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By Thomas C. Mowatt

Preliminary Bureau of Mines studies of mafic igneous rocks collected from the Rabbit Creek area, northwestern Alaska, indicated concentrations of platinum (412 to 1,406 ppb) and palladium (343 to 892 ppb) in five of eight samples analyzed. The samples represent boulders and cobbles of mafic/ultramafic rocks from this locality. They are not from outcrop. Petrologically, (on the hand specimen scale) the samples are crudely to well-layered and are troctolitic ± gabbroie in character, with primary igneous mafic minerals strongly altered. Small patches of interstitial sulfide minerals, including chalcopyrite, bornite, pyrrhotite, pyrite, and covellite are associated with these altered zones and elsewhere through the specimens. Copper values ranged from 0.1 to 0.3 pct in samples analyzed semiquantitatively; nickel, cobalt, and chromium contents are low. Chemical, mine alogic, and petrographic relationships suggest that the rocks of similar character outcropping in northwestern Alaska could also be considered as prospective for- concentrations or platinum, palladium, and copper.

Jan 1, 2011

By Chao Du, Xiaohui Ning, Hongmin Zhu, Qiuyu Wang, Shuqiang Jiao

"TiCxOl-x solid solutions were synthesized by sintering a mixture of titanium carbide and titanium monoxide at 1600 °C. The corresponding structures and morphologies of the TiCxOl-x solid solutions were characterized by XRD and SEM. A series of tests has been performed on the electrochemical dissolution behavior of TiCxOl-x solid solutions in NaCl-KCl molten salt. The influences of synthesis time and electrokinetic parameters on the anodic dissolution behavior were also investigated. The results showed that TiCxOl-x solid solutions can dissolve as Tin+ into alkali chloride melt. Titanium ion species dissolved from TiCxOl-x solid solutions changes between Ti2+ and Ti3+ depending on the applied potential. The tail gas on the anode was monitored by a mass spectrometer. It was found the synthesis time significantly affects the components of the anodic gas.IntroductionTitanium and titanium alloys have been desired greatly because of their many uses. The critical factor that restricts the range of uses for Ti is its high cost of extraction. The primary titanium metal, sponge titanium, is still produced industrially worldwide by a process invented by Dr. Kroll in the 1940s[1] •Since the early 1970s, the research focus of the titanium industry has been directed towards developing a continuous process to produce high purity titanium at low cost. [2-10] Of the many alternative methods that have previously been investigated, the electrolytic process has been considered a promising method for titanium metallurgy [4-10]. Recently, several electrolysis and related methods such as the PFC-Cambridge process[11-15], calciothermic reduction[16-18], USTB [19,20] and MER[21] process were extensively investigated.The USTB process is a new approach where the pure titanium can be directly obtained by the electrolysis with an anode of titanium oxycarbide in molten salts[19, 20]. The titanium oxycarbide was produced by carbothermal reduction of titanium dioxide under vacuum at a temperature"

Jan 1, 2011

The schlieren technique describes an optical analysis method designed to enhance light distortions caused by air movement. The ability to visualize air flow has significant implications for analyzing underground mine ventilation systems, including the enhancement of surveys and models. Currently, traditional schlieren methods are impractical underground. Background oriented schlieren (BOS) provides a solution to this problem. BOS requires two primary components, a professional quality digital camera and a schlieren background. A schlieren background is composed of a varying contrast repetitive pattern, such as black and white stripes. This background allows the camera?s sensor to capture minor light diffractions, such as those caused by air flow. Although BOS shows great potential for ventilation analysis, sensitivity is an issue. This paper seeks to validate the BOS technique for imaging flow through a regulator by comparing BOS images with traditional schlieren images. This paper also outlines initial experimental efforts used for the validation.

