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By Harry Wolf

The chemistry of the element uranium enables industry to employ either an acid or alkaline carbonate leach solution for most uranium ores. Either method my be used for conventional, in-situ, or heap leaching. Uranium recovery in the leaching process depends both on the solubility of the uranium minerals and, on the access of the leach reagent to them. The uranium leaching rate is proportional to the liberated mineral surface area and the chemical reactions involved in the dissolution step. The dissolution of U(VI) and the oxidation of u(IV) to U(VI) are the basic chemical reactions in the leaching process. The active surface area is a function of the effective porosity and the particle size of the ore (1). Ore pieces, with a high porosity and high permeability, may provide a large active surface area even in coarser fractions. This type of ore might be suitable for heap or in-situ leaching techniques. Nonporous and impervious ores are usually more amenable to conventional milling where the active mineral surface is exposed by grinding the ore down to the liberation size of the mineral.

Jan 1, 1981

By Ahmed M. Yousif, Walid M. Abdellah, Galal M. Abdel Wahab, Amal E. Mubark

The present work is concerned with selective dissolution of niobium from Gabal El Faliq concentrate sample by using fluoridefree process. The chemical analysis of concentrate sample revealed the presence of high amount of ZrO2, Nb2O5, Re2O3, and HfO2 assaying 33.6, 1.99, 4.8, and 1.2%w/w respectively. Several economic minerals including zircon, samarskite, fergusonite, and xenotimewere recorded in the studied sample. About 98%of Nb content was selectively dissolved at the optimumconditions of 1:2 concentrate sample: KOH weight ratio, 2.5 h fusion time, and fusion temperature of 550 °C. Organic solvent extraction process using Aliquat 336S in xylene was effectively used for preparing pure Nb2O5 (98.95%).

Oct 22, 2019

By MUSTAFA ERKAYAOGLU, ENVER YILMAZ

Coal is still a part of energy generation worldwide and has a significant role in the sustainable development of countries. The amount of shallow coal deposits is getting scarce, making efficient underground mining operations crucial for both local and global economies. In underground mining operations, longwall mining is a commonly utilized method to extract deep coal deposits. One of the leading engineering goals in longwall mining is increasing the efficiency of the system by investigating the effects of operational factors on equipment. This paper investigates the shearer performance for a longwall top coal caving operation by discrete event simulation that includes modeling the double-drum shearer, belt conveyors, stage loader, and armored face conveyors (AFC) to evaluate system performance by considering the amount of daily coal production of the shearer. As a result, the most influential factor on mine production is determined and a data-based framework is developed. This study suggests a framework for data collection, data analysis, and the interpretation of the operational data to evaluate the primary production unit’s performance. The models developed for the face coal extraction operations in a longwall top coal caving (LTCC) mine have a bi-directional cutting system and can be implemented in other operations readily.

Jul 2, 2021

By Kristian E. Waters, Hao Ma, Haibei Wang

Over the past few decades, ELM based separation processes have become an attractive and efficient way to remove toxic metal ions from the various aqueous waste effluent streams. This paper provides a comprehensive review of the generation, characterization, and applications of emulsion liquid membrane (ELM) from the more than 280 papers and books published so far. First, the ELM formation and the transport mechanism are introduced. Then the ELM stability and emulsion splitting methods are discussed in detail, followed by the latest research and findings of the extraction of copper and nickel using the ELM technique during the past few decades, including a thorough discussion of ELM operating parameters that impact ELM stability and extraction. In addition, the kinetics study and industrial application of this technique for the removal of coppers/nickel solutes are also presented and discussed.

Jan 6, 2023

By Lyman File

This paper discusses the overall challenges to construct a two-lane highway tunnel located in southwestern Colorado on U.S. Highway 160 for the Colorado Department of Transportation by the Kiewit Western Company. The purpose of this project is to provide the excavation and temporary support for a highway tunnel 280 m (916 feet) long. The tunnel cross section is 14.3 m (47 feet) wide by 8.5 m (28 feet) high, 105 m2 (1,130 SF).Construction methods include conventional drill and blast excavation with rockbolt and shotcrete ground support. This unique tunnel is being constructed under alpine tunnelling conditions and in the immediate vicinity of active highway traffic.

