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By A. R. Miller

A fuel cell locomotive incorporates the advantages of its competitors, namely catenary-electric and diesel-electric units, while avoiding their disadvantages. It possesses the environmental benefits, at the vehicle, of an electric locomotive but the higher overall energy efficiency and lower infrastructure costs of a diesel locomotive. The natural fuel for a fuel cell is hydrogen, which can be produced from many renewable sources or via nuclear energy, and thus a hydrogen-fuel cell locomotive will not depend on imported oil. Hydrogen produced from renewable primary energies or nuclear energy would provide a totally zero-emissions vehicle, that is, with zero carbon in the energy cycle. A project partnership among Vehicle Projects Inc of the USA, and South African partners Anglo American Platinum, Ltd, Trident South Africa, and Battery Electric, has designed and is launching a series of five prototype fuel cell-powered mine locomotives.

Jan 1, 2012

By W. Bendaikha, S. Larbi, A. Ramdane

An oolitic iron ore from Gara Djebilet, Algeria was characterized by X-ray diffraction, scanning electron microscopy, and energy dispersive spectrosopy and the phosphorus distribution between various phases studied. Two ore types were identified – a haematite-dominated, oolitic type and a more massive, magnetite-dominated type. The haematite-dominated ore had a higher phosphorus content, up to 0.6% in the iron oxide minerals, than the magnetite-dominated type (0.3% P). Owing to the very fine-grained texture of the gangue minerals, reducing the phosphorus content to levels suitable for steelmaking (below 0.05% P) by conventiobal means would entail an energyintensive process with a high carbon footprint. Preliminary leaching test work using a sulphurous geothermal water as lixiviant, assisted by solar thermal acceleration, gave very promising results, removing 0.13% of the residual P (or 21.7% removal of total P) from the high-phosphorus oolitic ore.

Mar 14, 2024

The Annual General Meeting of the South African Institute of Mining and Metallurgy was held in Kelvin House, Johannesburg, on Wednesday, 27th August, 1980. Mr D. A. Viljoen (President) was in the chair and declared the meeting open at 4.05 p.m. Obituaries President: It is my sad duty to announce the death of the following members of the Institute: T. C. A. Meyer (Past President, 1941 to 1942); E. G. Harding, T. A. Stannard, C. T. Hardy, W. C. Jackson, J. S. Sinton, G. H. Duggan, H. H. A. Muller (Life Fellows); W. M. Frames, K. Gebhard, W. M. Walker, S. L. S. Swart, N. W. Stansmore, H. E. Allen, B. W. F. Towne, R. A. Wilson, D. Waterman (Fellows), R. M. Peterson (Life Member); D. L. Gibbs (Member); B. M. Williams (Asso¬ciate Member); D. B. T. Cresswell, P. G. Guernier (Associates). As a mark of respect to the memory of the deceased, and in sympathy with the bereaved, please rise and observe a few moments of silence. Notules President: Kan ons die notules van die Algemene Jaar¬vergadering, wat op 22 Augustus 1979 gehou was en in die September uitgawe van ons Joernaal gepubliseer is, bevestig? Bevestig.

Jan 1, 1980

By M. Z. Emad, N. Abbas, Y. Majeed

Room-and-pillar mining is commonly employed for the extraction of rock salt in undergroundmines. Pillar stress is a major concern in these mines as it is directly related to stability and mineralrecovery. In this study a flat jack method was used to measure pillar stresses in three undergroundrock salt mines in Pakistan. The field work included determination of in-situ stress, in-situ elastic modulus, recording of field variables (pillar length and width, height and width of opening, opening width to height ratio, extraction ratio, and overburden height) and collection of salt block samples. The geomechanical properties of rock salt (uniaxial compressive strength, Young’s modulus, Brazilian tensile strength, and density) were also determined to estimate overburden stress, pillar strength, and factor of safety (both estimated and actual). It was found that the measured pillar stresses are proportional to the overburden stress values, with their magnitude ranging from 6.05 MPa to 11.97 Mpa, and the pillars were found to be stable. Regression analysis was performed to develop statistical models for in-situ stress and in-situ elastic modulus. Finally a quick guideline chart was developed to determine the suitable length of pillar for a given span and required level of safety.

