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By J. M. Paxton, R. L. Roscoe, G. A. McCreary, W. W. Muir, T. J. Drown, D. A. Barr, T. W. Law

"This paper reviews the complete cycle of a small mining operation in a remote section of northern British Columbia, including discovery, exploration, development and production. The discovery of high-grade epithermal gold-silver mineralization occurred in 1969 following a regional geochemical reconnaissance program designed to search for porphyry copper mineralization in the Cassiar-Omineca Mountains. Exploration and development from 1971 to 1979 included geological, geochemical and geophysical surveys; trenching, almost 30 000 feet of surface and underground drilling in about 100 holes and cross-cutting, drifting and raising on the principal goldsilver- bearing vein. This led to the delineation of 100000 tons at an estimated grade of0.9 oz gold per ton and 18 oz silver per [on to an average depth of 120 feet below surface. of a 100-ton per day mining operation employing about 50 personnel with all supporting infrastructure transported to the site by a Hercules aircraft. The operation was subsequently supported by its own Twin Otter aircraft with periodic Hercules campaigns supplying major items including fuel.The mining operation included both open-pit and cut-and-fill methods. The milling operation employed conventional cyanide leach process with cyanide destruction initially by alkali chlorination and subsequently by the Inco SOl /Air process.The fly-in operation, initially structured on a 21-day-in and 7-day-out basis was modified to al-t-day-in and Z-day-out basis with no loss in efficiency and with a significant increase in employee satisfaction. The operation, which earned the B.C. Small Mines Safety A ward in two consecutive years in its Ll-month operating history, emphasized safety and process hazard awareness. Wildlife studies in the environmentally sensitive mine area also showed that industry and wildlife can coexist in harmony.Most importantly, the paper compares the feasibility assumptions with actual operating experience."

Jan 1, 1986

By B. J. Fryer, R. P. Taylor

"As a monitor of the processes involved in the formation of granitoid mineral deposits the coherent group behaviour of the rare earth elements (REE) actively reflects changing fluid characteristics. For example, in the porphyry environment, magmatic-hydrothermal fluids produce potassic alteration with strong enrichment in the light rare earth element s (LREE), reflecting their high pH, low fluid/rock ratios, and the dominant role of CI- complexing in metal (i.e. Cu, Au) transport. With increasing fluid/rock ratios and decreasing pH accompanying the progressive involvement of meteoric fluids (and the production of propylitic, argillic, and phyllic alteration) anionic species such as F - and CO, 2- become important in metal (e.g. Mo, W,) transport through complexing, and their activity in the hydro thermal fluids is illustrated by mobilization of the heavy rare earth elements (HREE).The relative involvement of CI- versus F - versus CO32- in metal transport in other granite-related systems can also be monitored through REE behaviour. Hence granitoid tin-tungsten mineralization and associated greisenization typically exhibit heavy rare earth enrichment and evidence the importance of F' and CO32- in metal transport. Similarly, heavy rare earth element enrichment in hydrothermal uranium deposits can be related to the transport of uranium as carbonate complexes. REE are widely accepted as powerful tools in the study of rock petrogenesis, but their use has been neglected in the investigation of mineral deposits. The recognition of the systematic variation of REE distributions in granitoid mineral deposits suggests that the application of REE geo chemistry, particularly when integrated with fluid inclusion and isotope studies, can provide (1) an effective method for identifying the physicochemical controls of metal transport and (2) a useful criterion for elucidating metal distribution."

