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By Fathi Habashi

This Historical Metallurgy Note is the final part of a three-part series, the first two of which appeared in the November- December, 1997 and January, 1998 issues of the Bulletin. This series of articles is dedicated to the memory of Nikolai Maximovitch Pereskuryakov (1940- 1994), Rector of Saint Petersburg Mining Institute from 1992 to 1994 who passed away unexpectedly at the age of 54, shortly after celebrating the 275th Anniversary of the Institute.

Feb 1, 1998

By Fathi Habashi

Teaching mining, metallurgy, and geology preceded that of the other engineering disciplines. The first School of Mines was founded in 1756 in Potosi (Fig. 1) in New Spain (now Bolivia), 38 years before the first Polytechnic School (École Polytechnique) was founded in Paris. The schools of mines were also pioneers in the teaching of chem- istry. The teaching staff at these schools cre- ated the basic literature on metallurgy, mining, and geology. They analyzed and dis- covered numerous minerals and discovered the metals tungsten, beryllium, chromium, uranium, zirconium, vanadium, indium, and germanium. The history of some of the first schools is given together with biographies of some of their distinguished teaching staff.

Nov 1, 1997

By F. M. Makarinsky

"This paper describes the conversion of conventional froth flotation cells to open-trough type bank cells, with 'buried' vertical metal partitions. These changes have resulted in: total froth removal along the full length of each bank of cells; extended flotation cell retention times; and has extended the life of the metal components, particularly towards the upper flotation cell areas.INTRODUCTIONOver the past twenty years, the flotation cells used at Falconbridge Limited, Sudbury operations concentrators, have gone through major physical changes. The various concentrators generally started with 100 cubic foot Denver Sub 'A' flotation cells. From these units, we progressed to 'converted' DR units, and/or Denver DR units, if purchased new. (Figures 1, 2, 3)In 1980, the Strathcona concentrator started to pay more attention to the 'front end' rougher flotation cells. Initially, the converted DR flotation cells had 'cut-outs' removed (Figure 4) at all upper vertical cell partitions, towards the ff9th lip areas, in order to get additional froth removal."

Jan 1, 1985

By David McMullen

Radiation plays a critical role in the thermal behaviour of hydrometallurgical process equipment. This effect is particularly important when designing refractory lined equipment used in pressure leach/oxidation processes. In order to simplify this non-linear mode of heat transfer, the effects of radiation had previously been incorporated in an equivalent convective film coefficient in finite element methods (FEM). This prior method omits the effects of radiosity, a critical aspect of radiation heat transfer, which affects the design of refractory lining systems in autoclave vessels. Given that 60% of the heat loss in actual plant practice of an autoclave is due to radiation, reliability in the FEM is therefore impacted. This study validates the use of radiosity in FEM through thermal loading using a combination of simple geometries to be applied to complex environments such as vessel nozzle clusters. The added benefits of using a radiosity load includes an increase in confidence in thermal distribution results, greater accuracy in determining appropriate refractory lining systems, weld overlay sizing, and increased accuracy in structural analysis.

Jan 1, 2014

By M. Doucet

The introduction of high-nickel anodes to CCR in 2006 resulted in an increase of nickel in anodic slimes. Removal of the nickel in these slimes to below 3.0% is necessary in order to prevent slag viscosity problems in the subsequent pyrometallurgical step. A lower specification of 0.5% was chosen in order to minimize Ni losses to the slag and to recover this nickel as NiSO4. A 2-stage autoclave process, which was patented by CCR in 1992, was chosen to treat the high nickel slimes. Laboratory and plant?scale tests were performed in 2004 in order to validate the results of this process with the present slimes. These results along with corrosion tests were used to design two brick-lined autoclaves. These autoclaves were installed in October 2006 and successfully commissioned within 8 weeks. A "Design of Experiment" test program was performed in 2006 on an alternative autoclave process that reversed the cycles in the patented process. The effects of temperature and acid content were modeled using the results. The alternative process will be validated with the new autoclaves.