Jan 1, 2003

By Yao Yevenyo Ziggah, Victor Amoako Temeng, Solomon Evans Kweku Koomson

Tyre hours/life deficit is a major operational challenge facing the mining industry which adversely affects materials production and costs. An accurate forecast of the tyre life is key in addressing this menace. This study for the first time employed the hybrid intelligent technique by utilising three metaheuristic optimisation algorithms, including particle swarm optimisation (PSO), genetic algorithm (GA), and whale optimisation algorithm (WOA), as trainers for the parametric weights and biases to optimise multilayer perceptron neural network (MLPNN) for enhancing prediction of on-site dump truck tyre life in the mine. Four hybrid models known as PSO-MLPNN, WOA-MLPNN, GA-MLPNN, and BP-MLPNN were developed using a total of 157 tyre dataset records obtained from a surface mine in Ghana. In assessing the prediction performances for the models developed, five statistical performance metrics of variance accounted for (VAF), Nash–Sutcliffe efficiency index (NASH), coefficient of determination (r2), mean absolute percentage error (MAPE), and correlation coefficient (r) were utilised. Moreover, ranking, uncertainty analysis and Bayesian information criterion (BIC) techniques were utilised to establish the most effective hybrid model, whereas sensitivity analysis was conducted on the input parameters. Results achieved showed that PSO-MLPNN was the best for prediction because it had the least MAPE value of 1.196% and relatively high values of VAF (99.642%), NASH (0.996), r2 (0.996), and r (0.998). Besides, PSO-MLPNN had the best selection criteria values of 6, 7.1725, and 444.834 for the ranking, uncertainty analysis and BIC respectively. Hence, PSO-MLPNN is recommended for the prediction of on-site dump truck tyre life for the studied mine.

Mar 11, 2024

By H. Lawrence

In 1977, the Bureau of Mines awarded a grant to the State of South Carolina to explore the possibility of using Landsat multispectral scanner (MSS) data as an aid in monitoring surface mining activities in selected counties of the State. Work had been done in Aiken County prior to the grant by Bureau of Mines and State personnel at the EROS Data Center using both the GE Image 100 and ESL IDIMS systems. The initial work on the 1-100 consisted of locating and measuring the areas of various kaolin mines. The results were excellent on location, identification, and accurate area measurements of several mines as compared with aerial photos of each mine. The effort also included locating and measuring the size of all mines (including sand and gravel) within two U.S. Geological Survey (USGS) 7 ½ min quadrangle maps. Line printer overlays using the IDIMS equipment and software resulted in the location of all known mines within an estimated error less than ±91.4m (5300 feet). Mine acreage was calculated by counting each symbol (which represented one pixel) and multiplying by 1.1 (the number of acres per pixel). Figure 1 shows a portion of one quadrangle overlay. Table I gives a comparison of acreage measured for sever- al mines from the 1-100 and IDIMS systems vs. aerial photo measurements.

