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By Andre Vien, D. H. Hendriks, D. Willet, B. C. Flintoff

"For many years the training of mill operators was an informal process which involved senior operators training junior operators on an as-needed basis. Recognizing the needs and benefits of better training some companies, and even some provinces through legislation, have moved to ensure that a formalized training program exists in the plants. These programs tend to focus on basic safety and operations. Much remains to be done. With the more rapid incorporation of new processing and information technologies, and the goal to keep labour costs to a minimum by doing more with less, operator training has become a critical issue. This paper briefly examines the evolution of training programs, provides some measure of their effectiveness, and explores some recent developments which could have a very significant impact on the industry.PreambleOne can draw an analogy between operator training and the mechanical support of production equipment. When we buy a piece of process equipment it is critical that the mechanical installation be done properly to ensure that the device will operate at peak performance on start-up. Once the equipment is running, some form of preventive maintenance is required to ensure continued efficient operation. The operators and the equipment are both elements of the processing system, yet the former do not seem to get the same ""start-up"" or ""operating"" support. Are they not seen as critical to efficient operation? Why is this so? What impact does it have? How can we improve?These are all very logical and important questions, although the answers are not nearly so obvious. In the mineral processing industry, progress in operator training over the past thirty years has been limited and quite variable. To address the perceived need for a more coherent and consistent approach, some provinces have moved to incorporate basic training requirements in their legislation. Some plants have gone a few steps further by building integrated training programs into their operating culture. One conclusion which can be easily reached is that there are no standards, and that the range of training activity is great. In other words, a flotation operator is not a flotation operator is not a flotation operator. Their knowledge and skills are very much a function of training and experience, which are clearly corporate and site specific."

Jan 1, 1994

By I. Mc Dougall, H. Joubert, G. de Villiers

The use of sidewall copper cooling systems to prolong furnace campaign life is becoming an accepted technology solution in the base metals industry. Tenova Pyromet has designed and installed a number of sidewall copper cooling systems in base metals furnaces, including the platinum industry. Apart from increasing the furnace campaign life through the formation of a stable freeze lining, a well-designed copper cooling system enables the plant operator to focus more on optimizing the process to achieve throughput and recovery targets, and to accommodate more varied and available concentrate feed blends. The paper discusses the design of sidewall copper cooling systems for copper smelting and converting furnaces to achieve the above objectives. More specifically, the design of copper cooling systems for top submerged lance furnaces are discussed. An overall increase in furnace heat losses has been raised as a concern for intensively cooled sidewalls. The paper explores the overall heat loss expectations for copper cooled furnaces versus traditional refractory lined furnaces. In addition, the potential use of alternative cooling media is discussed. INTRODUCTION Base metal smelting and converting furnace technologies have been evolving continuously over the past century to satisfy the need for higher throughput, improved efficiency, and longer campaign life. To accommodate these demands, in particular higher smelting intensity and throughput, furnace bath containment systems had to improve. The use of pure refractory lining systems has slowly made room for the use of more intensively cooled lining systems (Joubert, Nikolic, Bakker & Mc Dougall, 2016). These cooling systems evolved from external shell cooling, such as shower or film cooling, to copper plate coolers extending into the furnace refractory lining, and high intensity stave or panel coolers (Verscheure, Kyllo, Filzwieser, Blanpain & Wollants, 2006). Consequently, an increasing number of base metal smelting and converting furnaces are equipped with copper cooling systems, including flash furnaces (Bryk, Ryselin, Honkasalo, & Malmstrom, 1958; Yasuda, Motomura & Kawasaki, 2014; Marx, Shapiro & Henning, 2010), top submerged lance primary smelting and fuming furnaces (Bhappu, Larson & Tunis, 1994; Kim, Lee & Lee, 2000; MacRae & Steinborn, 2018), top submerged lance converting furnaces (Viviers & Hines, 2005; Nikolic, Hogg & Voigt, 2018), primary platinum smelting electric furnaces (Nelson, Stober, Ndlovu, De Villiers & Wanblad, 2005; Jones, 2005; Hundermark, De Villiers & Ndlovu, 2006; Mc Dougall, 2013), and electric slag cleaning furnaces (Joubert, Nourse, Masters & Hundermark, 2005).

