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"Real-time, on-stream analysis of the metal content of process slurries is an essential prerequisite for process monitoring and advanced control of mineral processing circuits. On-stream X-Ray Fluorescence (XRF) sensors for base metal applications are available commercially and form the basis of many plant monitoring circuits. To date, these commercial technologies have been insufficiently sensitive to measure precious metals such as gold and platinum group elements, typically present at part-per-million (ppm) and sub ppm levels. CSIRO has developed a novel X-ray based technology, called UltraGold, which enables detection of gold in slurries on a real-time basis with a precision below 100 parts-per-billion. This technology is based on the use of advanced X-ray optics, extensive Monte Carlo computer modelling for analyser design, high accuracy X-ray spectrum fitting where the X-ray intensities are matrix corrected. In this paper, we will introduce this technology and discuss the results of a proof of principle study performed in the laboratory with plant slurries (tailings and concentrate) from an Australian beneficiation plant. Finally, we will discuss further planned improvements. As projected grades in (gold) mining around the world fall and several large-scale mines approach the limits of their economic reserves, this method can enable significantly reduced operating costs by rapid analysis to improve circuit efficiency and hence improve recovery significantly.INTRODUCTION This paper describes a study undertaken to explore the feasibility of applying CSIRO?s UltraGold XRF technology to the on-stream measurement of gold in process slurries. The provision of rapid, accurate information of gold grade in feed, tailings and concentrate streams would facilitate significantly improved process control and early detection of plant upsets, resulting in substantial cost-savings. CSIRO have patented X-ray fluorescence (XRF) techniques for the analysis of key elements in slurries present at part-per-million (ppm) and sub-ppm levels. Conventional, commercially available on-stream XRF instruments generally have detection limits in the tens of ppm range, precluding their use for analysis of elements like gold that are mined and processed at much lower concentrations."

Jan 1, 2017

By J. H. Pee, Y. J. Kim, H. U. Lee, G. H. Kim

The general recycling process of tungsten scrap to produce tungsten raw materials (tungstic acid, ammonium paratungstate (APT) and WO3) have been carried out by the oxidation, milling, sodium-fusion, dissolution, and extraction processes. Many studies on the high temperature oxidation of tungsten scrap have investigated various aspects such as swelling kinetics, fracture resistance, and the effect of alloying composition. However, the accelerating factors on the scrap oxidation rate during oxidation were not considered here. In general, oxidized products were fused with sodium carbonate or sodium hydroxide to produce Na2WO4. Later in the process, solid Na2WO4 was dissolved in water. This process required considerable reaction time and was a costly process. Therefore, the aim of this study was to increase the solubility of solid oxidized products to produce Na2WO4 solution by hydrothermal reflux method. Na2WO4 solution was used to produce CaWO4 and H2WO4 by general chemical reactions with calcium chloride and hydrochloric acid. Ammonia solution was also added to the tungstic acid to produce APT. In this study, the effect of ammonia addition on the APT precipitation process was investigated in detail.

Jan 1, 2015

By B. Wasmund, M. Parravani, M. Jastrzebski, Z. Coull

"One of the main drivers of overall profitability of pyrometallurgical vessels is refractory lining campaign life. Increased economic pressure to improve vessel life requires innovative solutions to the problem of refractory cooling. Hatch has recently developed a high-intensity, waterless cooling system that bridges the performance gap between external shell cooling and internal water-cooled copper elements. External shell cooling has a limited effectiveness in protecting the refractory lining, because it is thermally insulated from the hotface of the lining by its thickness. This situation does not improve until the lining itself has become worn near the end of the campaign. The patented technology developed by Hatch overcomes this problem by positioning high-velocity air-cooling channels within the lining, closer to the hotface where the cooling benefits can be realized throughout the entire duration of the campaign. The current paper presents the development and application of Internal Air Cooling technology as well as results from the pilot campaign in an operating commercial vessel. Various adaptations for this novel, cost-effective and inherently safe system are also discussed."