Jan 1, 1979

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this study is to assess the impact of different reagents, such as limestone, lime, magnesium oxide, and sodium hydroxide, in experiments carried out in the single purification step and in two consecutive purification steps by raising the pH of a rare earth sulfuric liquor with the aim to remove or reduce the impurity concentrations in the rare earth sulfuric liquor. The choice for the best purification condition was made based on the minimum loss of rare earth elements (REEs), reagent consumption, and residue generation. The exploratory experiments show that it takes place in the two consecutive purification steps, the first one consists in dosing the limestone pulp until it reaches a pH of 3.5 followed by an addition of a lime pulp reaching a pH of 5.0. Under this condition, the results were a total removal of Fe3+, PO4 3− , and Th4+ ions and a reduction of 99%, 87%, and 37% w/w in the Al3+, UO2 2+, and SO4 2− concentrations, respectively, in the purified rare earth liquor. Furthermore, the lowest REE losses (8.3% w/w) and reagent consumption (4.3 kg/m3 ) and also a low residue generation (7.5 kg/m3 ) were observed in this condition. Despite reaching similar results regarding impurity removal, the experiments done with the addition of limestone, lime, magnesium oxide pulps, and sodium hydroxide solution in the single purification step, where the pH was raised to 5.0, presented higher REE losses (64.9%, 42.5%, 44.8%, and 60.9% w/w, respectively) and a higher residue generation (43.2, 25.1, 11.1, and 13.6 kg/m3 , respectively). This occurred due to the co-precipitation of salts containing rare earth elements in their composition. The experiments conducted with limestone, lime, and MgO resulted in a higher consumption of reagents, while the same result was observed when NaOH was used (4.3 kg/m3 ). In the experiments carried out with the addition of magnesium oxide and sodium hydroxide, the respective purified rare earth liquors presented a high concentration of magnesium, sulfate, or sodium, which could impact the quality of the marketable rare earth salts, whereas the salts obtained under the best condition observed in this study seem to be amenable for use as raw material in an attempt to obtain rare earth products with an acceptable chemical quality.

By Shuie Li, Taibai Li, Tao Hu, Zhongjie Wang, Xiang Ge

As one of the main power sources, lithium-ion batteries (LIBs) will continue to be applied on a large scale in the future market. Commercialized LIBs cathode materials contain various valuable metal elements including Li, Co, and Ni. The development of green and efficient recycling technology is essential. Deep eutectic solvents (DESs) have recently emerged as a new class of green solvents that could potentially be applied for the LIBs recycling industry due to their capability to leach the active materials without the introduction of environmentally hazardous reagents as used in conventional hydrometallurgy process. Considering the rapid progress, a critical review focusing on the progress and fundamentals about the overall efficiency has practical significance for the further advancement of this field. Herein, we briefly introduce the overall process of using DESs for LIBs recycling and specifically focus on the efficiency of each step. Current fundamental understandings and new experimental approaches to enhance the efficiency of the leaching process, the extraction process, and reusability are summarized. We expect this review article to inspire scientists to use DESs as powerful tools for advancing the frontiers of LIBs recycling.

Jul 30, 2022

By Manuel Gomez

This report presents prediction equations for eleven factors indicative of metallurgical coal quality which have been developed from data obtainable during exploration. Five coke strength parameters and six carbonization product yields have been predicted for coking coals having volatile matter contents in the range 16.3 to 42.1 percent, dry basis. The prediction models developed contain information from the proximate and ultimate analyses, the size consist, and the petrographic composition of coking coals carbonized in BM-AGA retorts at 800°, 900°, and 1,000°C. The equations reported have been evaluated with independent data derived from the 900°C carbonization of 33 binary blends. Present results show that metallurgical coal quality can be predicted ahead of mining. Capability to forecast coal quality is useful in mine planning and should provide basic information for optimization of blending and crushing techniques, leading to the production of uniform coke.

Jan 1, 1968

By J. W. Furlan

Due to the time consuming nature of froth testing in a laboratory environment, it is required, due to practical limitations, to develop a method of applying a single set of performance test data (Visintainer & Whitlock, 2012) obtained for a single froth pump at a given speed, to a range of froth pump speeds and sizes, % air contents, and liquid viscosities. Head, efficiency, and flow all vary as functions of both liquid viscosity and air content. As such, it is necessary to develop a technique which can be used to interpolate from existing test data in order to predict froth pump performance for pumps of various sizes running at variable speeds. Details of the technique developed in order to achieve this goal as well as the insights gained from analysis of the resulting regressions are discussed. Additionally, comparisons are made between the performance predictions of this test-derived method and those of the Hydraulic Institute Standard for the effects of liquid viscosity on centrifugal pump performance (ANSI/HI 9.6.7-2010).