Jan 1, 2019

By Paul E. Mather, Matthew J. M. Krane

Anode or fire refining is the final pyrometallurgical step in the production of copper anode. Part of this process purifies liquid copper by reducing its dissolved oxygen with a natural gas-steam mixture. Until now there have been no transient models of this process coupling the injected gas jet mass transport with its chemical reactions. A transient, 1D flow, chemical reaction model was made to estimate the time-dependent behavior of anode copper composition, soot formation, and the transient gas jet composition along its height. Model estimates were made for reduction rate, soot emission rate, and exergy loss and destruction distributions for two melt temperatures and a range of steam addition rates. It was found that increases to melt temperature and steam addition rate increased reduction rate and decreased soot emission, while having little effect on exergetic performance. Estimates for reduction histories were compared to industrial data. INTRODUCTION Anode/fire refining is the final pyrometallurgical step in the production of copper anodes; it is essential for removing dissolved gases which cause porosity in cast anodes. Despite its significance, the open literature appears devoid of any transient models of the entire process; furthermore, there are very little published process data with which to validate any models made. This dual dearth of modelling work and process data inhibits studies of the tradeoffs between process and performance changes, desirable for decreasing reduction time and soot formation as well as quantifying changes in the exergy losses and destructions of the process. This work introduces a reduced-order, transient model of reduction during fire refining, examines performance trends with operating conditions, and compares model estimates with industrial data. Overview of anode refining The purpose of anode refining is to produce liquid copper which can be cast with minimal gas porosity, which disrupts the downstream electrorefining process. Dissolved sulfur is removed first, then oxygen, by reactions with different injected gases. The removal of oxygen (the reduction step) is the subject of this proceeding and is effected by the bubbling of natural gas, typically mixed with steam, through the melt from tuyeres. A typical refining run reduces dissolved oxygen from 3000 ppm to 300 ppm in 2–3 hours (Schlesinger, King, Sole, & Davenport, 2011). The refined copper is then cast as anodes. Figure 1 shows a schematic of the furnace vessel.

Jan 1, 2019

By S. Papanakli, Th. Rondoyanni, N. Sabatakakis, K. Kavoura, G. Tsiambaos

"A representative composite fault-related landslide of the Corinth Gulf graben named “Panagopoula” is reported that considered to be one of the most prone to slope instability sites along the main motorway and railway connecting Athens with the city of Patras. The presence of tectonically highly sheared and weathered geological formations, including Alpine basement (mainly flysch) contributes to the site instability, triggered/reactivated by seismic activity and heavy rainfalls. Although a series of remedial measures have been already constructed, the inclinometer readings during the last twenty years time period show a continuous very slow movement which indicates that the landslide is still ""active"". This fact has resulted to divert the axes of the new motorway and railway through twin tunnels which are under construction. INTRODUCTIONThe spatial and temporal evolution of landslides in the case of structurally complex slopes is lithologically and often structurally controlled while their type and frequency are mainly related to tectonic and lithological anisotropy (Baron et al. 2005; Hradecky et al. 2007). The triggering mechanisms mainly include: (a) excessive rainfall generating high pore pressure and (b) strong earthquakes resulting in dynamic loading conditions at the failure surface. Data such as past earthquakes or the precipitation records are useful to be gathered when a landslide model is examined since they could act as a landslide triggering mechanism. Recording of the movement through surface and inclinometer measurements as well as combination of the above information with historical records of failure could lead to a more accurate estimation of the location of the failure surface and understanding of the landslide mechanism.Slope instability in the southern segment of the Gulf of Corinth, Northern Peloponnesus, Greece, is ubiquitous and ranges from deep-seated bedrock failure to secondary earth flows in recent deposits. In this part of Greece, the periodically induced landslide events triggered by heavy rainfall, earthquake and anthropogenic activity are closely related to active fault tectonics. The Gulf of Corinth is considered as a typical example of a relatively simple asymmetric half-graben with major border faults to the south and a flexure of the northern shore. Panagopoula landslide is located along the trace of a WNW trending normal fault (dipping northwards) (Figure 1). The area is considered to be one of those most prone to slope instability along the E95 motorway and railway connecting Athens with the city of Patras."

Jan 1, 2015

By Finch. J. A., C. Perez, J. M. Ortiz, G. Cortes, A. B. Yañiez, F. Coddou, P. Morales, H. Elgueta

A campaign to perform characterization tests in a TankCell®-300 flotation cell installed at Chuquicamata Codelco's concentrator was conducted. The campaign included integrated gas dispersion measurements (gas velocity radial mapping and single point gas holdup and bubble size) and determination of frother concentration. Cell streams were sampled to assess metallurgical performance at the same time. The experimental program was designed to establish the bubble surface area flux operating range and its effect on performance, and the effect of using longer residence times and of a device designed to enhance mixing in the collection zone (FlowBooster(TM)). The gas dispersion results and their relationship to metallurgical performance are discussed.

