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By L. Ziyuan, S. Chunbao, K. Jue, H. Yang, S. Tichang

In this study, potassium ferrocyanide, a non-toxic cyanide precursor in dark and diffuse reflection environments, was applied as a reagent for the leaching of gold. The free cyanide ions were gradually released from the potassium ferrocyanide solution under the ultraviolet light. Orthogonal leaching experiments were performed in gold ore to analyse the effect of solution pH, potassium ferrocyanide dosage, and temperature in potassium ferrocyanide solution system under UV light. Response surface methodology (RSM) was applied to explore the role of potassium ferrocyanide in gold leaching, Optimised results showed that the gold recovery reached 67.74% in a high-alkaline environment at a 12.6 pH, 3.8 kg/t potassium ferrocyanide dosage, 62°C, and irradiance of 10mW/cm-2. The gold leaching kinetics was monitored by quartz crystal microbalance with dissipation (QCM-D) of potassium ferrocyanide solution. The results indicate that the gold extraction process consists of two processes: adsorption and leaching, and a rigid adsorption layer formed on the reaction surface. Furthermore, Xray photoelectron spectroscopy (XPS) analysis of the gold sensor surface after leaching reaction showed that -C≡N appears on the gold sensor surface, and the gold is oxidised to form AuCN complexes. Keywords: Gold leaching, potassium ferrocyanide, UV light, QCM-D, AuCN complexes

Jan 1, 2020

By B. P. von der Heyden, T. Blenkinsop, A. Mamuse

Zimbabwe hosts a varied array of coloured gemstones. With the exception of emerald deposits and several world-class pegmatites, few of the gemstone occurrences have received detailed attention from the scientific or mineral exploration communities. In the present contribution we summarize the status of knowledge of the gemstone deposits and occurrences in Zimbabwe, paying particular attention to the geological settings in which they were formed. Synthesis of this regional geological approach reveals that there may be significant exploration potential for further gemstone occurrences, particularly in the extensive pegmatite fields and in Al-enriched orogenic belts that have undergone greenschist to granulite facies metamorphism. Further socio-economic and developmental initiatives will aid in optimizing the value generation from this important sub-sector.