Jan 1, 2015

By C. Prévost, V. Leclerc, R. Pinto, M. Ruel

"A buffer’s ability to dampen production variations is directly related to its size. Small buffers cannot handle large variations in production, resulting in production losses when their inventory is depleted or saturated. This paper presents a predictive control algorithm used to regulate the inventory in a buffer of limited size, subject to large production variations caused by an upstream batch process. The algorithm was designed to manage the acid flow rates in an acid regeneration process, servicing batch leach reactors at Rio Tinto Fer et Titane, in Sorel-Tracy, Québec. The objective was to increase production by reducing equipment downtime caused by imbalances in the acid tanks servicing the leach reactors. The controller attempts to maintain acceptable acid tank volumes by optimizing the leach reactors acid/slag ratio and reaction time as a function of anticipated acid needs, all while maintaining product quality.INTRODUCTION Some beneficiation processes in extractive metallurgy require processing bulk material in batches. Typical examples of metallurgical beneficiation batch processes are smelting, leaching, electrowinning, elution and carbon-in-pulp. These processes are often situated midstream in an ore beneficiation flow sheet and either receive or transfer ore to continuous processes. Batch processes, by their very nature, introduce large variability in the flow sheet, because they process large finite quantities of material at nearly periodic time intervals. In order to dampen variations in production, various buffers–tanks and stockpiles–are utilized to accumulate ore upstream and downstream of batch processes. A buffer’s ability to dampen production variations is directly related to its size (Phillis & Gumede, 2011). Small buffers cannot handle large production variations, resulting in equipment downtime when their inventory is depleted or saturated (Everett, 2010, Berton et al., 2013). Consequently, the batch equipment production rates must be adequately managed to minimize production losses, attributed to depleted or saturated inventories, while maintaining product quality. Algorithms that anticipate or predict future production variations are often utilized to regulate buffer inventories, subject to large flow rate variations (Salvo et al., 2002; Bonvin, 2013). This paper presents a predictive control algorithm used to maintain an acceptable volume in a spent acid tank servicing several batch leach reactors. The algorithm is implemented at the acid leach plant of Rio Tinto Fer et Titane, in Sorel-Tracy, Québec."

Jan 1, 2017

By Keith Spence

"The notion of ""value"" has always been a subjective and contentious issue. Indeed, Value is in the eye of the beholder. There are varied methods and practices for valuing property, as there are industries in which they are applied. For example, there are ""replacement value"", ""insurance value, ""salvage value"", ""appraised value"", ""book value"" and ""fair market value"", to name a few, although in the mining industry, valuations usually refer to fair market value.In the Canadian mining industry, at present, there are no comprehensive regulations or guidelines that specify which approaches or methods are appropriate for use in the valuation of mineral projects. In January 1999, The Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission recommended that the Canadian Institute of Mining, Metallurgy and Petroleum establish a committee to review and advise on approaches and methodologies for the valuation of mineral properties. Among the approaches to be considered, are included the following: the Discounted Cash Flow Approach, the Cost Approach, the Option Pricing Approach and Market Comparables Approach. In addition, methodologies differ depending on whether the project is at the exploration stage or the producing stage.The CIMVal committee expects that its final report will form the basis for a standard Canadian Code for the valuation of mineral properties."

Jan 1, 2003

By Saikat Chatterjee, Xintong (Brett) Liu, Kinnor Chattopadhyay

Magnesia carbon bricks are commonly used in BOFs and are generally pre-heated before the BOF goes into service. Owing to very stringent emission regulations, the BOF pre-heating process need to be controlled and optimized so that, the emission standards are met. One of the major concerns in organic emissions are its stringent limits on emission rates and total volatile emissions. In the present work, an attempt has been made to integrate CFD and Thermodynamic models to predict the emission rate of volatile organics during the pre-heating process. A one dimensional heat transfer model was developed using visual basic and then integrated with thermodynamics calculations using FactSage 6.4. The parameters that affected organic emissions were the pre heating procedure, gas composition of the burner, heating rate and type of the burner. Typical composition of MgO-C bricks and binder materials were obtained from literature and vendor data sheets. Chemical reactions between organic materials, refractory and burner gasses were considered. The model predictions indicated that certain burner conditions could destroy all organics before it exits the vessel while other conditions needed the use of an after burner at the mouth of the vessel. The model was also able to predict the organic emission rates based on the chosen pre-heating profile. This kind of predictive model will be very useful for the steel industry and enable them to justify permit limit applications and stick to the limits by fine tuning their pre-heating process.