Feb 27, 2013

By V. T. McLemore

"Production of industrial minerals remains important to the rural economy of New Mexico. In 2014, 226 active mines and mills were registered in New Mexico and included four coal, eight potash, 11 metal, 33 industrial mineral and 170 aggregate and stone operations. New Mexico leads U.S. domestic production of potash, perlite, zeolite and travertine. Other production includes aggregate, humate, pumice, gypsum, salt, common and fire clay, scoria, limestone, fly ash, cement, magnetite, silica and decorative stone. New Mexico also has the potential for additional production of industrial minerals. One company is exploring for garnet. Cretaceous black sandstones in the San Juan Basin have drawn interest for titanium, rare earth elements (REEs), niobium and zircon, and other REE deposits are being explored. REE-thoriumuranium veins have been found in the Gallinas, Capitan and Cornudas Mountains and Laughlin Peak-Chico Hills. Exploration for beryllium has occurred in the Ojo Caliente No. 2, Cuchillo Negro and Victorio mining districts. Companies also are examining high-calcium limestone and high-magnesium dolomite for potential development, while aggregate continues to be important in urban areas and along highways. IntroductionIndustrial minerals and rocks are literally the building blocks of our way of life. They are an exceptionally diverse and vital group of raw materials that underpin almost all aspects of human activity, infrastructure and standard of living. Industrial minerals and rocks are used in the manufacture of many products, from ceramics to plastics to refractories to paper. Although industrial minerals permeate nearly every aspect of daily life, their presence and their roles are typically invisible. A widely used definition of industrial minerals and rocks is “any rock, mineral, or other naturally occurring substance of economic value, exclusive of metal ores, mineral fuels, and gemstones: one of the nonmetallics” (Bates, 1975). This definition includes the important construction materials sector as well as specialized industrial minerals, but complex interactions between consumer industries produce a number of apparent anomalies to this definition. Some metals are included as industrial minerals because their use is industrial rather than as a metal. Sulfur is now predominantly extracted as a byproduct of cleaning natural gas, one of the world’s major energy fuels.Production of industrial minerals has been and remains important to the rural economy of New Mexico. Industrial minerals constitute nearly 41 percent of the more than $3.1 billion generated by mineral production in New Mexico in 2014 (Table 1). In 2014, 226 active mines and mills were registered in New Mexico and included four coal, eight potash, 11 metal, 33 industrial mineral and 170 aggregate and stone operations (New Mexico Mining and Minerals Division, 2015a). New Mexico leads U.S. domestic production in potash, perlite, zeolite and travertine. Other industrial minerals production from New Mexico includes aggregate, humate, pumice, gypsum, salt, common and fire clay, scoria, limestone, fly ash, cement, magnetite, silica and decorative stone. Additional production statistics can be found in Harben et al. (2008). Major industrial mineral districts are shown in Fig. 1."

Jan 6, 2017

By Ali Kazmi, Wern-ping N. Chen

A load rating procedure was performed to evaluate safe load capacity of the Port of Miami Tunnel (POMT), FDOT Tunnel No. 871071 SR 887. The rating procedure performed on a total of eleven stations beneath roadways and with fill depth less than the tunnel exterior diameter (42 ft). Calculations on tunnel sections passing beneath roadways were performed to evaluate the structural response of the sections subject to moving vehicular loads, dead load, and earth pressures. Ratings were performed in accordance with AASHTO and FDOT guidelines. The procedure considered two types of vehicles (HL-93 and FL-120) and two rating levels (Design level and Permit level). As part of HL-93 vehicle, Tandem load was also considered for rating, separately. For HL-93 and HL-93 Tandem, inventory and operating level ratings were performed. The results show rating factors are high. The minimum rating factor is 16.8 using Inventory truck HL-93. For Permit level using FDOT FL-120 truck the minimum rating factor is 6.9. As can be seen, rating factors are higher than comparable analysis for bridges. This paper explains how the procedure can be implemented for tunnels and evaluates the rating results.

