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By N. Wagner, P. den Hoed, J. D. Steenkamp, S. Soqinase

In pyrometallurgical processes, metal oxides are reduced from molten slag through carbothermic reduction. It is of interest to evaluate the reactivity of the carbonaceous materials towards substances such as slag. Characterization techniques such as coal petrography can provide insight into the influence of feed coal properties and how they potentially dictate reductant performance. This study aimed to compare the petrographically determined organic composition of coal to reductant reactivity. Two South African medium-rank C bituminous coals and one anthracite sample were investigated together with high-carbon ferromanganese industrial slag. The reductant reactivity tests were conducted at 1500°C in a muffle furnace to assess the potential of carbonaceous reductant in reacting with the main slag components. SEM-EDS was applied to understand the extent of MnO (and to a lesser extent, SiO2) reduction from the slag. Coal 2, consisting of a greater proportion of vitrinite (59.5 vol% on a mineral matter-free basis and 54.7 vol% including mineral matter) was the most reactive reductant. The anthracite sample, with the highest inert maceral proportions (71.8 vol% including mineral matter and 76.8 vol% on a mineral matter-free basis), was the least reactive reductant.

Feb 6, 2023

By L. W. Helle

In this investigation, which was conducted at the Metallurgical Research Plant, Lulea, Sweden, a series of experiments were carried out using a water-model to simulate the gas rinsing of a ladle containing liquid metal. The factors examined include the effect of gas flowrate, the position of a porous plug or lance, the immersion depth of the lance, and the geometry of the bath at the time of complete mixing. Mixing times were recorded by conductivity measurements. The results showed that there is a threshold level for mixing above which no advantage is to be gained from an increase in the gas flowrate. It is suggested that the results can be applied to rinsing ladles in working situations, the levels being approximately 270 dm3/min for 40 t ladles and 780 dm3/min for 150 t heats. The optimum siting of the lance or porous plug is a position that is three-quarters of the internal radius from the centre of the ladle with the lance penetrating as deeply as possible into the ladle. The best design of liquid bath is that having a diameter-to-height ratio of I. An equation was developed for the calculation, by dimensional analysis, of the time required for mixing during gas rinsing, and a comparison of the calculated mixing times with the results from production trials shows a satisfactory agreement (with a correlation factor of 0,91). Thus, an equation is available for the calculation of the stirring time needed to completely mix the bath in production situations.

Jan 1, 1981

When designing coal mine roof support, it is necessary to account for the uncertainties and variability that inherently exist within the rock mass and support elements. The performance of a support system is affected by these uncertainties, which are not taken into account in the current deterministic design methodologies used in South Africa. The key to the design of a roof support system is a better understanding of roof behaviour and uncertainties that can been countered during extraction. This paper sets out to develop a method that takes all uncertainties that exist within the rock mass and the mining process into account and provides a quantitative risk-based design methodology.

Jan 1, 2009

By R. L. Castro

Currently, in several caving operations, the spacing between the drawpoints is determined by consulting Laubscher's design guide (Laubscher 1994, 2000), a methodology based on the gravity flow characteristics of the caved rock. Laubscher's methodology is based upon the height of interaction between adjacent flow zones, but does not allow calculation of primary recovery for a given layout. In this paper the authors present a technical and economic methodology based on the flow that occurs near the drawpoint and the associated development costs to estimate the optimal spacing. The flow model at the drawpoint was validated at the El Teniente mine, which extracts coarse caved rock. To validate the flow model, small-scale simulations using drawpoint clusters were conducted and results compared to extracted grades, marker recovery, and drill holes to determine ore remnants that are part of the production control programme at the mine. The results indicate that primary recovery depends on the height of interaction, which varies with the friction angle of the caved rock and the spacing between adjacent drawpoints. Primary recovery estimations indicate values from 85 per cent to 97 per cent depending on the drawpoint spacing used. Extrapolations were then conducted to estimate the primary recovery for different drawpoint configurations planned to be used in the New Mine Level of the mine. The results indicate that the optimal drawpoint spacing is 32 m x 20 m with a through length of 18 m. The methodology developed may be used to estimate optimal drawpoint spacing for block caving mines under different metal prices and mine cost conditions.

Jan 1, 2012

By N. C. Joughin

A simplified economic model is derived for the financial return from a new gold mining project. The model is used to analyze the effects of changes in the mining rate, capital costs, working costs, value of the reef and the stoping width. The most effective avenues for improving the return from a new project are indicated. It is shown that those technological innovations which would improve the return significantly, and therefore make it possible to open more mines, are the use of smaller mines, means for improving the mining rate to capital costs ratio for smaller mines, planning and control of mines by computer simulation, an improved mine valuation procedure and means for mining at a decreased stope tramming width.

