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By R. von Gal

Hazelett Strip-Casting Corporation has been producing the Hazelett® twin-belt casting machines for copper casting since the mid-1960s. The first commercial casters were developed for copper alloy strip and anode plate. In 1968, development work was started to adapt the twin-belt caster for copper bar casting to be rolled in-line into wire rod. Since then, 36 casters have been sold as part of the CONTIROD® system for the production of a substantial portion of the world's copper rod supply. A unique feature of the twin-belt caster is the mold's ability to comply with the size and shape of the cast bar as it shrinks during solidification. Maintaining contact between the mold and the bar provides a high rate of heat transfer as well as other benefits, including the prevention of surface imperfections caused by remelting in the mold. This paper will give an overview of the continuous evolution of the twin-belt caster technology with an emphasis on recent developments in compliant mold technology for copper casting.

Jan 1, 2007

By P. R. A. Andrews

"Areas of bubble contact were delineated for cassiterite in the presence of chloride, fluoride, sulphate, phosphate, oxalate and citrate ions using dodecylamine hydrochloride collector. The limits of pH, and the minimum collector concentration were established using the bubble pick-up technique.Bubble contact did not occur below the p.z.c. (point of zero charge), estimated to be 4.7, in the presence of chloride ion, and fluoride ion showed only a weak response in the same pH range. These anions are considered to act as indifferent electrolytes. Activation at pH values below the p.z.c. was obtained with sulphate, phosphate, oxalate and citrate ions; the greatest response was by oxalate and phosphate ions extending pick-up to between pH 2.0 and 2.5.Activation appeared to be strongest when anionic protonated species were in maximum concentration. Strong activation also corresponded to the formation of very stable metal ion species, thought to be formed on the surface of cassiterite, between exposed stannic ions and modifying anions; dodecylammonium ions being absorbed on the surface so modified."

Jan 1, 1991

By Andrea R. Gerson, Roger St. C. Smart, Russell Schumann, Joan E. Thomas, Warwick Stewart, Stuart Miller

Sequential Net Acid Generation (NAG) accelerated oxidation testing using peroxide was carried out on single sulfide mineral samples. The calculation of the nett acid production potential (NAPP) assumes that all the sulfide is present as pyrite and that dissolution results in a 2:1 ratio of H+:SO42-. NAPP as kg H2SO4/t is calculated as 30.6 x wt.% S present. To test whether this calculation is valid a NAPP* value was defined in which instead of using the wt.% S present for the calculation the wt.% S dissolved is used. Stoichiometric analysis of the dissolution products of the sulfide minerals as they would occur at pH 7 indicates, that in all cases, the ratio of H+:SO42- of 2:1 is viable. The NAG to pH 7 and NAPP* closely coincided for pyrite, bornite, chalcocite and covellite. For the three Cu-containing minerals, the NAG to pH 4.5 value was 0 as is predicted on the basis of the speciation likely to be present at pH 4.5. Acid generation is due to hydroxylation of the dissolved Cu between pH 4.5 and 7.0. The NAG to pH 7 and NAPP* values for chalcopyrite, arsenopyrite and pyrrhotite were in reasonable agreement but were not for either sphalerite or galena. Zn is not completely hydroxylated at pH 7 as is assumed by the calculation. For galena, surface analysis identified polysulfide formation on of the leach residue polysulfide. The formation of polysulfide is an acid consuming reaction. Therefore under conditions of accelerated oxidation the NAPP value is a reasonable estimate of the possible acid production in all cases except for sphalerite and galena. However, under conditions of less intense oxidation, for instance in columns, waste rock and tailings dumps, the formation of polysulfides is likely to be more widespread thus reducing the correlation between NAPP and the maximum possible acid production.

Jan 1, 2004

By T. R. Chari

The safe-level dilution of low-level radioactive wastes in large volumes of selected granular material is proposed as an alternative method of permanent waste disposal to current Canadian practice of concentration and encapsulation. Accepting the fact that a "background level" of radioactivity exists throughout the world, the authors feel that the concept of controlled dilution of radioactive wastes to a level in keeping with "background" is a plausible alternative to current thinking on the subject and is worthy of equal consideration.