Jan 1, 2009

By E. Benguerel, G. Monteith, L. Centomo, S. Pelletier

In early 2007, it became apparent that with changing concentrate feeds, the magnesium (Mg) load projected for CEZinc starting in 2009 and beyond would quadruple and overwhelm the current Mg process bleed capacity. A project was started, following design for six sigma (DFSS) standards, to select both the optimal process and to evaluate its target capacity for the Mg bleed circuit. The economic and process risks of under or over-designing while Mg reduction efforts were underway at the mines also needed to be evaluated. This paper describes the project methodology, the impact on the plant, and some potential optimizations for CEZinc's basic zinc sulphate (BZS) Mg bleed process.

Jan 1, 2008

By J. A. Finch, A. M. Elmahdy

Blending frothers is becoming common in flotation practice apparently enhancing performance. However, there have been no studies to understand the blend mechanism. In this paper, the effect of two frother blends ofF150 (polyglycol) with MIBC or pentanol (both alcohols) on bubble size, gas holdup and froth height is reported. The blends focused on a small addition of the polyglycol to the alcohols as base frother. The tests showed that the bubble size at blend concentration below the critical coalescence concentration (CCC) of the base frother was decreased but was significantly larger above the base CCC. Froth build-up showed a strong synergistic effect.

Jan 1, 2009

By Masatsugu Morimitsu

This paper introduces new technology of oxygen evolution anodes which can be applied to produce copper, zinc, cobalt, and other metals by electrowinning. The anode consists of nano iridium oxide particles dispersed in amorphous tantalum oxide matrix as a catalytic layer formed on a titanium substrate. The anode can reduce oxygen evolution potential by 0.25 to 0.55 V compared to commercially available lead alloy anodes and can suppress unwanted side reactions such as manganese oxyhydroxide, lead oxide, cobalt oxyhydroxide which occur during oxygen evolution in the electrowinning solutions. This technology is effective for environmentally friendly electrowinning processes with low energy consumption and less anodic deposition.

Jan 1, 2011

By M. Tanaka, H. Narita, T. Fuchikami, K. Morisaku, K. Nagao, T. Yoshida, K. Kuroda

The effect of various N-substituents on the performance of amide-containing tertiary amine compounds in the extraction of Rh(III) from HCl solutions was investigated to optimize the structure of these compounds for industrial use. It was found that N-2-ethylhexyl-bis(N-di-2-ethylhexyl-ethylamide)amine and tris(N-di-2-ethylhexyl-ethylamide)amine, which have long, branched alkyl chains, were suitable for Rh extraction, because they were soluble in a practical diluent (80 vol% n-dodecane?20 vol% 2-ethylhexanol) and stable against highly concentrated HCl/Rh solutions, and showed high selectivity for Rh(III) over Pd(II) and Pt(IV).

Jan 1, 2014

By M. Mirnezami, J. A. Finch, M. S. Hashemi A.

The surface of -30µm silica suspension (2% v/v) treated with 100 ppm Mg2+ at pH 11 was fully coated with Mg(OH)2. Under this condition, the silica is strongly positively charged (+30 mV) and the suspension is dispersed. Subsequent addition of Ca2+ promoted aggregation and reduced the surface charge. At this pH calcium is present as Ca2+ and CaOH+, i.e., positively charged ions interacted with the positive surface. Aggregation by a chemical bridging mechanism is proposed. The observation may be relevant to the widespread practice in mineral processing of adding lime to promote aggregation and settling in concentrate thickeners.

Jan 1, 2004

1.Overview of the Ministry of Energy, Mines and Petroleum Resources (MEMPR) 2.First Nations Perspective 3.Revenue Sharing Framework 4.Economic and Community Development Agreements (ECDA?s ) 5.Questions? The Ministry of Energy, Mines and Petroleum Resources (MEMPR) MEMPR manages the responsible development of British Columbia?s energy, mining and petroleum resource sectors. Through the promotion of teamwork and positive working relationships with our clients, MEMPR facilitates a climate for thriving, safe, environmentally responsible and competitive energy, mining and petroleum resource sectors. Works closely with others in Government (e.g.. Integrated Land Management Bureau) to engage First Nations in consultation processes as well as revenue sharing negotiations.