Jan 1, 2007

By Arthur Lieu

The mill effluent treatment circuit (Bulk Neutralization (BN)) in the Cameco Key Lake Operation was modified in 2008 to enhance the removal efficiency of selenium (Se) and molybdenum (Mo) from the mill process water. This modification was completed in part due to increased knowledge of the effects these elements have on biota. In addition, legacy effects from the historical operation of the Key Lake mill in regards to Se and Mo were shown to have an effect on the regional biota in the downstream receptors. This was a challenging initiative as there was no off the shelf technology available and the removal process had to be incorporated into an existing (brownfield) process. These modifications have resulted in significant reduction in the concentration of these elements in the Key Lake mill effluent. The removal efficiency for Se and Mo in the modified circuit has increased to 95% and 75%. As a result, concentrations of Se and Mo are now consistently less than 0.4 mg/l and 0.02 mg/l. In addition, the Se and Mo precipitates formed were extensively studied to ensure long-term geochemical stability in the Key Lake in-pit tailings facility. This presentation will provide additional detail on the hydrometallurgical removal mechanisms and process modifications required in the Key Lake BN circuit to remove these elements to trace levels.

Aug 1, 2010

By P. Latostenmaa, T. Veneranta, J. Järvi, E. J. Peuraniemi

Boliden Harjavalta has operated a copper flash smelter since 1949 thus the smelter celebrates 70th anniversary of flash smelting in 2019. This paper shortly describes the historical perspective of the smelter and gives an update of the current operational issues and process modifications made during the recent years. The plant has carried out several major investments lately providing a firm view on the future. A new landfill area for the final slag was commissioned in 2018. A modernization of the concentrate storage area, a new acid plant and a debottlenecking project of the smelting line have been recently commissioned. At the same time, the tankhouse capacity will be expanded. This paper focuses on smelter modernizations. INTRODUCTION Boliden is a metal company operating mainly in northern Europe with core competencies in the fields of exploration, mining, smelting and metal recycling. Boliden Harjavalta, located in Finland, is part of the Smelters Business area of the Boliden Group and operates a copper and nickel smelter with related sulphuric acid plant in Harjavalta, and a copper refinery in Pori. As a short historical review, Harjavalta’s history may be dated back to the year 1910 when the Outokumpu ore body in eastern Finland was discovered. By the end of 1913, a copper mine was in operation and a copper plant based on Hybinette process was ready for commissioning. Due to difficulties in metal recoveries and throughput the Hybinette process was permanently shut down in 1929, and 100% of the mining production was sold as concentrate abroad. As the mine production increased steadily, a decision of a new smelter was made in early 30’s. In 1936 Outokumpu’s copper smelter based on electric smelting was commissioned in Imatra. The smelter was dismantled and transferred to Harjavalta during the final stages of the Second World War. The copper refinery started in Pori already in 1941 and the first copper anodes were cast in Harjavalta in 1945. First sulphuric acid plant started operation in 1947. Due to the post-war shortage of electrical energy, the plant metallurgists initiated a major development work to start exploiting the latent heat of concentrates. Thus, the flash smelting method was developed in Harjavalta and commissioned in 1949. Ten years later, flash smelting was also applied for nickel concentrates. Table 1 summarizes major historical and technical milestones of Harjavalta. The history of flash smelting is described in details in another paper of this conference (Jåfs et al., 2019).

Jan 1, 2019

By Lastram Rolando, Larry J. Hulbert, Louis J. Cabri, J. H. Gille Laflamme, John L. Campbell, Soey H. Sib, Chris G. Ryan

"The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fine-grained minerals which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700/0 of the major Ni carriers and 78% of the major Cu qurier will be liberated at a grind of 80% -U,.7 ,an (-500 mesh) for typical low-grade gabbro (West zone, sample No.1). For typical ""clinopyroxenite"" (West zone, sample No.2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3) the liberation would be 71% and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total 24.5% for typical low-grade gabbro (West zone, sample No. I), 15% for typical ""clinopyroxenite"" (West zone, sample No.2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No.3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fine grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as some would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No.2 and No.3 is closely associated with magnetite. Palladium occurs in diverse ways. It occurs in the form of several Pd minerals (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tellurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chalcopyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerals and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate.However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No.2 and No.3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No.3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No.3, in order to improve Pt and Pd recoveries. Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefined Re-Ir-Qs..Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By M. A. Vos

