Search Documents

By Chun-Sheng Liao, Chun-Hua Yan, Sheng Wu, Fu-Xiang Cheng

"INTRODUCTIONChina is providing more than 90% of the rare earth products consumed in the whole world. Acidic extractants are commonly used in the extraction separation of rare earths. Saponification of the acidic extractants by basic substances is usually necessary for the purpose of increasing and stabilizing their extraction capacity, and meanwhile inorganic acids are required for both scrubbing and stripping. Thus acids and bases are the main consumed chemicals, and the resulting salts are the main pollutants generated by rare earth separation processes. Currently, due to increasing environmental concerns in China, rare earth solvent extraction separation techniques are being developed to reduce both consumption and emission of chemicals, which is driving the developments on both theories and processes for solvent extraction separations.In the 1970s Prof. Xu et al. developed the Theory of Countercurrent Extraction (Xu, Li, & Yian, 1985). In recent years, the development of novel processes for rare earth separation has moved beyond the earlier theory. One rare earth separation process, the so-called hyperlink process, has been developed in the past decade and proven in industrial practice to dramatically reduce both the consumption and emission of chemicals during multi-component solvent extraction separations, and therefore is now widely used in the Chinese rare earth separation industry (Liao, Wu, Cheng, Wang, Liu, Zhang, & Yan, 2013). The present article will give a brief review of the development of the theory of the hyperlink processes, and the hyperlink separation flowsheets for typical rare earth mines in China designed using the theory.HYPERLINK PROCESSES (LIAO et al., 2013)A flowsheet of multiple-component separation consists of a couple of separation units. The units of a conventional flowsheet separately consume chemicals for saponification and scrubbing and discharge wastewater with resulting salts. In contrast, the separation units in a hyperlink process are hyperlinked and thereby the chemical demands of the whole flowsheet are decreased. For a feed containing t components of A1, A2, …, and At, it has been proved in theory that the separation mode of (AtAt-1…A2)/(At-1At-2…A1) is preferred in a single separation unit. The hyperlinking between separation units can have two forms. The link between two units locating at a same separation level, such as between (A4A3)/(A3A2) and (A3A2)/(A2A1), is known as horizontal hyperlinking. The link between two units located on different levels, such as between (A4A3A2)/(A3A2A1) and (A3A2)/(A2A1), is known as vertical hyperlinking. Both the hyperlinking forms have been proven to save chemical usage and consequently to lower the pollution emissions in industrial practices as well as in theory."

Jan 1, 2016

By C. Sui, J. E. Nesset, M. Li, J. Y. Kim, S. L. Chryssoulis

"A plant study of zinc rougher flotation at Brunswick Mining was conducted using lime, soda ash and a combination of both as the pH modifiers in order to establish the effects on sphalerite and pyrite kinetics and mineral selectivity. The plant sampling and analysis was augmented by surface analysis using TOF-LIMS, SEM and XPS as well as fundamental precipitation and surface-charge studies in the sphalerite Ca/C03/S04 system.The results revealed the important role of carbonate ions in cleaning the sphalerite surface for effective activation by CuS04 to occur, and the beneficial role of combined soda ash and lime in increasing pyrite and galena depression.1.0 IntroductionThe studies reported in this paper were initiated as part of an investigation into the causes of a particularly pronounced seasonal deterioration in metallurgical performance at the Brunswick Mining concentrator during the summer of 1995. The concentrator treats a complex base metal ore having a typical feed composition of 9.0% Zn, 3.5% Pb, 0.4% Cu and 100g/t Ag at a current throughput of 9,000 TPD, although at the time of the problem in 1995, the average production rate was closer to 10,500 TPD. Zinc, lead, copper and bulk (zinc-lead) concentrates are produced with overall metal recoveries of 86% zinc, 63% lead, 60% copper and 60% silver; results which are typical of the lower recoveries associated with fine-grained, highly complex VMS and SEDEX type deposits. The main economic minerals of interest are an iron-containing (7% Fe) sphalerite, galena and chalcopyrite with the main diluent (about 60% wt) being pyrite.Figure 1 shows a simplified flowsheet of the Brunswick milling circuit while the seasonal decrease in summer metallurgy in 1995 is illustrated in Figure 2. Of significance is the rapid drop in copper and lead recovery in June while there is an apparent delay until late August-September before the zinc deterioration reaches its lowest point. A more typical seasonal effect within the experience of the authors is the reverse of the Brunswick situation, namely an improvement in summer performance thought to be associated with improved differential flotation kinetics during warmer weather leading to better mineral selectivity. The historical Brunswick experience was particularly severe during the summer of 1995 with estimated incremental losses of $10 Million for this period. The potential of the very significant economic benefits to be gained from understanding and hopefully improving the annual drop in performance led to an investigation involving the minesite metallurgical group, the Noranda Technology Centre (NTC) as well as researchers in Professor Jim Finch's group at McGill and the surface analytical services and interpretive skills of AMTEL."