May 1, 2010

Cameco Corporation is in the process of revitalizing the Key Lake mill. As part of this process, the company is considering installing the Rabbit Lake style strong acid stripping in solvent extraction. This would lead to using hydrogen peroxide for uranium precipitation. The process currently employs ammonia stripping and ammonia precipitation. As part of the process evaluation, an indirect fired drier pilot plant test was conducted. This paper will discuss the results of that test work, including the relationships between the following: ? Drying temperature and product grade ? Drying temperature and product colour ? Drying temperature and product reactivity with water ? Drying temperature and energy input requirements ? Drying temperature and shipping costs

Aug 1, 2010

By John Monhemius

Looking back over the past half century, it can be seen that the growth in the importance of hydrometallurgy for the production of non-ferrous and precious metals almost exactly parallels the rise of the environmental movement and its principal NGOs, such as Greenpeace and Friends of the Earth. The paper will review important landmarks in the development of the science and technology of hydrometallurgy and show how many of these have been influenced by pressures on the industry brought about by environmentalists. Successful innovations as well as commercial failures will be considered and reasons for the success or failure will be analysed and lessons drawn to guide future developments.

Jan 1, 2014

Commercial SOFC systems will likely utilize hydrocarbons or hydrogen produced from hydrocarbon fuels and therefore will likely be exposed to sulfur impurities. Conducting-Atomic Force Microscopy (C-AFM) is a scanning probe microscopy technique which maps both sample topography and conductivity with tens of nanometers resolution. In Ni-YSZ, C-AFM measures the resistance of the metallic network at scanned locations, with the ability to differentiate between interconnected and isolated metallic particles. We have applied C-AFM to Ni-YSZ SOFC anode materials, with the goal of monitoring changes in the conductivity of the Ni anode network resulting from SOFC degradation processes, such as H2S poisoning.

Jan 1, 2005

By Xiao Huang, Dongmei Wang, Prakash Patnaik

Further increase in gas turbine engine temperature necessitates continuous development and advancement to thermal barrier coatings. While tremendous effort has been devoted to developing new thermal barrier coating materials and processing methods in order to decrease the thermal conductivity, limited attention has been paid to radiative thermal transport through coatings. It is the purpose of this study to develop a new layered coating structure that can be used to effectively reduce the both radiative thermal transport as well as thermal conductivity, and to demonstrate the mechanism and effectiveness of the proposed multilayered structure. Mathematical modeling based on the multilayer quarterwave stack and simulation results are presented.

Jan 1, 2004

By Stuart M. Jones

This paper is derived from a document that compiles autogenous and semi-autogenous mill installations worldwide, through the end of 2010. Updates have been solicited from all major mill manufacturers and most have responded. A review of AG/SAG mills sold to date and in the last five years indicates that the AG/SAG mill market is very healthy and the trend is larger diameter mills with high diameter-to-length ratios. Ring motors (gearless) are the preferred drives for large mills even though the power transmitted through a gear drive is expected to near 11,000 kW per pinion in the near future.

Aug 1, 2010

By C. T. Morley

The steadily increasing interest in high pressure grinding rolls (HPGR) as a legitimate alternative comminution technology for hard rock applications has led to a proportional increase in the demand for trade-off studies comparing HPGR with more established approaches, typically SAG-based but including AG and stage-crushing designs. The primary trade-off is between a) the higher capital cost typically incurred with HPGR-based designs and b) the higher operating costs of the more traditional technologies. However, if, through circuit design innovation, the capital cost penalty of HPGR circuits could be eliminated or reversed, then the need for trade-off studies would diminish.

Jan 1, 2012

By F. Rosenblum, P. Spira

A laboratory test has been developed for assessing the patential hazard from self-heating of sulphides. The technique consists in measuring the rate of self-heating, from near ambient temperature, of a 1-kg sample in an insulated chamber controlled at standard atmospheric conditions. The rate of oxygen consumption is monitored simultaneously. The paper describes the apparatus and test procedure, and reports data on various ores and mill products. Tailings known to have caused problems underground when used as backfill have shown heating rates of over 3°C/h. A preliminary hazard rating guide for backfill based on the known behaviour of several sulphide materials is presented.