Feb 12, 2024

Visit to the Datsun Nissan Company's body pressing and assembly plant at Rosslyn, Pretoria, and the Claremont-Danville Tunnel on 27th February, 1970. The excursion arranged for the 27th February to the Datsun Nissan motor car assembly plant at Rosslyn, near Pretoria, in the morning and the Claremont-Danville tunnel in the afternoon was well supported by some 43 members. The visitors were met at the factory by Mr Rademeyer, the Industrial Relations Manager, and members of his staff and were taken to the artisan training centre for light refreshments. There is a well-equipped training section with an air-conditioned lecture hall; we were told that such training facilities were important because of the cosmopolitan nature of the artisan staff. The visitors were divided into small parties and taken to the tool die and jig-making section, which is perhaps the key department for a factory of this nature. There the many dies for the presses in the body pressing section, as well as the complicated jigs for body welding are made. The technique for making the castings for the dies is interesting. A polystyrene model of the casting is embedded in moulding sand. In a neighbouring foundry molten metal is pressed into the headers and burns away the polystyrene, which leaves no residue, and this exactly fills the space occupied by the model. This rough casting is then machined in large copying machines (costing as much as Rl80 000). An exact plastic model of the surface of the pressing required, set up in juxtaposition to this casting is traversed by a master stylus which operates the slave milling cutter, thereby machining the surface to close tolerances. The machined casting is cleaned up by hand and finally finished in large spotting machines, using a blue dye to show up high spots, to the fine degree of accuracy required. The body pressing section was next visited. There the large number of pressed parts which make up a vehicle body are pressed out of special deep drawing steel plate. Some of the largest presses were capable of applying a pressure of 1 200 tons and cost as much as Rl85 000 each. The visitors then followed through to the assembly section where jigs are used to hold together the many pressings, which are then spot welded into body frames. The frames go to an assembly line where they are finished to the stage for painting. The continuous crawl painting assembly line carries the frames through all the stages of prime coating with zinc phosphate sprayed on in a tunnel, followed by immersion of the lower parts in a priming bath, then drying and spray painting and baking in tunnels. The body frames, after painting, join another assembly line, where the doors, upholstery and many fittings are attached. After this stage the completed bodies are lowered onto and attached to the chassis units which are largely assembled from imported parts (engines, transmission units, etc.). From the end of the line the completed cars are driven off to the trial track and then pass through a tunnel with powerful water sprays to detect leaks in the body work. The proportion of locally made parts is just on 45 per cent. An interesting aspect of the assembly organization is that, of the 140 or 160 cars completed each day there may be included some of each of the Datsun model as well as some Renault and Alfa Romeo models models which are assembled by this company. The change from one model to another several times a day does not present any difficulty to the organization. Each section of the assembly plant 'buys' the units from the preceeding section and 'sells' to the succeeding section. This means that the responsibility of each section ends when the unit is sold to the next section. The cost of repairing any faults found subsequently is charged to the section where it is found, which puts a powerful emphasis on meticulous inspections between sections to safeguard their costs. After the tour the parties assembled at the lecture hall where a lavish cold buffet luncheon was provided by the company. After luncheon Mr A. R. C. Fowler, on behalf of the Institute, thanked the Managing Director, Mr W. J. Wilson and his staff for this most interesting and well organized visit. The party then left for the Claremont-Danville tunnel. The tunnel is being driven by General Mining Federale Kontrakteurs through the Daspoort Range, Pretoria, to link the suburbs of Danville, near Iscor, and Claremont, which at present can only be reached by a nine mile detour. It is estimated that some 6000 vehicles per day will use the tunnel. Before entering the tunnel a short talk was given by Mr Ross who is in charge of operations. He called on various officials and staff of the Consulting Engineering firm, Basil Read (Pty.) Ltd., to describe the tunnel and

By D. F. Malan, J. C. Esterhuyse

In this study we explore the use of a novel numerical modelling approach to study the effect of pillar reinforcement on pillar stability. Case studies in the literature indicate that tendons, strapping of the pillars, and shotcrete or thin spray-on liners are commonly used to reinforce pillars. No clear methodology exists to select the type of support or to design the capacity of the support required, however. This has led to ongoing collapses in some mines in spite of heavy support being used to reinforce unstable pillars. A limit equilibrium model with confinement on the edge of the pillar was used to simulate the interaction of the support with the failing pillar. The model correctly predicts that an increase in confinement will lead to a decrease in the extent of pillar failure. As the displacement discontinuity boundary element method allows for the efficient solution of largescale bord-and-pillar layouts, the effect of pillar confinement can now be studied on a mine-wide scale. Accurate calibration of the limit equilibrium model is, however, required before this method can be used for the design of effective pillar support.

May 3, 2023

By B. P. Watson, D. P. Roberts, R. A. Lamos

The Upper Group 2 (UG2) chromitite reef is a shallow-dipping stratiform tabular orebody in the South African Bushveld Complex, which strikes for hundreds of kilometres. Mining is extensive, with depths ranging from close-to-surface to 2 500 m. Pillars are widely used to support the open stopes and bords. Little work has been done in the past to determine the strength of pillars on the UG2 Reef and design was done using formulae developed for other hard-rock mines. This has led to oversized pillars with consequent sterilization of ore. In this paper we describe a back-analysis of stable and failed UG2 pillars on the Bushveld platinum mines, and provides a strength formula for UG2 pillars. The formula may be used cautiously on all Bushveld platinum mines with similar geotechnical, geometrical, and geomechanical conditions to the pillars in the database.