Dec 1, 2022

By Jerry C. Tien

Without a doubt, the scope of China?s coal boom has been nonstop. Despite the world economic slowdown, China?s year-on-year gross domestic product (GDP) jumped 10.3 percent year-on-year in 2010, boosted by a faster than expected 9.8 percent expansion in the fourth [ ] quarter. And, the first quarter of 2011 expanded another 9.7 percent. According to a frequently cited statistic, the country is building two mid-sized coal plants each week. This amounts to a yearly increase equivalent to the entire power grid in the United Kingdom. China?s coal production was doubled in the last 10 years, from 1.044 Gt (1.15 billion st) in 1999 to 3.2 Gt (3.52 billion st) in 2010. This is 3.2 times the U.S. production (986 Mt or 1.085 billion st) and nearly half (46.3 percent) of the world?s total coal production (6.91 Gt or 7.6 billion st). This rapid increase of demand for coal has made China the world?s largest coal importer in 2009. With the economic situation improving, this trend is expected to continue.

Jan 1, 2011

By Sheshang Singh Chandel, Prvan Kumar Katiyar, Navneet Singh Randhawa, Prince Kumar Singh

Mineral process wastes, such as metallurgical slags nowadays, are of significant metals and materials resources in the circular economy. The usability of iron-making slag is well established; however, steel slag still needs to be utilized due to various physicochemical constraints. In this context, we have reviewed the global steel slag generation, processing, characteristics, and potential application with suggestions for futuristic possibilities to address the technical, economic, and environmental aspects of steel slag recycling. The steel slags inherit characteristics from ore chemistry and their processing routes, which may be Blast Furnace-Basic Oxygen Furnace (BF-BOF) or Direct Reduced Iron-Electric Arc Furnace (DRI-EAF) steel-making routes with/without treatment in a Ladle Furnace (LF). The average generation of slags in BOF, EAF, and LF processes accounts for 110 kg, 70 kg, and 40 kg per tonne of steel, respectively. Considering global steel production of 1878 million tonnes in 2020, the associated slag by-products possess a significant resource of major components like FeO, CaO, SiO2, Al2O3, etc. Selecting a recycling technique depends on the slag's end use, logistics, and physicochemical characteristics. BOF and EAF slag are used ~ 48% in road construction applications and ~ 10% for industrial specific metallurgical use. EAF slag is preferred as cementitious material as compared to BOF. Hot-stage modification of BOF slag has emerged as a preferred method to achieve desired chemical and subsequent mechanical properties for end use. BOF slag has high carbon dioxide sequestration potential for in-plant remediation among steel slags.

Nov 20, 2023

By Rosa Malena Fernandes Lima, Kerollan da Silva Ramos, Joyce de Assis Silva, Geriane Macedo Rocha

This study evaluated the effects of collector type amide-amine compared with those of conventional etheramine acetate (both cationic collectors) on the surface properties of quartz and hematite. An examination of certain properties of the reagents indicated that the new collector amide-amine has CMC (critical micelle concentration) and pKa values (100 mg/L and 8.2, respectively) significantly lower than those of etheramine (800 mg/L and 9.4, respectively). Microflotation tests showed that the recoveries of quartz with amide-amine in all the concentrations tested were higher than those with etheramine. This is attributed to its lower CMC and pKa values. The selectivity window between quartz and hematite flotation using amideamine was higher at pH 10.5 (approximately 80% for 5 mg/L). Therefore, the use of starch is not necessary in siliceous itabirite flotation by amide–amine collector. Zeta potential measurements and infrared spectra reveal that the adsorption of amide-amine collector on quartz surface occurs mainly by electrostatic attraction. Considering the better collectability of amide-amine for quartz flotation and lower adsorption affinity for hematite surface than etheramine, the amide-amine is a promising collector to be used in reversal iron ore flotation.