Jan 1, 2015

By A. Zaidi

"The mining and metallurgy industry is highly energy intensive and one of the largest energy users in Canada. Energy costs are also a major component of total production costs in this industry as described in the 1990 Report of The Canadian Industry Program for Energy Conservation (CIPEC). For some plants, energy costs are reported to be up to 30% of total production costs. Therefore, a reduction in energy costs provides an opportunity to improve industry profitability. The specific energy intensity and production costs can be reduced by using modem energy efficient natural gas technologies. In addition, these technologies often improve product quality and increase productivity. Natural gas not only offers economic benefits, but is also environmentally benign as compared to other major energy sources. Emissions of NO"", CO2 particulates and SO2 are lower with natural gas than other fossil fuels.This paper provides a brief overview of some state-of-the-art gas technologies for the mining and metallurgy industry including cogeneration, oxy-air-fuel burners, ceramic immersion tube heaters, direct gas contact process, low NOx burners, and energy efficient liquid heating systems.CogenerationCogeneration is defined as the simultaneous production of electricity or mechanical power and useful process heat from a single fuel source. One of the primary considerations in selecting a cogeneration system is the relative quantities of electrical and thermal energy which are to be produced. Two types of systems are discussed below."

Jan 1, 1993

By Seong-Ho Ha, Shae K. Kim, Young-Ok Yoon

In the this study, surface segregation of Mg and Ca with Mg addition range from 5 to 10wt% in Al-Mg alloys with Mg+Al2Ca master alloy and its effect on the oxidation resistance were investigated. The addition of Mg+Al2Ca master alloy as the Mg alloying element led to the surface enrichment of Mg and Ca during high temperature oxidation. As a result of the oxidation test by TGA, the oxidation resistance of all the examined alloys was significantly improved with increasing Al2Ca content. The weight change of Al2Ca added Al-5Mg and Al-7.5Mg alloys indicated the complete oxidation resistance during the whole oxidation test time, while a slight weight increase was shown in the case of Al-Mg alloys even with Al2Ca addition. The improvement of the oxidation resistance in Al2Ca added alloys may be attributed to the formation of the protective oxide layer mixed with CaO and MgO on the surface.

Jan 1, 2015

By K. Bullock, M. Levesque, G. Lyle, D. L. Millar

ABSTRACT The options for reducing the carbon footprint of energy use in mining fall into three categories of activity: i) reducing demand, ii) improving energy utilization, and iii) adopting low carbon energy technologies. In addition to the environmental imperative, the economic case for these activities gains higher priority as the prices of electricity, gas, and liquid fuels increase. Low-carbon, energy-saving technology options that are available to mining industry companies lead to projects with return rates that must compete alongside other capital-intensive projects considered by mining company boards. Energy projects frequently involve longer payback periods and lower rates of return than those of competing bids for capital, such as new mineral property developments. For energy services companies that specialize in the financing, construction, efficient operation, and maintenance of energy projects, the same returns and payback periods can be considered acceptable or even attractive.