Jan 1, 1979

By D. Mraz

"In certain instances, rocks around underground excavations behave as a plastic mass. This paper offers several solutions to predicting the mode of plastic flow around cavities and designing mining pillars where plastic conditions exist.IntroductionWhen stresses around underground cavities exceed yield limits of the host rock, the material often behaves as a plastic mass. The best example of this phenomenon is the behaviour of salt rocks in deep salt and potash deposits (more than 500 m deep).However, many other soft rocks exhibit similar properties. For example, Jeremic(1) described certain types of coal yielding plastically under high pressure. Alder suggested that granulated rock behaves plastically.The object of this paper is to propose a de sign procedure for mining pillars exhibiting plastic flow due to the combination of rock properties and in-situ stresses.Prandtl(3) mathematically defined a concept of a generalized, perfectly plastic substance, not possessing the property of strain hardening (Fig. I). He had in mind, a solid with a quasi quasi-isotropic , polycrystalline structure having a well defined yield point, and he postulated that its material elements start and continue to deform plastically when the maximum shearing stress ""'MAX"" reaches a sharp limit, dependent on the mean value of the sum of the major and minor principal stresses:"

Jan 1, 1984

By A. Galibois, R. Singhal

"This paper highlights some of the potential application areas of knowledge-based systems in the mining industry. The basic theoretical principles associated with knowledge-based systems are discussed and the justification for mining applications is given. The paper concludes with a brief description of a prototype knowledge-based system applied to scraper selection that was developed at Université Laval on a LISP machine. IntroductionThe beginning of Artificial Intelligence coincided with the conception and development of the first computer systems some thirty years ago. At that time researchers were euphoric about the possibility of modelling the human reasoning process. Soon, however, they discovered that the combinatorial aspect of the set of possible solutions to a particular problem did not permit an in-depth evaluation.In the mid-60s researchers started to look at the heuristic approach because it was more suited to human behaviour with its congnitive abilities (i.e. representing, reasoning, problem solving and advising). The heuristic approach allows possible results rather than exact solutions and it is more rapid and cost effective than the exhaustive combinatorial analysis. The heuristic approach did allow some noticeable progress in the seventies with the development of the first expert system called MYCIN with the objective of diagnosing blood infection diseases."

Jan 1, 1988

By C. Sist, J. Shannon, J. Fossenier, J. F. Adams

With the cleanest and easiest to treat copper concentrates dwindling and becoming harder to find, electrorefineries must deal with the reality of higher impurity anodes. There are well-known strategies for managing nickel, bismuth, antimony, etc. using bleeds (Ni, Bi, Sb, As) or arsenic control (Bi, Sb) or hydrometallurgical add-on circuits (IX, MRT, SX for As, Bi, Sb). However, for integrated copper producers and those producing other base metals it is often worth considering a more holistic, global approach. This paper will discuss both the well-known strategies as well as some global strategies and the role that hydrometallurgy can play in them. Examples will include atmospheric and pressure leaching, selective precipitation and impurity recycling or fixation. INTRODUCTION In the electrorefining of copper, impure copper anodes are electrically corroded, and pure copper is deposited on cathodes by passing DC current through an acidic copper sulphate solution. The anode copper impurities either settle to the cell bottom as insoluble components (anode slimes) or remain in solution with minimal deposition at the cathodes when correct operating parameters are maintained. Consideration of impurities is important in all copper electrorefineries. A typical impure anode contains 98.5–99.5% copper (Schlesinger et al., 2011). Table 1 shows the range of impurities reported for all copper anodes in the 2007 survey of operating refineries (Moats et al., 2007). Also shown is an approximate “limit” of anode compositions within which the majority of refineries operate without additional impurity removal capacity (beyond conventional liberator/bleed circuits). The column is somewhat subjective and meant to be an approximation only since there are many factors that influence impurity deportments and refinery impurity tolerances. More recent world survey data from 2013 show the averages for all impurities trending upward from 2003 to 2013 (Moats et al., 2013). With a competitive market for good concentrate and more copper recycling from electronics (which contain high levels of impurities such as nickel, lead and antimony), this trend is expected to continue through the coming years. The traditional primary method of impurity control is refinery bleed through liberator cells which are employed in the vast majority of refineries (Moats et al., 2013). These are used to control copper (primary liberators), nickel, arsenic, antimony and bismuth (secondary and tertiary liberators). Other methods of impurity control include arsenic addition (upstream in the smelter deporting to anode or directly to electrolyte) to control antimony and bismuth (Kamath et al., 2003), ion exchange or molecular recognition technology (Hur et al., 2005; Navarro et al., 2012) for antimony and bismuth. Many refineries also operate nickel evaporators to remove nickel sulphate before recycling back acid. Some use, or are contemplating using, acid purification units to recycle acid and arsenic without nickel and making nickel carbonate (Kamath et al., 2003; Sheedy et al., 2006).