Jan 1, 1998

By D. T. Smith, S. J. Strohmayr

Originally developed as a step change in ultrafine grinding efficiency, the IsaMill™ has made inroads into conventional ball mill and tower mill mainstream grinding duties during the last 5 years - beginning with the Anglo Platinum mainstream grinding projects in South Africa. At the 2006 SAG Conference, plant testwork on the incorporation of IsaMill™ technology into the McArthur River (Northern Territory, Australia) Pb/Zn primary grinding circuit was reported. The IsaMill™ has now become an integral component of that circuit, treating up to 1mm top size feed and directly producing P80 45 µm rougher flotation feed. Two 1.1 MW IsaMills™ are now used in this duty contributing to a 27% increase in overall plant throughput and a reduction in rougher feed size distribution. In this paper, we report on the current state of development and performance of the IsaMill™ in the primary grinding duty at McArthur River and also consider future directions.

Jan 1, 2012

By I. Paredes, R. Díaz, H. Henao

Smelting of copper concentrate generates a significant amount of dusts which are collected in electrostatic precipitators. This material, which is a complex oxide of Cu, Fe, S, As, Sb, Bi and others, is difficult to recirculate into the smelting process due to the reported high concentration of arsenic. However, the dust also has concentration of copper above 10wt %, aside from reported contents of silver corresponding as much as 25wt% of the total inventories of this element in the smelters. Thus, it is of economic and environmental interest the development of a process able to reduce the concentration of arsenic in the dust and produce a material suitable to be recirculated into the smelting process. The present experimental work shows the results of a process of dust sulfidization-oxidition able to remove more than 65wt% of the arsenic present. INTRODUCTION Copper sulfide deposits worldwide exhibit increasing concentrations of arsenic. One case of interest would be the copper ores from the northern zone of Chile, which report high concentrations of enargite (Cu3AsS4) (Revista química, 2015) (Latinominería, 2014). The obtained concentrate from this ore is treated in a Fluidized Bed Roaster, producing calcines with low concentration of arsenic (<0.5 wt% As). This material is suitable to be treated in a Flash Furnace. At the roasting process, the arsenic is volatilized and then precipitated as fine particles of complex oxides. Most of this particulate material is removed from the gas stream through a device called Electrostatic Precipitator (Minería chilena, 2014). The experimental results reported in the literature indicate that arsenic present in these particulate materials (or dusts) cannot be eliminated in oxidizing atmospheres (air) or with inert gases (N2) in a Fluidized Bed Roaster even at temperatures as high as 700°C. There is also information that even the recovery of valuable metals from the dust is difficult through hydrometallurgical processes (private communication). This is how in some foundries these dusts are considered environmental liabilities. Regarding the decomposition of enargite (Cu3AsS4) in neutral atmosphere, it is reported in the literature (Padilla, 2001) that the main chemical reactions are:

Jan 1, 2019

By Carricajo T., S. Nazari

This paper discusses a unique dynamic solution for optimizing comminution area in real time. The proposed technology is a combination of model predictive controller, optimization methods and real-time digital twin for mineral processing. For grinding area, the ultimate goal of an effective control strategy is to maximize the mineral processing, reduce energy consumption and stabilized size classification. To have a continuous and effective comminution operation, a reliable control system that minimizes the need for human intervention is necessary. The implemented advanced control strategy for comminution area consists of two layers in hierarchical structure. The lower layer objective is to stabilize the process stabilization using model based predictive controller (MPC) technique. The unique MPC used in this layer is called BrainWave™ chosen for its robustness, convergence and delay handling; furthermore, the developed platform offers stable and repeatable solution and has short implementation time. The upper layer is a supervisory control, which sends the preferred process operation points to the lower layer to drive the process towards optimal performance. The goal of this layer is to optimize the process targets, as well as making decision. To increase process performance, automatic ore characteristic adaptations are implemented in this layer. A digital twin of comminution area is built in the second layer that runs amongst the process in parallel. By communicating, the process data in real time, a virtual densitometer is built that is being used in our advance process control strategy. Our control strategy has been developed, tested and implemented in various areas of a copper concentration plant. The targets for implementing advance process control are usually increased throughput, decrease energy consumption and variability reduction in particle size distribution. Overall, the results showed in different mine sites are increase throughput between 2 and 5%, specific energy consumption reduction about 15% and process variability reduction up to 60%. In this paper we discuss the results of the recent implementation of this technology on Minera Los Pelambres, Minera Collahuasi and CAP Minería. Their concentrator plants have installed control systems with the most updates optimization features, for SAG mill, ball mills and thickeners.

Jan 1, 2019

By L. A. Homeniuk, R. Bonnar

"The Athabasca Basin has been the scene of an intense exploration effort since the late 1960s, resulting in the establishment of this area as one of the major uranium districts in the world.The A thabasca Group is of Helikian age and unconformably overlies metamorphic rocks of Aphebian and Archean age. Most of the known uranium deposits have a close spatial relationship with the unconformity, graphitic meta-sediments, major northeast-trending structures and the basin edge. It should be noted that, in regard to the latter, some of the Cluff Lake deposits are exceptions.The pre-Helikian rocks underlying the Athabasca Group have been divided into six Iithostructural domains. The known uranium deposits are concentrated in the Wollaston and Mudjatik domains in the southeastern portion of the basin.The orebodies typically have a narrow high-grade portion below the unconformity and a broader, lower-grade disseminated zone in the overlying sandstone. Over-all grades average over 1% U3O8 and our estimate of known reserves totals more than 400 million pounds of contained U3O8. Some of the deposits have high concentrations of other metals, including nickel, arsenic, cobalt and gold. Ubiquitous chlorite and clay alteration is characteristic of the orebodies.Other Proterozoic basins in Canada of similar ages and having analogous geological settings to the Athabasca have received far less attention. Although little of the known uranium mineralization in these basins is related to the Helikian unconformity, there may be an exploration potential for deposits similar to those of the Athabasca basin.IntroductionThe Athabasca sedimentary basin is located within the Churchill Structural Province of the Canadian Shield in Northern Saskatchewan. The basin is elliptically shaped and is approximately 800,000 square kilometres in area.The objective of this paper is to summarize the various elements in the genesis of the unconformity-type uranium deposits of the Athabasca Basin and to evaluate the comparative potential of other Proterozoic basins to host similar unconformity-type deposits."

Jan 1, 1982

By B. M. Das, D. B. Cross

"In June 1983, the Computer Applications and Process Control Committee (CAPC) of the Canadian Institute of Mining and Metallurgy (CIM) circulated a questionnaire to coal mining, exploration and consulting companies in Canada to determine the industry&apos;s level of interest in holding a workshop-style meeting to introduce company personnel to ""state-of-the-art "" computer systems designed to carry out specific technical and management junctions. It was necessary to conduct the survey to determine the specific fields of application and the nature of training which are of most interest.Almost universally, the companies expressed interest in computer workshops and training for applications in the Canadian coal industry. The survey showed that all categories of personnel felt the need for some sort of training. Areas of specific interest identified were: exploration and geology, mine design, reserve calculations, coal mining technology, coal preparation, rock mechanics, ventilation, financial planning, and process simulation. The details of this survey together with an assessment of the significance of computer applications in the Canadian coal industry are presented in this paper."