Aug 1, 2021

By D. -X. Li

The paper covers many literature reports of processes using nitrogenous species as an oxidant for processing refractory gold ores, especially development in the pretreatment of refractory gold minerals by nitric acid. These processes include the high-pressure and the atmospheric-pressure oxidation methods. High-pressure oxidation processes are difficult to carry out, because they require high-capital cost autoclaves. Atmospheric-pressure oxidation processes are easier to manipulate, but complete absorption and reuse of NOx is difficult or multiple-stage absorption must be established for its reuse. So, some new methods were developed, such as catalytically oxidizing technology of NOx to allow subsequent recovery of gold. Keywords: nitric acid; pretreatment; refractory gold

Jan 1, 2009

By T. Vincent, J. Steele, C. Debrunner, M. Whitehorn

This paper presents current work on the development and use of stereovision for underground mining. Information on the calibration of the cameras and the feature-matching algorithm are presented. This system uses an intensity-based approach that evaluated correspondences along the epipolar line. Once features have been identified and their distance from the cameras computed, a three-dimensional map of the muck pile is developed. The approach used here uses a ray-tracing algorithm. This approach provides an uncertainty measure along with the elevation. A discussion of the use of this modelling information in the control of the LHD is included. Keywords: Robotics, automation, LHD, underground mining, vision sensing, task automation, tele-operation

Sep 1, 2001

By D. Borman

The location of underground positions in mines has usually fallen to their survey department's. Their usual tasks include: ? installation of a high-precision peg network like the National Survey grid as beacons ? offset measurements to the sidewalls, and sometimes hangingwall and footwalls, of development tunnels and excavations ? offsetting of stoping panels for the calculation of face ? advance and the square meterage of area removed. Other departments build their observations into the plans produced by the surveyors. If more precision is required, they ask the surveyors to `elevate' their points with a theodolite. Apart from the survey peg network and `elevations' these measurements are usually planer measurements suitable for producing plans, sections and projection sheets. When the only representation medium was a sheet of paper or transparency, this was perfectly suitable. However the development of CAD models of the workings has changed all this. Full 3D representation is not properly catered for in the tool sets in current use, and needless hours are spent converting analogue-type observations into digital form. The basic survey models need to be augmented by the observations of other disciplines that are also required to locate positions underground. These include: ? the need for geologists to plott their mapping and ? borehole logs into 3D space ? the need for samplers to position their sample points accurately because the geostatistical models are biased and inaccurate ? the need for stoping width recorders to position their thickness observations to prevent errant evaluation and bonuses ? the need for rock engineers to place their mappings into 3D to build true geotechnical models to manage geotechnical stresses ? the need for production officials to receive updated face ? positions during the month so that they can manage the ? production and utilize their resources properly. This paper covers a new method of positioning profiling points to a suitable degree of accuracy. I believe the method is sufficiently simple and cheap for all to use. Historical methods Platinum and gold orebodies, especially in South Africa, are generally narrow tabular deposits. This made them suitable for depicting on a 2D medium like paper. The determination of stoping or face widths was not a problem, as the ore is removed in a single stoping process. Such 2D representations could be easily positioned using tape offsetting between survey pegs or points tied in from survey pegs. Problems of dip were handled by using 'Stope Sheets' which chose a best fit projection for the whole area depicted or by using true dip section sheets for inclined tunnels. Rolling reef and potholes were the common areas of difficulty. Most mines now model their orebody and plan the extraction in computer graphics. This means that the representation of the current workings has to change to support this trend. It now becomes a truly 3D problem. Mining officials find it inconvenient to have their actual workings in single-line depictions while their orebody is depicted with top and bottom contacts and the planned tunnels in 3D shapes. Geological models which form the basis for the resource model and planning process are often out of date, as the updating process is slow. The geological mapping has to be plotted onto sections and plans. These are then digitized into graphics by a draughtsman and checked by the geologist. Only then does the interpretation and model update take place. Potential methods to create 3D 'Actuals' Global positioning systems (GPS) Surface mines have been blessed by the advent of GPS technology. These simple-to-operate pieces of equipment and compatible software make it possible for all types of mine employees to locate themselves, and therefore to locate their observations. GPS are often inexpensive and give an acceptable degree of accuracy. Only in deep pits or close to the highwalls are observations hindered. Such technology cannot however, work underground. Ground penetrating radar (GPR) GPR is reported to be very useful for estimating the positions of potholes and faults. However it is still considered as providing an estimate, not a definite measurement. GPR is good for seeing into solid rock, not into open spaces. Inertia reading devices Experiments with inertia reading devices have been conducted on the mines. They were the forerunners of GPS for military guidance systems, and were even used for city navigation in the early 70s. They do however work best with heavy or fast-spinning gyros. Anglogold Ashanti's attempt to use them were discontinued in the mid-90s when the developers asked for an additional few million rand for a device that would weigh more than 12 kg and have a limited operational life.