Jan 1, 2011

By M. Barati

A collaborative research between University of Toronto and Hatch was conducted to understand and optimize the process conditions pertaining to a novel steelmaking technology. In this technology, known as CRISP, direct reduced iron is continuously melted and refined in a stationary electric arc furnace. The major challenge against continuous operation of the electric furnace was identified to be minimizing the corrosion of the refractory in order to achieve uninterrupted operation for a minimum of one year. Theoretical analysis and bench scale experiments together with two pilot runs resulted in defining an operating window for slag chemistry that would minimize chemical attack to the refractory while satisfying the oxidizing conditions required for sufficient decarburization. An analysis of the process in terms of energy consumption and emission of greenhouse gases revealed that it is superior to the current batch DRI-based steelmaking technologies.

Jan 1, 2011

By Steven R. Lowe

Construction of a pump station, consisting of an inlet chamber, wet well and pump chamber, required excavation to a depth of 9.7 m (32 ft) below ground surface and more than 7.6 m (25 ft) below the ground water table in a rural, but rapidly developing part of southern New Jersey. Private houses are located [ ] within a few hundred feet of the pump station that use shallow wells for water supply. The pump station design anticipated support of the entire pump station on shallow foundations bearing directly on the underlying natural soils. However, during construction, uncontrolled ground water flow caused ground loss and damage to the bearing qualities of foundation soils. As a result, remedial repairs were required including support of the pump station on drilled pile foundations and releveling of the pump chamber that had settled. This case study is an example of where a poor understanding of the significance of upward flowing ground water had a major impact on the cost of construction. Anticipated subsurface conditions The pump station layout is shown in Fig. 1 with the locations of two borings made prior to construction superimposed. One of the borings was located within the footprint of the deep wet well excavation. Generally, this is not advisable where a deep excavation is required below the ground water table. This is because there is a history of projects where ground water seepage, or pressure, has broken out into an excavation through an ungrouted borehole and compromised the integrity of foundation soils. Logs of the borings did not indicate that the borings [ ] were grouted upon completion.

Jan 1, 2011

By I. A. Kunasz

This paper is not intended to review and re-state general information on lithium, but rather to analyze the paradigm that has caused such a rapid rise in lithium production and the development of new lithium producing centers. Details on pegmatites, brines, concentrate and chemicals are amply covered in a number of publications ? SME?s Industrial Minerals and Rocks, Industrial Minerals, Roskill and a host of other publications. There is no question that the latest interest in lithium has been driven by the potential development of the electric car. This stimulus prompts one to recall two symposia: 1. ?Lithium Resources and Requirements be the year 2000?, organized in 1976 by the U.S.G.S. in Denver (1) and the sequel 2. ?Lithium ? Needs and Resources? at Corning, N.Y. (2).

Jan 1, 2011

By D. Kwietnewski

With all of the unknowns associated with tunnel construction, how does a contractor choose a roadheader? This paper presents a review of several models of roadheaders being used in today?s tunnel projects. The features of different models of roadheaders are presented and compared. Roadheader size and cutter power generally determine which roadheader is best for a particular job. We will also present a model for matching features of the roadheader to the anticipated ground conditions such that the most efficient machine is selected for the project.

Jan 1, 2011

By V. I. Lakshmanan, R. Roy

"TiO2 is used in paints, plastics, rubber, paper, inks, textiles and other miscellaneous applications. The demand for the pigment grade Ti02 is growing at 3.0%/year on average and this invites the development of innovative and cost effective processes. The current processes are not designed to recycle the reagents and thereby discharge the effluents into the environment, causing an environmental concern.During this study, synthesis of TiO2 from an ilmenite concentrate was investigated using an innovative atmospheric mixed-chloride leach process. The solution purification was carried out using solvent extraction in two stages. In the first stage iron removal was carried out and in the second stage titanium was extracted. The strip solution obtained from the second stage solvent extraction contained the purified titanium and from this stream pigment grade Ti02 was recovered. The barren solution was used for reagent recovery and the regenerated leach liquor was recycled."