"Aggregates are the low-cost mineral raw material of building construction. Large volumes of aggregate are consumed each year. The availability of aggregates in southern Ontario is discussed in the context of the geological formations in which they occur. Sand and gravel are abundant in glacial deposits and in recent sediments. A knowledge of the glacial history is important for their discovery. Bedrock formations provide a variety of aggregates in Ontario. Knowledge of the rock types involved and of the depth of overburden are important for evaluation of the aggregate potential of bedrock resources in an area. Utilization of available resources intensifies as the population increases. Urban development makes it progressively more difficult to satisfy the demands of the construction industry. The effects of urban development on the aggregate resource base of an area are illustrated by developments and consumption statistics in the Toronto- centred region. There is an obvious need for a comprehensive survey of available resources in urban areas to serve as a guide in land-use planning. To fill this need, staff members of the Industrial Minerals Section, Geological Branch, Ontario Department of Mines and Northern Affairs, are engaged in mapping projects and mineral resource studies in southern Ontario as well as in some urban areas of northern Ontario."

Jan 1, 1972

By J. Olaf Sund

"THE November issue of the Bulletin carried in it ""Origin of the New Bruns1viclc Gypsum Deposits"" by J. Olaf Sund. This paper was a digested account of a Master's thesis at the University of New Brunswick which was a very useful compendium of information of gyp-sum in New Brunswick. It was a warded the President' s Gold .Medal and the First Prize in the Graduates' Section of the Students' Essay Competition. The present writer presents his congratulations to the winner of the competition. At the same time he must comment on the use of certain terms and on certain conclusions presented in the paper.The term ""unconformable"" has been used in several places in the paper to describe the relationship of gypsum to anhydrite in various deposits in New Brunswick in a sense which is quite alien to the accepted meaning. It has long been known tl1at the gypsum at the surface or near the surface in deposits in the Atlantic Provinces has come from hydration of anhydrite by surface and ground waters. The gyp-sum must be looked upon then as an alteration or even a weathering product. It cannot in this sense be called ""unconformable"" and thus arguments using the word in the accepted sense are invalid."

Jan 1, 1960

By R. Bonifaz, R. Subiabre

The Chagres Smelter, part of the Anglo American plc group, situated 80 Km north of Santiago in Chile, completed a series of operational improvement in 2005 resulting in an optimum capacity in its operational units. At present the Chagres Smelter has developed an operational strategy which seeks to reduce bottle-necks in the production process. In this way we have managed to lower operational cost, decrease energy consumption and maximize the capacity of the Acid, Oxygen, and Smelting, Converting, Refining and Casting units. A constant review of international benchmarks together with continuous staff improvement and the latest smelter technology have combined to place Chagres among the finest smelting works in the world. In response to environmental challenges, we have studied various options for investment that will yield a suitably profitable business to benefit both Anglo American and Chile. The most relevant technical indicators are: energy consumption=6,3 GJ/ton fine copper (1st in the world), intensity of smelting rate in Flash Smelting unit of 6,900 ton of copper concentrate/m2 of furnace area (1st in the world) and to be one of the top five smelters in achieving the lowest direct cash cost .