Jan 1, 1983

By Wei Ye, Lei Li, Xianjian Guo, Feng He

The purpose of the paper is to study the smelting process of copper concentrate with high Cu/S ratio produced in Africa or other areas around the world and theoretically analyze the influence of slag type on the smelting process. The paper has compared the processes used successfully in smelters, including CAPEX and OPEX and other factors, to provide reference for the industry to select the best process under specific conditions. INTRODUCTION At present, a great amount of copper concentrates with high Cu/S ratio, with chalcocite being the major source of copper, have been produced or are about to be produced in the Copperbelt in Africa and other countries in the world. The copper concentrate is usually high in copper (~30–55wt.%) and low in sulfur (~10–15wt.%). The conventional processes of smelting-converting and roasting-leaching-electro-winning for treating this type of concentrate is high energy and materials consumption such as electric power\fuels\flux et al. The direct-to-blister (one-step) smelting process can be considered favorable due to a reduction in processing steps. Up to now, there are four copper smelters in the world operating with the direct-to-blister smelting process. There certainly are problems in the process such as high copper content in the slag, strict operation requirement of slag cleaning electric furnace, etc. Except technical issues, the impact of factors on economical aspect such as power and material cost needs to be considered comprehensively in process selection. In this paper the technical issues of direct-to-blister smelting process, including slag treatment process, were analyzed and the comparison to the conventional processes and economic analysis of direct- to-blister smelting process to treat high Cu/S ratio concentrate were done.

Jan 1, 2019

By T. Boiselle, C. Gielen, P. Henry, J. M. Bier

"Hydrometal is specialized in the production of zinc sulphate from complex secondary raw materials. Electric Arc Furnace (EAF) dust is one of the more interesting potential sources to produce zinc sulphate. In order to minimize waste quantities generated from EAF dust treatment, our R&D team has developed and patented a new process to recover the Fe contained in the dust as iron oxide product to be used and sold into the pigment market. The process is based on a specific reductive leaching step of the zinc ferrite contained in EAF dust, followed by a purification step to remove impurities (Ni, Cr, Cu...) and finally the controlled precipitation of the iron oxide. The aim of the iron precipitation step is to obtain the right shape and length of crystals in order to guarantee the right color and tinting strength of the pigment. The innovative aspects of the process results in the controlled oxidation of the iron to get the right crystal size and good purity material. The iron product can be valorized as red or yellow pigment often produced by the Penniman-Zoph process.INTRODUCTION A Few Words about HYDROMETAL Hydrometal SA (Engis, Belgium) is a subsidiary of Jean Goldschmidt International SA (JGI) in Brussels. JGI is mainly involved in metal trading activities (Goldschmidt, 1995). In 1985, JGI acquired the leaching circuit of a Belgian electrolytic zinc producer located in Engis, a few kilometers south of Liège, near the river Meuse and it was decided to name this plant: SA HYDROMETAL. Hydrometal is well connected by water, rail and road from its central location in the industrial region of Liege, in the heart of Europe. The company received in 1997 an additional license to process and recycle toxic and hazardous waste. Figure 1 shows a picture of the plant."

Jan 1, 2016

By J. R. Shouldice

"IntroductionREEFS of Silurian age are recognized in southwestern Ontario, both in outcrop and from subsurface information. This paper deals with the so-called 'pinnacle' reefs which are known only in the subsurface. For the purpose of this paper, the pinnacle reefs are arbitrarily defined as those structures having a height of over 250 feet and a length of less than two miles. This definition eliminates numerous mounds and other broader, more subdued, structures of less certain origin, found in subsurface beds.The term 'pinnacle reef' is perhaps unfortunate, but it is in common usage in Ontario and is used elsewhere for different types of reefs. A new name is justified by the unusual environment and structure of the Ontario reefs, but it is unlikely that any other term would gain acceptance. Rather than propose a new term which would be ignored or result in further confusion and misuse, the name 'pinnacle', as defined above, is used in this paper.Pinnacle reefs have been found over a fairly large part of southwestern Ontario. The known reefs of this type parallel the southeast edge of lake Huron and •follow the strike of the structure contours which circle the Michigan basin (see Figure 1). In total, twenty-five such reefs have been discovered in southwestern Ontario."