Jan 1, 2011

By M. Nzotta, L. Teng, S. Seetharaman, A. Chychko

The objective of the present work is to optimize the EAF practice towards Mo alloying with maximum retention of the alloying element in molten steel. During Mo additions, there were significant losses to the dust (ca 7 %) and to the slag phase (ca 2 %), which had serious economic and environmental impacts. The present work was aimed at designing a suitable Mo precursor, an alternative to ferromolybdenum, as the Mo source and a process sequence for optimal retention of Mo in the steel. The design of the Mo source should be in such a way that low cost raw materials such as MoO3 concentrate have to be used, stable during the addition so that the vapour phase losses as MoO3 are kept minimum and the dissolution of the precursor in molten steel is easy without loss to the slag phase. After thermodynamic considerations, three precursor materials were chosen, viz. CaMoO4, MgMoO4 and Fe2MoO4. Synthetic mixtures of the component oxides in each case as well as pure MoO3 were investigated by TGA and high temperature XRD in order to find out the temperature range in which the compounds were formed. Experiments were also conducted separately where the evolved gases were analyzed. All the three precursors were formed easily and the loss of MoO3 to the vapour phase was found to be extremely low. Addition of the oxide mixtures to steel melts were conducted in three different scales, viz. 16 g, 500 g and 3 tons (induction furnacle). Initial experiments showed that MgMoO4 was not suitable since the Mo yield in the steel melt was not very high. Fe2MoO4 was found to perform best, the Mo yield reaching 98 %. Further trials were conducted in the 65 ton Electric Arc Furnace (EAF) at Uddeholms AB in Hagfors. Mixtures of mill scale, MoO3 and carbon in suitable proportions were added in a pre-determined addition sequence. It was found that, in the actual practice, the Mo yield reached 99 %, equaling in performance the addition of ferromolybdenum. The process offers an effective use of cheaper raw materials and very high Mo yield avoiding a pre-treatment step like the production of ferromolybdenum. This is both cost effective and environmentally advantageous. The process has been patented and is being currently implemented at Uddeholms AB, Hagfors, Sweden.

Jan 1, 2011

By G. Hamel

The LCL&L process (Low Caustic Leaching & Liming) is a patented hydrometallurgical route developed by Rio Tinto Alcan (RTA) to economically process spent pot lining (SPL) generated by aluminum cells. The three resulting end-products (carbonaceous, fluorinated and caustic liquor) are inert and have valorization possibilities. An industrial size pilot plant located in Saguenay (Quebec) was inaugurated in mid-2008 to demonstrate and optimize the technology. This paper describes characteristics of the LCL&L process and the experience acquired by RTA since the plant's start-up, including ramp-up capacity and technology challenges that were overcome. Possible end-products valorization methods are also presented. The carbonaceous end-product can be separated into carbon and brick rich fractions and used as either alternative fuel, reducing agents, or as raw material for third party processes. The development of a conversion process for the fluorinated end-product would allow its reuse as a substitute to fluorspar mineral for aluminum fluoride production. Finally concentrated caustic liquor is already valorized at the nearby RTA Vaudreuil alumina refinery.

Jan 1, 2011

By N. Ward

The Gualcamayo Mine is located in the Andes Mountains north of San Juan, Argentina (Figure 1). A property of Yamana Gold Inc, it declared commercial production in July 2009 and has a total mineral reserve and resource base of approximately 88,000 kg of gold. Crushing operations for the open-pit mine are located in a 13,500 m3 underground cavern with a ceiling height of 22 m. More than 3,600 m of tunnels are used to access the cavern and convey the ore. The Project as described in this paper relates to the design and construction of the Main Cavern, Conveyor System Exit Tunnel, the Mechanical System Access Tunnels, and two 4.20 m diameter shafts (Ore Pass #1 and Ore Pass #2) as shown in Figure 2. [ ] Preliminary engineering for the Project was performed by Hatch Chile. Rizzo Associates Argentina, S.A., a division of Paul C. Rizzo Associates, Inc (Rizzo) was contracted to provide geomechanical and geotechnical support for the construction of the access tunnel system and geomechanical design and construction supervision for the cavern and shafts.