Jun 5, 2023

By B. F. Giyani, A. Salama

Tanzania is a country with a variety of mineral deposits, including metallic minerals, gemstones, mineral fuels, industrial minerals, and critical minerals. This study provides an overview of mining legal framework, mineral occurrence and production, challenges in the mining sector, and government initiatives. The aim is to demonstrate the development of the mining sector in Tanzania and explore the potential for further mining investment in the country. The mineral production data showed generally increasing trends over the years, for example, gold production increased from 42 tonnes in 2018/2019 to around 50 tonnes in 2023/2024. Despite the growth, the mining sector encounters several challenges, including a lack of detailed geological information on mineral deposits, inadequate infrastructures in some remote mining sites, the existence of informal artisanal miners, and mineral smuggling. The Tanzanian government has introduced several initiatives to address these challenges, including carrying out the highresolution airborne geophysical survey to increase geological information in some areas, the formalisation of artisanal and small-scale mining, establishing mineral markets to combat mineral smuggling, and encouraging mineral value addition within the country.

Oct 24, 2025

By M. Grave

Rock Engineers are required to design safe cost effective support systems and stoping layouts for their respective mines. As each stope has its own unique environment, continual re evaluation is required in all stopes to maximize extraction and achieve value from the support standard. This paper presents numerical modelling used to plan early mining within the shaft pillar and a reevaluation of an existing stope support standard.

Jan 1, 2009

By B. McFadzean, M. Tadie, T. Dzingai, M. Becker

Ores from a single deposit may exhibit extensive variability in their mineralogy and texture. The ability to quantify this variability and link it to mineral processing performance is one of the primary goals of process mineralogy. This study focuses on the effect of alteration in three platinum group element ore samples from the Great Dyke in Zimbabwe – two of which were more pristine compared to the third, which was locally classified as ‘oxidized’ ore. These ores are known to be characterized by varying degrees of alteration, resulting in numerous challenges in flotation and affecting both grade and recovery. Alteration, by near-surface oxidation, of the valuable base metal sulphides and platinum group minerals resulted in lower flotation recoveries of Cu, Ni, Pt, and Pd. Evidence of incipient oxidation was more readily observed in the base metal sulphide assemblage than the platinum group mineral assemblage, even though the loss in recovery (because of oxidation) was most significant for Pd. Alteration through hydration resulted in a significant increase in mass pull and dilution of concentrate grade through the inadvertent recovery of naturally floating gangue comprising composite orthopyroxene and talc particles. In this study, the amount of naturally floating gangue was more strongly correlated with the talc grain size distribution than the grade of talc in the flotation feed. The oxidation and hydration alteration reactions are not necessarily mutually exclusive, although one may be more dominant than the other, giving rise to ore variability.