Jul 30, 2021

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this study is to assess the impact of different reagents, such as limestone, lime, magnesium oxide, and sodium hydroxide, in experiments carried out in the single purification step and in two consecutive purification steps by raising the pH of a rare earth sulfuric liquor with the aim to remove or reduce the impurity concentrations in the rare earth sulfuric liquor. The choice for the best purification condition was made based on the minimum loss of rare earth elements (REEs), reagent consumption, and residue generation. The exploratory experiments show that it takes place in the two consecutive purification steps, the first one consists in dosing the limestone pulp until it reaches a pH of 3.5 followed by an addition of a lime pulp reaching a pH of 5.0. Under this condition, the results were a total removal of Fe3+, PO4 3− , and Th4+ ions and a reduction of 99%, 87%, and 37% w/w in the Al3+, UO2 2+, and SO4 2− concentrations, respectively, in the purified rare earth liquor. Furthermore, the lowest REE losses (8.3% w/w) and reagent consumption (4.3 kg/m3 ) and also a low residue generation (7.5 kg/m3 ) were observed in this condition. Despite reaching similar results regarding impurity removal, the experiments done with the addition of limestone, lime, magnesium oxide pulps, and sodium hydroxide solution in the single purification step, where the pH was raised to 5.0, presented higher REE losses (64.9%, 42.5%, 44.8%, and 60.9% w/w, respectively) and a higher residue generation (43.2, 25.1, 11.1, and 13.6 kg/m3 , respectively). This occurred due to the co-precipitation of salts containing rare earth elements in their composition. The experiments conducted with limestone, lime, and MgO resulted in a higher consumption of reagents, while the same result was observed when NaOH was used (4.3 kg/m3 ). In the experiments carried out with the addition of magnesium oxide and sodium hydroxide, the respective purified rare earth liquors presented a high concentration of magnesium, sulfate, or sodium, which could impact the quality of the marketable rare earth salts, whereas the salts obtained under the best condition observed in this study seem to be amenable for use as raw material in an attempt to obtain rare earth products with an acceptable chemical quality.

By E. Costa Silva

Among the methods of mineral processing, gravity concentration methods are, probably, those which have lower costs, higher capacities and lower operational complexity. In order to be really effective, these methods require a feed size distribution in which the particles are liberated. Further, there must be a significant difference (usually higher than 1-1.5) among the real densities of the particles. However, in most cases, the traditional gravity concentrators (jigs, shaking tables, spirals and dense medium hydrocyclones) lose efficiency (sharpness of cut and recovery) when the mean diameter of particles are lower than 0.05mm and the difference among densities are smaller than 1. Most gravity concentrators developed in the last 20 years are based on the use of centrifugal forces that create large "apparent gravitational gradient" seeking to overcome the limitations of particles size distribution. This paper presents the experience of the CVRD Research Center in evaluation and development of new process based on using this new generation of gravity concentrators.

Jan 1, 1999

By M. Deul

For the first half of the 21st Century the USA will rely on the same mix of fuels as for the past 50 years: Petroleum will cost more and availability will decline as developing nations modernize. Increased use of natural gas for electric power generation will result in severe stress on gas supply. Coal will be the fuel of last resort. More than half the petroleum used is imported, about the same amount as used for transportation. Only coal can provide relief by fueling railroads through electrification while encouraging ‘piggy-back’ trailer haulage, co-generation for manufacturing and expanded passenger service.

Jan 1, 2002

By Muhammed Şener, Ahmet Gültek

The flotation chemicals are important in mineral processing, and new progress is made in this area day by day. For sanidine purification, some commercial collectors, which can be harmful to the environment, are used. In that respect, the poly(amidoamine) (PAMAM) dendrimers, which are non-toxic for the environment, are good candidates for flotation applications. In this study, the second-generation PAMAM dendrimer was used as a collector to remove magnetite from sanidine by microflotation method, and obtained results were compared with commercial collectors. The results showed that the PAMAM dendrimer is an efficient and selective collector for magnetite. PAMAM adsorption mechanism was determined by zeta potential and FTIR spectra. According to the microflotation results, 87.76% of magnetite recovered at pH 8 by using PAMAM as a collector. It was found that the flotation recovery with the PAMAM dendrimers is similar to the Aero 704 between pH 2 and 6 but less between pH 6 and 9 and more between pH 9 and 12. All experiments were carried out five times and the standard deviation of all results was evaluated with p = 0.05 confidence interval. The second-generation PAMAM dendrimers can be an alternative flotation chemical to the commercial ones concerning usability at a wide pH range, recovery potential, and environmentally benign.

Apr 28, 2023