Jan 1, 2006

By А. А. Vasiliev, Y. G. Seredkin, А. V. Aksenov, А. Y. Senchenko

Refractory gold-containing concentrates usually contain gold enclosed in sulphides as well as in rock-forming minerals. Another difficulty is that gold often occurs as very fine inclusions of several micrometres, and even smaller than 1 micrometre, or can be part of the mineral composition at the structure level. Processing of such concentrates is a challenge. Ultrafine grinding and further oxidation are applied for gold liberation. The paper deals with the results from the study of gold deportment using Qemscan, and atmospheric oxidation testwork involving Albion Process™ on a gold-containing concentrate with a high content of refractory gold in sulphides and gangue minerals. Albion process testing was performed at Institute TOMS with the participation of Glencore Technology Pty Ltd (Australia). Additionally, conventional cyanidation testwork was carried out for the concentrate processing. As an alternative technology of gold liberation, oxidising roasting with arsenic stabilisation was used. The results from the study make it possible to assess the efficiency of the above-mentioned methods of gold liberation, and applicability of Albion technology to recover gold from the refractory concentrate. Key words: Gold, refractory concentrate, Albion Process, atmospheric oxidation, oxidising roasting, leaching

Jan 1, 2020

By J. Witley

"Narrow tabular platinum group element deposits in the Bushveld Complex of South Africa are typically evaluated by diamond core drilling from surface. Several short deflections are drilled from each mother hole in order to obtain multiple intersections at a close spacing (less than 1 m). Examination of the intersections from deflection drilling revealed the importance of these deflections in understanding the representivity of the borehole, obtaining an estimate of the nugget effect, and mitigating the undesirable effect of the high grade variability at the ultra-short range that is a characteristic of these deposits. The use of deflections in estimation was investigated by means of a number of techniques and scenarios in order to find the most appropriate way to use them in an estimate. A significantly improved level of confidence was gained from using multiple close-spaced intersections rather than a single borehole intersection. IntroductionThe Upper Group 2 chromitite layer (UG2 or UG2 Reef) is known for its remarkable geological continuity, being traced almost uninterrupted for tens of kilometres. However, what is often less well emphasized is the high variability in platinum group element (PGE) grade and thickness (and therefore PGE content) and internal reef stratigraphy over very short distances (several metres or even tens of centimetres).This paper examines the application of short drill-hole deflections in evaluating UG2 PGE mineral resources at Marikana in the western Bushveld Complex of South Africa."