Sep 1, 2021

By J. W. Klokow, S. L. Mulder

Early removal of the shaft reef is usually considered necessary on deep level South African gold mines to avoid damaging stress build-up associated with traditional shaft-protection pillars. In the case of the relatively shallow Beatrix Gold Mine it was largely motivated by early access to ore and the consequent earlier return on invested capital. A number of options were considered to protect the shaft from possible damaging stress changes and to minimise deformations in the shaft-reef area. Numerical modelling was used to evaluate the options and to quantify as accurately as possible the likely deformations to be accommodated by the shaft steelwork designs. The option chosen was a combination of strategically placed satellite pillars and yield pillars, and backfill. Following the mining of a small inner cut during the shaft sinking process, full-scale mining is progressing away from the shaft. Suitable instrumentation has been installed to monitor deformations associated with the shaft reef removal. Enlever rapidement le filon du puits est en général considéré nécessaire dans les galeries de fond des mines d’or sud-africaines pour éviter l’accumulation nuisible de contraintes associée aux piliers de protection de puits traditionnels. Dans le cas de la mine d’or Beatrix, relativement peu profonde, l’enlèvement était motivé en grande partie par l’accès rapide au minerai et par conséquent un profit plus rapide sur l’investissement. Un certain nombre d’options furent considérées pour protéger le puits contre les changements de contraintes potentiellement nuisibles, et pour minimiser la déformation dans l’aire puits/filon. La modélisation numérique fut utilisée pour évaluer les options et pour quantifier aussi précisément que possible les déformations probables que la conceptualisation du puits devrait prendre en compte. L’option choisie fut une combinaison de piliers satellites placés à des points stratégiques avec des piliers de protection, et terre de remblayage. Pendant le fonçage de puits une petite coupure intérieure fut exploitée, et maintenant l’exploitation à grande échelle, au-delà du puits, est en cours. Les instruments nécessaires ont été installés pour surveiller les déformations associées à l’enlèvement du filon du puits. Die frühe Entfernung des Riffschachtes wird normalerweise bei südafrikanischen Tiefbaugoldmienen als notwendig erachtet um den zerstörende Druckaufbau zu vermeiden, welcher mit traditionellen Schachtschutzpfeilern verbunden ist. Im Fall der verhältnismäßig flachen Beatrix Goldmine war es hauptsächlich vom frühen Zugang zum Erz und dem konsequenten frühen Rückfluß des investierten Kapitals motiviert. Eine Anzahl an Optionen wurde erachtet um den Schacht vor möglichen zerstörenden Druckänderungen zu schützen und Deformationen im Riffschachtbereich zu minimieren. Um die Optionen zu bewerten und mögliche Deformationen so genau wie nur möglich quantitativ darzustellen die von den Schachtstahlkonstruktionen aufgenommen werden müssen, wurden numerische Modelle verwendet. Die gewählte Option war eine Kombination aus strategisch plazierten exzentrischen Pfeilern und Schutzpfeilern sowie Hinterfüllungen. Nach dem Vortrieb eines kleinen inneren Einbruches während des Abteufens wird der Vollvortrieb vom Schacht weg vorgenommen. Um die Deformationen, die mit der Riffschachtentfernung verbunden sind zu überwachen, müssen geeignete Instrumentenausrüstungen installiert werden.

Jan 1, 2003

By L. Schernikau, W. H. Smith

Oil, coal, and gas account for approximately 80% of global primary energy, but only a portion of total airborne CO2 eq (approx. 35% at GWP20 to 65% at GWP100), even though they account for 95% of total measured CO2 emissions. The benefits of these energy sources, as well as their related costs, are not all incorporated in current energy policy discussions. Global greenhouse gas policies must include documented changes in measured airborne CO2 eq to avoid spending large amounts of public funds on ineffective or sub-optimal policies. The authors examined airborne CO2, which is less than half of emitted CO2, as well as reported CH4 emissions and the global warming potential of CH4 as published by the IPCC for coal and natural gas. The surprising conclusion is that surfaced-mined coal appears ‘better for the climate’ than the average natural gas, and all coal appears beneficial over LNG. Therefore, current CO2-only reduction policies and CO2 taxes are leading to unintended consequences and the switch from coal to natural gas, especially LNG, will not have the desired impact of reducing predicted future global warming; in fact, quite the contrary. A large portion of anthropogenic global warming is attributed by the IPCC and IEA to CH4, but it must be noted that CH4 emissions from natural sources and from agriculture account for approximately 40% and 25% of annual global CH4 emissions respectively. Energy accounts for about 20% of documented CH4 emissions. CO2 contributes only approximately 35% of annual airborne anthropogenic GHG emissions after accounting for CH4, over a 20-year horizon. At a 100-year horizon, the contribution of CO2 increases to approximately 60%. Energy policies that do not consider all GHG emissions along the entire value chain will lead to undesired economic and environmental distortions. All carbon taxation and CO2 pricing schemes are incorrect and need to be revised. At IPCC’s GWP20 an approximately 2%1 higher loss of CH4 across the value chain prior to combustion of natural gas versus coal will lead to ‘climate parity’ of coal with natural gas. According to public data, natural gas value chains have high CH4 and undocumented CO2 losses. On a global average, using only IEA-documented CH4 data, natural gas emits approximately 15% more CO2 eq than surface-mined coal, over a 20-year horizon. This difference will increase as the use of shale gas and LNG expands. Investors should support all energy systems in a manner that avoids an energy crisis, including intermittent renewable energy systems where they make sense. If CO2 emissions need to be reduced, one of the most effective ways would be to install ultra-supercritical power plants with CCUS technology. However, the undisputed benefits of increased CO2 concentrations in the atmosphere because of its promotion of photosynthesis and plant growth effects (fertilization) need to be considered in energy policy decisions as well. The authors suggest that future research and development should concentrate on reducing net emissions from fossil fuel power plants and providing cost-effective and reliable new conventional power generation capacity, utilizing clean coal and clean natural gas technology.