Jan 1, 2007

By Ernest A. Hodgson

WHEN excavations are made, at depth, in hard brittle rock structures, as in certain mines in India, in South Africa, and in Ontario, the pressure due to overburden, together perhaps with inherent geologic strain, tends to become concentrated in the walls of some of these openings and the rock bursts, often closing the adjacent drifts and scopes and presenting a serious menace to the miners. Where the rock is much fractured and faulted, the danger is greater, since the pressures tend to shift without warning from point to point, sometimes within a few hours. Attempts have been repeatedly made to find some physical property of the rock which will change with pressure, which can be measured for rock 'in place' in the mine, and which will give an indication of the state of strain, thus warning of an approach to bursting conditions. Some of the properties tested have been the speed of propagation of elastic waves in the suspect rock, variations in temperature due to pressure changes, rate of closure of openings or shifts along fault planes, strain gauge measures, and others. Each of these has proved unsatisfactory for the purpose. The most promising method so far proposed has been the study of the very faint, sub-audible snaps (microseismims) which are produced in rocks under pressure. Such a study has been in progress at Lake Shore Mines since May, 1942. Instruments designed to pick up, amplify, and record the microseismims were perfected and a programme of observing, using the microseismic method, has been carried through with persistent diligence and at considerable expense. In 1943, experience with the method in a pillar section on the west side of the Lake Shore mine gave much promise of predicting bursts. A very heavy burst on January 29th of that year occurred in the exact section of the mine covered by the instruments, and the records indicated a measure of prediction. In response to repeated requests for information, a number of reports were given out, among others a radio talk by the writer over CJKL (Kirkland Lake), which was reported in full in the Northern News . Also, a detailed account of the occurrence was given in an illustrated paper by the writer (l).

Jan 1, 1945

By F. Q. Barnes

"Uranium, thorium and yttrium have been recovered, since the 1950s, from pyritic quartz-pebble conglomerates occurring in the basal sediments of the Quirke syncline at Elliot Lake. Gold, an element of interest in similar type deposits occurring worldwide, is a very minor constituent of the Elliot Lake conglomerates because the provenance area of the sediments had few gold-bearing rocks.Uranium, thorium and rare elements are found in resistate and diagenetic minerals occurring in the matrix of the conglomerates. The valuable elements are recovered from the acid soluble minerals during the milling process.Large uranium reserves occur in mines found on both limbs of the Quirke syncline. Major reserves are being developed on the South Limb of the syncline, where the Stanleigh Mine, among four past-producers, has been reactivated.IntroductionUranium and thorium commonly occur in anomalous amounts in coarse basal sediments. Radioactivity in basal conglomeratic sediments is generally attributable to resistate minerals, that rarely occur in concentrations high enough to be of economic significance. One type of basal conglomerate found worldwide, in Precambrian cratonic basins, has uranium or uranium and gold concentrations large enough to be of economic interest. Principal among the occurrences are the pyritic quartz-pebble conglomerates of the Huronian in Canada, of the Witwatersrand in South Africa and at Jacobina in Brazil.The uranium and gold mineralization of these conglomerates was derived from provenance areas where both elements occurred and were later concentrated through source degradation and deposition in placers in a reducing environment. Only the Huronian conglomerates, generally much richer in uranium but with negligible gold, have been exploited solely for their uranium content.The uraniferous conglomerates of the Huronian at Elliot Lake, 500 km north of Toronto, continue to represent a major world source and supply of uranium concentrate."

Jan 1, 1986

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to assist the mining industry in implementing continual improvement in management of major unwanted events, and so maximising health and safety performance. A comprehensive body of knowledge has been compiled from diverse mining industry experts for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This paper presents an overview of the body of knowledge captured from diverse mining industry experts for the management of unwanted strata incidents, and explosions in the underground environment. This knowledge is divided into a series of initiating events within both topics (as listed) with further degrees of classification based on design, operation, and management concerns. Strata Underground Initiating Events: Explosions Initiating Events Loss of strata control at longwall face Fire or ignition in a sealed area Loss of strata control in outbye roadways Fire or ignition in an unsealed goaf area Loss of strata control in roadways under development Fire or ignition in an extraction face Loss of control of overburden and caving behavior Fire or ignition in outbye Loss of pillar system stability Loss of control of goaf edge in pillar extraction Fire or ignition in a development panel or first working Loss of strata control in shafts The system guides the user in generating substantive and leading edge controls to assist industry stakeholders in the design, management and reporting of organisational and regulatory compliance requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry.