Jan 1, 2019

By R. D. Clark, Heinz Althoff

"The advantages and disadvantages of a mobile crushing plant with a belt conveyor system compared to a stationary crushing plant with haulage by heavy trucks are described. The capital expenditure and operational expenses are compared and the individual cost factors are explained.Every open-pit mine or quarry, however, is different and has to be assessed and analyzed individually in order to find the optimum and most economical solution. Due to the high truck haulage costs, many open-pit mines tend to the more economical solution with mobile crushing plants and continuous belt conveyor operation. IntroductionFor the material haulage within an open-pit mine the heavy truck is the most flexible means of transportation. However, due to the high fuel consumption, wear and labour costs, it is also the most expensive one. Therefore, many open-pit mines are looking for alternative solutions for the material transport A mobile belt conveyor system is most likely to meet the requirements because it is efficient and economical with regard to the power consumption. The material , however, has to be crushed at the mining face to lumps which are suitable for conveyor operation. For this purpose a mobile crushing plant is required.In some open-pit mines the crusher is also used to crush the material to lumps of smaller particle sizes in order to save crushing costs in the preparation plant.Although a cost comparison between a system with stationary crusher and truck haulage and a system with mobile crusher and belt conveyors favours in most cases the belt conveyor system, up till now only a few open-pit mines and quarries benefit world-wide from the advantages of the mobile crushing plant with continuous belt conveyor operation."

Jan 1, 1986

By C. Gu

Flow field design is critical for PEM fuel cells. The flow field design can affect reactant distribution to the catalyst surface, water management, thermal management and current collection. Therefore, it has tremendous impacts on the fuel cell performance and durability as well as reliability and operational flexibility. In this paper, an optical method is used to study the reactant distribution in the flow field channels of two commonly used flow field designs, straight channel design and serpentine channel design. Images of the flow patterns are shown followed by discussions of the flow patterns.

Jan 1, 2005

By H. Ikeman

"The highly specialized communication systems used in the mining industry place exacting demands on equipment and transmission media. Safely and reliability of services are perhaps the two most important factors. Fibre optics is ideally suited 10 meet these stringent requirements. Aside from being an intrinsically safe, non-sparking and EMI/RFI immune medium , fibre optics offers greater reliability , higher quality of services and superior flexibility over conventional copper or radio-based communication systems.This paper wilt show how fibre optics can be applied in mining industry applications. Emerging trends and concepts will be presented to show how fibre-optic-based integrated service communication networks and local distribution systems can be implemented.IntroductionCommunication requirements in today's mine s are varied and extensive. The communication system must be rugged , safe and reliable, yet provide an ever increasing amount of high quality services. Presently, these systems are implemented using conventional copper cable. As mining method s and technology advance and the demand for better and more communication services increases, traditional systems quickly reach their limitations. It is under these circumstances that we turn to fibre optic communication systems.Fibre optics is a mature technology which is finding its way into more and more applications worldwide. A fibre optic communication system can provide a level of performance unattainable by conventional cable systems yet ca n be cost competitive. As is well known, fibre optics provides a noise-free, noise-immune, high -capacity communications channel. Glass fibre, being dielectric and non-sparking, is an intrinsically safe communications medium. Clearly, it is ideally suited to the harsh environment present in a mine.From a communication systems point-of-view, the topology of a deep mine is unique. The objective of the systems engineer is to implement a total communications capability throughout this wide spread area. Ideally all classes of services should be accessible throughout the network-an integrated network concept. Recent advances in communications technology combined with fibre optics make this realizable."

Jan 1, 1984

By F. H. Samuel, J. E. Gruzleski, S. Valtierra, H. W. Doty, N. Andrade

In this work, the age-hardening behavior of cast Al-Si base alloys was investigated. It was found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu-Mg alloys. TEM observations reveal that the age-hardening behavior is related to the precipitation sequence of the alloy. For the Al-Si-Cu-Mg alloy, the first aging peak is the result from the high-density GP zones, while the subsequent are from metastable phases. The transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks.