Mar 2, 2022

By T. Lee

The mining industry, both here and internationally, is continually developing increasingly sophisticated software to compute mineral resource estimates, but these processes cannot compensate for a flawed geological interpretation of the geology of the economic commodity(s) concentrations. Quality assurance and quality control (QA/QC) is becoming increasingly common in association with the sampling and assaying practices within the industry. However, it is rare in the case of a geological interpretation associated with mineral resource estimation. Why? In the context of this paper, QA/QC relates to the use of statistical and graphical tools to show that the geological economic commodity concentrations have been appropriately domained. Domaining is essential to improve the chance of getting a mineral resource estimate right. Commodity value and acceptable concentration variation within a mineral resource can be ingredients that make mineral resource estimation difficult to get right. But it is possible to get it right a very high proportion of the time. It is more likely to occur when inappropriate data consolidation is minimised. In any case, inappropriate data consolidation is significantly reduced when the geological interpretation is strongly consistent with the data and it is demonstrable. To achieve quality global estimates of geological domain concentrations, it is essential that the geology of the prospect is understood sufficiently that the deposit is appropriately domained. Appropriate domaining occurs when sample populations are separated in such a way that only data in harmony with each other within the population contributes to the domain's concentration estimate. The paper will use four brief case studies to illustrate how QA/QC can be used to display data and validate the underpinning geological interpretation through its associated domaining to get it right when it comes to a mineral resource estimation.

Jan 1, 2007

By O. S. L. Bruinsma, M. J. Matsela, D. J. van der Westhuizen

The free ligand (FL) model is an intuitive model to calculate the equilibrium concentrations in solvent extraction (SX) based on the distribution coefficient (Kd) at infinite dilution and the fraction of free ligand available for extraction. In this work, the FL model is validated to account for co-extraction of Ni and for designing the extraction and scrubbing sections of Co/Ni separation in a base metal refinery. Cyanex 272 is employed as a selective Co extractant in the process to yield high purity Ni. To enhance the loading capacity of the extractant, 50 mol% of NaOH is pre-loaded into it. Experimental and FL modelling results show that four equilibrium stages are required to purify the 99% Ni feed to a 99.97% Ni raffinate. The 53.59% co-extract with 26.76% free ligand is purified with a reflux scrub of 30 g Co/L in one equilibrium stage to 99.01%, Co in the scrubbed extract. The FL model as well as the Co/Ni/Na-analysis of the aqueous phase confirm that in the scrubbing section, Ni in the extract is mainly replaced by Co. Finally, in the one stage stripper the Co concentration in the scrubbed extract is increased from 5.6 g Co/L in the extract to 30.5 g Co/L that is partially used as reflux scrub liquor.