Aug 1, 2013

By L. Zeka, I. Ndala, J. Frenay, S. Gaydardzhiev

"Reductive leaching of cobalt (III) from a heterogenite bearing ore has been performed. Pyrite was added to the system and simultaneously bioleached in order to provide ferrous iron as reducing agent. Within such arrangement the iron ions are continuously re-circulated inside a Fe 3+ / Fe 2+ loop. As a result Co(III) is solubilized in the presence of Fe 2+ ions in concentrations well below the stoichiometric requirement. The ore has been initially subjected to acid pre-leaching in order to guarantee that the available Co (II) has been entirely removed. Two technological parameters have been studied to show influence on the degree of cobalt leaching: concentration of ferric iron in the inoculum and the presence of bacteria. The bacterial role could be mainly viewed in supplying ferric ions in the system which chemically react with the pyrite to generate ferrous ions used as Co(III) reducing agent. Co(III) dissolution has been less efficient when the concentration of total iron in the system was low, but also when microorganisms were absent. SEM observations on leached heterogenite have evidenced bacterial attack on the mineral; however the precise role of bacterial presence on cobalt (III) leaching is still to be elucidated.INTRODUCTIONCobalt accompanies quite often copper in secondary oxidized ore deposits (Rumbu, 2013). In such associations cobalt is found both as CoII+ as well as CoIII+ (Deliens, 1974). In contrast to cobalt (III), cobalt (II) is leached relatively easy in sulphuric acid solutions. Cobalt (III) when present in mineral form belongs to the heterogenite mineral group with a simplified chemical formulae Co2O3.H2O or CoOOH. In order to be brought in solution, heterogenite should capture two electrons, likewise shown in reaction 1 below:"

Jan 1, 2016

By M. Boussuge

Ceramics and refractories have many common constituents and consecutively exhibit several analogous properties. For example, concerning the thermomechanical properties this paper will focus on, the type of creep that can be observed in both materials is often the same (kinematic hardening). Changes in microstructure (phase transformation, dehydration, sintering, crystallisation,...), induced by heating and/or cooling, can also drastically modify the mechanical behaviour of ceramics and refractories. But the coarse granulates, the porosity and the impurities contained in industrial refractories may lead to specific responses of this material to thermal and/or mechanical loadings. In particular, some differences can be observed with technical ceramics in the main type of damage observed in service : diffuse damage in refractories (microcracking) and localised damage in ceramics (macrocracking). In this paper, the possibilities of transferring a part of knowledge from ceramics to refractories will be discussed, in the field of thermomechanical properties : experimental characterization techniques, mechanical behaviour models. Finally, some problems caused by scale effects and by the integration of thermomechanical properties of refractories in the numerical simulation of industrial structures will be evoked.

Jan 1, 2004

By S. Knapp

Inconel 600 pipes welded to Carbon-Steel are used in CANDU nuclear reactors. Fracture of these welded tubes would have important consequences in term of safety, and therefore their mechanical properties need to be better understood. In this study, the weld region was analyzed at various length-scales using optical microscopy, micro hardness testing, small and large scale tensile testing and digital image correlation (DIC). Large grains were observed in the weld region and smaller grains in the Inconel and carbon steel base metals. Micro-hardness profiles showed variations across the weld and through thickness and were justified in terms of residual stresses in the sample. Large tensile samples were extracted from the welded pipe and were used to identify the material in which fracture initiates. In addition, the local strains in each material were obtained using digital image correlation. Local stress-strain curves were built from the DIC data and compared to stress-strain curves obtained from miniature tensile samples extracted from the carbon steel, Inconel and weld regions. The results demonstrate the advantage of using DIC for extracting local material properties in dissimilar weld systems. Variations in the materials stress-strain curves thought thickness are also presented and emphasize the need for obtaining a complete map of the mechanical properties in the weld region for predictive models to be accurate. Preliminary fracture studies will also be presented.