Jan 1, 2006

By M. Fall

The progressive depletion of ore available at shallow depths in several underground mines around the world means that underground mining operations would increasingly be carried out at greater depths and therefore at higher temperatures. However, our understanding of the effect of hot temperatures on the response (mechanical, economical, environmental) of cemented paste backfill (CPB) is still limited. Hence, an extensive laboratory investigation was conducted to study the performance of young and aged CPB, in response to deep mine temperatures. Several CPB samples with different compositions, cured at different temperatures (20 to 50°C) and different times (7 to 160 days) were tested regarding their mechanical properties, economical performance (binder consumption) and microstructural properties. The results show that hot temperatures significantly affect the performance properties of CPB at young and advanced ages. An increase in the curing temperature leads to a considerable improvement of the rate of gain of CPB strength and also to a significant increase of the strength of CPBs studied. CBP samples cured at hot temperatures show lower binder consumption and finer pore structure. Results of this study could serve as background information for the development of optimal mine backfill design procedures.

May 1, 2007

By J. Moyes

The Intec Copper Process is an internationally patented hydrometallurgical process for the extraction of pure copper and precious metals from sulfide concentrates. Developed and proven in Sydney, Australia at a cost of US$15m over the last ten years, the Intec Copper Process is now ready for commercial application. The Intec Copper Process has several notable advantages over both smelting and other hydrometallurgical processes. Starting from a base of substantially lower capital and operating costs than any other conventional or developing process, the Intec Copper Process is economically viable at capacity levels as low as 15,000tpa-Cu, and capable of accepting low grade and metallurgically complex concentrates. Precious metals are recovered within the Intec Copper Process circuit, without the need to re-treatment of the environmentally stable solid residues. The Intec Copper Process offers the lowest energy consumption of the available technologies, with no liquid emissions or production of noxious gases. Unlike smelting, sulfur is recovered in the solid residues in elemental form.

May 1, 2002

By R. Spring

"Soft-sensors are a computer software alternative to inadequate hardware instrumentation. Filters are averaging methods that reduce the noise in any sensor's signal. This paper introduces these topics and places them in a mineral processing context using then-product formula.Soft SensorsAs their name implies, ""soft-sensors"" are computer programs that estimate values for process variables (Tham, 1991). This approach is useful when the appropriate hardware sensor does not exist, is deficient, supplies only infrequent values, etc. For example, in mineral concentrators the traditional magnetic flowmeter/ nuclear density gauge instrumentation for measuring slurry flows costs $5,000 or more per flow and requires frequent maintenance. However, metal assays are commonly available from online X-ray fluorescence analyzers and application of the n-product formula (Taggart, 1945) to these assays conveniently provides software estimates of the flowrates (albeit only when the circuit is in steady-state).Soft-sensors are used by inferential controllers that base their control actions on the process values ""inferred"" by the soft-sensor. Such was the case at Brenda Mines where the rod mill feed tonnage controller used an inferred value of the cyclone overflow particle size (Bradburn, 1976). It was also the case at Brunswick Mining where reagent controllers adjusted reagent addition rates throughout the plant according to the various ore flowrates inferred by an expert system (Spring, 1991). A unique feature of the expert system soft-sensor was its dynamic flow models which compensated for residence times, material transport lags, etc. Thus the soft-sensor values were valid under both steady-state and nonsteady- state conditions."

Jan 1, 1992

By Philip M. J. Gray

"The real cost of conversion from ore to semi-fabricated non-ferrous metals has been increasing for many years. Consumer resistance and improved knowledge and techniques now available justify investment in revolutionary as well as evolutionary methods of extraction. Metallurgical factors in current practice which preordain high production costs are identified as: smelters' demand for clean minerals, use of processes with low intensity of working per unit of reactor volume, use of low-velocity reactions, use of long reactor retention times relative to the speed of reactions, dilution of values in solution and commitment to electric power as a source of energy.Six new types of flowsheet are proposed for processing from ore to metal, composed of steps which are economic to construct and maintain and making maximum direct use of fossil fuel and the energy content of minerals. The basic knowledge and technology for developing these flowsheets exists. It is very tentatively suggested that these routes might reduce the capital and production cost for conversion of ore to metal by 30-50%."

Jan 1, 1980

By O. Zach, K. Gamweger

"The Process of gas purging in molten Aluminium has been an industrial practise for many years. The melting of alloying elements and their rapid distribution in the bath is very important. To improve the mixing and homogenisation process, at RHI NON FERROUS METALS ENGENEERING GMBH a lot of CFD calculations were done. The so developed new ""purging program"" was tested at Alumino Catalan S.A., Spain. The results of the testtrials were very satisfactory and corresponds very well with the calculated data."