Jan 1, 1986

By P. Mottahed, E. K. S. Passaris, J. Q. Ran

"The jointed roof of underground mine openings in stratified rock can be analyzed in terms of a voussoir beam. Because of the essential indeterminacy of the structure, previous attempts of theoretically solving the equilibrium equation have been unsuccessful. Numericalanalysisby the finite element method taking the geometrical and joint non-linearity into consideration combined with the experimental method has been adopted to study the performance isopara of the voussoir beam. Deformation and failure mechanism is analyzed in relation to the failure modes. Equations are proposed to estimate the elastic buckling strength and the crushing strength of the voussoir beam and to verify the failure mode of shear sliding. For application of the mechanism of the voussoir beam in mining operations, methods are described to predict the stability of a jointed roof and to design the dimensions of mining openings.IntroductionThe roof stability of an underground mine opening has direct effects on the selection of support methods, opening dimensions and, more importantly, on the safety of mining personnel. The prediction of the roof stability can be of importance in the design of a mining method and in mining operations. The jointed roof of mine openings in stratified rock can be stable under transverse load depending on the roof geometry and properties of the roof material and joints. The stability of this type of roof can be analyzed in terms of a voussoir beam which was introduced by Evans (1941) to study the strength of underground strata. Brady and Brown (1985) analyzed the voussoir beam and suggested that the mechanism of the voussoir beam could be used in the design of underground mine openings in stratified rock instead of the traditional continuous beam theory."

Jan 1, 1993

By M. Choy, A. Kadiayi, E. Magdzinski

"Design of engineering controls to limit occupational noise exposure rely on accurate calculation inputs. Sound in mines can carry considerable distances. Mine ventilation engineers rely on noise propagation calculations to estimate silencer performance criteria for key mine fan installations that are often in proximity to occupied areas of a mine and can remain in service for decades. The blasted and rockbolted walls of hard rock mining tunnels have unique acoustical properties. Underground testing in an operating metal mine in Sudbury, Canada was performed and results processed to characterize noise propagation in mines, with the goal of improving the accuracy of noise calculations.INTRODUCTIONAs mine operators continue to improve and promote workplace safety, addressing noise at fixed infrastructure locations is observed as increasingly common. Underground fans are important to consider in this context, as they are typically loud, in proximity to occupied and sensitive workplaces, and operate nearly continuously. Predicting noise propagation from ventilation fans within underground mines has long been a challenge, with few available resources documenting acoustical properties as calculation inputs. Other factors in addition to rock face absorption properties include tunnel geometry and distance from the fan, which play critical roles in characterizing the noise level at any given point away from the fan. By understanding and establishing methods to better predict noise dissipation along underground mining tunnels, engineers can design noise controls with a greater degree of precision and confidence to effectively protect workers from over exposure to noise.This paper investigates classical methods of predicting reverberant room and direct field noise propagation. These prediction methods are then compared to noise measurements taken within the Fraser Mine of Glencore’s Sudbury Integrated Nickel Operations (Sudbury INO) Measurements were taken at a depth of ~881 m (2,889 ft), along an ~300 m (984 ft) long blasted hard rock mining tunnel. The noise along the mine tunnel resulted from the intakes of two 900 kW (1,200 hp) ventilation fans with a combined exhaust capacity of 300 m3/s (630,000 cfm)."