Dec 11, 2024

Book review Pearson, J. S. Ocean floor mining. Park Ridge (New Jersey), Noyes Data Corporation, 1975. 201 pp. NIM reports Report no. 308 A mineralogical study of gold particles in pulp residues from the Bracken Gold Mine. (7th Mar.,1968. Re-issued Oct. 1975.) Report no. 377 Examination of pulp samples, treated with cyanide, for coated gold.(7th Aug., 1968. Reissued Oct.1975.) Report no. 385 The determination of the nature of coatings on gold particles. (2nd Aug., 1968. Reissued Oct. 1975.) Report no. 452 The Purlex Process - a description of the pilot plant leading to the use of the process in South Africa. (13th Jan., 1969. Re-issued Oct. 1975.) Report no. 482 Review of work on the treatment of pegmatites. (9th Apr., 1969. Reissued Sep. 1975.) Report no. 1443 Gravity concentration tests on four samples from Tantalite Valley,S. W.A. (5th Jul., 1972. Re-issued Sep. 1975.) Report no. 1489 The breakage of S oderberg electrodes. (10th Nov., 1972. Re-issued Nov. 1975.) Report no. 1545 A mineralogical investigation of leach residues from the Blyvooruitzicht Gold Mine. (22nd May, 1973. Re-issued Nov. 1975.) Report no. 1583 Preliminary tests on winnowing for the recovery of mica. (12th Nov., 1973. Re-issued Sep. 1975.) Report no. 1652 The identification of diamonds from Premier, Finsch, and Jagersfontein Mines by statistical analysis of data obtained from instrumental neutron-activation analysis. Report no. 1723 The determination of zirconium and aluminium in zirconiumaluminium alloys. Report no. 1739 The determination of trace amounts of noble metals in sulphate media. Report no. 1771 The determination of silver, selenium, tellurium, antimony, tin, lead, and arsenic in anode sludges. Report no. 1772 A study of copper recovery by lime roasting and leaching. Corrigendum The Special Issue of Volume 76 of the Journal ('Recent Advances in Mineral Dressing, October 1975) should be corrected as follows. The South African Institute Of Mining And Metallurgy - Information On Membershlp The Institute was founded in 1894 as the Chemical and Metallurgical Society of South Africa. In 1904 it was reconstituted as the Chemical, Metallurgical and Mining Society of South Africa and in 1956 it became the South African Institute of Mining and Metallurgy. Die Suid-Afrikaanse Instituut vir Mynbou en Metallurgie - Inligting Oor Lidmaatskap Die Instituut is in 1894 gestig as die Chemiese en MIetallurgiese Vereniging van ::!nid-Afrika. In 190-1is dit omvorm tot die Chemiese Metallurgiese en Mynbouvereniging van Sllid-Afrika en in 1956 het dit die Suid-Afrikaanse Instituut vir Mynbou en l\Ietallurgie geword.

Jan 2, 1976

By P. W. J. van Rensburg

Our mineral heritage - PRESIDENTIAL ADDRESS given by P. W. J. van Rensburg, Pr. Eng.. B.Sc. (Eng.)(Rand) INTRODUCTION Stone Age people were living in various parts of South Africa as recent,ly as a thousand years ago, when they were displaced by Iron Age people with a culture developed in the far north. These invaders brought farming, building, and the earliest mining developments to the Transvaal, thus ushering in the beginning of our great mineral heritage. It is of particular interest to record that, up to comparatively recent times, some of these people were excavating iron-bearing shale rocks for their smelting furnaces on the Melville Koppies in J ohannesburg. Although the most recent the iron-smelting furnaces discovered on these koppies is estimated to be some five-hundred years old, it believed that these Iron Age people were driven out, and their settlements destroyed, by Zulu impis only one-hundred-and-fifty years ago.