Jan 1, 2004

By A. T. GRIFFIS, R. J. GRIFFIS

A large magnesite-talc body is locared in Delora Township, 11 km sourh-southeasr of Timmins, Onrario. The deposit occurs in part of an Archean greensrone belt dominated by volcanic and sedimenrary rocks and large bodies of ultramafic intrusions. The magnesite-talc zane is abour 1800 m long, has a maximum width of 300 m and has been drilled ro 120 m below surface. Chemical analyses of rhe main carbonate zane average 20 ro 28% soluble MgO (magnesia), 5 ro 6% rota/ iron oxide and less rhan 0.1 % CaO (lime). Mineralogically, the zane consists of approximately 54% magnesite, 28% rate, /5% quartz and 3% hematire. Perrographic srudies suggest that rhe various assemblages of magnesite, rate, quartz and serpentine were derived from a parenr serpenrinire (after dunire). An early carbonitization stage, which produced a high-magnesite, low-talc assemblage, preceded a farer decarbonitizarion stage, which formed rhe main magnesite-talc assemblage. Despite a favourably low calcium oxide content of rhe magnesite-talc rock, considerable iron in the magnesire /at rice has limited the quality of the beneficiared product: rhe besr flotation concentrate to dare yields 92 to 94% dead-burned MgO. Experimen- I L t r i i c:~:.•-4- -------- ? -_;> ,•----1---- ta/ work continues on finding a process whereby high-purity magnesia can be produced on a commercial scale.

Jan 1, 1984

By R. Minto, W. G. Davenport

The slag removed from the reverberatory furnaces of copper smelters contains significant copper values. A serious financial loss is involved, as further recovery operations are not normally carried out. This paper describes the factors affecting physical transport of matte into slag by gas bubbles, and the subsequent entrapment and flotation of matte drops. Three distinct patterns of transport behaviour have been identified from studies of a number of liquid/liquid systems, including liquid metal and liquid matte systems. A theoretical approach is proposed to explain these behaviour patterns, and to predict transport and entrapment behaviour in matte/slag systems. The concepts of "Film Coefficient" (ø) and "Flotation Coefficient" (?) are introduced. The effects of smelting process variables on the physical loss of copper matte in slag are also discussed.

Jan 1, 1972

By R. Roufail

Mineral liberation is accomplished by comminution and is the first step towards achieving successful downstream processes such as flotation or leaching. In metal mining, one of the most effective comminution methods that is used to grind particles below 10 microns is stirred milling. In this paper the study of particle breakage mode vs. mill operating parameters is addressed. Stirred mills' grinding action is mainly attrition, but operation can be manipulated to include breakage by compression or impact loading. Macro and micro analysis of particle breakage and grinding mechanisms are correlated. Macro analyses convey information that relates grinding mechanism to particle size and shape. It is speculated that the breakage mechanism in the horizontal stirred mills is massive fracture for the coarsest particles and attrition (abrasion) close to the grinding limit where the size reduction ratio approaches 1.0. For micro analysis, the particle breakage mode has a direct impact on fracture type either transgranular or intergranular. Intergranular particle breakage leads to higher mineral liberation compared to transgranular breakage. Similar minerals would have more homogeneous properties that convey a stronger bond compared to dissimilar, heterogeneous mineral bonds. Transgranular fracture requires higher energy than inter granular fracture; trans granular fracture toughness of pure single phase mineral is about 10-14 % higher than the intergranular fracture toughness. This communication presents the results of an investigation to assess how operating conditions can affect trans- vs. inter-granular breakage.

Jan 1, 2009

By M. Sabau

The Electrowinning Plant at INCO's Copper Cliff Nickel Refinery is a precious metals upgrading plant. The feed to the plant contains copper, nickel, cobalt, iron, significant amounts of precious metals and some impurities. Copper is the most abundant element in the feed. This paper describes the major equipment and process changes over the last twenty years, geared to improve the tankhouse operation, workroom environment and recovery of copper from the acidic solution. Copper is plated on to titanium blanks using explosion-bonded crossrods, animal glue as a levelling agent, and an organic surfactant for mist control. The installation of the stripping machine in 2001 required a number of changes: cathode and anode contacts were redesigned, flat bus bars were replaced with dog-bone type, spacer boards for cathodes and anodes were installed, longer anodes started to be used, and the plating cycle was extended from seven to fourteen days. A number of initiatives for improvement are being carried out. Explosion-bonded crossrods are being replaced with titanium-clad crossrods. The plan for the near future is to increase copper production by increasing current efficiency and current density. The possibility of lowering the iron concentration in electrolyte and changing the acid mist control method is being investigated.

Jan 1, 2007