Jan 1, 2017

By X. Zhang, Z. T. Yuan, C. Zhang, H. M. Zheng, X. M. Wang, L. X. Li, N. Li

In metal mines, comminution is commonly used to liberate minerals for subsequent mineral concentration processes, such as flotation, magnetic separation and gravity separation. However, ores are aggregates of valuable minerals and their disseminated gangue minerals, and these minerals exhibit diverse comminution behaviours. In carbonate-bearing iron ores, hematite, siderite, and quartz are the predominant minerals, of which hematite is the objective recoverable mineral. In this regard, the present study aimed to identify the imperfections in siderite minerals by X-ray computed tomography (XCT), and thus quantitatively characterise their size and shape in terms of Feret diameter and aspect ratio, as well as other parameters. XCT images indicated the protogenetic ubiquity of pores <5 μm in diameter and cracks of 7-8 μm inside siderite particles. In the ground product of artificially mixed siderite and hematite, siderite particles were smaller than hematite particles. Siderite particles had a larger surface area and greater surface roughness than hematite particles of the same volume, which was attributable to the intrinsic holes and cracks in siderite particles. This study provides an insight into the relationship between the inherent imperfections of minerals and their comminution properties. Keywords: Siderite; X-ray computed tomography; particle imperfections; grinding behaviour; sliming

Jan 1, 2020

By G. Bueno, L. M. Tavares, T. M. Campos

Iron ore pellet feed pressing has been one of the first and most successful applications of High- Pressure Grinding Rolls (HPGR) in the minerals industry. Vale S.A. has been one of the pioneers in this application, currently with six HPGRs in operation in the pelletising plants of the Complexo de Tubarão (Brazil). In spite of the important advances in the technology, risks still exist when scaling-up the process from small-scale information. The present work takes advantage of the recent advances in the mathematical modelling of the HPGR performance, using the population balance model to evaluate the modified Torres and Casali model prediction in iron ore pellet feed pressing for different scales of operation. Results are presented that compare the HPGR performance in different operational scales for iron ore pellet feed pressing, demonstrating the confidence of this model-based approach for scale-up to full-scale HPGRs used in pressing iron ore concentrates. Keywords: Scale-up, HPGR, pellet feed, modelling, simulation

Jan 1, 2020

By L. A. Cisternas, R. I. Jeldres, D. Calisaya

"Flotation of copper-molybdenum sulphide ores in seawater entails critical challenges such as selective recovery of molybdenite, effective pyrite depression, and reducing the lime addition required to reach highly alkaline conditions. It is essential that laboratory flotation tests aimed at solving these problems give reliable, reproducible results and indicate the correct approach for industrial operations. Rougher flotation of coppermolybdenum sulphide ores in seawater was investigated using two different cells: a modified Denver cell and a standard commercial cell. The effect of an organic reagent on the flotation performance was tested, and the fast/slow-floating model was used to describe the results. The modified Denver cell significantly improved the reproducibility of the flotation test results, due to technological enhancements such as the impeller being driven from below without a stator, which enables the whole froth surface to be scraped with a paddle at a constant depth and rate. Organic reagents are a promising alternative to inorganic reagents for depressing pyrite in seawater. However, further studies should be conducted to investigate their impact on molybdenite recovery, as well as to evaluate the possibility of depressing pyrite after molybdenite separation. The fast/slow-floating model was found to be appropriate for describing the flotation kinetics of the copper-molybdenum ores. The parameters are useful for comparing the performance at different conditions. IntroductionOwing to the increasing scarcity of fresh water, the use of seawater mining and mineral processing is becoming increasingly important (Cisternas and Moreno, 2014). Seawater can be desalinated by reverse osmosis, but this involves considerable costs, limiting it to the big mining companies (Akgul et al., 2008; Leidner et al., 2012; Ghaffour, Missimer, and Amy, 2013). Furthermore, desalination has environmental consequences (Lee, Arnot, and Mattia, 2011); for example, a desalination plant designed to process 2.5 m3/s requires an electrical energy supply of around 30 MJ/s. To supply this power demand, a thermoelectric plant burning bituminous/sub-bituminous coal mixtures at a thermal power generation efficiency of 35% might release around 1200– 1500 t of CO2 per day. Furthermore, the effluents from desalination plants are typically discharged into the sea, and their high temperature and ionic content inevitably modifies the marine environment, with unknown consequences. The direct use of seawater is, therefore, more attractive, but it also poses major challenges since seawater contains ions that adversely affect mineral recoveries. In particular, in the flotation of sulphide ores in seawater, the floatability of molybdenite is depressed (Castro, 2012; Laskowski, Castro, and Ramos, 2014)."