Jan 1, 2019

By Rodney G. Orr, Phil Robertshaw, Roland Loewer, Klau Lehnert-Thiel

This paper documents the 1988 discovery and subsequent evaluation (to 1991) of diamond bearing kimberlites in the Fort à la Corne area, Saskatchewan, by Uranerz Exploration and Mining Limited. Cameco Corporation began participating as a joint venture partner (50%) in mid-1989. The first indications that kimberlite-type intrusions might exist in the area carne from Geological Survey of Canada aeromagnetic maps. Because of the overburden thickness (over 100 m), magnetometer surveys continue to be the main exploration tool in defining pipe locations and sizes. Magnetometer surveys in varying levels of detail have outlined one main cluster and two sub-clusters, the main group being some 10 km by 50 km in size. In excess of 70 individual targets have been interpreted from the magnetics as probably representing kimberlites. The size range of the individual magnetically-defined bodies is between 1 ha and 74 ha. Proof that the magnetic anomalies were kimberlite intrusions carne in 1989 when each of seven test holes, all drilled on different targets, intersected the potential diamond host rock. The majority of the targets tested were diamond-bearing, with the indicator mineral chemistries suggesting that both peridotitic and ecIogitic diamond parageneses could be expected. To date, 18 individual kimberlite bodies have been drill-tested. A total of 39 bulk samples, amounting to 186 t (representing 360 t of theoretical sample recoveries) were processed in 1990 and 1991. One hundred and sixty diamonds were recovered, averaging 0.04 carats in weight, the largest being 0.6 carats. Most of the bulk sample grades are less than 2 carats/loo t; only three bulk samples have higher grades, the best being approximately 10.5 carats/l00 1. The diamonds are predominantly gem-quality stones.

Jan 1, 1992

"Classification is an important aspect of mineral processing plants and if not operated efficiently can compromise both the throughput and recovery of the circuit. This paper discusses the benefits that can be obtained by operating the classification section efficiently. Since classification in most of the mineral processing plants is carried out using either hydrocyclones or screens the case studies involving the two classifiers were used in the discussion. Studies where optimising the classification circuit lead to improvements in the performance of the overall plant were included to show the benefits of paying attention to this area that is usually neglected. The data from the mill-float mill float, SABC, and Single Stage SAG mill circuit case studies have shown that the circuit throughput can be increased throughputs without compromising recoveries by optimising the classification circuit. On plants where the ore can be liberated at coarser sizes the experimental results have shown that replacing hydrocyclones with high frequency screens can lead to improved plant throughput with no detrimental effect on recovery. The discussion has included information on design and operational considerations for plants that have or intend to use hydrocyclones or screens that could make the classification circuit more efficient.INTRODUCTIONComminution is the process in which particles are reduced in size mainly by crushing and grinding. In most mineral processing circuits comminution is carried out to liberate the valuable minerals prior to subjecting the ore to a recovery process were values are concentrated or extracted (Mainza, Evertsson, Benzer, Tavares, Powell, Rule, Plint, …, 2013). Comminution is an energy intensive process and is usually achieved in stages. It is common to have a classifier after each comminution stage. The process is carried out in stages to minimize energy usage and to improve the efficiency of the process in meeting product specifications. Although comminution circuits have been advancing classification has remained a key component of the comminution circuit design (Mainza et al., 2013). Mainza et al. (2013) summarised the role of classification in mineral processing circuit as: to allow material in the equipment that can promote high operational efficiency, to improve material handling in the circuit, to minimize overgrinding of material to reduce energy consumption, and to provide the best quality product to enter the next stage of processing. Classification stages are employed in comminution circuits to ensure that high throughputs are processed without compromising the product quality or to produce a fine product at relatively low energy. If neglected classification can have detrimental effects on plant performance."

Jan 1, 2016

By P. H. J. Mercier, M. Couillard

Aberration-corrected scanning transmission electron microscopy (STEM) allows for the nano-scale exploration of materials at unprecedented resolution and sensitivity. In this paper, we combine this approach with electron energy-loss spectroscopy (EELS) and energy dispersive X-ray spectroscopy (EDX) to analyze the carbon distribution in residual solids found in solvent-diluted bitumen product extracted from Alberta oil sands. Major components of these contaminant solids are ultrafine clays. Biwettable clays have been associated with the formation of solid-stabilized water-in-oil emulsion, which are known to increase the content of both water and mineral solids in the final bitumen product. We demonstrate that the residual solids present in bitumen product contain carbon intermixed with mineral particles of various size and shape. By probing the carbon content at the nanometer scale with the high chemical sensitivity of EELS, we provide direct evidence of carbon intermixing with clay platelets. This clay-organic association at the nanometer-scale will contribute to the biwettable, hydrophobic character of the platelets, and will therefore play a crucial role in the bitumen extraction process

