was possible to achieve giant magnetostrictions only at cryogenic temperatures. In the cubic Laves phase TbFe2 compound, saturation strains exceed 3000 x 10-6 at room temperature and above. Large magnetization 'jumps' can occur, causing huge spontaneous magnetostrictions with small triggering magnetic fields.

Jan 1, 1992

The oxidation of ferrous ions by oxygen in sulphate solutions is a very slow process, but it tills long been known that the addition of sulphur dioxide increases the rate of reaction very significantly. The kinetics and mechanism of the process were investigated in the laboratory and the results confirmed the advantage of adding small amounts of sulphur dioxide to the oxygen stream for the removal of iron from solutions. The effect of various parameters on the overall rate of iron oxidation and precipitation was studied. In particular, temperature, acidity and composition of the gas mixture were considered and the optimum conditions for the precipitation of goethite were determined.

Jan 1, 1991

By Frederick W. DeVries

The author was invited by "60 Minutes Australia" to provide on-site technical background on cyanide, mining, and the environment, in their investigation of the January 30, 2000, spill at the Aurul gold-recovery site in Baia Mare, Romania. Some remarks on the incident ?and its implications surround a showing of the fourteen-minute telecast. The thrust of the TV reporter was that aspects of the dam implied the owners' use of standards Jess than would have been met for installations in technologically more advanced locations (like Australia). As a result, the public-relations impact is one of embarrassment for the world mining industry.

Jan 1, 1998