Jan 1, 2017

By J. K. Pothal, S. Basu, R. Barik, P. K. Senapati, A. Dubey

The aim of this paper is to study the characteristics of limestone particles (size varies from 4 mm to 20 mm) during its transportation from open cast mines through pipes. The influence of four different size fractions of limestone samples (4–6 mm, 6–10 mm, 10–15 mm, and 15–20 mm) on pipe flow characteristics during vertical transport in a 100 mm NB hose pipe was investigated. The flow velocities in the vertically lifting pipe was varied from 0.95 m/s to 2.78 m/s and a rotary feeder of 2 to 4 tonne/hr. capacity was employed to feed the limestone samples to the lifting pipe. The pressure drop data for the different size fractions of limestone samples at different mixture velocities were analysed. The effect of input volume fraction and superficial velocity of limestone samples on hold-up ratio were discussed. It was indicated that there was no substantial increase in pressure drop of slurry samples in the studied range of concentrations (CW = 4.22% - 12.54%), particle size, and low to medium range mixture velocities with respect to water run head loss data. The hold-up for the larger size fractions (15–20 mm) of limestone samples was found to be significant as compared to smaller size fractions, which may be due to terminal settling velocities of individual fractions of the studied samples.

Mar 4, 2025

By F. M. L. Mulaudzi

Metal dusting is a corrosion phenomenon that occurs in strongly carburizing gas atmospheres at elevated temperatures. Reaction kinetics and product characterizations of Alloys 602CA and 800 were examined by scanning electron microscopy with energy dispersive X-ray analysis (SEM-EDX) and X-ray diffraction (XRD).The results showed that Alloy 602CA is more resistant to metal dusting than Alloy 800. Visual examination and SEM surface analysis showed that Alloy 800 suffered metal dusting attack after a relatively short exposure period. The amount of coke deposits increased on Alloy 800 with increased exposure from 96 to 336 hours. X-ray diffraction on the reacted surfaces identified graphite and austenite in both alloys and some iron oxides/spinel for Alloy 800.

Jan 1, 2012

By S. Blancher, A. Perroton, H Smith, T. Nzima, T. Wallmach, V. Dieudonné

Chromite beneficiation is generally performed by crushing and density separation using spirals. At the Dwarsrivier Chrome mine spiral efficiencies seam to vary, the reason for which is not evident. This sometimes results in the production of low-grade products, which are sold at relatively low prices. This paper represents a Qemscan® study that investigated mineralogical reasons for these variations. Variations in liberation of chromite particles as well as variations in chromite compositions were investigated. The results showed that the so-called low grade chromite product can be improved to become a high grade chromite product by means of a refinement in mineral processing. A detailed Qemscan® database (SIP file) was developed to account for variations in chromite chemistries. It can be shown that chemical variations with respect to Cr, Al, Mg and Fe in chromite particles reporting to the scavenger tails are larger than in the high grade product. A combination of these chemical variations together with a decrease in liberation of chromite particles in the scavenger tails can potentially help to recover more chromite particles from this specific process stream.

Sep 1, 2021

By Turgay Gurun

"Digital simulation can be used as an analytical tool to optimize the design of crushing plants without need for large-scale experimental programs.General mathematical description of a crushing operation permits the simulation of a crushing plant flowsheet under various operating conditions. The process model encompasses multistage open- and closed-circuit crushing of hard and soft rock. Crushing balances are analyzed in the light of crusher and screen performance and a comparison of different closed-circuit arrangements is made in terms of process and layout criteria.The simulation model allows comparison of process alternatives to be made in terms of equipment selection and capital and operating cost estimation. It thus provides the pertinent practical information to maximize plant efficiency, and to minimize expenditures in such items as equipment, structures, power consumption, and so on."