Jan 1, 1955

By H. Asgari, A. G. Odeshi, J. A. Szpunar

In the present study, the dynamic response of AZ and AE cast magnesium alloys to shock loading, are compared for strain rates ranging between 900 and 1200 s-1. Texture measurements showed that after shock loading, the (00.2) basal texture component of both alloys was strengthened. However, the strengthening magnitude was higher for AE samples. Also, it was observed that the twinning fraction decreased in both alloys with increase in the amount of alloying elements. In addition, cracks are formed at the interface between matrix and second phase particles in the AZ alloys. However, crack nucleation and fracture in AE alloys occurred at the sites where twins accumulated. Furthermore, analysis of the dynamic mechanical behaviors showed that the ductility of AE grade is higher than that of AZ alloy for all strain rates used in this research. This difference was explained by differences in deformation mechanisms of these alloys.

Jan 1, 2014

By Raynald Vézina, Richard Leclerc, Jean Boissonnault, Louis P. Gignac, Gérald Veillette

Since mid-1989, Cambior has increased its producing gold mines from four to six, having acquired the Chima Mine and brought the Silidor Mine onstream. In June 1990, the company announced that the Mouska project would also be put into production. Gold production reached almost 190 000 ounces in 1989 and is expected to exceed 220 000 ounces this year. Cambior has also a non-gold operation with an interest of 50% in the Niobec Mine and has recently signed an option agreement in the development of the Lac Knife graphite deposit in northeastern Quebec. During the past year, the company has extended its exploration activities to the United States and Indonesia, and now has interests in nearly 80 properties. Last May, Cambior signed an option agreement with Golden Star for a gold deposit in Guyana, the OMAI Project, containing at least 2 000 000 ounces of gold in situ.

Jan 1, 1990

By Michael L. Wayman

Native copper is copper which exists in nature in elemental, metallic form, rather than being chemically combined as is the case with the more usual oxides, sulphides, carbonates, etc. Several other metals, including gold, silver and platinum also occur in native form as do, rarely, iron, lead and mercury; a few naturally occurring native metal alloys, notably electrum (gold-silver) and tumbaga {gold-copper or gold-silver-copper) are also known. An analysis of the relative availabilities of native metals as nuggets in a useful size range111 shows native copper to be by far the most abundant of the native metals, exceeding both gold and silver by at least two orders of magnitude. While such an estimate is crude, it serves to illustrate why copper was one of the first metals to have been used by ancient peoples. Native copper is known to occur on all inhabited continents, although its exact occurrence and abundance in ancient times cannot be unambiguously determined because many surface deposits may have been totally exploited and are therefore no longer identifiable. It is clear, however, that native copper does or did occur in all areas inhabited by the early metal-using cultures, for example in the Andes, in Central America and in the Near East. It is remarkable that most of the world's native copper occurs in the deposits of the Lake Superior region, primarily on the Keweenaw Peninsula of northern Michigan and on Isle Royale, an island in Lake Superior some 50 miles north of the Keweenaw deposits. Canadian deposits of native copper are found in Newfoundland and Labrador, Nova Scotia, Quebec, Ontario, British Columbia, the Yukon and the Northwest Territories (on Victoria Island, Bathurst Inlet and the Coppermine River area). It was to locate the latter deposits that the explorer Samuel Hearne was sent overland from Hudson's Bay in 1770; they were also surveyed by Sir John Franklin's expeditions in the 1820s.

Jan 1, 1999

By E. Stansfield

Coal samples are sometimes taken from a wet spot in a mine, or from an open car or pile shortly after rain, and submitted for analysis in a dripping wet condition. Other samples are taken from a dry spot in the mine, or from an open car or pile after a period of dry weather. Comparison of the analyses obtained in the two cases would be absurd, although the samples might be of essentially the same coat apart from the surface moisture on the one. The analyst therefore attempts to reduce all samples to an equal basis by the operation known as air-drying. Air-drying is practised by the chemist for three reasons: (1) To make it possible to grind the coal to powder. (2) To bring the coal sample to a condition in which it will not change in weight rapidly whilst portions are being weighed out for analysis -in other words, to bring it into equilibrium with the air in the laboratory. (3) To determine the water-retaining power of the coal. Any kind of drying is satisfactory for (1); the coal should be dried more or less according to the humidity at the time in the laboratory for (2); whilst it should be always dried to the same extent for (3). In other words, no method can be satisfactory for both (2) and (3). In this paper the only question considered is (3) -that is, air-drying the coal under standard conditions so that strictly comparable results can be obtained for the water content of coals after air-drying. After a sample of wet coal is exposed, it loses moisture until it is in equilibrium with the air at the time: thus the coal will loose distinctly more water in air of 20 per cent relative humidity, for example, than it would in air of 80 per cent.