Jan 1, 2014

By H. Karabulut, S. Gündüz, K. Karacif, M. A. Erden

The corrosion properties of iron-based composite materials containing graphite and silicon carbide (SiC) reinforcement were investigated. The effects of silicon carbide reinforcement were investigated by adding 0.5% graphite and 1%, 2%, and 4% SiC. A powder metallurgy method was used to produce the composite samples. Iron, graphite, and silicon carbide powders were blended for one hour with a threeaxis mixer and then unidirectionally pressed under a pressure of 750 MPa. After pressing, the composite materials were sintered at 1100°C for one hour. The corrosion properties and microstructure, density, and hardness properties of the composite materials that can affect the corrosion properties were also investigated. It was determined that the pore ratio and hardness of the composite material increased, and corrosion resistance decreased, with increasing silicon carbide content.

Jun 2, 2022

It is perhaps somewhat unusual for a contributor to comment on the authors' reply to his critique. However, I should like to return to a specific comment made by the authors. Award to Bob Laburn The Federation of Societies of Professional Engineers (FSPE) is pleased to announce that the 1984 FSPE Award for Services to the Engineering Profession was presented to Dr R. J. (Bob) Laburn at a function held on 14th February, 1984.

Jan 1, 1984

By J. M. Stewart

The purpose of my few comments is to try to create a healthy perspective to constructively link considerations of the sessions to follow to those of the earlier sessions. I propose to do this by considering some of the issues and priorities related to the development of backfill systems and technology for South African gold mines.

Jan 1, 1988

By D. P. Enright, D. D. Howat

Austenitic manganese-steel castings are very widely used in crushing and grinding in the' gold-mining industry in South Africa, The service life of a casting in a short-head crusher is difficult to predict because there are no clear-cut criteria by which such a judgement can be made, The addition of molybdenum and zirconium to the castings for crushers failed to result in improved performance, The results of extensive tests with through-hardened steel castings were very disappointing, mainly because of a design factor in the bowl liner. The design of the bowl liner is an important determinant of the life and performance of these castings. The extent to which the material in a crusher is reduced in size has profound effects on the consumption of metal and power, and on the effective life of a casting. Tests on manganese-steel castings in an 8 ft by 12 ft rod mill provided data on the total consumption of metal, and on the variations in the pattern and rates of wear of liners over lengthy periods. Progressive changes in the wear profiles of the lifter bars and the other liner components showed unexpected features. There are clear indications that, whereas a set of lifter bars will at first lift the charge strongly with relatively little slippage, there is a later period characterized by more slippage and greater wear on all the liner components.