Jan 1, 2012

By Y. Thibault, L. Morin, R. Cameron, D. Gould

"There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite tailings in the Sudbury area alone, with an average nickel grade ~0.8% (plus cobalt). Pyrrhotite is a highly reactive sulphide mineral that has the potential to generate acidity; consequently, it is stored in large tailings ponds that require perpetual treatment to avoid the production of acidic drainage. Re-processing this material using bioleaching technologies has the potential to recover valuable metals, while reducing the toxicity, reactivity, and acid generating potential of the remaining residues. CanmetMINING is currently developing a stirred-tank bioleaching process to recovery nickel and cobalt from pyrrhotite-rich tailings. Stirred-tank experiments have been conducted with one tailings sample over a range of pH and temperature conditions, resulting in 80 to 90% and 70 to 80% leaching of nickel and cobalt respectively in 10 days.INTRODUCTION Sulphide tailings may represent a significant financial liability for mining companies as these wastes may produce acidic drainage under some disposal conditions. As a result, the companies must post financial bonds large enough to ensure there are sufficient funds for perpetual management of these wastes. At the same time, there are billions of dollars in metals incorporated into these mining wastes waiting to become valorized. Many sulphide tailings are amendable to bacterial oxidation for metal extraction. Re-processing of tailings using bacterial leaching has the potential to recover valuable metals from waste; and reduce the toxicity, the reactivity, and the acid generating potential of the remaining residue. By reprocessing these wastes there is an opportunity to significantly reduce liabilities and financial assurance bonds, while recovering metal values. There are an estimated 50 to 100 million dry metric tonnes of low-grade nickeliferous pyrrhotite-rich tailings in the Sudbury area alone with an average nickel grade ~0.8% (Peek et al., 2011) plus cobalt and copper. Pyrrhotite is separated from pentlandite concentrates by magnetic separation and flotation. It is already finely ground and has often been segregated from other tailings material, making „mining? relatively inexpensive. This represents roughly (> $100/ton) in contained value, with negligible mining costs. This paper reports on the development of a stirred-tank bioleaching process for recovering nickel and cobalt from pyrrhoitite-rich tailings, which is currently underway at Canmet MINING."

Jan 1, 2017

By D. M. Maijer, S. M. Mohseni, A. B. Phillion

The microstructure evolution kinetics of aluminum alloy B206 during artificial aging has been investigated using non-isothermal calorimetry. A combination of differential-scanning calorimetry (DSC) and tensile tests have been utilized to develop an Avrami model to predict the precipitation kinetics as a function of the thermal processing parameters. The Avrami coefficients, found based on a Kissinger analysis, compare well against those reported in the literature for aluminum-copper alloys. The rapid precipitation kinetics predicted by the Avrami model at temperatures higher than 200°C were assessed through a qualitative comparison against hardness measurement results. In contrast to the continuous hardening observed at 150°C, the material softens with continuing heat treatment at 250°C resulting in an overaged state. This can be attributed to the rapid precipitation kinetics at this temperature, leading to the termination of the precipitation-hardening effects at early stages of artificial aging.

Jan 1, 2015

By J E. McMynn

The development of the Granduc mine presents a number of problems which are peculiar to its location and surrounding terrain. Because the development tunnels portal onto an area which is covered by an extensive glacier, and the mountain-side is subjected to dangerous snow slides, it was decided to construct an underground powerhouse to supply the necessary electric power and compressed air. This paper deals with the special problems inherent in the design and -construction of an underground plant. It involves the installation of diesel-electric generating equipment having an aggregate capacity of 1,050 kw.,and of air compressors with a total capacity of 2,400 cfm. Items dis-cussed include the selection of equipment to meet site conditions, the ventilation and cooling of the underground room, and the protection of personnel and equipment from explosions and fire. A short discussion on the automatic supervisory and alarm installation is also included. THE Granduc mine is located 135 miles north of Prince Rupert and 25 miles north of Stew-art. This seems quite accessible, mileage-wise, but, due to mountains,