Jan 1, 2011

By David Preece

The Thirlmere aqueduct was constructed over 110 years ago to provide water from the Lake District (in the north-west of England) to the city of Manchester some 60 miles (100 km) away. The aqueduct remains, to this day, a key piece of infrastructure in the distribution of raw water in the north-west of England. A short section of the aqueduct was identified as being in poor condition during routine inspections by the owner. Subsequent investigations attributed the conduit damage to the movement of unstable ground over the conduit. Bachy Soletanche Ltd was subsequently appointed to carry out the design and construction of the slope stabilisation works and to undertake repairs inside the damaged conduit. The works were undertaken on an existing slope which, in places stands at a gradient of up to 40º to the horizontal. Strict limitations on plant and equipment were imposed by the client (United Utilities) to ensure that slope and conduit loading and associated vibrations were kept to an absolute minimum during construction. An intensive instrumentation system was installed to monitor surface movements, ground movements at depth, conduit movement and strains across existing planes of weaknesses within the conduit. The solution comprised the installation of spaced piles up-slope and down-slope of the conduit. Restrictions were imposed on the minimum stand-off distance between the outside face of the conduit and the piling works so targeted permeation grouting was undertaken to improve the ?connection? between the conduit and the down-slope piles. The presence of existing sub conduit groundwater flows was suspected and the permeation grouting was focused in areas to minimize disruption to the groundwater regime. The paper presents the basis of the design and highlights the combined construction and instrumentation methods adopted to minimise damage to this valuable asset.

Jan 1, 2011

By F. Ntengwe

The Konkola Mine, a subsidiary of the Konkola Copper Mines Plc (KCM) which is owned by the Vedanta group of companies of India and Zambia Consolidated Copper Mines Holding limited, is located at Chililabombwe in the northern extension of Zambia's Copperbelt province. In its operations, the mine has been experiencing problems in ascertaining the optimum degree of fineness and the operating density of the hydrocyclone overflow in order to achieve high flotation performance. It was believed that recovery of sulphide copper minerals from Konkola ore is a function of the fineness of the grind so that it might be an economical justification to modify the grinding plant in order to run at lower cyclone overflow densities than the case is now. In an effort to improve these operations, it was decided to carry out test work on various hydrocyclones of sizes 0.381 m, 0.4575 m and on 0.508 m. The later was found to give satisfactory results and was installed on the plant. Despite giving satisfactory results there was need to investigate further to establish the working densities and size. Increasing the density of cyclone overflow decreases the per cent passing 75 pm at least in the range 1080-1 150 g/l. Furthermore, hydrocyclones give better separation at low densities of feed and hence the efficiency is high at low feed densities. Circulating load increases with an increase in feed densities and an decrease in the grind. The flotation performance in both sulphide and oxide copper minerals rougher stages is enhanced with an increase in the degree of fineness of the grind, with an optimum being obtained at a density of 1 150 g/l and 81.4% passing 75 µm. Keywords Konkola mine, hydrocylone, optimum degree of fineness, sulphide copper minerals.

Jan 1, 2011

By Shenghui Guo, Ying Lei, Wei Li, Jinhui Peng, Libo Zhang, Yu Li

"In this work, the Panzhihua low grade ilmenite and graphite were milled for 1, 2, 4 and 8 h firstly, then the temperature rising behavior of milled sample in microwave field were studied. The average heating rate of samples milled for 1, 2, 4, 8 h were 1.86, 4.08, 2.82, and 2.32 K/s; Before optimize the microwave reduction process, several experiments were conducted in order to confirm the parameters range. After milled for 4 or 8 h and reduced above 930 oC, the Fe metallization are higher than 90%; Then the optimization was investigated by using response surface methodology (RSM), the significance of predict model and each terms were analyzed, and the optimization parameters were given as: milling time is 4 h; reduction temperature is 1001 or 1070oC; the holding time is 37.5 or 26.9 min. Under these conditions, the Fe metallization given by predict model is 91 or 92 %.IntroductionThere is about 9.66 billion tons of Vanadic Titan-magnetite deposits in Panzhihua, China. In this reserve, there is about 8.73×108 t of TiO2, accounting for 90.54% of the Chinese reserves, and 35.17% of the international reserves and ranking first in the world. [1] Titanium mineral deposits are classified into Rock type and Placer type. Rock type is the igneous mineral, which have high content of FeO (Relative to Fe2O3) and gangue. The Panzhihua ilmenite is a typical rock type ilmenite ore. The higher contents of MgO, CaO, SiO2 and the complex mineralogy are making its direct reduction progressively more difficult."