Jan 1, 1980

By P. J. A. Beukes, C. C. La Grange

INTRODUCTION Some years ago the authors proposed a modified procedure1 for carrying out micum index determinations2. The modifications consisted of using a drum of 50 cm internal length, i.e. half the length of the standard micum drum (a modification also adopted by the B.S.J.3), and the use of a + 25 mm coke instead of + 60 mm coke for the test. The proposed modified test and formulae for converting results obtained from it to standard micum test results and vice versa were based on the results obtained during the investigation of about 200 test cokes made in ovens of the South African Steel Industrial Corporation Limited (Iscor), the Fuel Research Institute co-operating with the experiments. Extensive testing of cokes has since been done at the Fuel Research Institute using both the standard and the modified procedures. The numerous test results obtained during this trial period fully support and strengthen the confidence originally expressed by the authors in the modified testing procedure. The scope of the modified micum index determination has in the meantime been extended by applying the testing procedure also to test cokes made in the Institute's experimental coke ovens, and also in this case the modified procedure has proved its usefulness. A difficulty is that when comparing the characteristics of cokes made in the Institute's two experimental coke ovens with each other and with those of cokes made from similar blends in commercial coke ovens, for example those of Iscor, the index values obtained invariably do not check exactly due mainly to inherent differences between the different types of oven4. For instance, resistance to abrasion of a coke made in Iscor's ovens is always appreciably higher than that of a coke made from the same blend (and having a similar moisture content) in the experimental ovens. This makes direct comparisons and the prediction of quality to be expected from commercial products, based on experimental coke oven results, difficult. It may also be added that workers in Great Britain some years ago reported a similar experience5. In the authors' opinion the main reason for the discrepancy is the relatively low height of the experimental ovens resulting in a much lower static pressure on the charge during coking than that obtaining in a commercial oven. The difficulty was pointed out and briefly discussed in a publication4 which appeared at a time when the micum test for coke evaluation had only just been introduced at the Institute, so that only B.S. shatter and abrasion test results were available for discussion in the publication. Needless to say, the introduction of the micum test by no means solved nor even alleviated the problem. On numerous occasions during the past few years the Institute has had to conduct contract investigations in its experimental coke ovens on behalf of companies which invariably desired an indication of the quality of coke likely to be obtained from certain coals or blends when coked commercially, more particularly in Iscor's type of coke ovens. It was, therefore, essential to accumulate statistical data which would enabe the prediction to be readily made. Fortunately the compilation of comparative coke-quality index values for the three types of oven under consideration has become possible as a result of coking investigations conducted in co-operation with Iscor over a number of years. During this period Iscor, on numerous occasions, kindly made available to the Institute portions of coals and blends coked in the Corporation's coke ovens, thus enabling parallel coking tests to be carried out in the Institute's experimental ovens. In this way enough statistical data became available to establish relationships between coking results obtained in Iscor's ovens and results obtained on similar coal charges in the Institute's ovens. The most practical and acceptable method of overcoming the problems of finding a suitable and simple basis enabling direct comparison between the cokes of the different origins mentioned to be made, is the assignment of descriptive arbitrary quality ratings, as indicated below, to the cokes obtained, it being argued that the quality rating assigned to coke made from a given coal or blend in the different coke ovens under standardized conditions should be the same, irrespective of differences in the index values obtained when subjecting the cokes to the usual coke evaluation tests. The system, which should enable the sponsors of coking investigations in the Institute's experimental ovens to make their own interpretations of the results obtained, is explained below. ARBITRARY QUALITY CLASSIFICATION OF COKES The Ml0m index1 (percentage material smaller than 10 mm after the test) of a blast furnace coke is a measure of its tendency towards breeze formation during handling -a low value indicating a low tendency. This is generally of greater importance under ruling South African conditions, than the M'40 index1 (percentage material larger than 40 mm after the test), which can be regarded as a measure of resistance to shatter. In fact, if the M10m value of a coke as made in Iscor's ovens is higher than about 11, the tendency of the coke to form breeze during handling and in the blast furnace is relatively so high that hardly any notice need be taken of its M'40 value, even if this is comparatively high. For this reason, therefore, much more weight should normally be assigned to Ml0m indices in the quality evaluation of cokes made from South African coking coals and blends, as the coals

By G. H. Morton

The tenth international symposium on the application of computer methods in the mineral industry (APCOM) was held in Johannesburg in April; the first time it had taken place outside North America. In the technical sessions fifty-seven papers were presented, providing a review of current work and including some important original contributions. These papers and a full account of the discussion at the symposium will soon be published in a single volume. The Technical Programme The first session of the symposium included an opening address given by Mr J. W. Shilling, President of the Chamber of Mines of South Africa, and a keynote address by Mr K. F. Lane of the Rio Tinto Corporation Limited. Mr Shilling spoke about the history of the South African mining industry and about some of the work of the Chamber of Mines. He stressed the importance of the symposium in familiarising those in mining with computer applications, and expressed his hope that it would stimulate and inspire scientists and engineers in the effort to develop safer and more economic methods of mining. Mr Lane, talking about economic and financial modelling, gave a fascinating account of the experience of RTZ over the last twelve years. In a very honest appraisal of the substantial progress that had been made, he confessed some disappointment not only in the cost and

By P. Sebola, S. Rasmeni, K. Seripe, D. Chetty

"South Africa’s Northern Cape Province hosts semi-precious and gemstone occurrences that are sporadically mined on a small scale by local communities. Tiger’s eye, a gemstone known for its chatoyancy properties, is found in important deposits located near the town of Prieska, where is it intermittently mined. Challenges faced by small-scale and informal mining include mining without proper permits, risky mining practice in dangerous terrain, and illegal export of raw material without concerted effort at domestic beneficiation. As part of a study aimed at job creation and social upliftment in the region, tiger’s eye deposits in the Prieska area were assessed to assist small-scale miners to understand tiger’s eye grades and their distribution. This will allow not only more efficient and safer mining of these deposits, but also beneficiation of the raw product into tumbled stones, cabochons, jewellery, and other small artefacts for sale. A hub established in Prieska by Mintek trains locals in the beneficiation of tiger’s eye. Supply to the hub must make use of a consistent grading system, which is discussed in this paper. Together with proper mine licensing, such an approach will develop mining and beneficiation skills, and create and sustain employment for the local community. IntroductionTiger’s eye is a semi-precious stone known for its chatoyancy property, which is caused by parallel, silicified asbestos fibres that impart a silky lustre to specimens. Deposits of tiger’s eye in the surrounds of the town of Prieska, Northern Cape Province, formed the focus of a study aimed at small-scale mining and beneficiation of this commodity. The Prieska tiger’s eye deposits are located along the N10 route to Upington (Figure 1). Tiger’s eye is unevenly distributed and occurs as lenses of various sizes, interbedded in gently folded metasedimentary rocks of mostly banded iron formation (BIF). The tiger’s eye occurrence in the Northern Cape Province, especially in the Prieska area, has not been extensively researched. There is thus limited information available in the public domain. The lack of knowledge on tiger’s eye distribution has resulted in local small-scale miners adopting a trial-and-error method of mining. Basic geological mapping and field evaluation of the deposit, coupled with professional judgement, are important aspects of any small-scale mining operation and can contribute significantly to the formulation of various acceptable and equally viable mining methods and practices."