Jan 1, 1963

By J. B. Edwards

"The case is presented for the use of simulators for the computer-based training (CBT) of mining plant operators and for introducing them to automatically controlled systems. As well as their use in the classroom, the role of simulators is examined for ""on-plant"" use in trouble-shooting, fault-finding and maintenance of automatic systems. Case studies are presented showing how specific simulators are becoming established or have potential in the areas of automated materials handling, machine testing, setup and guidance. The evolution of scientific simulations into simulators of widespread practical use is discussed and present-day limitations of computer speed and graphics are considered. Related areas of research for the Canadian Centre for Automation and Robotics in Mining (CCARM) are identified.IntroductionCCARM's Commitment to Simulator DevelopmentAs automation is progressively developed and exploited in mining operations, there arises an urgent need to educate and train staff responsible for its introduction and operation in our mines and for its maintenance. For this purpose , an essential ingredient of an automation program is the development of appropriate mining system simulators for use by a wide variety of personnel. The author has been fortunate to have been closely involved with the development of automatic control systems for a variety of mining machines and mining systems in the United Kingdom. A key ingredient of the research phase in each case has been the use of simulation techniques. As projects have moved toward their commissioning and exploitation phase, the simulations have evolved into simulators tailored for use by machine operators and maintenance personnel. Illustrative case studies are presented later. The researach of the newly constituted Canadian Centre for Automation and Robotics in Mining (CCARM) will likewise involve extensive simulation, and the development of simulators (from the scientific programs) for use at the mine by operators and technicians will be given high priority in the Centre's over-all work program."

Jan 1, 1990

By John Shirokoff, Ladan Khaksar

"Cyclic polarization technique and also potentiodynamic measurements were applied to study corrosion behavior of 13% chromium steels in chloride containing environment. Potentiodynamic measurements were performed at 25 and 75 °C with 0, 10 and 20 g/l NaCl in 0.01 M hydrochloric acid solution. At the same time, the significant pitting parameters such as corrosion potential (Ecorr), pitting potential (Epit), protection potential (Epro) and passive current (Ipass) of cyclic polarization curves with various NaCl concentration were analyzed and compared to describe the corrosion behavior of 13% chromium stainless steel. Surface measurement techniques such as SEM and EDS were used for morphology and analysis of corrosion products. The results showed that both temperature and Cl- concentration had significant effects on corrosion behavior of 13% chromium stainless steel in acidic solution.INTRODUCTION Of all the corrosion resistant alloys (CRA) used in oil and gas developments, martensitic stainless steels (MSS) are some of the most common ones these days. These steels not only have the advantages of normal steels: high strength, cost-effective, easy to manufacture, available in a wide variety of product forms, but they also have good CO2 corrosion resistance at higher temperatures as a result of their 11% minimum chromium content. One of the most common types of MSS used in the oil and gas industry is 13% chromium steel. NACE and API standards both reference several different varieties of 13% chromium steels for use in oil and gas projects(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013). All types of 13% chromium steels have about 12 to 14% chromium and other minor alloying additions, and can be placed into two general groups: conventional and modified. Conventional 13% Cr steels (13Cr) are those most common in oil and gas, some of which are CA6NM (UNS J91150), AISI 410(UNS S41000), and AISI 420 (UNS S42000). These alloys have excellent corrosion resistance when compared to carbon steels up to about 300°F (150°C) and are used for a variety of wellhead, tubular, and downhole components however they have very limited resistance to cracking in H2S (Vallourec Group, 2015). Modified 13% Cr (M13Cr) steels came from the need for increased corrosion resistance at higher temperatures, increased H2S cracking resistance, and increased yield strength above 85 ksi (586 Mpa) primarily for tubular goods and other downhole equipment. These features were developed by taking a conventional 13Cr steel and adding nickel (Ni), molybdenum (Mo), copper (Cu), and other alloying elements. M13Cr provides better corrosion resistance than 13Cr up to about 350°F (177°C), yield strengths up to 110 ksi (758 Mpa), and also improved H2S cracking resistance(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013)."

Jan 1, 2017

By John F. Dougherty

Recently, there has been much debate as to the relevance of reporting financial results using the conventional accounting systems, which is based on historical costs, during a period of rapid inflation. In the following paragraphs , the symptoms, if not the causes, of inflation, its detrimental effect on the financial soundness of business in general and the financial reporting changes being advocated to overcome perceived weaknesses in the present financial reporting system in accounting for the effects of inflation will be reviewed. Finally, a course of action as a sound approach to the financial reporting problem will be recommended.