Jan 10, 1973

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 22nd August, 1973. Dr J. P. Hugo (President) was in the Chair. There were also present 64 Fellows, 20 Members, 5 Associates, 3 Students, and 34 Visitors, making a total of 126. The President declared the meeting open at 4.05 p.m. OBITUARIES The President: It is my sad duty to announce the death of the following members of the Institute C. Boocock, R. J. G. Moore, M. P. Pearse, and A. I. Sussman, all Fellows, and W. T. Dalling, a Life Member. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. MINUTES Die President: Item twee op die agenda is die bekragtiging van die notules van die jongste Algemene Vergadering van die Instituut. Daar die notules in die Augustus uitgawe van die Joernaal gepubliseer is, vra ek u toestemming dat dit as sulks bekragtig word. Toestemming verleen. WELCOME TO VISITORS The President: It is my very great pleasure to welcome all the distinguished guests who have honoured us with their presence this afternoon; in particular, a hearty word of welcome to the Honorary President of the Institute, Mr Plumbridge, the President of the Chamber of Mines. You are doubly welcome here, sir, and we thank you for your presence. Also to that old member and stalwart, the Honorary Vice-President of the Institute, Mr Tommy Gibbs, the Government Mining Engineer-you're very welcome, Mr Gibbs. Then, we are particularly privileged this afternoon to have an Honorary Member with us, the Minister of Mines for Rhodesia, Mr Dillon. You will recall that he honoured us with his company last year. Mr Dillon, we are very appreciative and hope that this is now a standing arrangement. We are also honoured by the presence of some thirteen Presidents, Vice-Presidents, or Chairmen of our sister scientific and technical organizations. I shall rapidly read their names, but they must all feel assured that they are very welcome here today. Firstly, one of our own Past Presidents and members, Mr Geoff Goode in his capacity as President of the Associated Scientific and Technical Societies of South Africa; Mr L. R. Robinson, President of the South African Institution of Mechanical Engineers, and Mrs Robinson; Mr G. Goedhals, President of the South African Institute of Electrical Engineers ; Dr Antrobus, President of the Geological Society of South Africa, and Mrs Antrobus; Mr T. V. Dean, Vice-President of the Institute of Land Surveyors of the Transvaal, and Mrs Dean; Mr R. M. Stroh, President of the Mine Ventilation Society of South Africa; Mr Ken Steele, President of the Association of Mine Managers, and Mrs Steele; Mr Mike Gericke, President of the South African Council for Professional Engineers; Mr R. G. Matthews, President of the Institute of Mine Surveyors of South Africa; Mr P. H. Pettifor, President of the Institute of Production Engineers, London, and Mrs Pettifor ; Dr Nico Stutterheim, Chairman of the South African Institute of Chemical Engineers, and Mrs Stutterheim; Professor F. A. van Duuren, Chairman of the Engineers' Liaison Committee in Pretoria; also, I haven't spotted him but I trust he is here-Mr Alex Bain, who is Chairman of this Institute's Witbank/Middelburg Branch. To one and all, ladies and gentlemen, a hearty word of welcome. Not last on our list, a word of welcome to Mr Eric Boden, the Manager of A.S. and T.S. We also have with us I trust, Dr Deist, and his good lady-Dr Deist will be figuring in our proceedings later this afternoon. Also Mr Barcza and Mrs Barcza. Mr Bareza, a former President of the Institute, also has a task to perform. Then, I hope two of our student prize winners are here-Mr Beetge and Mr Painting. Then we also have Mr Roberts, who is welcome in his capacity as co-author with Dr Deist. Then, last of all, a hearty word of welcome to Dr Helen Glen (I am not sure whether she has arrived yet, but she is certainly due to come)-the new Honorary Editor of the Institute's Journal. MEMBERSHIP The President: I have pleasure in announcing that, their names having been published in accordance with By-law 5.2.2, the following have been elected by Council to membership in the following grades Fellows: W. G. Jayes and F. K. Wright Members: D. W. Penman, A. W. Bryson, and D. L. Gibbs Graduates: R. J. Adey, J. P. Bond, R. C. Dunne, G. M. Entwhistle, J. M. Rendu, J. P. S. Turner, and A. P. van Jaarsveld Associates: A. Ellis, B. R. Hambly, A. J. Johansen, and G. W. Tregoning

Jan 10, 1973

By A. N. Brown

The Eighteenth International Symposium on the Appli¬cation of Computers and Mathematics in the Mineral Industries was held in London from 26th to 30th March, 1984. The Symposium was organized by the Institution of Mining and Metallurgy under the leadership of Mr M.J. Cahalan, Chairman of the Organizing Committee. The venue chosen was the Royal School of Mines, Imperial College of Science and Technology, in South Kensington. Some 300 delegates from all parts of the world attended, which included a delegation from South Africa that numbered about 20 persons. This extremely successful series of international meet¬ings was begun in 1961 in Tucson, Arizona, and has grown in strength and importance over the years. The arrange¬ment of the symposia is regulated by the International Council for APCOM under the Chairmanship of Professor R.V. Ramani (U.S.A.), the other current members being Professor J. Elbrond (Canada), Dr Thys B. Johnson (U.S.A.), Professor Young C. Kim (U.S.A.), Professor D.G. Krige (R.S.A.), Professor A.J. Lynch (Australia), Professor C.T. Shaw (U.K.), Dr A. Weiss (U.S.A.), and Professor F.L. Wilke (F.R.G.). There is no doubt that the enthusiasm and dedication of this small group of people and the excellent working relationship that exists between them are responsible for the continued success of APCOM meetings.