Jan 1, 2014

By David A. Grieve, David E. Pearson

"A rank-map of Crowsnest coalfield, showing the distribution of the bituminous coal measures and the locations of major structures, has been produced from vitrinite reflectance measurements on over600coal samples. The timing of coalification in relation to these major structures has also been determined.In the west-central portion of the coalfield a complete stratigraphic succession of coal measures which rides on major thrust surf aces is all of high-volatile bituminous rank, but despite the structural discordance no break in rank is discernible across these structures. The thrust faults therefore predate much of the coalification.Three major valleys expose cross sections of the folded coal measures and in each an increase invitrinite reflectance is demonstrable as individual seams are traced from ridge crest to valley floor. Thus, in these sections, a significant amount of coalification post-dates folding. The proportion of this post-folding coalification is found to increase toward the south of the coalfield.A late gravity-fault, exposed along the east crop of the coalfield, places high-volatile coal-bearing successions in contact with low-volatile coal and demonstrably is a reactivated thrust fault. Coalification at this locality occurred between these two different ages of faulting.The variations in rank and the subtleties of the coalification pattern have, together with systematic changes in the maceral composition of coal seams, had a profound effect on coal quality in the coalfield. Coking coals with a variety of properties occur together with some coals that have no caking capacity."

Jan 1, 1985

By D. Harris, G. Ye, G. Oprea, J. Rigby, T. Troczynski

Sintering and ceramic bonding in refractory castables take place mainly in the binding system during the first heat-up and in service. Consequently the strength and the corrosion resistance of the hot face layer depend on the sintering ability of the complex mix of ceramic powders constituting the binding system. As a result, the use of nano- sized reactive powders in the binding system mixes would activate the sintering and enhance the ceramic matrix formation at temperatures below 1300°C. Our work presents the experimental data on sintering behavior of binding systems containing magnesium aluminate and alumina nano-powders in the temperature range of 800-1450°C. The results indicated that a ceramic matrix, similar to high temperature fired bricks, could be generated after firing at the relatively low temperatures available in the non-ferrous smelting furnaces.

Jan 1, 2004

By E. L. Day

"In the early 1930s during the course of test work with a simple gold ore, it was evident that the time required to dissolve the gold by cyanidation was very much longer than should have been needed theoretically for the maximum size gold particles in the ore, A similar conclusion appeared to be valid for other gold ores. In a cyanidation system there are many factors which can influence the dissolution rate of gold, and a decision was made to investigate the more obvious variables, because a literature survey at the time showed that with the exception of the work of Yamazarki on the dissolution of silver in cyanide solution, virtually no attention had been given to this subject, Our work was not reported because the intention was to do this on completion of the Study, but owing to the demands on the Section's personnel for other work the investigation was never completed. Although other investigators have since studied the problem, the methods which we adopted and some of the conclusions may be of interest to metallurgists concerned with gold ore treatment.Form of GoldExperiments with gold ores were not possible because of the number of uncontrollable variables present in a gold ore-cyanidation system, therefore pure metal and reagents were used. Initially some experiments were carried out with gold leaf, but it was soon apparent that metal in this form was unsuitable because the uneven thickness of the leaf caused it to break up into pieces and. there was difficulty in determining precisely when complete dissolution had taken place, Numerous factors both expected and unexpected were found to influence considerably the results and much experimental work was necessary to establish the procedures which were finally adopted, Experiments were carried out with gold in the form of foil, wire, rings and sols. Finally, gold foil in the form of cylinders was adopted for most of the experiments although some work with gold in the sol form was included in the programme. Also some experin1ents were carried out with a gold ore to see if effects which were obtained with sodium chloride on gold sols were applicable to gold ores."