Jan 1, 1923

By John H. Schloen

"The object of this paper is to review electrolytic copper refining as it was in 1954(1), as it is now in 1984, and to comment on the many improvements which have been made in the last thirty years.In 1954, and even in 1984, the ASTM specification B 115 for cathode copper was 99.90% minimum copper plus silver content and 100% minimum electrical conductivity, IACS standard. However, to meet competition and to satisfy the requirements of the fabricators and the electrical industry, the electrolytic refinery must supply a product of 99.95% to 99.96% minimum copper content, and 101fJlo minimum electrical conductivity.The range of cathode impurities reported by 20 major copper refineries in 1954 are given in Table I.The much more rigid British Specification, DD 78, for high-purity cathode copper, specifies individual elements, as well as groups of elements, as shown in Table 2.The Svenska test has been replaced by a similar procedure which uses 2.r mm diameter wire. The ISO test is the one listed in the DD 78 specification. In Table 3, corresponding values for the Svenska and ISO test s are given for various wire bar coppers."

Jan 1, 1986

By F. Cheuk, E. Krause, V. G. Papangelakis, G. A. Moldoveanu, S. Abendschein

Systematic studies have been conducted at the University of Toronto in order to evaluate lanthanide extraction from clay minerals from different geographical regions. It was found that rare earth elements (REE) are easily recovered into an aqueous solution via an ion exchange mechanism by leaching with electrolyte solutions containing monovalent cations under ambient conditions. In this study we assessed extraction levels of individual REEs as a function of initial clay composition and leaching conditions. It was found that, in spite of variations in clay origin, all clays consistently reached peak REE extraction levels with fast kinetics. However, terminal extractions were clay-specific. The feasibility of using seawater as a leaching solution and potential synergies with ammonium sulphate as a lixiviant was also investigated. Seawater was found to be inferior to using ammonium sulphate, and provided no observable synergy in leaching performance when used together. The aqueous phase trapped in leached clays was shown to contain significant amounts of REE, as demonstrated in clay washing tests. Techniques to improve the REE concentration in leachate through process variations were investigated. However, it was found that most techniques capable of increasing REE concentrations in the resultant leachate also resulted in reduced REE extraction.

Jan 1, 2014

"In the past year, mining at the Doyon Mine has shifted entirely from open pit to underground. The mine produced 234 692 ounces of gold in 1989 and is expected to produce 225000 ounces in 1990. The Doyon Mill has been running slightly above design capacity, and recovery has increased 3%.IntroductionThe Doyon Mine is located 25 miles east of Rouyn-Noranda, Quebec (Figure I).It is a joint venture owned by Lac Minerals and Cambior, with each holding a 50% interest. Lac Minerals operates the mine under the direction of a management committee.Production at the Doyon Mine began in 1980 with the start up of the Main Zone pit. Shortly thereafter the Doyon Mine became the largest open pit gold producer in Canada.In 1983, a ramp leading to the fourth level and exploration drifts were driven. Results were very encouraging, therefore the decision was made to sink a 2150-foot deep shaft, which was completed in 1986.In mid-1986, production began in the West pit, while underground mining of the West Zone started shortly thereafter, at the end of the same year.In 1987 the mill capacity was increased to 3300 tons per day and the Main Zone underground operations commenced."