Jan 1, 2011

By Trevor R. Ellis

Minerals appraisers/valuers often find great difficulty in attempting to employ the sales comparison approach to the market value appraisal of development and operating stage mineral properties. An important factor generally overlooked is a comparison of net operating income (NOI) margins on a per-unit-of-production basis between mineral properties, whether these be demonstrated or forecast margins. NOI margins can vary greatly between mines or quarries that are producing similar products. Ultimately, the expected NOI margin determines what a buyer is willing to pay for an income-producing property. Here, common criticisms of the sales comparison approach by mineral appraisers are introduced. These are counterbalanced by raising some issues in the way the inputs for the income approach are usually derived by minerals appraisers and by review of some conspicuous examples of the much-too-common misuse or abuse of the income approach in market value mineral appraisals. Example transaction analyses and sales comparison analyses are used to demonstrate the author?s methodology for adjusting units of resource in his transaction adjustment tables. The examples are used as the basis for a discussion of ways to employ adjustments for operating economics and many other factors, while warning against the potential for double counting. The conclusions include a recommendation that minerals appraisers attempt to apply at least two of the three valuation approaches when appraising the market or fair value of development and operating stage mineral properties, the two being the sales comparison and income approaches.

Jan 1, 2011

By Jared Ball, Darren Snashall, Paul Telford, Pengfu Tan, Ben Hogg

"The foamed converter charges were up to 3 8 per month in Xstrata Copper Smelter at Mount Isa. The issue of high converter foamover frequency had remained unsolved for many decades in Mount Isa. A thermodynamic model of copper P-S converter and a viscosity model of converter slag have been developed to simulate the slag blow and copper blow, in order to understand the mechanism of converter foamover. The model predicts the chemistry and viscosity of slag during slag blow and copper blow. The effects of oxygen potential, charge of dirty reverts, slag carryover, under-blowing, over-blowing, and temperature on the foamover and viscosity of slag in copper blow have been discussed. A theory has been developed to understand the mechanism of converter foamover. The practical solutions have also been developed and implemented in Mount Isa Copper Smelter. Some improvements of the industrial operations have been presented. After a series of improvements, the number of foamed charges per month in the converter operations has been decreased significantly from 35 in Aug 2008 to only one per month in 2009/2010.1. IntroductionThe Copper Smelter in Mount Isa receives the concentrate containing about 25% copper and produces anode copper that contains about 99% copper. There are several stages in the process. The first stage carries out in the ISASMELT™ furnace. The ISASMELT™ process produces a molten copper matte containing about 60% copper. An iron-silica slag and a sulfur dioxidebearing off-gas are the by-products of the process. The slag is taken to the slag dams for cooling before it is recycled through the Mount Isa Copper Concentrator.The matte is sent to Peirce-Smith converters. The converters further remove iron and sulphur to produce blister copper which contains about 97% copper. The anode furnaces remove any remaining sulphur and oxygen to produce anode copper that is about 99. 7% pure. This is cast into anodes and sent to the Xstrata Copper Refinery in Townsville for final refining.In the copper pyrometallurgical industrials, slag foaming is an important phenomena which occurs when the gas bubbles have stability and not rupture. Foaming greatly increases the interfacial area between matte, slag and gas and is essential for the operation of high intensity smelting processes. However, foaming or foamover is undesirable in P-S converter since it can damage the equipment and injure the operators. Figure 1 shows that the whole process of a foamover development in a converter."