Jan 1, 1984

By P. O. Osifo, K. Premlall, X. Goso, R. H. Matjie, M. R. Mulaudzi, J. R. Bunt, K. Mphahlele

This study investigates the transformation of pyrolytic spent tyre-derived char and crumb rubber into high-performance activated carbon chars for industrial wastewater remediation. Utilising an in-house macro-thermogravimetric analysis system under an argon atmosphere, spent tyre-derived activated carbon char were synthesised via physical temperature activation and aqua regia demineralisation. Comprehensive characterisation using x-ray diffraction, Raman spectroscopy, and scanning electron microscopy, revealed a predominantly amorphous structure with nanoscale crystallites (~1 nm) and active surface functional groups. Proximate analysis confirmed that both crumb rubber and leached tyre crumb rubber with aqua regia derivatives achieved favourable compositions (ash ≈ 9.6%; fixed carbon ≈ 84%), comparable to commercial activated carbon (AC). At an optimal activation temperature of 850°C, the char of tyre crumb leached with aqua regia variant exhibited a significant surface area of 300 m²/g. Crucially, the tyre crumb char produced at 850°C variant developed a pore volume of 0.8 cm³/g—effectively doubling that of commercial activated carbon (0.4 cm³/g)—facilitating the sequestration of large organic molecules. In application tests using high-strength starch wastewater, char of tyre crumb leached with aqua regia and tyre crumb char, both produced at 850°C, achieved total organic carbon removal efficiencies of 60% and 50%, respectively, bridging the performance gap between waste-derived and commercial adsorbents. These findings validate waste tyres as a viable, low-cost precursor for industrial-grade adsorbents, offering a sustainable circular economy route for tyre valorisation and reduced industrial disposal costs. Future research will focus on kinetic modelling and the recovery of zinc from spent tyre-derived activated carbon char residues.

Mar 30, 2026

DD3-tunnels (PD BH's) ? Rotary coreholes 111no. (124) ? Percussion holes Ono. (37) ? Sampling (rock and soil) ? Soil and rock permeability ? testing ? BH Televiewer Surveys [ ]

Jan 1, 2007

By O. Barron, C. Felix

In 2023, polymer electrolyte membrane fuel cell membrane electrode assemblies accounted for about 62% of the global fuel cell market share and this demand is expected to grow. Commercialisation requires technologies capable of cost-effective, high-volume manufacturing. The membrane electrode assembly is crucial and represents a significant cost to polymer electrolyte membrane fuel cell manufacturing. Manufacturing the electrode components for membrane electrode assemblies at high volumes can reduce production costs while delivering on the forecasted industry demands. Roll-to-roll is a mature coating technology applied in various manufacturing industries such as batteries, printed electronics, microelectronics, photovoltaics, printing, paper consumables, etc., with significant potential for polymer electrolyte membrane fuel cell manufacturing. While the high-volume production process for membrane electrode assembly manufacturing differs from laboratory-scale, the membrane electrode assembly structure remains unchanged. Roll-to-roll is a continuous coating process with speeds of 10 m/min being achieved. In this work, MicrogravureTM and slot-die coating methods have been adopted and have shown promising outcomes for producing gas diffusion electrodes for membrane electrode assemblies. An overview of the MicrogravureTM and slotdie coating methodologies is provided, and a discussion on preliminary results and challenges are presented. Work on MicrogravureTM gas diffusion electrode manufacturing has already achieved comparable performance with spray-coated gas diffusion electrodes. The influence of coating parameters and drying on the coated catalyst layer quality is discussed.