Jan 1, 1990

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By T. L. Carpenter

"The presence of excessive water in the Gibraltar East Stage 1 pit initiated studies into the ground-water conditions that might be expected in mining the Granite Lake and Pollyanna pits. Hydrologic information obtained from a pump test program in 1974 indicated that deep-well dewatering could be successfully achieved. In 1976, a deep-well dewatering system consisting of eight wells was installed on the periphery of the Pollyanna pit . it has been responsible for a significant decrease in mining costs.This paper presents a brief summary of the engineering principles involved in the design of the Gibraltar dewatering system and the problems encountered in the installation and operation of deep-well pumps. IntroductionGibraltar Mines is an open-pit copper-molybdenite mine located approximately 230 air miles north of Vancouver in the central interior of British Columbia (Fig. I). The property consists of three separate major orebodies; Gibraltar East, Granite Lake and Pollyanna (Fig. 2). Mining commenced during the summer of 1971, in the Gibraltar East Stage 1 pit. The Granite Lake Stage 1 pit was mined from mid 1974 to mid 1976. The Pollyanna Stage 1 pit is currently being mined and the Gibraltar East Stage 2 is being developed for production. This report is intended as an outline of the studies and tests leading up to and including the installation of the Pollyanna pit dewatering system, the problems encountered and the results obtained.GeneralIn the summer of 1973, mining in the Gibraltar East pit progressed below ""daylight"" on the down-hill side and ground water very quickly became a costly nuisance in the day-to-day mining operations. Mining, maintenance and blasting costs reflected these problems. Concern was also voiced about adverse effects of ground water on pit wall stability. This concern later became a reality in the Gibraltar East and Granite Lake pits. A study was initiated to investigate various methods and costs of dewatering the pit areas. The study included in-pit sumps, deep peripheral wells and a drainage gallery system located below the pits."

Jan 1, 1980

By J. C. Ingles

"A survey of possible methods for controlling cyanide concentration indicated that the simplest method would involve the use of a potentiometric technique. Such a method was suggested by a paper from the laboratory of Mines Safety Appliances, which described a method for determining hydrogen cyanide in air. In this application, the cyanide was absorbed in caustic and a silver electrode immersed in the caustic solution provided a measure of the cyanide concentration. However, our attempts to use the silver electrode in this simple manner to measure the cyanide concentration of solutions were not very successful. A study of the mechanism by which a silver electrode responds to cyanide concentration made it evident why this simple procedure is not satisfactory.Basically, the silver electrode provides an indication of the free silver ion concentration of a solution, and generally speaking, ignores the other ions' present. It can be used to measure an anion if this anion complexes silver. This technique has been used in complexing studies to determine the activities of such anions as acetate, citrate, oxalate and chloride. To do this, the electrode has to be placed in a solution which initially contains a known concentration of free silver ions. Addition of the complexing anion causes a drop in the free silver ion concentration and hence a change in the potential of the silver electrode. The change in potential can be expressed in terms of the concentration of the complexing anion, and used to indicate its concentration in the solution being analysed. The determination of chloride-ion by a silver-silver chloride electrode is an example of an application of this technique. The solubility of the silver chloride with which the electrode is coated provides the initial free silver-ion concentration. Depression of this free silver-ion concentration by the presence of the excess chloride ion of the sample solution results in a change in the potential of the electrode which is proportional to the chloride-ion concentration."