Jan 1, 2011

By Donald A. Cranstone

Donald Cranstone holds B.Sc. (Honours) and M.Sc. degrees in Geology from the University of Manitoba and a Ph.D. in Economic Geology from Harvard University. He has worked as a mine geologist, a provincial geological survey geologist and as a senior exploration geologist. He joined what is now the Minerals and Metals Sector of Natural Resources Canada in 1971, where he has been a commodity specialist for gold, for copper and another 28 metals. He is a senior mineral economist, currently engaged in analysis of mineral exploration and discovery success in Canada and of the future of the Canadian mining industry. Abstract This paper examines the history of Canadian non-petroleum mineral production. The outlook over the next 25 years, for mining in Canada and in each province and territory, is reviewed. The outlook for mining in Canada and in most provinces/territories is favourable, but problems seem likely in a few jurisdictions unless new orebodies are brought into production. In terms of exploration potential, Canada consistently ranks among the top three countries in the world. Over the last eight years, Canada has consistently been second only to Australia as a destination for exploration investment. For the first time, Canada is ranked in terms of total mineral production, including coal and construction materials, relative to all the countries of the world including countries of the former communist bloc.

May 1, 2001

By J. F. Wright

Introduction Previous to 1924 the mining fields of Manitoba and adjoining territory had not been prospected in detail, and the reports of the exploration of the mineral discoveries to that date had been discouraging. As a result of the apparent failure of all the mining operations, some considered that geological conditions in the country westward from lake Superior extending across western Ontario, eastern and northern Manitoba, and northern Saskatchewan, were different from those in the northeastern part of Ontario, where large gold mines had been developed. Discoveries of importance thus were necessary to renew interest in the mining possibilities of this part of the Canadian Shield, and the successful operations at Flin Flon and Howey in large part were responsible for the beginning of the present activity in what may be described as the part of the pre-Cambrian Shield within central Canada. In Manitoba, the more important developments at present are in the Central Manitoba, Gods Lake, and Knee Lake fields. The large area from west of Flin Flon east to Herb Lake, also, is being explored carefully for gold deposits of merit. A number of properties in Red Lake, Woman Lake, and Pickle Crow areas are being drilled and explored underground. Many of the mines of the Lake of the Woods area, that were producing gold 30 years ago, are re-opened, and new prospects in this field and in the country to the east are being explored. The recent development of Little Long Lac mine in an area near the railway, and considered by some to have been thoroughly prospected years ago, has stimulated interest in the areas formerly prospected. In the autumn of 1934, the belts of greenstone and sediments in the country east of lake Nipigon were staked, and deposits in these fields will be explored in detail this year. This paper is presented to discuss the general features of the geology and gold deposits of the various prospecting fields in Manitoba and adjoining territory. Details of a number of the areas and mines will be presented at this meeting in papers by Barton on Little Long Lac, Tanton on Sturgeon River, Baker on Gods Lake, and Brownell and Kinkel on Flin Flon. Although mining was not active in most of this territory previous to 1930, geologists of the various government departments continued field studies and interesting reports were issued.

Jan 1, 1935

By H. Higuchi

The Sumitomo Metal Mining Company Ltd. (SMM) started to produce electrolytic nickel at the Niihama Nickel Refinery in 1939. In 1992, the conventional matte electrorefining process was converted to the matte chlorine leach electrowinning (MCLE) process, which is currently in practice. SMM has mainly used two kinds of nickel matte as the raw material for the MCLE process. Treatment of new raw materials, which have different impurity contents from the original nickel matte, has become mandatory because of changes in the market. Therefore, the MCLE process has been required to increase its flexibility to treat the different impurity contents in the new raw materials. An increase in the capacity for iron removal is included in such requirements. A new iron removal circuit in the MCLE process, based on a process development study, was recently installed. The iron removal circuit is in operation, and efforts are currently underway to optimize the performance of the circuit by changing the present operating parameters. In addition to the removal of the iron, the application is also expected to improve the nickel recovery. The outline of the new circuit and the current iron balance in the MCLE process are described in this paper, together with the effect of the circuit on iron treatment capacity.

Jan 1, 2006