Jan 1, 1981

By C. Zangerl, H. Lechner

"Large scale rock slides in deeply incised Alpine valleys are common hazards that can endanger human life, settlement areas and critical infrastructure such as highways, railways and reservoirs (Bonzanigo et al., 2007). In order to perform reliable forecasts of the behaviour of rock slides influenced by large dam reservoirs the geometry, the kinematics, the deformation behaviour and the hydrogeological situation need to be understood profoundly. Based on generic rock slide models the influence of the rock slide geometry on the stability as well as the impact of the buoyancy forces and water load of the reservoir at the toe of the slope are the main focus of this study. Various assumptions of hydraulic conductivity, groundwater conditions of the rock slide and impoundment depth of the reservoir are analysed using limit equilibrium approaches.Generally, deep seated rock slides are characterised by deformation along one or multiple shear zones where most of the measured total slope displacement localizes. Many large rock slides, especially those observed in foliated, mica-rich crystalline rock masses (e.g. paragneisses, mica schists, phyllites), do not fail suddenly or reach high velocities. Instead, many of them move slowly and reach velocities of centimetres per year or even less. Some show episodic accelerations, sometimes reaching alarming levels, but then subside to non-critical levels again. However, there is a potential that deep-seated rock slides fail rapidly, develop into far-reaching run-out rock flows, and cause catastrophic events. Whereas the role of triggers in promoting phases of acceleration is often understood, the same cannot be said regarding the kinematics and dynamic processes by which the rock slide mass decelerates, re-stabilises or accelerates to a catastrophic degree once the trigger impetus has been removed. Thus key questions of the presented work concern the geotechnical, geometrical and hydrogeological conditions under which a slowly moving rock slide is triggered to accelerate to irreversible, maybe dangerous velocities. The development of the sliding zone is generally influenced by pre-existing discontinuities such as brittle fault zones, shear and tensile fractures, foliation and bedding planes. These geological structures determine the geometry of the sliding zone which can either be rotational or translational. During the gravitationally induced failure process the geometry of the rock slide undergoes a change.Several observed post-failure geometries in metamorphic rocks show a concave topography in the middle to upper part of the rock slide and a typical convex or bulge-like topography at the toe of the slope (Zangerl et al., 2012). Whereas the sliding zone of the upper part of such a rock slide mass is rather steep and planar, the inclination of the sliding zone at the toe can be close to zero and act against the driving forces (Alonso et al., 2010). A shear zone that meets alluvial deposits at the foot of the slope encounters a stabilizing impact on the mechanical behaviour. This buttressing effect of alluvial sediments has a remarkable influence on the slope stability."

Jan 1, 2015

By G. D. Hibbard

New regions of material property space can be accessed by combining microstructural design at the nm-scale with architectural design at the µm- or mm-scale. In the first case, large strength increases associated with grain size reduction to below 50 nm have driven extensive research efforts into the development of nanocrystalline materials [e.g. 1-3]. For many potential structural applications, however, the density of a nanocrystalline material is just as important as its strength. In fact, reducing the density is more important than increasing the strength for certain weight specific materials performance indices, and it is especially critical for applying structural nanomaterials in the aerospace and automotive sectors. We have developed a new type of structural nanomaterial wherein the effective density of the parent metal is reduced by more than an order of magnitude by incorporating an internal periodic cellular architecture of open space. In one example a low density cellular nanocrystalline material was created by electroforming nanocrystalline Ni around a rapid-prototyped acrylic photopolymer microtruss, Figure 1 [4]. Microtruss materials have periodic cellular architectures that are specifically designed to undergo stretching-dominated deformation as opposed to the bending-dominated deformation in conventional open cell metal foams [5,6]. This new cellular nanocrystalline hybrid material combined the structural efficiency of microtruss architectures with the ultra-high strength that can be achieved by grain size reduction to the nm-scale. Although it played a critical role as a cathode support during the initial stages of nanocrystalline electrodeposition, the polymer core did not contribute significantly to the inelastic buckling resistance of the composite metal/polymer struts and it may therefore be desirable to remove it post deposition by means of chemical dissolution or thermal decomposition [4]. Nanocrystalline electrodeposition can also be used to reinforce conventional cellular metals (Figure 2), creating new types of cellular composites such as metal/metal microtruss hybrids [7-10] and metal/metal foam hybrids [11,12]. For example, nanocrystalline Ni-Fe alloy sleeve thicknesses of up to 400 µm were used to reinforce an aluminum alloy microtruss that had been fabricated using a stretch-bend approach; the nanocrystalline sleeves had the effect of increasing the microtruss strength by up to a factor of twelve and the specific strength by a factor of three [8]. Alternatively, much thinner sleeves can be electroplated to produce structural coatings. In one example, a nanocrystalline Ni coating was designed to provide both corrosion protection and inelastic buckling resistance [10]. Because the ultra-high strength material was optimally located at the furthest distance from the neutral bending axis, only a thin coating of 50 µm was needed to double the inelastic buckling resistance of the 1.13 mm x 0.63 mm cross-section plain carbon steel struts [10]. Overall, the mechanical performance increase that can be obtained through electrodeposition depends on a complex interaction between the starting cellular architecture and the nanocrystalline sleeves.

Jan 1, 2010