Jan 1, 1965

By C. Robinson

The Diavik Diamond Mine is located in one of the most remote and forbidding places in the world, 220 kilometres south of the Arctic Circle and on the bed of a vast northern lake, Lac de Gras. A single road, built out of ice and crossing frozen lakes, connects the mine with other operations and Yellowknife, the capital of the Canada's Northwest Territories. Diamonds were first discovered in the Lac de Gras region in the early 1990s, and construction of the Diavik Diamond Mine was completed in 2003. Diavik currently mines three kimberlite pipes. Open pit mining has now concluded and all three pipes are mined using underground mining methods. In early 2010, Diavik began mining and processing initial ore from its new underground mine; underground mining operations are expected to continue beyond 2020. The initial mine ventilation system was an exhausting (pull) system with fresh air supplied by a fresh air raise and a main ramp. Return air was exhausted via two raises and a secondary ramp. The system had a total flow capacity approximating 401-411 m3/s. With planned increased production and with changes in mining method, it has been proposed to change the mine ventilation system to a positive (forcing) ventilation system in order to meet projected increases in flow requirements of 566-708 m3/s. Extensive engineering work was developed in order to successfully achieve the changes in system configuration. In the proposed configuration, the main ramp is in an exhaust configuration and exhaust raises are converted to fresh air raise. A number of system implementation options were investigated and phased plans for system execution have been developed. The proposed changes to the ventilation system are substantial and involve extensive construction work. Work was commenced in 2011, each planned phase has been successfully completed to date, and system changes continue today in order to achieve complete system flow reversal and increased flow distribution. This paper details the design of the modified ventilation system and commissioning work which will allow the mine to meet its future production targets.

Aug 1, 2013

By John L. Rich

A New Field for the Mining Industry A new field for the mining industry is in prospect. This is the recovery of the petroleum which has been left in the ground in the older oil fields whose yield has declined until they are no longer profitable to operate in the ordinary way. The fact that an oil field has reached the economic limit for operation by pumping does not necessarily 'mean that the oil has ? been exhausted. In many such cases not over one-fifth, or even one-tenth, of the total oil content of the field may have been taken out when this stage has been reached. This means that there exists a large reserve of oil which can be recovered by whatever process best takes advantage of the natural conditions under which the oil occurs. Mine drainage is one of the processes by which this oil may be recovered. Its relative importance will depend partly on the ingenuity and wide-awakeness of mining engineers, and on mining capital. The opportunity is undoubtedly at hand. In order that we may be in a position to judge the possible advantages of mining methods for the recovery of this oil, I have reviewed, on the following pages, the methods now in use, and have discussed the physical conditions of the reservoir rocks in which the oil is found, and the suitability of the various recovery processes, in use or proposed, in the light of these reservoir conditions.

Jan 1, 1927

By B. S. W. Buffam

"The property of Moneta Porcupine Mines, Limited, consists of a group of eight claims in Tisdale township, Ontario. It includes part of the townsite of the town of Timmins, and adjoins the west boundaries of the Hollin_ger Consolidated and Mace properties. The Moneta property was first staked in 1909, about a year after the first discovery of gold in the Porcupine camp. In 1910 the Moneta Company was incorporated and some preliminary exploratory work performed by Nova Scotia Mines of Cobalt. In 1912 English interests advanced $90,000 for diamond drilling and underground work. One drill hole gave high assays, but apparently the records were poorly kept or the cores were interchanged. As a consequence, when underground exploration was undertaken in 1923 it was directed south rather than west and no ore was found . In 1924 about 5,000 feet of diamond drilling was done in the southern part of the property, but without intersecting ore.In 1931 W. E. Segsworth assumed the direction of the property. Diamond drilling commenced on August 18, 1936. The first hole intersected 9.9 feet of ore averaging 1.23 oz. gold a ton. Underground work was started early in 1937. A mill was erected in the autumn and the first gold brick was poured January 29, 1938.The Moneta mill began operation on January 2, 1938, and the following table gives a summary of the production to June 30, 1943, when the mill was closed."

Jan 1, 1954

By A. W. Johnston, R. E. Barrett

"The Central Patricia mine is in the greenstone belt north of lake Sc. Joseph in northwestern Ontario. It is 90 miles north of Allanwater on the Canadian National railway and 220 miles east of the Manitoba boundary. The unusual feature of the ore of this mine is that the gold does not occur in quartz but in sulphide minerals filling fractures in iron formation.AREAL GEOLOGYThe rocks of the area in which the mine occurs belong to the Early Precambrian. They consist · of andesite lavas and tuff interbedded with greywacke-like sediments and iron formation . A siliceous phase of the sediments lying north and south of the greywacke enclosing the ore-bearing iron formation in places resembles a sheared and sericitized quartz porphyry. This is shown in the legend of Fig. 1 as quartz porphyry and quartzite, but it is possible that the quartz porphyry-like phase is sediment. A northwest- striking dyke of diabase crosses the property 3,000 feet east of the shaft ( Fig. 1).IRON FORMATIONAlthough there are numerous bands of iron formation in the v1cm1ty of the mine, ore has been found to date in only one main and two lesser zones. The iron formation bands range in width from a few inches to 60 feet, and are interrupted along their strike by gaps that are parallel and rake to the east at about 65°. The iron formation is definitely banded and laminated."