Jan 1, 2011

By O. Ozdemir

Soda ash, an essential raw material for major industries, such as the glass, chemicals, soap and detergents, pulp and paper, mining and water treatment industries, is traditionally produced by chemical and thermal treatment of trona ore. The treatment processes for trona ore are not only chemically expensive but also energy intensive. Hence, the production of a high-purity trona concentrate at a lower energy and operating cost is of considerable interest to the trona industry. In this study, we describe a possible two-stage process for concentrating trona ore, involving dry magnetic separation followed by flotation, to remove insoluble impurities from the trona ore. The results showed that a trona concentrate of 91.7% purity with a recovery 91.1% can be obtained by two-stage magnetic separation, which could be further improved to 98.1% purity at a recovery of 83.8% by subsequent flotation of the non-magnetic trona product. The purity of trona concentrate is limited by the particle size and impurity content of the trona ore. The operating parameters for magnetic separation and flotation have been identified to obtain an acceptable quality concentrate.

Jan 1, 2011

Thallium is an uncommon heavy metal that may be found in concentrations that exceed regulatory limits in mining influenced water associated with processing cadmium, copper, gold, lead, and zinc ores. This study evaluated cost-effective modifications to lime precipitation treatment to reduce thallium concentrations to below the EPA drinking water MCL of 2 ppb. The oxidative precipitation of Tl+ to Tlß+ by potassium permanganate was explored for thallium removal at low concentrations (1 ppm initial thallium). Laboratory batch tests were performed to evaluate the removal of thallium from synthetic solutions. Three ratios of potassium permanganate to oxidizable metals in solution were used (one-half, one and two times stoichiometry). Thallium was removed to less than 1 ppb for all stoichiometric ratios evaluated within 10 minutes of reaction. The efficacy of oxidative precipitation for thallium removal is presented.

Jan 1, 2011

By Jeffrey Meissner, Charles Dowding

Cracking is one of the concerns cited by owners of structures adjacent to construction or mine blasting. During the past decade a large number of measurements have documented the low level of crack response produced by typical, ground motions compared to those produced by climatological effects. These data support the observation that there is a level below which ground motions do not cause even cosmetic cracking. As with all new findings, these crack response measurements need to be thoroughly investigated for all possible alternative interpretations. Among these alternatives is that uncracked locations are more affected than cracked locations. This paper presents measurements to shed light on the influence of existing cracks and the response of uncracked, but weak locations. Blast and weather induced responses of cracked and uncracked areas of gypsum wall board are compared in two structures: one near a surface coal mine in Indiana, the other near a limestone quarry in Florida. The ground motions that excited one of the structures were unusual in that the dominant excitation frequencies of 5 Hz were near the structure’s natural frequency and amplitudes exceeded 0.7 ips (18mm/s).

Jan 1, 2011

By Timothy C. Siegel

In response to a solicitation for ground improvement for the construction of a new hospital in Owensboro, Kentucky, the team of Berkel & Company Contractors and Dan Brown and Associates PC designed and installed lightly reinforced cast-in-place piles (known commercially as Cast-in place Ground improvement Elements or CGEs) as part of a composite ground system. The concept of the design is that the structure load is shared between the piles and the soil subgrade. The load sharing is controlled (to some degree) by the placement of a cushion between the pile head and the bottom of the overlying spread foundation. In an effort to confirm the design principles and to better understand the behavior of composite ground, the design-build team performed plate load tests on ground with a single CGE and with a group of CGEs. The small plate test (on ground with a single CGE) characterized the stiffness of the cushion. The large plate tests showed that the cushion will distribute the applied load to the CGEs and to the soil subgrade between the CGEs. On the basis of the plate tests, it was concluded that the plate stiffness can influence the test results. The use of a concrete layer was effective at supplementing the plate stiffness. The cushion was shown to be an important component of a composite ground system by allowing mobilization of the soil subgrade resistance and avoiding a stress concentration at the tops of the CGEs that would otherwise be present if the spread foundation and piles were rigidly connected. Because the composite ground system engages the resistance of the soil subgrade, the structural demand is reduced and consequently there is a potential for savings when compared to a conventional pile foundation. Several foundations for the new Owensboro hospital are being monitored for vertical movement during construction of the superstructure that will extend through 2011. At the time of this paper (mid 2011) the settlement of the foundations due to only part of the structural load (primarily the structural steel) has been negligible.

Jan 1, 2011