Jan 1, 1978

By A. J. Paul Laprairie

The process for which it is to be used is too often the only consideration in the design of a vessel. A de-sign allowing for practical manufacture and erection, as well as for proper maintenance, can often give over-all economies. Most platework in-stalled today is of welded construction. Therefore, metallurgical control is important in its manufacture. Also, because many concentrating and re-fining processes tend to be corrosive, the subject of protective coatings as a part of the manufacturing process is extremely important. The plant de-signer should know how to evaluate and specify controls for the metallurgy and for the coatings. Mining operations are becoming more sophisticated in the field of mechanical engineering. More and more emphasis is being given to preventive maintenance. The first step in any maintenance program, however, is good inspection service. This paper will suggest methods for the inspection of platework, and outline methods for repair and replacement.

Jan 1, 1963

By J. Robison, H. Pieterse, C. C. Smith, M. Luque, S. Chipman

Phase change during pressure let down releases significant amounts of energy that must be controlled to avoid undo wear and tear on equipment. Hydrometallurgical slurries require flow control equipment (valves and tanks) made of expensive materials to withstand the abrasive, and often corrosive nature of the slurry. Presented is a model of the nozzle of a let-down choke which is designed to control the flow pattern that exits the choke (valve) as it enters the receiving tank. This model can be used to design chokes which allow for the dissipation of the energy released during pressure let down by spreading the stream over a significant portion of the slurry pool in the receiving tank to minimize wear on equipment near the nozzle exit and the bottom of the slurry tank. An example uses the model to choose the nozzle expansion (area) ratio to select the outlet slurry velocity and slurry expansion angle.

Jan 1, 2004

By W. G. Scott

IT IS APPROPRIATE that your Institute should have chosen, for its 1956 Annual General Meeting, the Capital City of a province which is making such rapid advances in mining. The railway industry is proud to be playing an active role in this development, expenditures on equipment and railway construction in the Province of Quebec alone in recent years being in ?excess of a quarter of a billion dollars. In looking up some background material for this address I ran across a definition of a mine by Mark Twain, the great American humorist, which I thought might amuse you. He said that a mine was "a hole in the ground owned by a liar". I am sure that if he were alive to witness the enormous value attached to Canada's mineral resources today he would quickly change his definition. Canada's postwar record of mining development has been staggering in its variety and enormity. Historically, only the ?construction of our transcontinental rail ways outranks the largest of three of these development projects - the aluminum undertaking at Kitimat; the Quebec-Labrador iron ore deposits ; and the petroleum and natural gas developments in Wes tern Canada.

Jan 1, 1956

By S P. Giambra

The 50,000-ton-per-day Concentrator and Crushing Plant, complete with its related water supply, tailings disposal and concentrate handling systems, was started up in a five-month period, with the entire plant obtaining its design capacity six months after the first mill became operational. Individual mill lines, with their spiral circuits, achieved design capacities within a week after the first treatment of ore through each mill. Construction and start-up proceeded together in many areas of the plant, and considerable organization and cooperation between the Owner, the Engineer and the Contractors permitted a smooth transition from construction to operation. PLANT DESCRIPTION THE Carol Lake Plant of the Iron Ore Company of Canada l1as been well described in various technical magazines. The purpose of this paper is to present a brief outline of the start-up of the con-centration complex. This start-up was accomplished in a period of five months, with the plant producing one million tons of concentrate and achieving its design-rated tonnage less than six months after the first ore was treated.

Jan 1, 1963

By B. I. Boyko

As part of the Ministry of the Environment's Resource Recovery Program, the Province of Ontario has constructed a $13 million "Experimental Plant for Resource Recovery" in Metropolitan Toronto. The technology and unit operations involved in the processing of municipal solid wastes at a rate of 40 tons per hour at this facility are reviewed. Shredding, air separation and classification, screening, magnetic separation and composting are some of the operations featured at this plant. Recoverable commodities expected include paper, ferrous metals, an air-classified light fraction (shredded paper and film plastic), glass and compost. Existing and potential markets for these materials are discussed.

Jan 1, 1978