Jan 1, 1954

By S. Hussien, P. Somasundaran, P. Patra

"Rare earth elements (REEs) are essential for many applications in electronics, energy harvesting, and defense. The common resources for economic extraction of REEs are oxides such as bastnaesite and monazite, which are scarcely available in the earth’s crust. On the other hand, REEs are available in many clay and phosphate ores where REEs substitute Ca or Si in the mineral lattices or as physically adsorbed cations at negatively charged sites on the clay surface. While REE oxides readily dissolve in acid, making the chemical leaching of REEs an economically viable option, adopting a similar approach for leaching of silicates and phosphate ores is unfeasible because of significantly low REEs content in these ore deposits. Bio-leaching approaches are environmentally benign and economically viable. We investigated the bio-leaching (Acidothiobacillus ferrooxidans (Af) and the fungal Aspergillus niger (An)) of REEs from a phosphate ore, and examined the factors governing the leaching processes. Based on the shake flask leaching studies, an increase in surface area combined with an increase in pulp density (1-15 wt. %) was found to lead to an increase in the amount of REEs leached. In contrast, an increase in the surface area by reducing the particle size from 75 to 35 led to a decrease in the amount of REEs leached. These differing attributes are proposed to be due to the poor bacterial growth/activity with high F- ions in the leaching media, F- released from the edge-sites of the smaller particles. On the other hand, several advantages that associate with the Af bacterial bio-leaching processes relate to the media composition (Mg2+ and (NH4)+) and phenomena occurring at the electrical double layers of the mineral and bacterial- water interfaces. These studies suggested that leaching of particles occur in a layer-by-layer manner.INTRODUCTIONRare Earth Elements (REEs) are essential for many important applications, such as in electronics, energy generation, and defense. The common resources for economic extraction of REEs are typically carbonates such as bastnaesite and monazite, which are scarcely available in the earth’s crust (Y. Kanazawa and M. Kamitani, 2006). REEs are abundantly available in many clay and phosphate ores where REEs substitute Ca or Si of the mineral lattices. Conventional acid leaching of REEs from oxides is not economically feasible for clay and phosphate ores because of significantly low REE content (parts per billion) in these ores (Tian, J., Chi, R., Yin, J., 2010a; Moldoveanu G. A. and Papangelakis V. G., 2013; WK Goyne, LS Brantley and J Chorover, 2010). In some cases, REEs could be extracted from these ores via chemical leaching routes as they constitute reasonable amounts of REEs (0.1 - 1% REEs). A major challenge faced in general in chemical leaching processes (Chi, R., 1988) is the loss of REEs in the phosphate/gypsum precipitates/crystals, which are overcome in a step-by-step manner by sequentially removing impurities such as fluorine and calcium, including steps carried out at elevated temperatures. On the other hand, bio-leaching approaches provide environmentally benign and economical alternatives. Acidophilic bacteria are currently being used for industrial scale bio-leaching of Au/Cu/Ni from low grade ores. Studies on bioleaching of REEs from red mud (Al2O3) using Penicillium tricolor and Aspergilus niger (An), and, of bio-leaching (lab-scale) of phosphate rocks using Acidithiobacillus ferrooxidans (Af) have been reported (Boon, M., Heijnen, J.J., 1993; Qu, Y. and Lian, B., 2013). We conducted bacterial (Af) bio-leaching of REEs from a phosphate ore in shake flasks and columns, while examining the key factors that govern leaching kinetics."

Jan 1, 2016