Jan 1, 2016

By T. Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques and controlled bulk leaching studies. The anodic dissolution process has been established to be a sevenelectron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions, which suggests that the sulphur is oxidized to thiosulphate and the copper and iron released as Cu+ and Fe2+ in these systems. The deportment of Fe2+ and S2O3 2- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, supporting formation of different sulphur species as proposed for the sulphate and carbonate salts. Scanning electron microscopy and energydispersive spectroscopic analysis of the mineral surface after leaching indicate presence of an iron–sulphur surface layer completely free of copper in the sulphate system, an iron-rich surface layer in the perchlorate solutions, and absence of surface layer build-up in carbonate solutions. XRD analysis of a bulk leach residue from leaching in ammoniaammonium sulphate solutions showed the surface layer to be mostly amorphous (90%). The crystalline content (10%) is composed of 95% polymorphs of anhydrous iron oxide hydroxide FeO(OH). Choice of ammonium salt and the hydrodynamic environment of leaching have been shown to influence the presence or absence of the surface product, as well as its nature. IntroductionHydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different routes for hydrometallurgical treatment of chalcopyrite can be followed. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilization of copper (I) and copper(II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation [1] (Beckstead and Miller., 1977a):"

Jan 1, 2016

By K. L. Morton

This technical note reviews the status quo of mud rushes and flooding, which have claimed them lives of many people in underground mines in South Africa and globally. Given that the causes are well known and can be managed, the note calls for the development of a national and global standard on flood and mud rush prevention in order to save lives.

Mar 30, 2026

By M. J. Nicol

An electrochemical investigation of the dissolution of copper, nickel, and copper-nickel alloys in ammonium carbonate solutions by M. J. NICOL, Ph.D., B.Sc. (Hons.) (Wits.) (Visitor) The dissolution of copper and nickel in ammonium carbonate solution was studied by techniques involving electrohemical anodic dissolution and ring-disc electrodes. The rate of oxidation of both copper and nickel by copper (11) was shown to be controlled mainly by diffusion to the surface. Variations in rate with changes in copper (11) concentration, agitation, pH, ammonia concentration, temperature, and copper (I) concentration were investigated and rationalized in terms of their effects on the electrochemical half-reactions involved. Evidence was found for the passivation of nickel and nickel-copper alloys of more than 50 per cent nickel.

Jan 6, 1975

By M. C. Mulligan

Counter current decantation (CCD) thickener circuits are used to recover soluble metal as pregnant liquor solution from ore leach residue. The basis of CCD operation is to concentrate suspended solids thereby minimizing liquor content in underflow slurry that flow in one direction. Then the underflow slurry liquor is diluted with wash liquor that flows in the opposite direction and the suspended solids are concentrated again and again. The amount of liquor in the thickener underflow contributes to determining the number of CCD stages required to recover the desired amount of soluble metal. Furthermore, similar results could be achieved at a lower wash quantity, reducing the size of downstream equipment. High density thickeners (HDT) are designed to use gravity and compression, and minimize the amount of liquor in the underflow thus minimizing the number of CCD stages. This paper reviews the process used to select HDTs rather than high rate thickeners (HRT) for the Ruashi II copper-cobalt hydrometallurgical process in the Democratic Republic of Congo (DRC), using laboratory HDT simulations, to CCD simulations and thickener design details.