Jan 1, 2014

By B. Friedrich, A. Birich

Gold has been a metal of special importance for mankind for several thousand years. Its outstanding chemical resistance is an important property of this noble metal, but becomes a disadvantage when it comes to gold recovery. The established processes are based on highly aggressive and toxic reagents. Different alternative leaching reagents with a significantly lower toxicity proved to be promising alternatives in the last decades. Major research activities in this field focused on gold ores, so that leaching of secondary resources were not described sufficiently. Based on literature research and extensive experimental investigations, a reagent assessment was conducted for hydrometallurgical gold recovery from electronic waste. It was found that besides thiourea and halides, thiosulfate in particular represents an alternative of major relevance. A variety of different electronic waste (e-waste) specimens were investigated to identify suitable leaching conditions. As a result, an almost complete and selective gold recovery in less than 48 hours from different electronic waste types and components was achieved by thiosulfate leaching. Within the experiments conducted, it was found that the leaching behaviour of cyanide alternative lixiviants differ strongly from leaching of primary ores. Keywords: Gold leaching, cyanide alternative, thiosulfate, electronic waste

Jan 1, 2020

By M. -A. de Ville d’Avray, J. Bosman, S. Brochot

Dense Medium Separation (DMS) technologies are used for light (coal, lithium) or heavy (chromite, iron ore, diamonds) minerals concentration, but also for ore pre-concentration (Pb/Zn) or waste (plastics). Dense media are mainly formed from a suspension of magnetite or ferrosilicon in water. Such DMS circuit design or optimisation requires a full and detailed material balance which can be obtained by the aid of modelling and simulation tools. This balance is not limited to ore and its valuable minerals, but also the recovery of the dense medium itself. If the density is the main property used for separation, the particle size plays a non-negligible role, and, more precisely, the liberation classes which can be associated to the washability curve. The paper presents how the modelling and simulation platform USIM PAC can answer this challenge with the set of models for DMS operating units such as drums or cyclones, and their associated screens (drainage, rinsing) and magnetic separators for medium recovery. Some examples for mineral concentration will illustrate this approach. Keywords: Process simulation, process modelling, dense medium separation, process optimisation

Jan 1, 2020

By G. Akdogan, J. H. Zietsman, C. Dorfling, D. Attah-Kyei

The development of newer and improved electrical products has led to an increase in the rate at which older products are discarded as waste. The main focus of electronic waste is the printed circuit board (PCB) because of the inherently high value of contained metals such as gold and copper. Several options for treatment of the non-metallic fraction including material recycling, where the residue may be used as inclusions in concrete or asphalt materials with minimal processing or chemical recycling, where chemicals and fuels are produced from the residue using pyrolysis exist. In this paper, the utilisation of the non-metallic leached PCB waste fraction as reductant in secondary copper smelting was investigated. Analysis of the leached residue revealed that PCB is highly amorphous and has a carbon content of 28.5%, an oxygen content of 23.1%, with the ash and volatile matter contents 40.1% and 44.8% respectively. Thermodynamic simulations of secondary smelting of copper were conducted in terms of metal recovery, and the energy required when PCB was used as a reductant. The results were also compared with that of coal and PCB-coal blends. The simulations revealed that as PCB in the blend used as reductants increases, the amount of energy required for the smelting operation decreases. Metal recovery slightly decreased as the mass percent of PCB in the blend increased due to lower carbon content present in PCB relative to coal. The results also highlighted the energy saving with PCB-coal blends which was around 160 kWh per ton of feed relative to coal. The decrease in the amount of energy required for the operation is attributed to the higher volatile content of the PCB, which is also a part of the reduction process. Keywords: PCB leach residue, alternative reducing agent, secondary copper smelting

Jan 1, 2020