Jan 1, 1967

By Ros Taplin

Realizing the potential of cutting greenhouse gases (GHGs) associated with mining, a variety of approaches has been proposed for their mitigation. The Clean Development Mechanism (CDM) under the Kyoto Protocol to the UN Framework Convention on Climate Change (UNFCCC) has been a key mechanism to assist in implementation of mitigation measures. The objectives of CDM are not only to assist Annex I countries in meeting their GHG emissions reduction targets with cost-effective reduction but also to achieve sustainable development in non-Annex I countries. However, apart from China, India, Brazil and Mexico, many developing countries are still in the stages of formulation or realizing CDM strategies. Projects associated with methane capture and flaring are the fourth most prevalent type of CDM project internationally. This research primarily has addressed emissions abatement and sustainable development aims and effectiveness of registered CDM projects associated with coal mining in China. The paper reviews 30 currently registered CDM projects in China on the UNFCCC database and six other non- Chinese projects. Systematic evaluation involving content analysis of documentary evidence regarding coal mining CDM projects is presented in relation to firstly, quantitative reduction of GHG emissions and secondly, sustainable development outcomes. The projects have been assessed via a set sustainability criteria. Overall it was found that sustainable development goals are only briefly referred to in Project Design Documents, Letter of Approvals and validation documents. Varying types of sustainability initiatives have been implemented with weak to strong indications of effectiveness. This has implications for the future effectiveness of CDM projects in the mining sector, the proposed new market mechanism under UNFCCC, and for assessment of projects under mechanisms established outside the UNFCCC.

Aug 1, 2013

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few – but very important – instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By A. Alfantazi, L. Choudhary

Gold leaching in thiosulfate solution has attracted widespread research interest through the last two decades primarily due to its perceived environmental benefits in comparison to the conventional gold cyanidation technique. However, the data on the corrosion and/or corrosion-induced failures of plant infrastructure materials in the solutions relevant to thiosulfate gold leaching are very limited. Accordingly, this study aims to characterize the electrochemical corrosion behavior of stainless steel 316L in the thiosulfate gold leaching solutions. Electrochemical corrosion response was investigated using potentiodynamic polarization and electrochemical impedance spectroscopy. The morphology of corroded specimens was analyzed using scanning electron microscopy.

Jan 1, 2014

By L. V. Volkov

The equilibrium of the CuO-Cu20-Cu+-Cu2+ system with various chloride ion concentrations in solution in the presence or absence of an oxidant was investigated. It is shown, that, regardless of the presence or absence of chloride ions or oxidant (oxygen) in the system, the process can be divided into three stages, which are characterized by differing rates and mechanisms of metallic copper cementation and cuprite precipitation and, hence, lead to differing rates of the dissolution of nickel into solution. The effect of the concentrations of chloride ion and oxidant on the phases in the process residues is also discussed. The addition of an oxidant increases the amount of cuprite (Cu20) in the leach residue. With increasing chloride ion concentrations, the rate of copper cementation increases, even without an oxidant in solution. The results of these laboratory experiments and the mechanisms developed are consistent with analysis of samples of industrial cement copper obtained from the Severonickel Combine.

Jan 1, 2007

By A. A. Ruitenberg, G. Ruitenberg, J. Chandra

"The Caledonian Belt is mainly underlain by Late Precambrian and possibly Early Palaeozoic rocks, which are in part overlain by younger strata. Most of these rocks are weakly deformed, except for those in some linear . zones, which have been intensely deformed by cataclasis. Mineral deposits related to two distinct metallization episodes have been recognized. The earliest are zinccopper- lead sulphide deposits, which have been concentrated in the axial regions of late-stage cross-folds within the main cataclastic zone. The host rocks are andesitic and dacitic tuffs which show effects of intense talcose alteration, silicification and chloritization. Deposits related to the second episode are mainly composed of copper sulphides with locally abundant tennantite and tetrahedrite, which occur in brecciated and fractured carbonate-quartz veins. These veins postdate the late-stage cross-folds. VLF-EM and high-sensitivity magnetics proved to be very effective in delineating the geology of these deposits."

Jan 1, 1972