Jan 1, 2009

Limestone formations in the United States can be subject to relatively high horizontal stresses due to the existence of tectonic loading of the limestone strata. Underground limestone mines use the room-and-pillar method, in which 12- to 18-m-wide rooms are typically excavated. The stability of these excavations can be compromised by the horizontal stress, resulting in a rockfall hazard. Rockfalls are the cause of 15% of all reportable injuries in underground limestone mines. Horizontal stress related damage can occur in the form of guttering along one or more sides of an excavation, roof beam buckling or oval shaped roof falls, with the long axis perpendicular to the major horizontal stress. Numerical analyses show that the pillar layout and orientation of the mine workings have an effect on the horizontal stress distribution within the roof. The effects of high horizontal stresses can be mitigated by orientating the heading development direction parallel to the maximum horizontal stress, reducing the number of cross-cuts and offsetting the cross-cuts to limit the potential lateral extent of horizontal stress related roof falls. The modeling approach described in this paper can be used as a tool to evaluate potential roof failure and optimize the stability of room and pillar layouts.

Jan 1, 2008

By J. C. M. De Souza

The Samarco pipeline, the longest in the world for iron ore slurry transportation, started operation in 1977 to transport concentrate from the Germano facilities, in the state of Minas Gerais, to the pelletizing plant, located 396 km away, in the state of Espirito Santo, on the south-east coast of Brazil. Designed for a nominal capacity of 12 million tons per year, the pipeline reached 15.5 million/year due to operational improvement and, in late 2005, it was resized to transport 16.5 million tons per year, with the installation of a booster station. In order to ensure the accurate performance of the system, a pipeline cleaning programme was carried out and, since it has been 29 years from the operation start-up, precise knowledge of the pipe condition would be fundamental to guarantee the success of the project. The cleaning programme demonstrated the potential of operational gains from this initiative, and its effect on the corrosion control and future measures, which should be permanently adopted to maintain the improved capacity. The intelligent pig runs provided essential data used to establish a pipeline integrity programme that allowed Samarco to develop a pipe repair plan based on the severity and significance of the features and to implement a future pipe replacement plan.

Jan 1, 2007

By J. H. van Laar, L. J. van der Walt, P. L. Crouse, H. Bissett, G. J. Puts

"SynopsisSilicon carbide nanopowders were produced using a microwave-induced plasma process operating at 15 kPa absolute and at atmospheric pressure. Methyltrichlorosilane (MTS) served as precursor, due to its advantageous stoichiometric silicon-to-carbon ratio of unity, allowing it to act as both carbon and silicon source. Argon served as carrier gas, and an additional hydrogen feed helped ensure a fully reducing reaction environment. The parameters under investigation were the H2:MTS molar ratio and the total enthalpy. The particle size distribution ranged from 20 nm upwards, as determined by SEM and TEM micrographs. It was found that an increase in enthalpy and a higher H2:MTS ratio resulted in smaller SiC particle sizes. The adhesion of particles was a common occurrence during the process, resulting in larger agglomerate sizes. SiC layers were deposited at 15 kPa with thicknesses ranging from 5.8 to 15 µm.IntroductionIt is well known that methyltrichlorosilane (CH3SiCl3 or MTS) decomposes to form silicon carbide (SiC) and hydrogen chloride (HCl) as shown in Equation [1]. The reaction kinetics and mechanisms for this reaction are thoroughly reported in the literature (Sone et al., 2000; Papasouliotis and Sotirchos, 1999; Kaneko et al., 2002; Wang et al., 2011)."

Jan 1, 2015

By E. J. Magri, D. M. Hawkins

This paper deals with an experimental programme carried out with a gold analyser in the period June to September 1979 at Loraine Gold Mines. The results were found to be reproducible, with no overall or conditional bias when the measurements were compared with those obtained from chip samples. The standard error of estimation of a 3 m reef exposure, which was the sampling interval, can be reduced by a factor of 2,5 if the complete stretch is scanned, rather than the taking of one chip sample in its centre. Complete statistical and computational procedures were developed for the fitting of the normal-Iognormal model to observed analyser data and for the determination of the most likely gold grade for a particular analyser measurement. (This corection procedure is necessary since a significant number of negative analyser measurements can be observed.) Panel averages of uncorrected scans showed a small conditional bias relative to those of corrected scans. However, uncorrected panel averages can be used for on-the-spot decisions regarding whole panels. For standard calculations of ore reserves, use should be made of corrected scans. Under reasonable assumptions, the use of the detector in the selective mining of low-grade narrow reefs such as the Basal Reef at Loraine Gold Mines, when compared with the conventional chip-sampling method, can result in a saving of as high as R40 million in present-money terms over the life of a project. The difference could be even larger in a highly variable reef like the B Reef at Loraine Gold Mines.

Jan 1, 1987