May 27, 2025

By J. A. L. Napier

One of the most important characteristics of tabular mine stress analysis is the need to represent the complex evolution of mining face positions and the accompanying induced stress changes in the rock mass. Integration of seismic activity with numerical modelling requires flexible and efficient solution schemes in which both off-reef damage and large-scale fault slip can be effectively represented. A new approach is investigated in which the stope closure and ride variables can be found using a moving least squares estimator. Some advantages of this approach over traditional element-based tessellation schemes are identified. At the same time, shortcomings of this method are noted when the displacement discontinuity variable is approximated by a polynomial shape function. Difficulties and possible solutions to the shape function formulation near excavation edges are discussed. Une des caractéristiques les plus importantes de l’analyse des contraintes minières tabulaires est la nécessité de représenter la complexe évolution des positions du front de taille et des changements concomitants des contraintes occasionnées dans la masse rocheuse. L’intégration de l’activité sismique avec la modélisation numérique requiert des projets souples et efficaces qui permettent la représentation des dommages hors-filon et des glissements de faille à grande échelle. Une approche nouvelle est étudiée qui permet de trouver la fermeture de la taille et les variables de montage en utilisant un estimateur par les moindres carrés mobile. Certains des avantages de cette approche sur les traditionnels projets basés sur une structure en mosaïque sont identifiés. En même temps, les défauts de cette méthode sont notés lorsqu’on calcule la variable de discontinuité du déplacement approximativement par une fonction de forme polynomiale. Les difficultés et solutions possibles à la formulation de la fonction forme près des bords d’excavation sont discutés. Eine der wichtigsten Charaketeristika der taublaren Grubenspannungsanalayse ist die Notwendigkeit, die komplexe Entwicklung der Abbaupositionen und der damit verbundenen induzierten Spannungsänderungen der Gesteinsmasse neu vorzulegen. Die Integration der seismischen Tätigkeit mit einem numerischen Modell erfordert flexible und effiziente Lösungsschemata, in denen sowohl Schäden ausserhalb des Riffs als auch Verwerfungen großen Ausmaßes effektiv dargestellt werden. Ein neuer Vorstoß wird untersucht in welchem die Strossenschliessung und Schneisenvariablen unter Verwendung des Schätzwertes der kleinsten quadratischen Abweichungen (Gaussscher Schätzwert) gefunden werden. Einige Vorteile dieser Annäherung im Vergleich zu der traditionellen Element-basierenden Tessellation sind identifiziert. Gleichzeitig werden Unzulänglichkeiten dieser Methode vermerkt, wenn die Verschiebungsdiskoniuitätsvariable durch eine polynomische Formfunktion angepaßt wird. Schwierigkeiten und mögliche Lösungen zur Formfunktionsformulierung nahe Exkavationsrändern werden besprochen.

Jan 1, 2003

By I. Satola, J. Aromaa

In this work we have reviewed methods to classify corrosivity of ground waters. Weight loss and stress corrosion cracking (SCC) corrosion tests have been done for rebar and steel strand. No clear indication of SCC was found. The application of tensile stress to 85 % of yield strength increased general corrosion rate significantly in very corrosive waters. The effect of corrosion protection on the axial behavior of steel strands was determined by double pipe axial tests with different embedment lengths. The results showed a significant difference on behavior between epoxy-coated steel strands, galvanized steel strands and plain steel strand. Dans la présente étude, nous avons passé en revue des méthodes permettant de classifier la corrosivité des eaux souterraines. Des tests portant sur les pertes de poids et sur la corrosion FCC (la fissuration par corrosion sous contrainte) ont été effectués pour les barres d’armature et les torons. Aucune indication nette de FCC n’a été constatée. L’application d’une contrainte de traction allant jusqu’à 85 % de la limite d’élasticité a accru de manière significative la vitesse générale de corrosion dans les eaux très corrosives. L’effet de la protection contre la corrosion sur le comportement axial des torons en acier a été déterminé au moyen de tests axiaux à double tube avec des longueurs d’enrobage différentes. Les résultats ont mis en évidence une différence significative quant au comportement entre les torons en acier à revêtement époxy, les torons en acier galvanisés et les torons en acier standard. In dieser Arbeit haben wir Methoden geprüft, die korrosive Wirkung des Grundwassers einstufen. Gewichtsverlust- und SCC-Korrosionstests wurden für Stahlstäbe und Drahtlitzen durchgeführt. Es wurden keine sicheren Hinweise auf Spannungsrisskorrosionsbrüche gefunden. Bei Anwendung einer Dehnbelastung von 85 % der Streckspannung bzw.Ergebnisstärke stieg die allgemeine Korrosionsrate in stark korrosivem Wasser deutlich an. Die Wirkung des Korrosionschutzes bei axialem Verhalten von Stahldrahtlitzen wurde durch axiale Tests an Doppelleitungen unterschiedlicher Versenkungslänge determiniert. Die Ergebnisse zeigten im direkten Vergleich von epoxidbeschichteten, galvanisierten und normalen Stahldrahtlitzen beachtliche Unterschiede im Verhalten auf.

Jan 1, 2003